CN1735465A - Coating line and process for forming a multilayer composite coating on a substrate - Google Patents
Coating line and process for forming a multilayer composite coating on a substrate Download PDFInfo
- Publication number
- CN1735465A CN1735465A CN 03803917 CN03803917A CN1735465A CN 1735465 A CN1735465 A CN 1735465A CN 03803917 CN03803917 CN 03803917 CN 03803917 A CN03803917 A CN 03803917A CN 1735465 A CN1735465 A CN 1735465A
- Authority
- CN
- China
- Prior art keywords
- coating composition
- priming coat
- coating
- substrate
- coat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 239000011248 coating agent Substances 0.000 title claims abstract description 343
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- 239000000203 mixture Substances 0.000 claims abstract description 276
- 238000004070 electrodeposition Methods 0.000 claims abstract description 129
- 238000000151 deposition Methods 0.000 claims abstract description 61
- 230000037452 priming Effects 0.000 claims description 333
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- 239000007787 solid Substances 0.000 claims description 42
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- JLZVTZOKUJLPGY-UHFFFAOYSA-K [O-]C(CC(CC([O-])=O)(C([O-])=O)O)=O.N.[Zr+4] Chemical compound [O-]C(CC(CC([O-])=O)(C([O-])=O)O)=O.N.[Zr+4] JLZVTZOKUJLPGY-UHFFFAOYSA-K 0.000 description 1
- RDCGLTNRGBOZTG-UHFFFAOYSA-M [O-]C(CO)=O.N.[Zr+4] Chemical compound [O-]C(CO)=O.N.[Zr+4] RDCGLTNRGBOZTG-UHFFFAOYSA-M 0.000 description 1
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 1
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- 238000003916 acid precipitation Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 125000002015 acyclic group Chemical group 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000002318 adhesion promoter Substances 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
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- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000002947 alkylene group Chemical group 0.000 description 1
- XPNGNIFUDRPBFJ-UHFFFAOYSA-N alpha-methylbenzylalcohol Natural products CC1=CC=CC=C1CO XPNGNIFUDRPBFJ-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000000908 ammonium hydroxide Substances 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
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- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
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- 239000012752 auxiliary agent Substances 0.000 description 1
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- CREXVNNSNOKDHW-UHFFFAOYSA-N azaniumylideneazanide Chemical group N[N] CREXVNNSNOKDHW-UHFFFAOYSA-N 0.000 description 1
- 229920005601 base polymer Polymers 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 235000019445 benzyl alcohol Nutrition 0.000 description 1
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- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000010974 bronze Substances 0.000 description 1
- MHHVLUQNBMCCAS-UHFFFAOYSA-N butyl prop-2-enoate;2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C.CCCCOC(=O)C=C MHHVLUQNBMCCAS-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- IUFBBBDTDAHZOQ-UHFFFAOYSA-N carbonic acid;zirconium Chemical compound [Zr].OC(O)=O IUFBBBDTDAHZOQ-UHFFFAOYSA-N 0.000 description 1
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- 235000019438 castor oil Nutrition 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
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- 238000002425 crystallisation Methods 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- HPXRVTGHNJAIIH-UHFFFAOYSA-N cyclohexanol Chemical compound OC1CCCCC1 HPXRVTGHNJAIIH-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
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- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
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- CYWSWQNTXBTMBA-UHFFFAOYSA-N ethyl 2-methylideneoctanoate Chemical compound CCCCCCC(=C)C(=O)OCC CYWSWQNTXBTMBA-UHFFFAOYSA-N 0.000 description 1
- 229940035423 ethyl ether Drugs 0.000 description 1
- 125000000219 ethylidene group Chemical group [H]C(=[*])C([H])([H])[H] 0.000 description 1
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- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- MSYLJRIXVZCQHW-UHFFFAOYSA-N formaldehyde;6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound O=C.NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 MSYLJRIXVZCQHW-UHFFFAOYSA-N 0.000 description 1
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- VPVSTMAPERLKKM-UHFFFAOYSA-N glycoluril Chemical compound N1C(=O)NC2NC(=O)NC21 VPVSTMAPERLKKM-UHFFFAOYSA-N 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 229910052735 hafnium Inorganic materials 0.000 description 1
- VBJZVLUMGGDVMO-UHFFFAOYSA-N hafnium atom Chemical compound [Hf] VBJZVLUMGGDVMO-UHFFFAOYSA-N 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 125000005842 heteroatom Chemical group 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
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- 150000002430 hydrocarbons Chemical class 0.000 description 1
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- VAKIVKMUBMZANL-UHFFFAOYSA-N iron phosphide Chemical compound P.[Fe].[Fe].[Fe] VAKIVKMUBMZANL-UHFFFAOYSA-N 0.000 description 1
- WTFXARWRTYJXII-UHFFFAOYSA-N iron(2+);iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[Fe+2].[Fe+3].[Fe+3] WTFXARWRTYJXII-UHFFFAOYSA-N 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 150000003951 lactams Chemical class 0.000 description 1
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- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
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- 150000002736 metal compounds Chemical class 0.000 description 1
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- 125000005641 methacryl group Chemical group 0.000 description 1
- 229940063557 methacrylate Drugs 0.000 description 1
- DCUFMVPCXCSVNP-UHFFFAOYSA-N methacrylic anhydride Chemical compound CC(=C)C(=O)OC(=O)C(C)=C DCUFMVPCXCSVNP-UHFFFAOYSA-N 0.000 description 1
- VPKDCDLSJZCGKE-UHFFFAOYSA-N methanediimine Chemical compound N=C=N VPKDCDLSJZCGKE-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
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- RCHKEJKUUXXBSM-UHFFFAOYSA-N n-benzyl-2-(3-formylindol-1-yl)acetamide Chemical compound C12=CC=CC=C2C(C=O)=CN1CC(=O)NCC1=CC=CC=C1 RCHKEJKUUXXBSM-UHFFFAOYSA-N 0.000 description 1
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- 230000007935 neutral effect Effects 0.000 description 1
- UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- IJZKJRUCRGJGKO-UHFFFAOYSA-N oxalic acid;zirconium Chemical compound [Zr].OC(=O)C(O)=O IJZKJRUCRGJGKO-UHFFFAOYSA-N 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 150000004714 phosphonium salts Chemical group 0.000 description 1
- 238000007539 photo-oxidation reaction Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 229920006009 resin backbone Polymers 0.000 description 1
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- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
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- 239000003784 tall oil Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 150000003866 tertiary ammonium salts Chemical class 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
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- 239000004408 titanium dioxide Substances 0.000 description 1
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- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical class [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 description 1
- 150000003755 zirconium compounds Chemical class 0.000 description 1
Landscapes
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
Description
Component: | Gross weight (gram) |
N-butoxy propyl alcohol | 15.00 |
The 1-octanol | 5.00 |
CYMEL 327 1 | 22.22 |
Phosphorylation epoxy resin 2 | 1.63 |
TINUVIN 1130 3 | 3.00 |
Deionized water | 10.00 |
Scentless petroleum solvent 4 | 8.00 |
Acrylic acid-polyester latex 5 | 41.07 |
Waterborne polyurethane resin 6 | 39.23 |
Titania slurry 7 | 148.76 |
The carbon black slurry 8 | 25.60 |
SETALUX 6802 AQ-24 9 | 118.75 |
Dimethylethanolamine 10 | 2.86 |
Deionized water | 37.56 |
20 ° of gloss | Dorigon DOI | The scanning of BYK ripple | Fischer microhardness N/mm 2 | The directed FF value of aluminium | ||
Long wave | Shortwave | |||||
Method 1 * | 90 | 90 | 2.2 | 13.9 | 145.7 | 1.65 |
Method 2 | 92 | 90 | 2.2 | 13.2 | 147.4 | 1.78 |
Wavelength (nm) | 300 | 350 | 400 | 450 | 500 |
Method 1 * | 0 | 0 | 2.03 | 3.01 | 3.06 |
Method 2 | 0 | 0 | 0 | 0 | 0 |
Component: | Gross weight (gram) |
N-butoxy propyl alcohol | 15.00 |
The 1-octanol | 5.00 |
CYMEL 327 | 22.22 |
The phosphorylation epoxy resin of embodiment A | 1.63 |
TINUVIN 1130 | 3.00 |
The scentless petroleum solvent of embodiment A | 8.00 |
Acrylic acid-the polyester latex of embodiment A | 74.53 |
The polyurethane resin of embodiment A | 0 |
The titania slurry of embodiment A | 148.76 |
The carbon black slurry of embodiment A | 25.60 |
SETALUX 6802 AQ-24 | 118.75 |
The dimethylethanolamine of embodiment A | 3.46 |
Deionized water | 63.51 |
Component: | Gross weight (gram) |
N-butoxy propyl alcohol | 15.00 |
The 1-octanol | 5.00 |
CYMEL 327 | 22.22 |
The phosphorylation epoxy resin of embodiment A | 1.63 |
TINUVIN 1130 | 3.00 |
The scentless petroleum solvent of embodiment A | 8.00 |
Acrylic acid-the polyester latex of embodiment A | 57.87 |
The polyurethane resin of embodiment A | 19.23 |
The titania slurry of embodiment A | 148.76 |
The carbon black slurry of embodiment A | 25.60 |
SETALUX 6802 AQ-24 | 118.75 |
The dimethylethanolamine of embodiment A | 3.32 |
Deionized water | 62.85 |
Component: | Gross weight (gram) |
N-butoxy propyl alcohol | 15.00 |
The 1-octanol | 5.00 |
CYMEL 327 | 22.22 |
The phosphorylation epoxy resin of embodiment A | 1.63 |
TINUVIN 1130 | 3.00 |
The scentless petroleum solvent of embodiment A | 8.00 |
Acrylic acid-the polyester latex of embodiment A | 41.20 |
The polyurethane resin of embodiment A | 38.46 |
The titania slurry of embodiment A | 148.76 |
The carbon black slurry of embodiment A | 25.60 |
SETALUX 6802 AQ-24 | 118.75 |
The dimethylethanolamine of embodiment A | 3.05 |
Deionized water | 66.03 |
Component: | Gross weight (gram) |
N-butoxy propyl alcohol | 15.00 |
The 1-octanol | 5.00 |
CYMEL 327 | 22.22 |
The phosphorylation epoxy resin of embodiment A | 1.63 |
TINUVIN 1130 | 3.00 |
The scentless petroleum solvent of embodiment A | 8.00 |
Acrylic acid-the polyester latex of embodiment A | 7.87 |
The polyurethane resin of embodiment A | 76.92 |
The titania slurry of embodiment A | 148.76 |
The carbon black slurry of embodiment A | 25.60 |
SETALUX 6802 AQ-24 | 118.75 |
The dimethylethanolamine of embodiment A | 2.31 |
Deionized water | 82.94 |
Primary coat embodiment | Method # | Film thickness (mils) | 20 ° of gloss | The scanning of BYK ripple | Cutting test b | |||
Primary coat | NHWB 300146 | TKU 1050AR | Long wave | Shortwave | ||||
B | 2 | 0.60 | 0.29 | 1.63 | 91 | 2.9 | 15.6 | 2 |
C | 2 | 0.64 | 0.30 | 1.63 | 90 | 2.6 | 16.0 | 2 |
D | 2 | 0.63 | 0.29 | 1.63 | 90 | 2.1 | 15.6 | 2 |
E | 2 | 0.63 | 0.28 | 1.63 | 89 | 3.2 | 15.4 | 2 |
-- | 3 a | -- | 0.67 | 1.63 | 92 | 3.5 | 18.0 | 2 |
Claims (80)
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US35652002P | 2002-02-13 | 2002-02-13 | |
US60/356,520 | 2002-02-13 | ||
US10/366,222 | 2003-02-13 |
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CN1735465A true CN1735465A (en) | 2006-02-15 |
CN100542691C CN100542691C (en) | 2009-09-23 |
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CNB038039176A Expired - Lifetime CN100542691C (en) | 2002-02-13 | 2003-02-13 | In substrate, form the paint line and the method for multi-layer composite coatings |
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CN (1) | CN100542691C (en) |
ES (1) | ES2358191T3 (en) |
Cited By (12)
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DE4438504A1 (en) * | 1994-10-28 | 1996-05-02 | Basf Lacke & Farben | Coating layer formulation for use in aqueous multi-layer coating systems |
EP0823289B1 (en) * | 1995-04-27 | 2002-09-25 | Kansai Paint Co., Limited | Method of multilayer coating |
DE19606716C1 (en) * | 1996-02-23 | 1997-08-14 | Herberts Gmbh | Process for multi-layer painting |
US6221441B1 (en) * | 1999-05-26 | 2001-04-24 | Ppg Industries Ohio, Inc. | Multi-stage processes for coating substrates with liquid basecoat and powder topcoat |
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2003
- 2003-02-13 CN CNB038039176A patent/CN100542691C/en not_active Expired - Lifetime
- 2003-02-13 ES ES03739774T patent/ES2358191T3/en not_active Expired - Lifetime
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Also Published As
Publication number | Publication date |
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CN100542691C (en) | 2009-09-23 |
ES2358191T3 (en) | 2011-05-06 |
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