CN1741965A - Processes for manufacturing water filter materials and water filters - Google Patents

Abstract

A process for producing a water filter material is provided. The process includes the steps of providing a plurality of mesoporous activated carbon particles, and treating said plurality of mesoporous activated carbon particles to produce a plurality of mesoporous activated carbon particles having a bulk oxygen percentage by weight of less than about 2.3%.

Description

The manufacture method of water filtration material and water filter

Technical field

The present invention relates to the field of water filtration material and water filter manufacture method.More particularly, the present invention relates to comprise the field of the water filter manufacture method of mesoporosity activated carbon granule.

Background technology

May include many different types of pollutents in the water, comprising as particle, harmful chemical and as bacterium, parasite, protozoon and viral micro-organisms organism.Under many circumstances, must be with after these contaminant removal, water can use.For example, in many medical application fields and manufacturing processed, all need to use highly purified water at some electronic component.The embodiment that another one is more general is that water must be removed any noxious pollutant before drinkable (promptly suitable for drinking).Although still there is risk in existing modern method for purifying water for the general population, particularly the people for baby and compromised immune has sizable risk.

In the U.S. and other developed country, typically comprise following one or more impurity in the municipal treated water: suspended solids, bacterium, parasite, virus, organic substance, heavy metal and chlorine.Sometimes, the fault of water treatment system and other problem can cause bacterium and virus in the water not to be removed fully.In other country,, contact with polluted water to have caused fatal consequence because some regional density of population constantly increase, the water source constantly reduces and do not have water treating equipment.Because drinking water source movement general and humans and animals is adjacent, so microbial contamination is unhealthful subject matter.Grow the microorganism produced pollution in the water and estimate can to cause about six million people's death every year, half is wherein arranged is that youngster below 5 years old is heavy.

1987, Environmental Protection Agency (EPA) proposed " guidance standard of test microbes water purifier and protocol ".This protocol has been formulated minimum requirements to the performance of drinking water treatment system, and the effect of these water treatment systems is to reduce some unhealthful specific pollutant in public water source and the individual water source.Effusive disease caused by infectious water poison clearance rate was 99.99% (or being equivalent to 4log) in the requirement supply water source, and bacteria clearance is can meet the demands 99.9999% (or being equivalent to 6log).According to the EPA protocol, virus its concentration in the water that flows into should be 1 * 10 ⁷Every liter, bacterium its concentration in the water that flows into should be 1 * 10 ⁸Every liter.Because intestinal bacteria (E.coli, bacterium) ubiquity in water supply, and it will produce relevant risk, the bacterium in therefore this microorganism being studied as great majority after being drunk.Similarly, MS-2 bacteriophage (or abbreviating the MS-2 phage as) is a kind of representative microorganism that typically is used for virus sweep, because its size and shape (promptly about 26nm, and be icosahedron) similar to a lot of viruses.Therefore, can represent that to the removing ability of MS-2 bacteriophage it removes other viral abilities with water filter.

Because these requirements and, therefore still need a kind ofly can remove bacterium and/or the filtering material of virus and the manufacture method of strainer in the fluid to improving the common concern of drinking water quality.

Summary of the invention

The invention provides the manufacture method of water filtration material.This method may further comprise the steps: a plurality of mesoporositys activated carbon granule is provided, handles described a plurality of mesoporositys activated carbon granule to prepare a plurality of body oxygen weight percents less than about 5% mesoporosity activated carbon granule.

The accompanying drawing summary

Though this specification sheets by particularly pointing out and clearly claimed claim of the present invention is drawn a conclusion, should believe by following explanation and can understand the present invention better in conjunction with the accompanying drawings, wherein:

Fig. 1 a is the BET nitrogen adsorption isothermal line of acid activated carbon granule CA-10 in mesoporosity and mesoporosity alkaline reduction oxygen activity charcoal particle TA4-CA-10;

Fig. 1 b is the BET nitrogen adsorption isothermal line of mesoporosity alkalescence activated carbon granule RGC and mesoporosity alkaline reduction oxygen activity charcoal THe4-RGC;

Fig. 2 a is that the particulate mesopore volume distributes among Fig. 1 a.

Fig. 2 b is that the particulate mesopore volume distributes among Fig. 1 b.

Fig. 3 a is a particulate point of zero electric charge chart among Fig. 1 a.

Fig. 3 b is a particulate point of zero electric charge chart among Fig. 1 b.

Fig. 4 is the cross-sectional side view according to the axial-flow type strainer of the present invention's manufacturing.

Fig. 5 a illustrates the function of the intestinal bacteria bath concentration of the activated carbon granule among Fig. 1 a for the time.

Fig. 5 b illustrates the function of the intestinal bacteria bath concentration of the activated carbon granule among Fig. 1 b for the time.

Fig. 6 a illustrates the function of the MS-2 bath concentration of the activated carbon granule among Fig. 1 a for the time.

Fig. 6 b illustrates the function of the MS-2 bath concentration of the activated carbon granule among Fig. 1 b for the time.

Fig. 7 a illustrates intestinal bacteria and flows concentration about the function by the cumulative volume of water behind 2 strainers; One of them strainer comprises RGC mesoporosity alkalescence gac, and another then comprises coconut microporosity activated carbon granule.

Fig. 7 b illustrates MS-2 and flows concentration for the function by the cumulative volume of water behind 2 strainers; One of them strainer comprises RGC mesoporosity alkalescence gac, and another then comprises coconut microporosity activated carbon granule.

Detailed description of the preferred embodiments

The relevant portion of the document of all references is incorporated herein by reference. Quoting all of any document May not be interpreted as its approval as prior art of the present invention.

I. definition

Term used herein " strainer " and " filtration " are meant respectively and remove microorganism (and/or removing other pollutent) by main absorption and/or size exclusion mode to relevant structure or the mechanism of less degree.

Phrase used herein " filtering material " means the aggregate of filtering particle.This aggregate that forms the filtering particle of filtering material can be similar or the foreign peoples.Can be evenly or non-uniform Distribution (as the layer of different filtering particles compositions) at filtering material inner filtration particle.The filtering particle that forms filtering material also need not to be of similar shape or size, and can loose or interconnective form provide.For example, filtering material can comprise and activated carbon fiber bonded mesoporosity alkalescence activated carbon granule, these filtering particles or can provide by loose correlation form, by polymeric adhesive or otherwise partly or entirely adhesive form form one-piece construction.

Phrase used herein " filtering particle " means individual member or the silver that is used to form to the small part filtering material.For example, a fiber, a particulate, a globule etc. all are considered to a filtering particle in the present invention.In addition, the big I of filtering particle changes, from impalpable filtering particle (as very thin powder) to palpable filtering particle.

Phrase used herein " filtering material pore volume " is meant that size is greater than the cumulative volume of the intergranular pore of 0.1 μ m in the filtering material.

Phrase used herein " filtering material cumulative volume " is meant the intergranular pore volume and is filtered the volume sum that particle occupies.

Term used herein " microorganism ", " microorganism organism " and " germ " trans-substitution mutually.These terms refer to have bacterium, the various microorganisms of virus, parasite, protozoon and germ feature.

Phrase strainer particulate used herein " bacterium is removed index " (BRI) is defined as:

BRI=100 * [1-intestinal bacteria equilibrium state bath concentration/intestinal bacteria contrast concentration)],

Wherein " intestinal bacteria equilibrium state bath concentration " is meant bacterium concentration under the equilibrium state in bath, comprises a large amount of filtering particles in the bath, and its total outer surface area is 1400cm ², and the Sauter mean diameter is less than 55 μ m, as hereinafter described in more detail.Test at two time points of being separated by 2 hours,, then can reach balanced when e. coli concentration changes when remaining within half order of magnitude.Phrase " intestinal bacteria contrast concentration " is meant colibacillary concentration in the contrast bath, and it equals about 3.7 * 10 ⁹CFU/L.The Sauter mean diameter refers to the particulate diameter that its area capacity ratio is identical with the whole particle distribution.Notice that term " CFU/L " is meant " colony-forming unit in every liter ", it is the exemplary term that is used for the intestinal bacteria counting.The BRI index is to record under the situation of not using the chemical agent with sterilization effect.A kind of suitable method of expressing the filtering particle degerming ability is that (BLRI), it is defined as in employing " the bacterium logarithm is removed index ":

BLRI＝-log[1-(BRI/100)]。This BLRI index is " log " unit (" log " represents logarithm here).For example, the BRI index of filtering particle equals at 99.99% o'clock, promptly is equivalent to the BLRI index and equals 4log.Two kinds of exponential test procedures of BRI and BLRI have hereinafter been provided.

" the virus sweep index " of phrase filtering particle used herein (VRI) is defined as:

VRI=100 * [1-(MS-2 phage equilibrium state bath concentration/MS-2 phage contrast concentration)], wherein " MS-2 phage equilibrium state bath concentration " is meant phage concentration under the equilibrium state in bath, comprise a large amount of filtering particles in the bath, its total outer surface area is 1400cm ², and the Sauter mean diameter is less than 55 μ m, as hereinafter described in more detail.Test at two time points of being separated by 2 hours,, then can reach balanced when MS-2 concentration remains unchanged when being within half order of magnitude.Phrase " MS-2 phage contrast concentration " is meant the concentration of MS-2 phage in the contrast bath, and it equals about 6.7 * 10 ⁷PFU/L.Note, term " PFU/L " expression " every liter of pnagus medius forms unit ", it is the exemplary term that is used for the MS-2 counting.This VRI index is to record under the situation of not using the chemical agent with sterilization effect.A kind of suitable method of expressing the filtering particle degerming ability is that (VLRI), it is defined as in employing " viral logarithm removing index ":

VLRI＝-log[1-(VRI/100)]。This VLRI index is " log " unit (" log " represents logarithm here).For example, the VRI of filtering particle equals 99.9%, and then its VLRI equals 3log.Hereinafter provided the test procedure of VRI and VLRI value.

Phrase used herein " strainer bacterium logarithm is removed (F-BLR) " is meant the bacterium removing ability that flows through initial 2,000 filtering material pore volume after filters.F-BLR defines and is calculated as follows:

The colibacillary outflow concentration of F-BLR=-log[()/(colibacillary inflow concentration)], wherein in whole test, " colibacillary inflow concentration " is continued to be set at about 1 * 10 ⁸CFU/L, and measurement " colibacillary outflow concentration " after about 2,000 filtering material pore volumes flow through strainer.This F-BLR is " log " unit (" log " represents logarithm here).If note to flow out the limit of detection that concentration is lower than assay technique, think that then this outflow concentration that is used to calculate F-BLR is limit of detection.Equally, notice that F-BLR records under the situation of not using the chemical agent with sterilization effect.

After phrase used herein " strainer virus logarithm is removed (F-VLR) " is meant and flows through initial 2,000 filtering material pore volumes, the virus sweep ability of strainer.

F-VLR defines and is calculated as follows:

The outflow concentration of F-VLR=-log[(MS-2)/(the inflow concentration of MS-2)],

Wherein in whole test, " the inflow concentration of MS-2 " is continued to be set at about 1 * 10 ⁷PFU/L, and measurement " the outflow concentration of MS-2 " after about 2,000 filtering material pore volumes flow through strainer.This F-VLR is " log " unit (" log " represents logarithm here).If note to flow out the limit of detection that concentration is lower than assay technique, think that then this outflow concentration that is used to calculate F-VLR is limit of detection.Equally, notice that F-VLR records under the situation of not using the chemical agent with sterilization effect.

Phrase used herein " total outer surface area " means total geometric outer surface of one or more filtering particles and amasss, as hereinafter described in more detail.

Phrase used herein " than outer surface area " means total outer surface area of per unit mass filtering particle, as hereinafter described in more detail.

Term used herein " micropore " means width or diameter less than the 2nm intragranular hole of (perhaps being equivalent to 20 ).

Term used herein " mesopore " means width or diameter between the intragranular hole that (perhaps is equivalent between 20 and 500 ) between 2nm and the 50nm.

Term used herein " macropore " means width or diameter greater than the 50nm intragranular hole of (perhaps being equivalent to 500 ).

Phrase used herein " total pore volume " and derivative thereof mean all intragranular holes, the i.e. volume of micropore, mesopore and macropore.It is under 0.9814 condition that total pore volume is calculated as at relative pressure, the nitrogen adsorption volume that records by BET method known in the art (ASTM D 4820-99 standard).

Phrase used herein " micro pore volume " and derivative thereof mean the volume of all micropores.It is under 0.15 condition that micro pore volume is calculated as at relative pressure, the nitrogen adsorption volume that records by BET method known in the art (ASTM D 4820-99 standard).

Phrase used herein " mesopore and macropore volume sum " and derivative thereof mean the volume of all mesopores and macropore.Mesopore and macropore volume sum equal the poor of total pore volume and micro pore volume, or are equivalent to, and are calculated as at relative pressure and are respectively 0.9814 and at 0.15 o'clock, the nitrogen adsorption volume that records by BET method known in the art (ASTM D 4820-99 standard) poor.

Phrase used herein " mesopore scope pore size distribution " means the pore size distribution that calculates by Barrett known in the art, Joyner and Halenda (BJH) method.

Term used herein " carbonization " and derivative thereof mean the method that reduces non-carbon atom in the carbonaceous material.

Term used herein " activation " and derivative thereof mean a kind of carbonization material more porous method that becomes that makes.

Term used herein " activated carbon granule " or " activated carbon filtration particle " and their derivative mean the carbonized particles that experiences reactivation process.

Phrase used herein " point of zero electric charge " means a critical pH, is higher than negative electricity on this total surface lotus that is worth carbonized particles then.Measuring the well-known test procedure of point of zero electric charge will set forth hereinafter.

Term used herein " alkalescence " means the point of zero electric charge of filtering particle greater than 7.

Term used herein " acidity " means the point of zero electric charge of filtering particle less than 7.

Phrase used herein " mesoporosity activated carbon filtration particle " means a kind of activated carbon filtration particle, and wherein mesopore and macropore volume sum are greater than 0.12mL/g.

Phrase used herein " microporosity activated carbon filtration particle " means a kind of activated carbon filtration particle, and wherein mesopore and macropore volume sum are less than 0.12mL/g.

Phrase used herein " mesoporosity alkalescence activated carbon filtration particle " means a kind of activated carbon filtration particle, and wherein mesopore and macropore volume sum be greater than 0.12mL/g, and point of zero electric charge is greater than 7.

Phrase used herein " mesoporosity alkaline reduction oxygen activity charcoal filtering particle " means a kind of activated carbon filtration particle, and wherein mesopore and macropore volume sum are greater than 0.12mL/g, and point of zero electric charge is greater than 7, and body oxygen weight percent is 1.5% or littler.

Phrase used herein " mesoporosity acid activated carbon filtration particle " means a kind of activated carbon filtration particle, and wherein mesopore and macropore volume sum be greater than 0.12mL/g, and point of zero electric charge is less than 7.

Phrase used herein " raw material " is meant and comprises any precursor that can produce mesopore and macropore between mesopore and macropore or carbonization and/or pot-life.

Phrase used herein " axial flow " is meant and flows through a plane surface and perpendicular to this surface.

Phrase used herein " runoff " typically be meant flow through substantially cylindrical or the primary circle conical surfaces, and perpendicular to those surfaces.

Phrase used herein " positive zone " is meant that filtering material is exposed to the zone that flows into water at first.For example, in the axial-flow type strainer, positive zone is the transverse cross-sectional area of filtering material at the fluid intake place, and in the radial-flow type strainer, positive zone is the external region of filtering material.

Phrase used herein " filter depth " is meant and flows into water flow to the filtering material outlet from inlet slant range.For example, in the axial-flow type strainer, filter depth is the thickness of filtering material, and in the radial-flow type strainer, filter depth is the external diameter of filtering material and half of difference in internal diameters.

Phrase used herein " average fluid residence time " and/or " average fluid duration of contact " are meant when fluid flows through filtering material, the mean time that it contacts with strainer inner filtration particle, and be calculated as the ratio of filtering material pore volume and rate of flow of fluid.

Phrase used herein " strainer hole rate " and/or " filter bed layer porosity " are meant the ratio of filtering material pore volume and filtering material cumulative volume.

Phrase used herein " inlet " is meant that fluid can enter the parts of strainer or filtering material by it.For example, inlet can be the part-structure of strainer, or is the positive zone of filtering material.

" outlet " used herein is meant that fluid can outflow filter by it or the parts of filtering material.For example, outlet can be the part-structure of strainer, or is the transverse cross-sectional area of fluid outlet filtering material.

II. mesoporosity activated carbon filtration particle

Find that unexpectedly compare with microporosity activated carbon filtration particle, mesoporosity activated carbon filtration particle can adsorb the more microorganism of volume.Find that equally unexpectedly compare with the acid activated carbon filtration particle absorption in mesoporosity, mesoporosity alkalescence activated carbon filtration particle can adsorb the more microorganism of volume.In addition, be surprised to find that also that and do not reduce the mesoporosity alkalescence activated carbon filtration particle absorption of body oxygen weight percent and compare, mesoporosity alkaline reduction oxygen activity charcoal filtering particle can adsorb the more microorganism of volume.

Although be not bound by any theory, but about porosity, the applicant supposes that a large amount of mesopores and/or macropore are that pathogenic agent, their pili and the surface aggregate thing (as protein, lipopolysaccharides, oligose and polysaccharide) of formation pathogenic agent adventitia, capsid and coating provide absorption position (opening of mesopore/macropore or inlet) more easily, and this is because the typical sizes of this type of material is similar to the inlet size of mesopore and macropore.In addition, the mesoporosity rate may be relevant with one or more surface propertieies such as the surfaceness of carbon with open grain.

In addition, be not bound by theory, the applicant supposes that alkaline activated carbon surface is included as the microorganism that attracts volume more and essential functionality type, and more volume is the microorganism that acid relatively activated carbon surface attracts.The ability that is adsorbed to alkaline activated carbon surface strengthens and may attract the microorganism of negative electricity on the lotus typically and the fact of lip-deep functional group thereof owing to alkaline activated carbon surface.The applicant supposes that further when alkaline gac was placed in the water, it can produce sterilizing agent by redox molecule oxygen.Although the reductive final product is an oxyhydroxide, the applicant thinks and has formed reaction oxygen intermediate such as superoxide, hydroperoxide and/or hydroxyl, and their life-span sufficiently longs are to diffuse to the bulk solution from carbon.

In addition, the applicant thinks that carbon becomes and has more alkalescence along with body oxygen weight percent reduces.Low body oxygen weight percent can cause the absorption of improved bacterium/virus, this be because: (1) carboxylic acid still less and therefore still less negative surface to resist bacterium/virus; (2) hydration surface still less make when bacterium/virus attempt to be adsorbed to the surface when going up water easier of its displacement (, bacterium/virus is replaced other kind time-like power loss still less that has occupied surface location).The reason in back (promptly, hydration surface still less) also conforms to following viewpoint, be that ideal surfaced (will discuss hereinafter) should be hydrophobic a little (in other words, ideal surfaced should have enough oxygen to substitute onto on the edge carbon atom so that it is wetted, but can not replace too many and make that it is too hydrophilic).

Filtering particle can be made different shape and size.For example, filtering particle can be made simple shape, for example powder, particulate, fiber and little pearl.Filtering particle can be made sphere, polyhedron, cylindric, and other symmetric, asymmetric and irregular shape.And filtering particle also can form composite form, as net, curtain, aperture plate, non-woven material, be made into material, and bonding block, it can be formed by above-mentioned simple form in yes or no.

The shape and size of filtering particle can be different, and its size of filtering particle of using in any single strainer needn't be unified.In fact, to have different sizes also be desirable to the filtering particle in single strainer.Usually, the size of filtering particle between about 0.1 μ m between about 10mm, preferably between about 0.2 μ m between about 5mm, more preferably between about 0.4 μ m extremely between about 1mm, most preferably between about 1 μ m extremely between about 500 μ m.For spherical and cylindrical pellet (as fiber and globule etc.), above-mentioned size is meant the diameter of filtering particle.For the different substantially filtering particle of shape, above-mentioned size is meant its overall dimension (for example length, width or height).

Filtering particle can be the product of any precursor, and described precursor comprises between mesopore and macropore or carbonization and/or pot-life can produce mesopore and macropore.For example, but not in order to limit, filtering particle can be wooden matrix activated carbon particle, active carbon from coal particle, mud coal matrix activated carbon particle, asphalt based active carbon particle, tar matrix activated carbon particle, beans matrix activated carbon particle, other wood fibre based activated carbon granule, and their mixture.

Gac can show as acidity, neutrality or alkaline.Acid and oxygen containing sense thing or functional group are relevant, for example, but are not in order to limit phenol, carboxyl, lactone, Resorcinol, acid anhydrides and ketone.Up to now, alkaline and following sense thing is relevant, as pyrone, chromene, ether, carbonyl, and the basal plane πDian Zi.Acid or the alkalescence of activated carbon granule is by " point of zero electric charge " method (Newcombe, G. wait the people, Colloids and Surfaces A:Physicochemical andEngineering Aspects, the 78th volume, the the 65th to 71 page (1993)) determine, be incorporated herein this paper for your guidance.This technology further describes in VI joint after this.The point of zero electric charge that filtering particle of the present invention can have between 1 and 14, be preferably greater than about 4, be preferably greater than about 6, be preferably greater than about 7, be preferably greater than about 8, more preferably greater than about 9, most preferably between about 9 and about 12.

The point of zero electric charge of gac is relevant with body oxygen weight percent ratio inverse.The body oxygen weight percent that filtering particle of the present invention can have is less than about 5%, preferably less than about 2.5%, preferably less than about 2.3%, preferably less than about 2%, be more preferably less than about 1.2%, most preferably less than about 1%, and/or greater than about 0.1%, be preferably greater than about 0.2%, more preferably greater than about 0.25%, most preferably greater than about 0.3%.The point of zero electric charge of activated carbon granule is also relevant with the redox potential that comprises particulate water (ORP), and this is because point of zero electric charge is the measuring of ability (like this to alkaline carbon at least) of carbon reduction oxygen.The redox potential that filtering particle of the present invention can have (ORP) is less than about 570mV, preferably less than about 465mV, preferably less than about 400mV, preferably less than about 360mV, preferably less than about 325mV, most preferably between about 290mV and about 175mV.

The resistance of activated carbon filtration particle or filtering material is one of its critical nature, and this is because resistance relates to the ability that they form filter block.For example, can utilize the resistive heating method to form filter block, wherein apply electric current it is heated by 2 ends at filtering material.The resistance of filtering material will be controlled its ability that heats at short notice.By utilizing as above-mentioned embodiment 3 and 4 mentioned conditions form filter block with measuring resistance, and by with the resistance between 2 faces of 2 electrode contact measurements of 2 faces of filter block and voltmeter.The exemplary resistive of embodiment 3 and 4 middle filtrators is respectively about 350 Ω and about 40 Ω.Also have, respectively respectively do for oneself about 1.3M Ω and about 100 Ω of the strainer resistance made from CARBOCHEM CA-10 in the foregoing description 1 and the TA4-CA10 in the foregoing description 2.

Can obtain filtering particle by handling raw material as described below.These treatment condition can comprise Atmospheric composition, pressure, temperature and/or time.Atmosphere of the present invention can be reducing atmosphere or inert atmosphere.The heating and filtering particle can obtain having the filtering material of going back original surface oxygen functionality in the presence of reducing atmosphere, steam or inert atmosphere.The embodiment of suitable reducing atmosphere can comprise hydrogen, nitrogen, DA, carbon monoxide and/or their mixture.The embodiment of suitable inert atmosphere can comprise argon, helium and/or their mixture.

When activated carbon granule does not comprise any noble metal catalyst (as platinum, gold, palladium), treatment temp can be between about 600 ℃ and about 1, between 200 ℃, preferably between about 700 ℃ and about 1, between 100 ℃, more preferably between about 800 ℃ and about 1,050 ℃, most preferably between about 900 ℃ and about 1,000 ℃.If activated carbon granule comprises noble metal catalyst, treatment temp can be between about 100 ℃ and about 800 ℃, preferably between about 200 ℃ and about 700 ℃, more preferably between about 300 ℃ and about 600 ℃, most preferably between about 350 ℃ and about 550 ℃.

Treatment time can be between about 2 minutes and about 10 hours, preferably between about 5 minutes and about 8 hours, more preferably between about 10 minutes and about 7 hours, most preferably between about 20 minutes and about 6 hours.Gas flow rate can (be the every gram carbon of standard liter per hour between about 0.25 standard L/h.g; 0.009 standard ft ³/ h.g) and about 60 standard L/h.g (2.1 standard ft ³/ h.g) between, preferably between about 0.5 standard L/h.g (0.018 standard ft ³/ h.g) and about 30 standard L/h.g (1.06 standard ft ³/ h.g) between, more preferably between about 1.0 standard L/h.g (0.035 standard ft ³/ h.g) and about 20 standard L/h.g (0.7 standard ft ³/ h.g) between, most preferably between about 5 standard L/h.g (0.18 standard ft ³/ h.g) and about 10 standard L/h.g (0.35 standard ft ³/ h.g) between.During the processing pressure can keep greater than, be equal to or less than normal atmosphere.It should be understood that and also can adopt other method to make mesoporosity alkaline reduction oxygen activity charcoal filtering material.

Also having, is to obtain filtering material, depends on raw materials usedly, can repeat repeatedly this type of processing of raw material as mentioned above.

Raw material can commercially obtain or prepare with method well known in the art, Jagtoyen for example, M. with the Carbon of F.Derbyshire, the 36th volume (the 7th to 8 phase), people's such as the 1085th to 1097 page (1998), Evans Carbon, the 37th volume, people's such as the 269th to 274 page (1999) and Ryoo J.Phys.Chem B, the 103rd volume (the 37th phase), described in the 7743rd to 7746 page (1999), its content is incorporated herein by reference.Be used to activate/the typical chemical substance of carbonization comprises phosphoric acid, zinc chloride, ammonium phosphate etc., they can unite use with the method described in two kinds of periodicals of just having quoted.

Brunauer, Emmett and Teller (BET) specific surface area and Barrett, Joyner and Halenda (BJH) pore size distribution can be used for representing the feature of particulate pore structure.Preferably, the BET specific surface area of filtering particle is between about 500m ²/ g and about 3,000m ²Between/the g, preferably between about 600m ²/ g and about 2,800m ²Between/the g, more preferably between about 800m ²/ g and about 2,500m ²Between/the g, most preferably between about 1,000m ²/ g and about 2,000m ²Between/the g.Referring to Fig. 1 a, be depicted as the typical nitrogen adsorption isothermal line of wooden matrix activated carbon (TA4-CA-10) of the mesoporosity alkaline reduction oxygen that utilizes the BET method to record and the acid wooden matrix activated carbon in mesoporosity (CA-10).Referring to Fig. 1 b, be depicted as the typical nitrogen adsorption isothermal line of alkaline wooden matrix activated carbon (RGC) in the mesoporosity that utilizes the BET method to record and mesoporosity alkaline reduction oxygen wood matrix activated carbon (THe4-RGC).

Can measure the total pore volume of mesoporosity alkalescence activated carbon granule in the BET nitrogen adsorption process, and be calculated as the nitrogen adsorption volume that relative pressure P/Po equals at 0.9814 o'clock.More particularly, and as known in the art, total pore volume is " is the nitrogen adsorption volume of unit with mL (STP)/g " under 0.9814 condition by relative pressure, multiply by conversion factor 0.00156 and calculate, at this moment under STP (standard temperature and pressure) condition, the nitrogen of certain volume is converted to liquid.The total pore volume of filtering particle is greater than about 0.4mL/g, or greater than about 0.7mL/g, or greater than about 1.3mL/g, or greater than about 2mL/g, and/or less than about 3mL/g, or less than about 2.6mL/g, or less than about 2mL/g, or less than about 1.5mL/g.

Can measure mesopore and macropore volume sum in the BET nitrogen adsorption process and be calculated as the difference that equals total pore volume and nitrogen adsorption volume at P/Po at 0.15 o'clock.The mesopore of filtering particle and macropore volume sum can be greater than about 0.12mL/g, or greater than about 0.2mL/g, or greater than about 0.4mL/g, or greater than about 0.6mL/g, or greater than about 0.75mL/g, and/or less than about 2.2mL/g, or less than about 2mL/g, or less than about 1.5mL/g, or less than about 1.2mL/g, or less than about 1mL/g.

The BJH pore size distribution can utilize Barrett, Joyner and Halenda (BJH) method is measured, it is at J.Amer.Chem.Soc. the 73rd volume, the the 373rd to 380 page (nineteen fifty-one) and " ADSORPTION, SURFACE AREA, AND POROSITY " (Gregg and Sing, second edition, Academic Press, New York nineteen eighty-two) be described in, its content is incorporated herein by reference.In one embodiment, arbitrary aperture is between about 4nm and about 6nm the time, and pore volume can be at least about 0.01mL/g.In an alternative embodiment, arbitrary aperture is between about 4nm and about 6nm the time, and pore volume can be between about 0.01mL/g and about 0.04mL/g.In another embodiment, between about 4nm and about 6nm the time, pore volume can be at least about 0.03mL/g for the aperture, or between about 0.03mL/g and about 0.06mL/g.In a preferred embodiment, between about 4nm and about 6nm the time, pore volume can be between about 0.015mL/g and about 0.06mL/g for the aperture.Fig. 2 a illustrates and utilizes the mesoporosity alkaline reduction oxygen activity charcoal (TA4-CA-10) that the BJH method calculates and the typical mesopore volume of the acid wooden matrix activated carbon in mesoporosity (CA-10) to distribute.The typical mesopore volume that Fig. 2 b illustrates alkaline wooden matrix activated carbon (RGC) in the mesoporosity that utilizes the BJH method to calculate and mesoporosity alkaline reduction oxygen wood matrix activated carbon (THe4-RGC) distributes.

The ratio of mesopore and macropore volume sum and total pore volume is greater than about 0.3, be preferably greater than about 0.4, be preferably greater than about 0.6, most preferably between about 0.7 and about 1.

Total outer surface area obtains by multiply by the filtering particle Mass Calculation than outer surface area, and is of a size of the basis with filtering particle.For example, can obtain the ratio outer surface area of single dispersion (promptly having same diameter) fiber by the ratio that calculates fiber area (area of ignoring 2 cross sections of fiber ends) and fibre weight.Like this, the ratio outer surface area of fiber equals: 4/D ρ, wherein D is that Fibre diameter and ρ are fibre density.For monodispersed spheroidal particle, equal by the similar ratio outer surface area that calculates: 6/D ρ, wherein D is that particle diameter and ρ are pellet density.For polydisperse fiber, sphere or erose particle, pass through by D than the calculating of outer surface area _3,2Substitute D, and employing calculates with above-mentioned identical separately formula, wherein D _3,2Being the Sauter mean diameter, is its area capacity ratio and the identical particulate diameter of whole particle distribution.The method of measurement Sauter mean diameter well known in the art is a laser diffractometry, for example can adopt Malvern equipment (available from the Malvern Instruments Ltd. that is positioned at Britain Malvern).The ratio outer surface area of filtering particle can be between about 10cm ²/ g and about 100,000cm ²Between/the g, preferably between about 50cm ²/ g and about 50,000cm ²Between/the g, more preferably between about 100cm ²/ g and about 10,000cm ²Between/the g, most preferably between about 500cm ²/ g and about 7,000cm ²Between/the g.

When the test procedure that proposes according to this paper is measured, mesoporosity or mesoporosity alkalescence or mesoporosity alkaline reduction oxygen activity charcoal particulate BRI value can be greater than about 99%, be preferably greater than about 99.9%, more preferably greater than about 99.99%, most preferably greater than about 99.999%.This is equivalent to, and mesoporosity or mesoporosity alkalescence or mesoporosity alkaline reduction oxygen activity charcoal particulate BLRI value are preferably greater than about 3log, more preferably greater than about 4log, most preferably greater than about 5log greater than about 2log.When the test procedure that proposes according to this paper was measured, mesoporosity or mesoporosity alkalescence or mesoporosity alkaline reduction oxygen activity charcoal particulate VRI value can be greater than about 90%, be preferably greater than about 95%, more preferably greater than about 99%, most preferably greater than about 99.9%.This is equivalent to, and mesoporosity or mesoporosity alkalescence or mesoporosity alkaline reduction oxygen activity charcoal particulate VLRI value are preferably greater than about 1.3log, more preferably greater than about 2log, most preferably greater than about 3log greater than about 1log.

Be used for axial-flow type strainer (people such as Yao, Environ.Sci.Technol. the 5th roll up, the the 1102nd to 1112 page (1971)) the content of stable state, one dimension, " cleaning " bed filtration theory (dispersion transmission and the desorb of supposition microorganism can be ignored) be incorporated herein by reference, it has been described:

C/C _o=exp(-λL) (1)

Wherein C is an effluent concentration, C _oBe inflow concentration, λ is a filter factor, and its unit is the inverse of length, and L is a filter depth.Attention is based on above-mentioned definition, when adhesion of microorganisms does not flow through distance L in strainer, the collision number that it experienced will be (the L of λ/α), wherein α is " cleaning " bed sticking coefficient (being also referred to as collision rate), and it is defined as and adheres to microbe number that captures the surface and the ratio that collides the microbe number that captures the surface.If the L in the formula 1 is by R _o-R _IReplace, then this formula also is applicable to radial-flow type strainer, wherein R _oBe external diameter, R _iBe internal diameter, and filter factor is averaged on the whole thickness of strainer.The filter factor that comprises particulate bed (but not fiber) is as follows:

λ＝(3(1-ε)ηα)/2d _c (2)

Wherein ε is the filter bed layer porosity, and η is single capture rate, and it is defined as microbe number and the ratio that flows to the microbe number that captures the surface that collision captures the surface, and d _cFor capturing particle diameter.The factor in the following formula (3/2) is effective to sphere or like spheroidal particle.To cylindrical particle (for example fiber), this becomes (4/ π), then d _cBe cylindrical diameter.Also have, notice that term " cleaning " bed means that the capture surface does not also have to cause because of the microorganism of accumulation capacity the decline (promptly blocking) of new microbe sedimentation effect.

Based on above-mentioned " cleaning " bed filtration model, F-BLR and F-VLR can be calculated as follows:

F-BLR or F-VLR=-log (C/C ₀)=(λ L/2.3) (3)

Utilize Rajagopalan and Tien model (RT model; AIChE J., the 22nd volume (the 3rd phase), the 523rd to 533 page (1976) and AIChE J., the 28th volume, the 871st to 872 page (nineteen eighty-two)) single capture rate η is as follows in calculating:

η＝4A _s ^1/3Pe ^-2/3+A _sLo ^1/8R ^15/8+0.00338A _sG ^6/5R ^-2/5 (4)

Wherein

$A_S=\frac{2(1-r^5)}{2-3r+{3r}^5-{2\mathrm{<figure-callout\; id="6"\; label="r"\; filenames="A0382594600351.png,A0382594600361.png"\; state="\{\{state\}\}">r</figure-callout>}}^6,}$

γ=(1-ε) ^1/3, Pe is zero dimension pendant Klatt (Peclet) number

$\mathrm{Pe}=\frac{3\mathrm{\&mu;\&pi;U}{d}_c{d}_m}{\mathrm{kT}},$

Lo is zero dimension London (London)-Van der Waals number

$\mathrm{Lo}=\frac{4\mathrm{<figure-callout\; id="9"\; label="H"\; filenames="A0382594600421.png"\; state="\{\{state\}\}">H</figure-callout>}}{9\mathrm{\&pi;\&mu;}{d}_m^{2}U},$

R is a zero dimension interception number

$R=\frac{d_m}{d_c},$

G is a zero dimension precipitation number

$G=\frac{g({\mathrm{\&rho;}}_m-{\mathrm{\&rho;}}_f){\mathrm{<figure-callout\; id="2"\; label="d\; m"\; filenames="A0382594600351.png,A0382594600361.png"\; state="\{\{state\}\}">d</figure-callout>}}_m^{}}{18\mathrm{\&mu;U}},$

μ is dynamic fluid viscosity (equaling 1mPas for water), U be superficial fluid velocity (be calculated as: to the axial-flow type strainer, U=4Q/ π D ², wherein Q is a rate of flow of fluid, D is the diameter in filter face zone; To the radial-flow type strainer, U (R)=Q/2 π RX, wherein X is the length of strainer, R is R _iAnd R ₀Between radial position), d _mBe microorganism diameter (perhaps if microorganism is aspheric, then for being equivalent to the diameter of spheroid) that k is that Boltzmann constant (equals 1.38 * 10 ^-23Kgm ²/ s ²K), T is a fluid temperature (F.T.), and H is that (it typically equals 10 to the Hamaker constant ^-20J), g is that gravity constant (equals 9.81m/s ²), ρ _mBe the density of microorganism, ρ _fBe fluid density (equaling 1g/mL) for water.For purpose of the present invention and material, H equals 10 ^-20J, T equals 298K, ρ _mEqual 1.05g/mL, μ equals 1mPas.Also have, for the purpose of the present invention, d _cBe volume medium Dv, 0 _.5, it is 50% the particle diameter in smaller diameter particles that makes total particle volume.Also have, average fluid residence time is calculated as:

To the axial-flow type strainer,

$\mathrm{\&tau;}=\frac{{\mathrm{\&epsiv;\&pi;D}}^{2}L}{4Q},$

To the radial-flow type strainer,

$\mathrm{\&tau;}=\frac{\mathrm{\&epsiv;\&pi;}({\mathrm{<figure-callout\; id="0"\; label="R"\; filenames="A0382594600331.png,A0382594600351.png"\; state="\{\{state\}\}">R</figure-callout>}}_0^2-R_i^2)X}{Q}$

Sticking coefficient, α typically calculates with experimental technique, for example uses " microbe andradiolabel kinesis " (MARK) technology, and it is described in people such as Gross (WaterRes., the 29th volume (the 4th phase), the 1151st to 1158 page (nineteen ninety-five)).Single capture rate η of strainer of the present invention can be greater than about 0.002, be preferably greater than about 0.02, be preferably greater than about 0.2, be preferably greater than about 0.4, more preferably greater than about 0.6, most preferably between about 0.8 and about 1.The filter factor λ of strainer of the present invention can be greater than about 10m ^-1, be preferably greater than about 20m ^-1, more preferably greater than about 30m ^-1, most preferably greater than about 40m ^-1, and/or less than about 20,000m ^-1, preferably less than about 10,000m ^-1, be more preferably less than about 5,000m ^-1, most preferably less than about 1,000m ^-1

When the test procedure that proposes according to this paper is measured, the F-BLR value that comprises mesoporosity or mesoporosity alkalescence or mesoporosity alkaline reduction oxygen activity charcoal particulate strainer of the present invention can be greater than about 2log, be preferably greater than about 3log, more preferably greater than about 4log, most preferably greater than about 6log.When the test procedure that proposes according to this paper is measured, the F-VLR value that comprises mesoporosity or mesoporosity alkalescence or mesoporosity alkaline reduction oxygen activity charcoal particulate strainer of the present invention can be greater than about 1log, be preferably greater than about 2log, more preferably greater than about 3log, most preferably greater than about 4log.

In a preferred embodiment of the invention, filtering particle comprises wooden matrix activated carbon particulate mesoporosity activated carbon granule.These particulate BET specific surface area is between about 1,000m ²/ g and about 2,000m ²Between/the g, total pore volume is between about 0.8mL/g and about 2mL/g, and mesopore and macropore volume sum are between about 0.4mL/g and about 1.5mL/g.

In another preferred embodiment of the present invention, filtering particle comprises wooden matrix activated carbon particulate mesoporosity alkalescence activated carbon granule.These particulate BET specific surface area is between about 1,000m ²/ g and about 2,000m ²Between/the g, total pore volume is between about 0.8mL/g and about 2mL/g, and mesopore and macropore volume sum are between about 0.4mL/g and about 1.5mL/g.

In another preferred embodiment of the present invention, filtering particle comprises the mesoporosity alkaline reduction oxygen activity charcoal particle that is initially acidity but is treated to alkaline reduction oxygen under DA atmosphere.These particles are wooden matrix activated carbon particle.Treatment temp is between about 925 ℃ and about 1,000 ℃, and the ammonia flow velocity is between about 1 standard L/h.g and about 20 standard L/h.g, and the treatment time is between about 10 minutes and about 7 hours.These particulate BET specific surface area is between about 800m ²/ g and about 2,500m ²Between/the g, total pore volume is between about 0.7mL/g and about 2.5mL/g, and mesopore and macropore volume sum are between about 0.21mL/g and about 1.7mL/g.The indefiniteness embodiment that is converted into the acid gac of alkaline reduction oxygen activity charcoal will set forth below.

In another preferred embodiment of the present invention, filtering particle comprises the mesoporosity alkaline reduction oxygen activity charcoal particle that is initially mesoporosity alkalescence and handles with inert atmosphere (being helium).These particles are wooden matrix activated carbon particle.Treatment temp is between about 800 ℃ and about 1,000 ℃, and the helium flow velocity is between about 1 standard L/h.g and about 20 standard L/h.g, and the treatment time is between about 10 minutes and about 7 hours.These particulate BET specific surface area is between about 800m ²/ g and about 2,500m ²Between/the g, total pore volume is between about 0.7mL/g and about 2.5mL/g, and mesopore and macropore volume sum are between about 0.21mL/g and about 1.7mL/g.The indefiniteness embodiment that is converted into the alkaline gac of alkaline reduction oxygen activity charcoal will set forth below.

III. Processing Example

Embodiment 1

Handle the acid gac in mesoporosity with the preparation mesoporosity alkaline reduction oxygen charcoal of giving birth to alive

Will be by available from being positioned at Ardmore, the Carbochem of PA, the quality of Inc. is the CARBOCHEM of about 2kg ^The acid wooden matrix activated carbon particle in CA-10 mesoporosity, placing model is on the smelting furnace travelling belt of BAC-M, and smelting furnace is by being positioned at Cranston, and the C.I.Hayes Inc. of RI makes.Temperature is set at about 950 ℃ in the stove, and the treatment time is about 4 hours, and atmosphere is DA, and its mobile volumetric flow rate is about 12,800 standard L/h (i.e. 450 standard ft ³/ h, or be equivalent to about 6.4 standard L/h.g).Activated carbon granule after the processing is called TA4-CA-10, and its BET thermoisopleth, mesopore volume distribute and the point of zero electric charge analysis is shown in respectively among Fig. 1 a, 2a and the 3a.BET numerical value, mesopore and macropore volume sum, point of zero electric charge, BRI/BLRI, VRI/VLRI, body oxygen weight percent and redox potential (ORP) are shown in the VI joint.

Embodiment 2

Handle mesoporosity alkalescence gac with preparation mesoporosity alkaline reduction oxygen activity charcoal

Will be by available from being positioned at Covington, the quality of the MeadWestvaco Corp. of VA is the MeadWestvaco Nuchar of about 2kg ^The wooden matrix activated carbon particle of RGC mesoporosity alkalescence, placing model is on the smelting furnace travelling belt of BAC-M, and smelting furnace is by being positioned at Cranston, and the C.I.HayesInc. of RI makes.Temperature is set at about 800 ℃ in the stove, and the treatment time is 4 hours, and atmosphere is helium, and its mobile volumetric flow rate is about 12,800 standard L/h (i.e. 450 standard ft ³/ h, or be equivalent to about 6.4 standard L/h.g).Activated carbon granule after the processing is called THe4-RGC, and its BET thermoisopleth, mesopore volume distribute and the point of zero electric charge analysis is shown in respectively among Fig. 1 b, 2b and the 3b.BET numerical value, mesopore and macropore volume sum, point of zero electric charge, BRI/BLRI, VRI/VLRI, body oxygen weight percent and redox potential (ORP) are shown in the VI joint.

IV. strainer of the present invention

Referring to Fig. 4, described is an exemplary filter of making according to the present invention.Strainer 20 comprises a cylindrical shell 22 of 26 with inlet 24 and outlet.As known in the art, depend on the designed use and the desired properties of strainer 20, shell 22 can be in a variety of forms, shape, size and arrangement provide.For example, strainer 20 can be the axial-flow type strainer, wherein will enter the mouth 24 and outlet 26 be arranged so that liquid flows along the axis of shell 22.Alternatively, strainer 20 can be the radial-flow type strainer, wherein will enter the mouth 24 and outlet 26 be arranged in and make the radial flow of fluid (as liquid, gas or its mixture) along shell 22.No matter be axial-flow type or radial-flow type configuration, strainer 20 can preferably be configured to provide at least about 0.5in. ²(3.2cm ²) positive zone, more preferably at least about 3in. ²(19.4cm ²), most preferably at least about 5in. ²(32.2cm ²), and filter depth is preferably at least about 0.125in. (0.32cm), preferably at least about 0.25in. (0.64cm), more preferably at least about 0.5in. (1.27cm), most preferably at least about 1.5in. (3.81cm).To the radial-flow type strainer, filter length can be 0.25in. (0.64cm) at least, more preferably at least about 0.5in. (1.27cm), most preferably at least about 1.5in. (3.81cm).Further, strainer 20 can both comprise the axial-flow type part, comprised the radial-flow type part again.

Do not depart from scope of the present invention, shell also may be made in the parts of another structure.Although the strainer among the present invention is specially adapted to water, will be appreciated that its fluid that also is applicable to other (for example air, gas, and gas and mixtures of liquids).Like this, then strainer 20 is intended to represent common liquid filter or gas filter.As known in the art, for flow velocity and the designed use that adapts to strainer 20, can to enter the mouth 24 and outlet 26 size, shape, spacing, arrangement and position select.Preferably, strainer 20 is designed to be applied to dwelling house or commercial potable water, comprise, but be not limited to, household filter, refrigerator strainer, portable water combiner are (for example, the apparatus of camping is as kettle), be installed in strainer on the water tap, the strainer under the sink, medical apparatus strainer, industrial strainer, air filter etc.Filter configurations, drinking water apparatus, drinking person utensil and other are applicable to that the embodiment of water filtering device of the present invention is disclosed in United States Patent (USP) 5,527,451; 5,536,394; 5,709,794; 5,882,507; 6,103,114; 4,969,996; 5,431,813; 6,214,224; 5,957,034; 6,145,670; 6,120,685; With 6,241,899, be incorporated herein by reference in view of the above.For potable water applications, strainer 20 preferred disposition are for making flow velocity less than about 8L/ minute, or less than about 6L/ minute, or between about 2L/ minute and about 4L/ minute, and strainer can comprise the filtering material less than about 2kg, or less than the filtering material of about 1kg, or less than the filtering material of about 0.5kg.In addition, for potable water applications, strainer 20 can preferably be configured to make average fluid residence time to be at least about 3s, preferably at least about 5s, preferably at least about 7s, more preferably at least about 10s, most preferably at least about 15s.Also have, for potable water applications, strainer 20 can preferably be configured to make the filtering material pore volume to be at least about 0.4cm ³, preferably at least about 4cm ³, more preferably at least about 14cm ³, most preferably at least about 25cm ³

Strainer 20 also comprises the filtering material 28 that can unite use with other filtering system, and other filtering system comprises reverse osmosis system, ultraviolet system, ion exchange system, water electrolysis system and other water treatment system well known by persons skilled in the art.

Strainer 20 also comprises filtering material 28, and wherein filtering material 28 comprises one or more filtering particles (for example fiber, particle etc.).One or more filtering particles can be the mesoporosity, and more preferably mesoporosity alkalescence most preferably is mesoporosity alkaline reduction oxygen, and has the feature that the front is discussed.The mesoporosity, or mesoporosity alkalescence, or mesoporosity alkaline reduction oxygen activity charcoal filtering material 28 can make up other material or combination of materials such as active carbon powder with the particle that is formed at other material or combination of materials, activated carbon granule, activated carbon fiber, zeolite, inorganics (comprises activated alumina, magnesium oxide, diatomite, silicon-dioxide, mixed oxide such as hydrotalcite, glass etc.), cationic substance (comprises polymkeric substance such as polymeric amide (polyaminoamides), polymine, polyvinylamine, diallyl dimethyl ammoniumchloride, polydimethyl amine-epoxy chloropropane, the polyhexamethylene guanyl guanidine, can be attached to fiber and (comprise polyethylene, polypropylene, the EMA anhydride copolymer, carbon, glass etc.) poly--[2-(2-oxyethyl group)-ethoxyethyl group]-chlorination guanidine), and/or erose material (comprises carbon, diatomite, sand, glass, clay etc.) and their mixture.Can make mesoporosity alkalescence gac with it the embodiment of bonded filtering material and filtering material combination be disclosed in the United States Patent (USP) 6,274,041,5 that is incorporated herein by reference, 679,248 and the U.S. Patent application 09/628,632 that is incorporated herein by reference equally.As previously mentioned, the form that filtering material can be loose or interconnected (as by polymeric binder or the part or all of bonding one-piece construction that forms of alternate manner) provides.

Size by changing above-mentioned filtering particle, shape, complex compound formation, electric charge, porosity, surface tissue, functional group etc. can make filtering material be used for different purposes (as prefilter or after filter).As just describing, filtering material also can with other material mixing to be applicable to special purpose.No matter filtering material whether with other material mixing, it all can be used as loose bed, filter block (comprising United States Patent (USP) 5,679, the 248 described coextrusion pieces that are incorporated herein by reference) and their mixture.The preferred method that can be used for filtering material comprises that the filter block (wherein bonding force comes from the baking of ceramic), the utilization that form by pottery-carbon mixing is made are described in the United States Patent (USP) 6 that is incorporated herein by reference, 077, powder between the non-woven material in 588, utilization are described in the United States Patent (USP) 5 that is incorporated herein by reference, wet tenacity method in 928,588, make the resin glue activation (it is incorporated herein by reference) that forms filter block or by being described in the resistive heating method that PCT applies for serial WO 98/43796.

V. filter embodiment

Embodiment 3

The strainer that comprises mesoporosity alkalescence activated carbon granule

Will be available from being positioned at Covington, about 18.3gNuchar of the MeadWestvaco Corp. of VA ^RGC mesoporosity alkalescence active carbon powder (D _{V, 0.5}Equal about 45 μ) and available from being positioned at Cincinnati, the Equistar Chemicals of OH, about 7g Microthene of Inc. ^New LDPE (film grade) (LDPE) FN510-00 tackiness agent and available from being positioned at Norcross, the Select of GA, about 2g Alusil of Inc. ^70 silico-aluminate powder mixes.Then mixed powder is poured in the circular aluminium-making mould into the about 3in. of this mould internal diameter (about 7.62cm), the about 0.5in. of the degree of depth (about 1.27cm).With die sealing and be positioned in the heated press with cylinder, kept 1 hour down for about 204 ℃ in temperature.Then, with mold cools down to room temperature, open, and remove the axial-flow type strainer.Being characterized as of this strainer: positive zone: about 45.6cm ²Filter depth: about 1.27cm; Strainer cumulative volume: about 58mL; Strainer hole rate (to hole): about 0.43 greater than about 0.1 μ m; With filtering material pore volume (to hole): about 25mL (recording) by mercury penetration method greater than about 0.1 μ m.Described in following test procedure, strainer is positioned over Teflon ^In the shell.When flow velocity for about 200mL/ minute the time, to about initial 2,000 filter hole volumes, the pressure of this strainer reduce to about 17psi (about 1.2bar, 0.12MPa).The numerical value of F-BLR, F-VLR, η and α is shown in the VI joint.

Embodiment 4

The strainer that comprises microporosity alkalescence activated carbon granule

Will about 26.2g coconut microporosity alkalescence active carbon powder (D _V.0.5Equal about 92 μ) and available from being positioned at Cincinnati, the Equistar Chemicals of OH, the 7g Microthene of Inc. ^New LDPE (film grade) (LDPE) FN510-00 tackiness agent, and available from being positioned at Norcross, the Selecto of GA, about 2g Alusil of Inc. ^70 silico-aluminate powder mixes.Then mixed powder is poured in the circular aluminium-making mould into the about 3in. of this mould internal diameter (about 7.62cm), the about 0.5in. of the degree of depth (about 1.27cm).With die sealing and be positioned in the heated press with cylinder, kept 1 hour down for about 204 ℃ in temperature.Then, with mold cools down to room temperature, open, and remove the axial-flow type strainer.Being characterized as of this strainer: positive zone: about 45.6cm ²Filter depth: about 1.27cm; Strainer cumulative volume: about 58mL; Strainer hole rate (to hole): about 0.44 greater than about 0.1 μ m; Filtering material pore volume (to hole): about 25.5mL (recording) by mercury penetration method greater than about 0.1 μ m.Described in following test procedure, strainer is positioned over Teflon ^In the shell.When flow velocity was about 200mL/ minute, to about initial 2,000 filter hole volumes, the pressure of this strainer was reduced to about 17psi (about 1.2bar, about 0.12MPa).The numerical value of F-BLR, F-VLR, η and α is shown in the VI joint.

VI. test and calculation procedure

Following test procedure is used to calculate BET as herein described, point of zero electric charge, BRI/BLRI, VRI/VLRI, body oxygen weight percent, redox potential (ORP), F-BLR and F-VLR value.This paper has also described the calculation procedure that is used for single capture rate, filter factor, average fluid residence time and F-BLR value.

Though measure BRI/BLRI value and VRI/VLRI value at water-bearing media, but need not to limit the final use of filtering material among the present invention, although BRI/BLRI value and VRI/VLRI value are calculated for water-bearing media, filtering material can finally use with other fluid as previously mentioned.And, below the selected filtering material that uses with the explanation test procedure do not limit the scope that processing among the present invention and/or filtering material are formed, also do not limit when using this test procedure and can not assess employed filtering material kind among the present invention.

The BET test procedure

Utilize the nitrogen adsorption technology (as to be described in technology among the ASTM D 4820-99, its content is incorporated herein by reference) with being positioned at Miami, CoulterSA3100 series of tables area that the Coulter Corp. of FL makes and aperture analyser carry out multiple spot nitrogen and adsorb and measure BET specific surface area and pore volume distribution under about 77K.This method also can obtain micropore, mesopore and macropore volume.For the TA4-CA-10 filtering particle among the embodiment 1, the BET zone is about 1,038m ²/ g, micro pore volume are about 0.43mL/g, and mesopore and macropore volume sum are about 0.48mL/g.For the THe4-RGC filtering particle among the embodiment 2, the BET zone is about 2,031m ²/ g, micro pore volume are about 0.81mL/g, and mesopore and macropore volume sum are about 0.68mL/g.The value separately of noting raw material CA-10 and RGC is: be respectively about 1,309m ²/ g, about 0.54mL/g, about 0.67mL/g; With about 1,745m ²/ g, about 0.70mL/g, about 0.61mL/g.The typical BET nitrogen thermoisopleth of filtering material and mesopore volume distribute and are shown in respectively among Fig. 1 a and the 1b among the embodiment 1 and 2.As known in the art, will be appreciated that and to measure by the alternative BET that carries out of Other Instruments.

The point of zero electric charge test procedure

Can prepare the KCl aqueous solution of about 0.010M by reagent grade KCl and water, water new distillation and getting in argon gas.Be used for the distillatory water conservancy and carry out the deionization processing with continuous reverse osmosis and ion-exchange.The KCl aqueous solution branch of about 25.0mL volume is filled in the flask of six about 125mL, and each flask is furnished with 24/40 ground glass stopper.Add the standard aqueous HCl or the NaOH solution of microliter amount in each flask, make its initial pH value scope between about 2 and about 12.Utilize Orion 420A type pH meter to write down the pH value of each flask then, this pH meter has Orion 9107BN type triode combination pH/ATC electrode, and it is by being positioned at Beverly, and the Thermo Orion Inc. of MA makes, and this pH value is called " initial pH value ".In each flask in six flasks of about 0.0750 ± 0.0010g activated carbon granule adding, at record " final pH value " before, the aq suspension about 24 hours to blocking under the room temperature stirs (speed is about 150rpm).Fig. 3 a shows the initial and final pH value of utilizing CA-10 and the test of TA4-CA-10 absorbent charcoal material to record, and Fig. 3 b shows the initial and final pH value of utilizing RGC and the test of The4-RGC absorbent charcoal material to record.The point of zero electric charge of CA-10, TA4-CA-10, RGC and THe4-RGC is respectively about 5.0, about 9.7, about 8.8 and about 8.6.As known in the art, will be appreciated that can be by alternative this test procedure that carries out of Other Instruments.

The BRI/BLRI test procedure

Use is positioned at Richmomd, the Phipps ﹠amp of VA; Bird, the PB-900 that Inc. makes ^TMProgrammable JarTester test set, this device have 2 or a plurality of Pyrex ^Glass beaker (by the decision of test material quantity).The diameter of beaker is that (about 4.5 ") highly are about 15.3cm (about 6 ") to about 11.4cm.Each beaker comprises about 500mL and is subjected to the dechlorination tap water of the municipal administration supply that e. coli microorganisms pollutes and the splash bar that rotates with about 60rpm speed.This splash bar is a stainless steel blade, and its length is that (about 3 "), highly (about 1 "), thickness are about 0.24cm (about 3/32 ") to about 7.6cm for about 2.54cm.Splash bar is placed at the bottom of the beaker about 0.5cm, and (about 3/16 ") located.First beaker does not comprise any filtering material, and with comparing, other beaker comprises the filtering material of capacity, and its Sauter mean diameter is less than about 55 μ m, makes in the beaker that total geometric outer surface of material is long-pending to be about 1400cm ²This Sauter mean diameter is obtained by following method: a) sieve out the sample with wide distribution of sizes and high Sauter mean diameter; Or b) utilize size reduction technology well-known to those having ordinary skill in the art, reduce filtering particle (as, if the filtering particle size is greater than about 55 μ m, or if filtering material is integrated or adhesive-bonded form) size.For example, but not conduct restriction, the size reduction technology comprises crushing, grinds and mills.The exemplary apparatus that is used for size reduction comprises that jaw crusher, gyratory crusher, roll crusher, pulverizer, heavy impact milling, medium-sized runner milling and liquid can shredders, as the centrifugal atomization device, to the stamp ejector or have the injector of anvil.Size reduction can be used for loose or the adherent filtering particle.Before testing, should remove the biocide coating in arbitrary filtering particle or the filtering material.Alternatively, can not having the coating filtering particle in the test substitutes.

After adding filtering particle in the beaker, the reproduction copies of collecting the water of the about 5mL of each volume from each beaker at different time is used for analyzing, and reaches balance in the beaker that comprises filtering particle.The typical sampling times is: about 0, about 2, about 4 and about 6 hours.Also can use miscellaneous equipment known in the art to replace.

The intestinal bacteria of using are ATCC# 25922, and by being positioned at Rockville, the American Type Culture Collection of MD (U.S.'s species are cultivated set) provides.Target e. coli concentration in the contrast beaker is set at about 3.7 * 10 ⁹CFU/L.Can utilize membrane filtration technique according to being positioned at Washington, #9222 method described in " the Standard Processes for the Examination of Waterand Wastewater " that the American Public Health Association (APHA) of DC publishes the 20th edition is chemically examined intestinal bacteria, and its content is incorporated herein by reference.Limit of detection (LOD) is about 1 * 10 ³CFU/L.

The exemplary BRI/BLRI of filtering material the results are shown among Fig. 5 a and Fig. 5 b among the embodiment 1 and 2.The amount of the acid absorbent charcoal material in CA-10 mesoporosity is about 0.75g, and the amount of TA40-CA-10 mesoporosity alkaline reduction oxygen activity raw material of wood-charcoal material is about 0.89g.The amount of RGC mesoporosity alkalescence absorbent charcoal material is about 0.28g, and the amount of THe4-RGC mesoporosity alkaline reduction oxygen activity raw material of wood-charcoal material is about 0.33g.All four amounts are corresponding about 1,400cm ²Outer surface area.E. coli concentration among Fig. 5 a in the contrast beaker is about 3.7 * 10 ⁹CFU/L then is about 3.2 * 10 among Fig. 5 b ⁹CFU/L.The interior e. coli concentration of beaker that comprises CA-10, TA4-CA-10, RGC and THe4-RGC sample reached balance in about 6 hours, their value is respectively: about 2.1 * 10 ⁶CFU/L, about 1.5 * 10 ⁴CFU/L, about 3.4 * 10 ⁶CFU/L and about 1.2 * 10 ⁶CFU/L.Then, BRI value separately is calculated as about 99.94%, about 99.9996%, about 99.91% and about 99.97%, and BLRI value separately is calculated as about 3.2log, about 5.4log, about 3.0log and about 3.5log.

The test procedure of VRI/VIRI

The testing apparatus that is adopted is identical during with mensuration BRI/BLRI value with test procedure.First beaker does not comprise filtering material, and in contrast, other beaker comprises the capacity filtering material, and the Sauter mean diameter of material is less than about 55 μ m, makes in the beaker that total geometric outer surface is long-pending to be about 1400cm ²Before testing, should remove the biocide coating in arbitrary filtering particle or the filtering material.Alternatively, can not having coating filtering particle or filtering material in the test substitutes.

The MS-2 bacteriophage that uses is ATCC# 15597B, and by being positioned at Rockville, the American Type Culture Collection of MD (U.S.'s species are cultivated set) provides.Target MS-2 concentration in the contrast beaker is set at about 2.07 * 10 ⁹PFU/L.Can be according to C.J.Hurst at Appl.Environ.Microbiol., the 60th volume (the 9th phase), the step described in the 3462nd page (1994) is carried out the MS-2 chemical examination, and its content is incorporated herein by reference.Also can adopt other assay method known in the art to replace.Limit of detection (LOD) is about 1 * 10 ³PFU/L.

The exemplary VRI/VLRI of filtering material the results are shown among Fig. 6 a and Fig. 6 b among the embodiment 1 and 2.The amount of the acid absorbent charcoal material in CA-10 mesoporosity is about 0.75g, and the amount of TA40-CA-10 mesoporosity alkaline reduction oxygen activity raw material of wood-charcoal material is about 0.89g.The amount of RGC mesoporosity alkalescence absorbent charcoal material is about 0.28g, and the amount of THe4-RGC mesoporosity alkaline reduction oxygen activity raw material of wood-charcoal material is about 0.33g.All four amounts are corresponding about 1,400cm ²Outer surface area.MS-2 concentration among Fig. 6 a in the contrast beaker is about 6.7 * 10 ⁷PFU/L then is about 8.0 * 10 among Fig. 6 b ⁷PFU/L.The interior MS-2 concentration of beaker that comprises CA-10, TA4-CA-10, RGC and THe4-RGC sample reached balance in 6 hours, their value is respectively about 4.1 * 10 ⁴PFU/L, about 1 * 10 ³PFU/L, about 3 * 10 ³PFU/L and less than about 1.0 * 10 ³PFU/L (limit of detection).Then, VRI value separately is calculated as about 99.94%, about 99.999%, about 99.996% and greater than about 99.999%, and VLRI value separately is calculated as about 3.2log, about 5log, about 4.4log and greater than about 5log.

Body oxygen weight percent test procedure

The model of utilizing PerkinElmer is 240 Elemental Analyzer (OxygenModification; PerkinElmer, Inc.; Wellesley MA) measures body oxygen weight percent.The pyrolytic decomposition of sample in helium flow when this technology is based on the Platinised plated Carbon about 1000 ℃.The carbon sample spends the night at the vacuum oven inner drying, and temperature is about 100 ℃.As known in the art, will be appreciated that can be by alternative this test procedure that carries out of Other Instruments.The exemplary body oxygen weight percent numerical value of filtering material CA-10, TA4-CA-10, RGC and THe4-RGC is respectively about 8.3%, about 1.1%, about 2.3% and about 0.8%.

Redox potential (ORP) test procedure

Utilization is available from Orion Research, and (Beverly, model MA) is that the platinum oxidation reducing electrode of 96-78-00 is measured redox potential (ORP) to Inc., and follows ASTM standard D1498-93.This step relates to the suspension of about 0.2g carbon in about 80mL tap water, and reads the electrode reading in gentle agitation after about 5 minutes, and unit is mV.As known in the art, will be appreciated that can be by alternative this test procedure that carries out of Other Instruments.Exemplary redox potential (ORP) value of filtering material CA-10, TA4-CA-10, RGC and THe4-RGC is respectively about 427mV, about 285mV, about 317mV and about 310mV.

The F-BIR test procedure

The shell of axial-flow type strainer with mesoporosity carbon is by Teflon ^Make, and be that capping and pedestal are formed by 2 parts.Two-part external diameter is about 12.71cm, and (about 5 "), internal diameter are about 7.623cm (about 3 ").With O shape ring (thickness of about 7.623cm (internal diameter of about 3 ") and about 0.318cm (about 1/8 ")) compression seal capping oppositely is placed in the pedestal.(the NPT gas thread of about 1/16 ") colludes groove junctor string in capping and pedestal with the entrance and exit flexible pipe with about 0.159cm.Will about 1.27cm (thick about 6.99cm (pact of taking advantage of of about  ") The stainless steel splitter of ") external diameter (having the hole of about 0.482cm (about 3/16 ") and the screen cloth that the downstream side has about 6 sieve apertures at upstream side) oppositely is placed in the capping of shell.The effect of splitter is to enter the mouth distributions on all fronts of strainer.The capping of shell and pedestal are meshing with each other and make and to have compression seal, thereby with the strainer sealing in the enclosure.(fastener of about  ") combines capping and pedestal to utilize four about 0.635.

Strainer is installed in the enclosure, by about 1 * 10 ⁸The water that the e. coli contamination of CFU/L is crossed is with about 200mL/ minute flow velocity this strainer of flowing through.The water inventory that flows into can be about 2,000 filtering material pore volumes or more.The intestinal bacteria of using are as ATCC# 25922, and by Rockville, the American Type Culture Collection of MD (U.S.'s species are cultivated set) provides.Can utilize membrane filtration technique according to being positioned at Washington, #9222 method described in " the Standard Processes for theExamination of Water and Wastewater " that the American Public HealthAssociation (APHA) of DC publishes the 20th edition is chemically examined intestinal bacteria, and its content is incorporated herein by reference.Also can adopt other assay method known in the art to replace (as COLILERT ^).When measuring with membrane filtration technique, limit of detection (LOD) is about 1 * 10 ²CFU/L is when using COLILERTO ^Then be about 10CFU/L during commercial measurement.After water flows through initial approximately 2,000 filtering material pore volumes, will flow out water collection and chemical examination, and utilize definition to calculate the F-BLR value with intestinal bacteria bacterial count to existing.

To the axial-flow type strainer of embodiment 3 and embodiment 4, the example results that is used for calculating the F-BLR value is shown in Fig. 7 a.The flow velocity that is used for Fig. 7 a is about 200mL/ minute, and colibacillary inflow concentration is about 1 * 10 ⁸With about 1 * 10 ⁹Change between the CFU/L.(on every Tuesdays) checks strainer with the amount of about 20L weekly, and the convection current water outlet is chemically examined as mentioned above.The average fluid residence time of RGC strainer is about 7.5s, and that the coconut strainer is about 7.65s.The F-BLR value of RGC strainer is calculated as about 6.8log among the embodiment 3.To the coconut strainer among the embodiment 4, the collection of flowing out water rests on about 40L (it is equivalent to about 1,570 filtering material volume of voids), and this is because of demonstrate penetrating almost completely at this volume of water place strainer.When about 1,570 filtering material volume of voids, the F-BLR value is calculated as about 1.9log.

The F-VIR test procedure

The shell of axial-flow type strainer with mesoporosity carbon is with identical described in the top F-BLR step.With about 1 * 10 ⁷The current that PFU/L MS-2 polluted are through shell/filter system, and flow velocity is about 200mL/ minute.The water inventory that flows into is about 2,000 filtering material pore volumes or more.The MS-2 bacteriophage that uses is as ATCC# 15597B, and by Rockville, the AmericanType Culture Collection of MD (U.S.'s species are cultivated set) provides.Can be according to the Appl.Environ.Microbiol. of C.J.Hurst, the 60th volume (the 9th phase), the program described in the 3462nd page (1994) is carried out the MS-2 chemical examination, and its content is incorporated herein by reference.Also can adopt other assay method known in the art to substitute.Limit of detection (LOD) is 1 * 10 ³PFU/L.After water flows through initial approximately 2,000 filtering material pore volumes, will flow out water collection and chemical examination, and utilize definition calculating F-VLR value with MS-2 bacteriophage counting to existing.

To the axial-flow type strainer of embodiment 3 and embodiment 4, the example results that is used for calculating the F-VLR value is shown in Fig. 7 b.The flow velocity that is used for Fig. 7 b is about 200mL/ minute, and the inflow concentration of MS-2 is about 1 * 10 ⁷Change near the PFU/L.(on every Tuesdays) checks strainer with the amount of about 20L weekly, and the convection current water outlet is chemically examined as mentioned above.The F-VLR value of RGC strainer is calculated as greater than about 4.2log among the embodiment 3.To the coconut strainer among the embodiment 4, the collection of flowing out water rests on about 40L (it is equivalent to about 1,570 filtering material pore volume), and this is because of demonstrate penetrating almost completely at this volume of water place strainer.When about 1,570 filtering material pore volume, the F-BLR value is calculated as about 0.3log.

The calculation procedure of single capture rate, filter factor, average fluid residence time and F-BLR value

Utilize single capture rate of formula 4 calculating strainers, after non-dimensional number is described in this formula.Use following parameter that the axial-flow type RGC strainer among the embodiment 3 is carried out example calculation: ε=0.43, d _m,=1 μ m, d _c=45 μ m, H=10 ^-20J, ρ _m,=1.058g/mL, ρ _f=1.0g/mL, μ=1mPas, T=298K, water flow velocity Q=200mL/ minute, strainer diameter D=7.623cm, U=0.0007m/s, given η=0.01864.Identical and α=1 of parameter, filter factor can be calculated as according to formula 2: λ=354.2m ^-1In addition, the F-BLR value of same filter can be calculated as about 1.95log according to formula 3.Use and the coconut strainer among the embodiment 4 is carried out similar example calculation, given η=0.00717 and λ=65.5m with top identical parameter ^-1At last, the F-BLR value of same filter can be calculated as about 0.36log according to formula 3.

The present invention can add and comprise information, this information will inform that the human consumer uses carbon filtering particle of the present invention and/or filtering material to provide and comprises the beneficial effect of removing microorganism by literal and/or picture, and this information can comprise the claim that is superior to other filtering product.In highly required variation, this information can comprise that the content of microorganisms that utilizes the present invention to make nano-scale reduces.Therefore, use the packing of the information that is printed on very important, this information will by literal and/or by picture inform the human consumer utilize the present invention will provide as described herein such as tap water, be more suitable for beneficial effect such as tap water.This information can comprise as on advertisement in all generic media and packing or strainer originally on one's body explanation and icon inform the human consumer.

The present invention is to the selection of embodiment and describe in order to provide the best to illustrate to principle of the present invention and practical application thereof, thereby make those of ordinary skills in various embodiments, use the present invention, and imagining and carry out various modifications for adapting to concrete application.When the extension of being authorized being made an explanation according to principle fair, legal, equality, all such modifications and changing all in accessory claim book of the present invention within the restricted portion.

Claims (21)

1. method of making filtering material said method comprising the steps of:

(a) provide first material, wherein said first material comprises a plurality of mesoporositys activated carbon filtration particle; With

(b) handle described first material to prepare second material, described second material comprises a plurality of mesoporositys activated carbon filtration particle, and described a plurality of mesoporositys activated carbon filtration particulate body oxygen weight percent of wherein said second material is less than about 5%.

2. the method for claim 1, wherein said treatment step (b) comprise described a plurality of mesoporositys activated carbon filtration particle are exposed under the temperature between about 600 ℃ and about 1,200 ℃.

3. the method for claim 1, described a plurality of mesoporositys activated carbon filtration particulate point of zero electric charge of wherein said second material is greater than about 6.

4. the method for claim 1, described a plurality of mesoporosity activated carbon filtration particulate redox potentials (ORP) of wherein said second material are less than about 400mV.

5. the method for claim 1, described a plurality of mesoporositys activated carbon filtration particulate body oxygen weight percent of wherein said second material is less than about 2%.

6. the method for claim 1, wherein said method also comprises inserting step (c), described inserting step (c) is made up of to filter housing the described a plurality of mesoporositys activated carbon filtration particle that inserts described second material, and described shell has water inlet and water out.

7. the method for claim 1, described a plurality of mesoporositys activated carbon filtration particulate BRI value of wherein said second material is greater than about 99%.

8. the method for claim 1, described a plurality of mesoporositys activated carbon filtration particulate VRI value of wherein said second material is greater than about 90%.

9. method of making filtering material said method comprising the steps of:

(a) provide first material, wherein said first material comprises a plurality of mesoporositys activated carbon filtration particle; With

(b) handle described first material to prepare second material, described second material comprises a plurality of mesoporositys activated carbon filtration particle, and described a plurality of mesoporositys activated carbon filtration particulate body oxygen weight percent of wherein said second material is less than about 2.3%.

10. method as claimed in claim 9, wherein said treatment step (b) comprises processing atmosphere, described processing atmosphere is selected from hydrogen, DA, carbon monoxide, argon, nitrogen, steam, helium and their mixture.

11. method as claimed in claim 9, wherein said treatment step (b) comprise the temperature between about 600 ℃ and about 1,200 ℃.

12. method as claimed in claim 9, wherein said treatment step (b) comprise the temperature between about 100 ℃ and about 800 ℃, and wherein said a plurality of mesoporositys activated carbon filtration particle comprises noble metal catalyst.

13. method as claimed in claim 9, described a plurality of mesoporositys activated carbon filtration particulate point of zero electric charge of wherein said second material is between about 9 and about 12.

14. method as claimed in claim 9, described a plurality of mesoporosity activated carbon filtration particulate redox potentials (ORP) of wherein said second material are between about 290mV and about 175mV.

15. method as claimed in claim 9, described a plurality of mesoporositys activated carbon filtration particulate body oxygen weight percent of wherein said second material is between about 1.2% and about 0.1%.

16. a method of making filtering material said method comprising the steps of:

(a) supply raw materials;

(b) handle described raw material to prepare first material, described first material comprises a plurality of mesoporositys activated carbon filtration particle; With

(c) handle described first material to prepare second material, described second material comprises a plurality of mesoporositys activated carbon filtration particle, and described a plurality of mesoporositys activated carbon filtration particulate body oxygen weight percent of wherein said second material is less than about 5%.

17. method as claimed in claim 16, wherein said raw material to small part comprises wooden basic particle, coal-based granular, mud coal base particle, asphaltic base particle, tar base particle, beans base particle, other wood fibre based particle and their mixture, wherein said treatment step (b) comprises described raw material is exposed under the temperature between about 300 ℃ and about 600 ℃, and wherein said treatment step (c) comprises that the described a plurality of mesoporositys activated carbon filtration particle with described first material is exposed under the temperature between 600 ℃ and about 1200 ℃.

18. method as claimed in claim 17, wherein said method also are included in described a plurality of mesoporositys activated carbon filtration particle that described treatment step (c) washs described first material before.

19. method as claimed in claim 18, wherein said treatment step (b) comprises and exposes about 1 hour of described raw material to about 3 hours time, and wherein said treatment step (c) comprises about 1 hour of the described a plurality of mesoporositys activated carbon filtration particle about 6 hours time extremely that exposes described first material.

20. method as claimed in claim 19, wherein said treatment step (b) comprise the existence of acid, described acid is selected from phosphoric acid, zinc chloride, ammonium phosphate and their mixture.

21. a method of making filtering material said method comprising the steps of:

(a) provide first material, wherein said first material comprises a plurality of mesoporositys activated carbon filtration particle; With

(b) handle described first material to prepare second material, described second material comprises a plurality of mesoporositys alkalescence activated carbon filtration particle, described a plurality of mesoporositys alkalescence activated carbon filtration particulate body oxygen weight percent of wherein said second material is less than about 2.3%, mesopore and macropore volume sum are greater than about 0.6mL/g, point of zero electric charge is greater than about 8, redox potential (ORP) is less than about 325mV, and the BRI value is greater than about 99.9%, and the VRI value is greater than about 99.99%.

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