CN1737068A - Black fluorescent ink - Google Patents

Black fluorescent ink Download PDF

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Publication number
CN1737068A
CN1737068A CN 200510043020 CN200510043020A CN1737068A CN 1737068 A CN1737068 A CN 1737068A CN 200510043020 CN200510043020 CN 200510043020 CN 200510043020 A CN200510043020 A CN 200510043020A CN 1737068 A CN1737068 A CN 1737068A
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China
Prior art keywords
modified
resin
oil
black
synolac
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CN 200510043020
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Chinese (zh)
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CN1317342C (en
Inventor
冯文
夏春
柴立新
陈勇
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China Banknote Printing and Minting Group Co Ltd
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China Banknote Printing and Minting Corp
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Priority to CNB2005100430208A priority Critical patent/CN1317342C/en
Publication of CN1737068A publication Critical patent/CN1737068A/en
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Abstract

The invention provides a black fluorescent ink which mainly comprises 5-50% of fluorescent material, 5-40% of black pigment, 1-40% of blue pigment, 10-60% of linking material, 0.1-40% of filler, 2-60% of adjuvant. The linking material is one or more of phenolic resin, alkyd resin, rosin ester, polyamide resin, acrylic resin and acrylic acid derivative.

Description

Black fluorescent ink
Technical field
The present invention relates to a kind of printing ink based on artificial resin.
Background technology
Fluorescent ink is to add fluorescent material in common ink, and it is false proof to be mainly used in print product, can present color fluorescence such as red, green, blue under ultraviolet lamp, is applicable to all kinds of Valued Securities, bill, product external packaging, trade mark, embellish and pressing.Present colourless or shades of colour under the existing fluorescent ink natural light, but still do not have the fluorescent ink application that outward appearance is a black, major cause is the black ink strong covering power, has the drawback of the coloured fluorescence of shielding, causes the unconspicuous shortcoming of fluorescence falsification preventing feature.
Summary of the invention
The object of the invention provide a kind of applicable to various mode of printings, have the black fluorescent ink of good antifalse effect, it has solved existing black ink strong covering power and has caused the unconspicuous shortcoming of fluorescence falsification preventing feature.
Technology of the present invention solves its scheme:
A kind of black fluorescent ink, its weight percent is formed and is comprised:
Fluorescent material 5～50%, mineral black 5～40%, blue pigment 1～40%,
Connect material 10～60%, auxiliary agent 2～60%.
The preferable weight percent of above-mentioned black fluorescent ink is formed and is comprised:
Fluorescent material 10～40%, mineral black 5～20%, blue pigment 1～20%,
Connect material 20～55%, auxiliary agent 3～45%.
The preferable weight percent of above-mentioned black fluorescent ink is formed and is comprised:
Fluorescent material 15～35%, mineral black 5～15%, blue pigment 1～8%,
Connect material 20～40%, auxiliary agent 3～30%.
Above-mentioned black fluorescent ink comprises that also weight percent is 0.1～40% stopping composition.
The preferable weight percent of above-mentioned black fluorescent ink is formed and also can be comprised:
Fluorescent material 10～40%, mineral black 5～20%, blue pigment 1～20%,
Connect material 20～55%, stopping composition 1～25%, auxiliary agent 3～45%.
The preferable weight percent of above-mentioned black fluorescent ink is formed and also can be comprised:
Fluorescent material 15～35%, mineral black 5～15%, blue pigment 1～8%,
Connect material 20～40%, stopping composition 4～22%, auxiliary agent 3～30%.
Above-mentioned low-melting ink vehicle is one or more in resol, Synolac, rosin ester, polyamide resin, gummy oil, acrylic resin and the acrylic acid derivative resin;
Above-mentioned auxiliary agent is that stand linseed oil, wax are removed one or more in stick, siccative, solvent, the tensio-active agent; Described stand linseed oil is the 6# stand linseed oil.
Above-mentioned stopping composition is colloid calcium, lime carbonate or aerosil.
Above-mentioned siccative comprises one or more in organic acid cobalt, manganese, zirconium, lead, aluminium, calcium, zinc, cerium, alum, the lanthanum salt;
Above-mentioned wax is removed stick and is comprised one or more of palm wax, fir wax, beeswax, insect wax, wool wax, paraffin, Microcrystalline Wax, montanin wax, ore deposit ceresine, polyethylene wax etc.;
Above-mentioned tensio-active agent comprises one or more in various anion surfactants, the nonionogenic tenside;
Above-mentioned solvent comprises one or more in the mixture, K20-295 solvent, water equal solvent of high-boiling point kerosene, 120# solvent oil, 200# solvent oil, 210# solvent oil, 320# solvent oil, S-82B solvent oil, C12 solvent, C13 solvent, C12 solvent and C13 solvent.
Above-mentioned resol is the Abietyl modified nonyl phenol and the rosin modified phenolic resin of formaldehyde condensation, or Abietyl modified diphenylol propane, the rosin modified phenolic resin of nonyl phenol and formaldehyde condensation, make through glycerine esterification with the rosin reaction again, or Abietyl modified xylenol glycerine resol, or Abietyl modified tetramethylolmethane resol, or the rosin modified phenolic resin of Abietyl modified phenol and formaldehyde condensation, or the rosin modified phenolic resin of Abietyl modified diphenylol propane and formaldehyde condensation, or the resol resin that in the presence of catalyzer, generates of diphenylol propane and formaldehyde, make through glycerine esterification with the rosin reaction again, or Abietyl modified xylenol glycerine resol, or Abietyl modified diphenylol propane tetramethylolmethane resol;
Above-mentioned Synolac is plant oil modified Synolac, rosin modified alkyd resin or rosin derivative modified alkyd resin; Above-mentioned plant oil modified Synolac is modification of flax oil glycerine one a phthalate anhydride Synolac, or modification of flax oil glycerine-isophthalic alkyd resin, or modification of flax oil glycerine-tetramethylolmethane-isophthalic alkyd resin, or modification of flax oil glycerine-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or modification of flax oil glycerine-TriMethylolPropane(TMP)-isophthalic alkyd resin, or modification of flax oil TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified glycerine one phthalate anhydride Synolac, or tung oil-modified glycerine-isophthalic alkyd resin, or tung oil-modified glycerine-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified glycerine-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or tung oil-modified glycerine-TriMethylolPropane(TMP)-isophthalic alkyd resin, or tung oil-modified TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or tung oil-modified TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or tung oil-modified TriMethylolPropane(TMP)-tetramethylolmethane-isophthalic alkyd resin;
Above-mentioned Gum Rosin is rosin and derivative ester thereof;
Above-mentioned polyamide resin is a lower molecular weight ethanol-soluble type polyamide resin, or high molecular is total to molten type polyamide resin;
Aforesaid propylene acid resin and acrylic acid derivative resin are epoxy acrylates, or acrylic acid modified polyester resin, or polyalcohol modified epoxy acrylic resin, or fatty acid modified epoxy acrylic resin, or epoxy soybean oil acrylic resin, or acrylated polyurethane resin, or polyether-modified acrylated polyurethane resin, or fatty acid modified acrylated polyurethane resin, or polyester acrylic urethane resin, or epoxy methacrylic resin, or polyalcohol modified epoxy methacrylic resin, or fatty acid modified epoxy methacrylic resin, or the epoxy soybean oil methacrylic resin, or the methacrylic acid urethane resin, or polyether-modified methacrylic acid urethane resin, or fatty acid modified methacrylic acid urethane resin, or polyester methacrylic acid urethane resin.
Advantage of the present invention is:
1, anti-counterfeiting characteristic is obvious.Black fluorescent ink of the present invention can present down fluorescent characteristicss such as red, green, blue look in long wave Ultraluminescence (365nm), compare with other coloured Antiforge fluorescent ink, has solved black to the covering of fluorescent characteristics, and fluorescent characteristics is obvious, has antiforge function.
2, false proof secret.Proportioning is proper between the fluorescent material of black fluorescent ink of the present invention and the pigment, and is identical with common tusche in appearance, but can present color fluorescence such as red, green, blue under ultraviolet lamp, and the printing ink fluorescent characteristics is obvious, and is false proof hidden, is easy to popular the discriminating.
3, be applicable to various mode of printings.The printability of black fluorescent ink of the present invention is good, is applicable to mode of printings such as offset printing, gravure, protruding seal, silk-screen and flexo.
4, printing quality is good.Black fluorescent ink outward appearance of the present invention is common black, adopts the usual manner printing, the fullness of shade unanimity.
Embodiment
The Different Weight per-cent of black fluorescent ink of the present invention is formed as shown in table 1:
Table 1
Black fluorescent glue printing ink Black fluorescence engraving intaglio printing ink Black fluorescence shadow is write gravure ink Black fluorescence letterpress printing ink Black fluorescence silk-screen ink Black fluorescence flexo printing ink
Fluorescent material 5-50 5-50 5-50 5-50 5-50 5-50
Mineral black 5-40 5-40 5-40 5-40 5-40 5-40
Blue pigment 5-40 5-40 5-40 5-40 5-40 5-40
Synolac 1-40 0-40 0-40 1-40 0-40 0-40
Resol 1-40 1-40 0-40 1-40 0-40 0-40
Urethane resin 0-40 0-40 0-40 0-40 0-40 0-40
Gummy oil 0-40 0-40 0-40 0-40 0-40 0-40
Rosin ester 0 0-40 0-40 0-40 0-40 0-40
Polyamide resin 0 0-40 0-40 0-40 0-40 0-40
Colloid calcium 1-40 0-40 0-40 0-40 0-40 0-40
Lime carbonate 0-40 1-40 0-40 0-40 0-40 0-40
Aerosil 0-40 0-40 0-40 0-40 0.1-40 0-40
Stand linseed oil 0.1-40 0-40 0-40 0-40 0-40 0-40
Wax is removed stick 0.1-40 0.1-40 0.1-40 1-40 0-40 0-40
Siccative 0.1-10 0.1-10 0-10 0.1-10 0-10 0-10
Solvent 0-40 1-40 0.1-40 0-40 0.1-40 0.1-40
Tensio-active agent 0 1-10 0 0 0 0
Add up to 100 100 100 100 100 100
The concrete weight percent of black fluorescent ink of the present invention is formed shown in table 2, table 3, table 4:
Table 2
Black fluorescent glue printing ink Black fluorescence engraving intaglio printing ink
Prescription 1 2 3 4 5 6 7 8 9 10
Fluorescent material 15 25 35 5 40 15 25 35 15 50
Mineral black 8 8 8 25 8 7 7 6 5 6
Blue pigment 2 2 2 20 5 1 1 1 10 2
Synolac 37 5 20 10 17 9
Resol 5 30 25 10 5 33 34 25 13 10
Urethane resin 6 8 12
Rosin ester
Gummy oil 5 10
Polyamide resin
The cellulose nitrate ester
Colloid calcium 20 5 5 15 15
Lime carbonate 22 7 4 40 14
Aerosil
Stand linseed oil 5 6 3 5 6
Wax is removed stick 2 2 1 5 1 5 5 5 5 5
Siccative 1 1 1 5 3 1 1 1 1 1
Solvent 9 6 9 10 6
Tensio-active agent 7 5 6 1 4
Add up to 100 100 100 100 100 100 100 100 100 100
Table 3
Black fluorescence shadow is write gravure ink Black fluorescence letterpress printing ink
Prescription 11 12 13 14 15 16 17 18 19 20
Fluorescent material 15 25 35 40 15 15 35 25 5 50
Mineral black 4 7 4 7 15 8 10 10 8 5
Blue pigment 1 1 1 1 4 2 2 2 1 20
Synolac 40 20 40 35 10
Resol 25 20 40 15 28 15 37 8
Urethane resin
Rosin ester 9 10 40
Gummy oil
Polyamide resin 10
The cellulose nitrate ester 13
Colloid calcium 15 5 10 5
Lime carbonate
Aerosil
Stand linseed oil
Wax is removed stick 1 1 1 2 1 4 4 2 3 1
Siccative 1 1 1 1 1
Solvent 45 37 29 10 25
Tensio-active agent
Add up to 100 100 100 100 100 100 100 100 100 100
Table 4
Black fluorescence silk-screen ink Black fluorescence flexo printing ink
Prescription 21 22 23 24 25 26 27 28 29 30
Fluorescent material 15 25 35 10 15 15 25 35 15 10
Mineral black 8 7 7 7 10 7 7 7 20 40
Blue pigment 1 1 1 40 5 1 1 1 5 15
Synolac
Resol 20
Urethane resin 20 20 5 28 18
Rosin ester 6
Gummy oil
Polyamide resin 20 25 30 15
The cellulose nitrate ester
Colloid calcium
Lime carbonate
Aerosil 6 5 5 3 5
Stand linseed oil
Wax is removed stick
Siccative
Solvent 50 36 32 20 60 49 42 27 42 20
Tensio-active agent
Add up to 100 100 100 100 100 100 100 100 100 100
Fluorescent material and pigment: used ultraviolet fluorescent material and pigment for printing ink among the present invention, fluorescent material wherein can be rare earth organic complex or have macromolecular pigment dyestuff of conjugated structure or inorganic fluorescent material.Pigment for printing ink can be pigment dyestuff and/or mineral dye.Proportioning is proper between fluorescent material and the pigment, and the printing ink fluorescent characteristics is obvious, is easy to identification.
The low-melting ink vehicle feature: the connection material in the printing ink can be by different forming according to different mode of printings, printable fabric etc., wherein resin is the main component that connects in the material, comprises resol, Synolac, rosin ester, polyamide resin, acrylic resin and acrylic acid derivative resin etc.
Siccative comprises the composite drying agent of one or more formation in organic acid cobalt, manganese, zirconium, lead, aluminium, calcium, zinc, cerium, alum, the lanthanum salt, for example 404 siccative etc.;
Wax is removed the blended wax that stick comprises one or more formation of palm wax, fir wax, beeswax, insect wax, wool wax, paraffin, Microcrystalline Wax, montanin wax, ore deposit ceresine, polyethylene wax etc.
Material therefor of the present invention is well known materials, and the printing industry those of ordinary skill can be obtained by commercial.
Black fluorescent ink of the present invention adopts basic black production technique, that is:
Ink formulations test and printing:
The concrete title material and the weight percent of black fluorescent glue printing ink (prescription 1) are as follows:
Fluorescent material 15%, mineral black 8%
Blue pigment 2%, Synolac 128%,
Synolac 29%, resol 5%,
Gummy oil 5%, colloid calcium 20%,
6# stand linseed oil 5%, blended wax 2%,
Composite drying agent 1%.
The concrete title material and the weight percent of black fluorescent glue printing ink (prescription 2) are as follows:
Fluorescent material 25%, mineral black 8%,
Blue pigment 2%, Synolac 5%,
Resol 30%, polyurethane resin 6%,
Gummy oil 10%, colloid calcium 5%,
6# stand linseed oil 6%, blended wax 2%,
Composite drying agent 1%.
The concrete title material and the weight percent of black fluorescent glue printing ink (prescription 3) are as follows:
Fluorescent material 35%, mineral black 8%,
Blue pigment 2%, Synolac 110%,
Synolac 2 10%, resol 25%,
Colloid calcium 5%, 6# stand linseed oil 3%,
Blended wax 1%, composite drying agent 1%.
The concrete title material and the weight percent of black fluorescent glue printing ink (prescription 4) are as follows:
Fluorescent material 5%, mineral black 25%
Blue pigment 20%, Synolac 15%,
Synolac 2 5%, resol 10%,
Colloid calcium 15%, 6# stand linseed oil 5%,
Blended wax 5%, composite drying agent 5%.
The concrete title material and the weight percent of black fluorescent glue printing ink (prescription 5) are as follows:
Fluorescent material 40%, mineral black 8%
Blue pigment 5%, Synolac 110%,
Synolac 27%, resol 5%,
Colloid calcium 15%, 6# stand linseed oil 6%,
Blended wax 1%, composite drying agent 3%.
Printing effect: high-speed offset press printing, speed are 8000～10000/hour, and the printing lines are smooth, and the site is full, do not fly China ink, emulsification, scumming and heap China ink phenomenon in the printing, and trace adheres to well.
Anti-counterfeiting performance is estimated: printing is common black under daylight, can present red, green, blue isochrome fluorescence under the irradiation under the 365nm UV-light.
The concrete title material and the weight percent of black fluorescence engraving intaglio printing ink (prescription 6) are as follows:
Fluorescent material 15%, mineral black 7%,
Blue pigment 1%, resol 115%,
Resol 2 18%, lime carbonate 22%,
Blended wax 5%, composite drying agent 1%,
210# solvent oil 9%, tensio-active agent 7%.
The concrete title material and the weight percent of black fluorescence engraving intaglio printing ink (prescription 7) are as follows:
Fluorescent material 25%, mineral black 7%,
Blue pigment 1%, Synolac 9%,
Resol 1 25%, resol 2 9%,
Lime carbonate 7%, blended wax 5%,
Composite drying agent 1%, 210# solvent oil 6%,
Tensio-active agent 5%.
The concrete title material and the weight percent of black fluorescence engraving intaglio printing ink (prescription 8) are as follows:
Fluorescent material 35%, mineral black 6%,
Blue pigment 1%, resol 1 15%,
Resol 2 10%, urethane resin 8%,
Lime carbonate 4%, blended wax 5%,
Composite drying agent 1%, 210# solvent oil 9%,
Tensio-active agent 6%.
The concrete title material and the weight percent of black fluorescence engraving intaglio printing ink (prescription 9) are as follows:
Fluorescent material 15%, mineral black 5%,
Blue pigment 10%, resol 1 10%,
Resol 2 3%, lime carbonate 40%,
Blended wax 5%, composite drying agent 1%,
210# solvent oil 10%, tensio-active agent 1%.
The concrete title material and the weight percent of black fluorescence engraving intaglio printing ink (prescription 10) are as follows:
Fluorescent material 50%, mineral black 6%,
Blue pigment 2%, resol 10%,
Urethane resin 12%, lime carbonate 14%,
Blended wax 5%, composite drying agent 1%,
210# solvent oil 6%, tensio-active agent 4%.
Printing effect: high speed carved gravure machine printing, speed is 4000～10000/hour, and the printing lines are smooth, and the site is full, does not fly China ink in the printing, wipes dirty, scumming and heap China ink phenomenon, and trace adheres to well.
Anti-counterfeiting performance is estimated: printing is common black under daylight, can present red, green, blue isochrome fluorescence under the irradiation under the 365nm UV-light.
It is as follows that black fluorescence shadow is write the concrete title material and the weight percent of gravure ink (prescription 11):
Fluorescent material 15%, mineral black 4%,
Blue pigment 1%, resol 25%,
Rosin ester 9%, blended wax 1%,
120# solvent oil 35%, 210# solvent oil 10%.
It is as follows that black fluorescence shadow is write the concrete title material and the weight percent of gravure ink (prescription 12):
Fluorescent material 25%, mineral black 7%,
Blue pigment 1%, polyamide resin 16%,
Cellulose nitrate ester 13%, blended wax 1%,
120# solvent oil 30%, 200# solvent oil 5%,
320# solvent oil 2%.
It is as follows that black fluorescence shadow is write the concrete title material and the weight percent of gravure ink (prescription 13):
Fluorescent material 35%, mineral black 4%,
Blue pigment 1%, resol 20%,
Rosin ester 10%, blended wax 1%,
120# solvent oil 20%, 210# solvent oil 5%,
S82B solvent oil 4%.
It is as follows that black fluorescence shadow is write the concrete title material and the weight percent of gravure ink (prescription 14):
Fluorescent material 40%, mineral black 7%,
Blue pigment 1%, rosin ester 40%,
Blended wax 2%, 120# solvent oil 5%,
210# solvent oil 5%.
It is as follows that black fluorescence shadow is write the concrete title material and the weight percent of gravure ink (prescription 15):
Fluorescent material 15%, mineral black 15%,
Blue pigment 4%, resol 40%,
Blended wax 1%, 120# solvent oil 15%,
210# solvent oil 10%.
Printing effect: shadow is write the intaglio printing press printing, speed be 100-150 rice/minute, the printing lines are smooth, the site is full, trace adheres to well.
Anti-counterfeiting performance is estimated: printing is common black under daylight, can present red, green, blue isochrome fluorescence under the irradiation under the 365nm UV-light.
The concrete title material and the weight percent of black fluorescence letterpress printing ink (prescription 16) are as follows:
Fluorescent material 15%, mineral black 8%,
Blue pigment 2%, Synolac 1 20%,
Synolac 2 20%, resol 15%,
Colloid calcium 15%, blended wax 4%,
404 siccative 1%.
The concrete title material and the weight percent of black fluorescence letterpress printing ink (prescription 17) are as follows:
Fluorescent material 35%, mineral black 10%,
Blue pigment 2%, Synolac 20%,
Resol 1 15%, resol 2 13%,
Blended wax 4%, composite drying agent 1%.
The concrete title material and the weight percent of black fluorescence letterpress printing ink (prescription 18) are as follows:
Fluorescent material 25%, mineral black 10%,
Blue pigment 2%, Synolac 1 15%,
Synolac 2 25%, resol 15%,
Colloid calcium 5%, blended wax 2%,
Composite drying agent 1%.
The concrete title material and the weight percent of black fluorescence letterpress printing ink (prescription 19) are as follows:
Fluorescent material 5%, mineral black 8%,
Blue pigment 1%, Synolac 1 20%,
Synolac 2 15%, resol 37%,
Colloid calcium 10%, blended wax 3%,
Composite drying agent 1%.
The concrete title material and the weight percent of black fluorescence letterpress printing ink (prescription 20) are as follows:
Fluorescent material 50%, mineral black 5%,
Blue pigment 20%, Synolac 10%,
Resol 8%, colloid calcium 5%,
Blended wax 1%, composite drying agent 1%.
Printing effect: embossing machine printing, speed are 4000～8000/hour, and the printing lines are smooth, and printing is planted and do not flown China ink, sticks with paste sign indicating number, shallow colored phenomenon, and trace adheres to well.
Anti-counterfeiting performance is estimated: printing is common black under daylight, can present red, green, blue isochrome fluorescence under the irradiation under the 365nm UV-light.
The concrete title material and the weight percent of black fluorescence silk screen printing ink (prescription 21) are as follows:
Fluorescent material 15%, mineral black 8%,
Blue pigment 1%, polyamide resin 1 15%,
Polyamide resin 2 5%, aerosil 6%,
120# solvent oil 35%, 210# solvent oil 10%,
320# solvent oil 5%.
The concrete title material and the weight percent of black fluorescence silk screen printing ink (prescription 22) are as follows:
Fluorescent material 25%, mineral black 7%,
Blue pigment 1%, resol 20%,
Rosin ester 6%, aerosil 5%,
120# solvent oil 25%, 210# solvent oil 8%,
320# solvent oil 3%.
The concrete title material and the weight percent of black fluorescence silk screen printing ink (prescription 23) are as follows:
Fluorescent material 35%, mineral black 7%,
Blue pigment 1%, polyamide resin 1 15%,
Polyamide resin 2 5%, aerosil 5%,
120# solvent oil 25%, 210# solvent oil 5%,
320# solvent oil 2%.
The concrete title material and the weight percent of black fluorescence silk screen printing ink (prescription 24) are as follows:
Fluorescent material 10%, mineral black 7%,
Blue pigment 40%, polyamide resin 1 10%,
Polyamide resin 2 10%, aerosil 3%,
120# solvent oil 10%, 210# solvent oil 5%,
320# solvent oil 5%.
The concrete title material and the weight percent of black fluorescence silk screen printing ink (prescription 25) are as follows:
Fluorescent material 15%, mineral black 10%,
Blue pigment 5%, polyamide resin 5%,
Aerosil 5%, 120# solvent oil 25%,
210# solvent oil 12%, 320# solvent oil 23%.
Printing effect: the printing of silk screen machine, speed is 2000～6000/hour, and the printing lines are smooth, and the site is full, does not fly China ink, scumming phenomenon in the printing, and trace adheres to well.
Anti-counterfeiting performance is estimated: printing is common black under daylight, can present red, green, blue isochrome fluorescence under the irradiation under the 365nm UV-light.
The concrete title material and the weight percent of black fluorescence flexo printing ink (prescription 26) are as follows:
Fluorescent material 15%, mineral black 7%,
Blue pigment 1%, polyamide resin 28%,
120# solvent oil 37%, 210# solvent oil 10%,
320# solvent oil 2%.
The concrete title material and the weight percent of black fluorescence flexo printing ink (prescription 27) are as follows:
Fluorescent material 25%, mineral black 7%,
Blue pigment 1%, polyamide resin 1 15%,
Polyamide resin 2 10%, 120# solvent oils 35%,
200# solvent oil 5%, 320# solvent oil 2%,
The concrete title material and the weight percent of black fluorescence flexo printing ink (prescription 28) are as follows:
Fluorescent material 35%, mineral black 7%,
Blue pigment 1%, polyamide resin 1 20%,
Polyamide resin 2 10%, 120# solvent oils 20%,
210# solvent oil 5%, S82B solvent oil 2%.
The concrete title material and the weight percent of black fluorescence flexo printing ink (prescription 29) are as follows:
Fluorescent material 15%, mineral black 20%,
Blue pigment 5%, polyamide resin 18%,
120# solvent oil 17%, 210# solvent oil 10%,
320# solvent oil 15%.
The concrete title material and the weight percent of black fluorescence flexo printing ink (prescription 30) are as follows:
Fluorescent material 10%, mineral black 40%,
Blue pigment 15%, polyamide resin 1 5%,
Polyamide resin 2 10%, 120# solvent oils 8%,
200# solvent oil 5%, 320# solvent oil 7%.
Printing effect: flexible printing press printing, speed are 6000～10000/hour, and the printing lines are smooth, and the site is full, do not fly China ink, scumming and heap China ink phenomenon in the printing, and trace adheres to well.
Anti-counterfeiting performance is estimated: printing is common black under daylight, can present red, green, blue isochrome fluorescence under the irradiation under the 365nm UV-light.

Claims (10)

1, a kind of black fluorescent ink is characterized in that: the weight percent of described black fluorescent ink is formed and is comprised:
Fluorescent material 5～50%, mineral black 5～40%,
Blue pigment 1～40% connects material 10～60%,
Auxiliary agent 2～60%.
2, black fluorescent ink according to claim 1 is characterized in that: the weight percent of described black fluorescent ink is formed and is comprised:
Fluorescent material 10～40%, mineral black 5～20%,
Blue pigment 1～20% connects material 20～55%,
Auxiliary agent 3～45%.
3, black fluorescent ink according to claim 1 is characterized in that: the weight percent of described black fluorescent ink is formed and is comprised:
Fluorescent material 15～35%, mineral black 5～15%,
Blue pigment 1～8% connects material 20～40%,
Auxiliary agent 3～30%.
4, black fluorescent ink according to claim 1 is characterized in that: described black fluorescent ink comprises that also weight percent is 0.1～40% stopping composition.
5, black fluorescent ink according to claim 4 is characterized in that: the weight percent of described black fluorescent ink is formed and is comprised:
Fluorescent material 10～40%, mineral black 5～20%,
Blue pigment 1～20% connects material 20～55%,
Stopping composition 1～25%, auxiliary agent 3～45%.
6, black fluorescent ink according to claim 4 is characterized in that: the weight percent of described black fluorescent ink is formed and is comprised:
Fluorescent material 15～35%, mineral black 5～15%,
Blue pigment 1～8% connects material 20～40%,
Stopping composition 4～22%, auxiliary agent 3～30%.
7, according to the described black fluorescent ink of arbitrary claim of claim 1 to 6, it is characterized in that:
Described low-melting ink vehicle is one or more in resol, Synolac, rosin ester, polyamide resin, gummy oil, acrylic resin and the acrylic acid derivative resin;
Described auxiliary agent is that stand linseed oil, wax are removed one or more in stick, siccative, solvent, the tensio-active agent; Described stand linseed oil is the 6# stand linseed oil.
8, according to claim 4 or 5 or 6 described black fluorescent inks, it is characterized in that:
Described stopping composition is colloid calcium, lime carbonate or aerosil.
9, black fluorescent ink according to claim 7 is characterized in that:
Described siccative comprises one or more in organic acid cobalt, manganese, zirconium, lead, aluminium, calcium, zinc, cerium, alum, the lanthanum salt;
Described wax is removed stick and is comprised one or more of palm wax, fir wax, beeswax, insect wax, wool wax, paraffin, Microcrystalline Wax, montanin wax, ore deposit ceresine, polyethylene wax etc.;
Described tensio-active agent comprises one or more in various anion surfactants, the nonionogenic tenside;
Described solvent comprises one or more in the mixture, K20-295 solvent, water equal solvent of high-boiling point kerosene, 120# solvent oil, 200# solvent oil, 210# solvent oil, 320# solvent oil, S-82B solvent oil, C12 solvent, C13 solvent, C12 solvent and C13 solvent.
10, black fluorescent ink according to claim 7 is characterized in that:
Described resol is the Abietyl modified nonyl phenol and the rosin modified phenolic resin of formaldehyde condensation, or Abietyl modified diphenylol propane, the rosin modified phenolic resin of nonyl phenol and formaldehyde condensation, make through glycerine esterification with the rosin reaction again, or Abietyl modified xylenol glycerine resol, or Abietyl modified tetramethylolmethane resol, or the rosin modified phenolic resin of Abietyl modified phenol and formaldehyde condensation, or the rosin modified phenolic resin of Abietyl modified diphenylol propane and formaldehyde condensation, or the resol resin that in the presence of catalyzer, generates of diphenylol propane and formaldehyde, make through glycerine esterification with the rosin reaction again, or Abietyl modified xylenol glycerine resol, or Abietyl modified diphenylol propane tetramethylolmethane resol;
Described Synolac is plant oil modified Synolac, rosin modified alkyd resin and rosin derivative modified alkyd resin; Described plant oil modified Synolac is modification of flax oil glycerine-phthalate anhydride Synolac, or modification of flax oil glycerine-isophthalic alkyd resin, or modification of flax oil glycerine-tetramethylolmethane-isophthalic alkyd resin, or industry sesame oil modified glycerol-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or modification of flax oil glycerine-TriMethylolPropane(TMP)-isophthalic alkyd resin, or modification of flax oil TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or modification of flax oil TriMethylolPropane(TMP)-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified glycerine-phthalate anhydride Synolac, or tung oil-modified glycerine-isophthalic alkyd resin, or tung oil-modified glycerine-tetramethylolmethane-isophthalic alkyd resin, or tung oil-modified glycerine-TriMethylolPropane(TMP)-phthalate anhydride Synolac, or tung oil-modified glycerine-TriMethylolPropane(TMP)-ask phthalic acid Synolac, or tung oil-modified TriMethylolPropane(TMP)-isophthalic anhydride Synolac, or tung oil-modified TriMethylolPropane(TMP)-tetramethylolmethane-phthalate anhydride Synolac, or tung oil-modified TriMethylolPropane(TMP)-tetramethylolmethane-ask phthalic acid Synolac;
Described Gum Rosin is rosin and derivative ester thereof;
Described polyamide resin is a lower molecular weight ethanol-soluble type polyamide resin, or high molecular is total to molten type polyamide resin;
Described acrylic resin and acrylic acid derivative resin are epoxy acrylates, or acrylic acid modified polyester resin, or polyalcohol modified epoxy acrylic resin, or fatty acid modified epoxy acrylic resin, or epoxy soybean oil acrylic resin, or acrylated polyurethane resin, or polyether-modified acrylated polyurethane resin, or fatty acid modified acrylated polyurethane resin, or polyester acrylic urethane resin, or epoxy methacrylic resin, or polyalcohol modified epoxy methacrylic resin, or fatty acid modified epoxy methacrylic resin, or the epoxy soybean oil methacrylic resin, or the methacrylic acid urethane resin, or polyether-modified methacrylic acid urethane resin, or fatty acid modified methacrylic acid urethane resin, or polyester methacrylic acid urethane resin.
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CN101665033B (en) * 2009-09-30 2011-06-22 焦作市卓立烫印材料有限公司 Anti-counterfeiting bar code printing thermal transfer ribbon and preparation method thereof
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US20200165038A1 (en) * 2017-08-17 2020-05-28 Sun Chemical Corporation Tamper-evident materials, adhesives, seals, and containers
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CN101665033B (en) * 2009-09-30 2011-06-22 焦作市卓立烫印材料有限公司 Anti-counterfeiting bar code printing thermal transfer ribbon and preparation method thereof
CN102184673A (en) * 2010-12-01 2011-09-14 中山国安火炬科技发展有限公司 Scrapable anti-counterfeit structure
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CN102837519A (en) * 2012-08-01 2012-12-26 广东乐佳印刷有限公司 Fluorescence anti-counterfeiting method for printed matter
CN103242709A (en) * 2013-05-24 2013-08-14 苏州凹凸彩印厂 Four-color gloss quick set offset ink and preparation method thereof
CN103666023A (en) * 2013-12-11 2014-03-26 苏州谊恒印务有限公司 Water-based letterpress ink
CN103666021A (en) * 2013-12-11 2014-03-26 苏州谊恒印务有限公司 Pure natural ink
CN104479453A (en) * 2014-12-18 2015-04-01 天津市云龙油墨股份有限公司 Tetra pack printing ink
CN104974597A (en) * 2015-07-23 2015-10-14 东莞市英科水墨有限公司 Water-based fluorescent ink
CN105058999A (en) * 2015-08-12 2015-11-18 河南卓立膜材料股份有限公司 Thermal transfer ribbon with night luminous function and preparation method thereof
CN105385237A (en) * 2015-12-28 2016-03-09 王璐 Environment-friendly silk-screen printing ink
CN105440800A (en) * 2015-12-28 2016-03-30 王璐 High-efficiency fluorescence ink
CN106243829A (en) * 2016-09-30 2016-12-21 广州元禄信息科技有限公司 A kind of High-performance ink for clothing popularity printing
CN106854395A (en) * 2016-12-26 2017-06-16 海宁市佳峰彩印包装有限公司 A kind of fastness high improves litho ink and preparation method thereof
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CN109021704A (en) * 2018-05-25 2018-12-18 安徽猛牛彩印包装有限公司 A kind of printing ink for the fluorescence falsification preventing performance that adhesive force is strong
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