CN1735396A - Composition for improving hair volume - Google Patents
Composition for improving hair volume Download PDFInfo
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- CN1735396A CN1735396A CN 02818794 CN02818794A CN1735396A CN 1735396 A CN1735396 A CN 1735396A CN 02818794 CN02818794 CN 02818794 CN 02818794 A CN02818794 A CN 02818794A CN 1735396 A CN1735396 A CN 1735396A
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Abstract
The compositions of the present disclosure relate to improved compositions for improving the appearance of volume in hair comprising a liquid carrier and particles having a mean particle size of less than about 300 microns; wherein, after treatment with the composition, the hair demonstrates a friction coefficient of from about 1 to about 2 and has a hair feel rating of at least about 8.
Description
Invention field
The present invention relates to improve the topical compositions of the outward appearance volume of hair.More particularly, the present invention relates to the compositions as shampoo, conditioner or approved product, said composition can be improved the volume of hair.
Background of invention
Often hear that the someone complains " bad one day of hair ".For different people, " bad hair " can be meant peace directly, too curling or just uncontrollable." straight hair " normally has the complaint that the people of thin, sparse hair sends.In order to obtain good hair volume, promptly tangible hair is huge, and these people expect that their hair has bigger volume and more substantial.The volume that many factor affecting hairs are arranged is with substantial: diameter of hair, the interaction between hair fiber, native configurations (type that curls, straight type, undaform), bending stifiness, hair density (number/cm
2), and hair length.
In order to increase hair volume, people use approved product to fix with the interaction between change fiber and the fiber and with the typing that their are created.This is especially true for Hairsetting gel and mousse product.When they were in wetting state on hair, gel and mousse product help promotion comb or brush were to the grasping of hair fiber and therefore help the creation Hairsetting.Exsiccant the time, forming polymeric bonds between the hair fiber He on the hair fiber surface.These keys help hair volume and typing fixing and that maintenance is created.In addition, the polymeric bonds that forms of approved product at hair by combing or destroyed when being brushed.Destructive key has jagged edge, and therefore the friction between its fortifying fibre also helps to keep hair volume and typing.Yet, can make hard in the trichoesthesia, sticking wet and/or be clamminess as these approved product.
Other technology that is used to increase the hair volume outward appearance comprises hair-waving, hair straightening, combing and extruding backward.These methods all pay attention to changing the character of people's hair matrix.Yet all these methods all can injure hair.Other effort that increases diameter of hair has obtained small results or has caused serious hair damages.Therefore, still need a kind of method that when improving hair volume, can keep good trichoesthesia.
Summary of the invention
The present invention relates to be used to improve the compositions of the outward appearance volume of hair, it comprises:
A) liquid-carrier,
B) has granule less than about 300 microns mean diameter;
Wherein, after described compositions-treated, described hair demonstrates about 1 to about 2 coefficient of friction and at least about 8 trichoesthesia grade.
The invention still further relates to the method for using said composition.
To those skilled in the art, by reading the disclosure of the specification, these and other feature of the present invention, aspect and advantage will become apparent.
Detailed Description Of The Invention
Though this description be believed by following explanation and can understand the present invention better by particularly pointing out and clearly claimed claim of the present invention is drawn a conclusion.
The present composition comprises liquid-carrier and has granule less than 300 microns mean diameter.Each of these solvents, and preferred or optional component describe in detail in back of the present invention.
Except as otherwise noted, all percentage ratio, umber and ratio are all in the gross weight of compositions of the present invention.All wt is based on content of active substance as being attached to ingredients listed, therefore, except as otherwise noted, does not comprise solvent or by-product in the material that may be included in commercially available acquisition.
Except as otherwise noted, the molecular weight that uses just like the present invention be weight average molecular weight, represent with gram/mole.
Herein, " comprise " and be meant and add other step of not influencing final result and other composition.This term comprise " by ... form " and " basically by ... composition ".The compositions and methods of the invention can comprise, by or form by neccessary composition and restrictive condition of the present invention and any additional or optional ingredients, component, step or described restrictive condition basically.
The term " (hollow) of hollow " that uses as the present invention is meant the granule with the zone of sealing, and described zone is substantially free of solid matter, and the zone of sealing accounts for 10% to 99.8% of granule cumulative volume.
The term " fluid (fluid) " that uses as the present invention is meant liquid or gas, and it is easy to exist with the shape of its container, and container is the wall of described flexible hollow particle.
The term " flexible (flexible) " that uses as the present invention is meant that hollow particle of the present invention is easy to compression, but described hollow particle will regain their initial volume when pressure descends.
The term " fluid of sealing (fluid-encapsulated) " that uses as the present invention is meant that hollow particle of the present invention structurally is a hollow.Even so, according to the present invention, term " structural hollow " also allows to comprise in the hollow particle at least a additional materials.
The term " permeable (permeable) " that uses as the present invention is meant the material that allows liquid or gas to pass through under specified criteria.
The term " polymer " (polymer) that the present invention uses " will comprise or material that the monomer polymerization of the monomer by a type or the monomer (that is copolymer) by two types or more kinds of types makes.
The term " spheroid (sphere) " that uses as the present invention is meant spherical body, and it is the point set at metric space, and these distances of putting fixing point are approximately constants.At this, " being similar to " is meant that described fixing point is in ± 15% distance.
Compositions or its component of so describing were suitable for use in human hair and scalp and contact skin as described in the term that uses as the present invention " was suitable for being applied to human hair (suitable for application tohuman hair) " and is meant does not have unsuitable toxicity, incompatibility, unstability, atopic reaction etc.
Be dissolved in the water of polymer in the present composition as described in the term " water miscible (water soluble) " that uses as the present invention is meant.Generally speaking, described polymer is under 25 ℃, in by the concentration of aqueous solvent weight 0.1%, preferred 1% concentration, more preferably 5% concentration, most preferably 15% concentration dissolving.
The list of references of all references is incorporated herein by reference.Quoting of any document is not to its approval as the availability of claimed prior art of the present invention.
A. liquid-carrier
The present composition typically is the form (under environmental condition) of dumpable liquid.Therefore, said composition typically comprises liquid-carrier, its preferably in by the weight of compositions about 20% to about 95%, preferred about 60% to about 85% content exists.Liquid-carrier is preferably aqueous.Aqueous carrier can comprise water, or water and organic solvent can miscible mixture, but preferably include the organic solvent of water and minimum or little concentration, except as other must or the microcomponent of optional components mix in the compositions concomitantly.
B. granule
The present composition comprises granule.The water insoluble solid granule of different shape and density is useful.In preferred embodiments, granule tends to have spherical, oval, irregular or any other shape, and wherein the ratio of full-size and minimum dimension (being defined as aspect ratio) is lower than 10.More preferably, particulate aspect ratio is lower than 8.Also more preferably, particulate aspect ratio is lower than 5.
Yet, found that aspect ratio also is useful greater than 10 granule, as long as they remain that accumulative granule piles up in being included in Aquo-composition the time or particulate piling up separately.Particulate non-limiting example like this is Laponite SCPX-2549 and Gelwhite H NF, derive from Southern ClayProducts Inc., Flamenco Ultra Silk 2500 and Timica Silkwhite 110W derive from Engelehard Corp..
Granule can be colored or colourless (for example white).Suitable powder comprises bismuth oxychloride, titanated mica, pyrogenic silica, spherical silicon dioxide, polyisobutylene acid methyl ester, the special fluorine human relations of micronization, boron nitride, acrylate polymer, aluminium silicate, starch ocentyl succinic aluminum, bentonite, calcium silicates, cellulose, Chalk, corn starch, kieselguhr, bleaching earth, glyceryl starch, Strese Hofmann's hectorite., Shionox, potter's clay, aluminosilicate magnesium, magnesium carbonate, magnesium hydroxide, magnesium oxide, magnesium silicate, magnesium trisilicate, maltodextrin, Montmorillonitum, microcrystalline Cellulose, rice starch, silicon dioxide, Talcum, Muscovitum, titanium dioxide, Dodecanoic acid, zinc salt, Grillocin P 176, zinc neodecanoate, zinc abietate, zinc stearate, polyethylene, Alumina, attapulgite, calcium carbonate, calcium silicates, dextran, potter's clay, nylon, silanized silica, the silkworm silk powder, sericite, Semen sojae atricolor powder, tin ash, titanium hydroxide, tricresyl phosphate magnesium, Endocarpium Juglandis powder and their mixture.Aforesaid powder can be used lecithin, aminoacid, mineral oil, silicone oil or various other reagent or ground surface processing alone or in combination, and its coating is in powder surface and make on the particle properties hydrophobic.
Powdery components also can comprise various organic and inorganic pigments.The normally various aromatics types of organic pigment comprise azo, indigo class, tritan., anthraquinone and xanthine dyestuff, and it is designated as D﹠amp; C and FD﹠amp; C indigo plant, palm fibre, green, orange, red, Huang etc.Organic pigment is made up of the insoluble metallic salt of certified color additives usually, is called the color lake.Inorganic pigment comprises ferrum oxide, ultramarine pigment and chromium or chromic oxide gel pigment and their mixture.
Useful in the present invention granule can be inorganic, synthetic or semisynthetic in compositions.Hybrid particles also is useful.Synthetic granule can be made by crosslinked or noncrosslinking macromolecule.Granule of the present invention can have surface charge or their surperficial available organic or inorganic material as for example surfactant, polymer and inorganic material-modified.The granule complex also is useful.
The embodiment of useful inorganic particle comprises various silica dioxide granules, comprising colloidal silica, pyrogenic silica, precipitated silica and silica gel.The non-limiting example of colloidal silica comprises Snowtex C, Snowtex O, Snowtex 50, Snowtex OL, Snowtex ZL, derive from Nissan Chemical America Corporation and derive from W.R.Grace ﹠amp with what trade name Ludox sold; The colloidal silica of Co.The non-limiting example of pyrogenic silica comprises deriving from Degussa Corp. and with trade name Cab-O-Sil, comprise that Cab-O-Sil M-5, HS-5, TS-530, TS-610 and TS-720 derive from those of Cabot Corp. with Aerosil 130, Aerosil 200, Aerosil 300, Aerosil R972 and AerosilR812 of hydrophilic and hydrophobic form.The non-limiting example of precipitated silica comprises those with hydrophilic and hydrophobic form, derives from Degussa Corp. trade name Sipernat, comprises Sipernat 350,360,22LS, 22S, 320,50S, D10, D11, D17 and C630; W.R.Grace ﹠amp; Co. those that those that sell with trade name Syloid, J.M.Huber Corp. are sold with trade name Zeothix and Zeodent and derive from those of Rhodia with trade name Tixosil.Also being useful on of the present invention is the spherical silicon dioxide of various particle diameters and porosity.The particulate non-limiting example of spherical silicon dioxide comprises MSS-500/H, MSS-500/3H, MSS-500, MSS-500/3, MSS-500/N and MSS-500/3N, derives from KOBO Products Inc.; Derive from Presperse Inc., trade name Spheron, comprise Spheron P-1500 and L-1500 those and derive from SunjinChemical Co., trade name Sunsil comprises Sunsil 20,20L, 20H, 50L, 50,50H, 130L, 130 and those of 130H.Other non-limiting example that is useful on inorganic particle of the present invention comprises various silicate, as derive from those of 3M, trade name CM-111 CosmeticMicrospheres, glass particle is as deriving from those of Nippon Paint Corp., trade name GlamurGloGlass Chips and PrizmaLite Glass Spheres; Talcum, Muscovitum, sericite and various natural and synthesis of clay comprise bentonite, Strese Hofmann's hectorite. and Montmorillonitum.
Synthetic particulate embodiment comprises nylon, silicone resin, poly-(methyl) acrylate, polyethylene, polyester, polypropylene, polystyrene, politef, polyurethane, polyamide, epoxy resin, urea resin and acrylic clear powder.Useful particulate non-limiting example is Microease 110S, 114S, 116 (micronization synthetic wax), Micropoly 210,250S (micronization polyethylene), Microslip (micronization politef), and Microsilk (combination of polyethylene and politef), all these derives from Micro Powder, Inc..Other embodiment comprises MP-2200, BPA-500 (polyisobutylene acid methyl ester), EA-209 (ethene/acrylic ester copolymer), SP-501 (PA-12), SP-10 (PA-12), ES-830 (polyisobutylene acid methyl ester), BPD-800, BPD-500, BPA-500 (polyurethane) and CL2080 (polyethylene) granule, derive from Kobo Products, Inc., polyethylene powders derives from QuantumChemical as those, trade name Microthene, comprise MN701, MN710, MN-714, MN-722 and FN5100 and those derive from Shamrock Technologies, Inc., trade name CeraPURE, the nylon granule is as deriving from those of ElfAtochem, trade name Orgasol, acrylate copolymer derives from Advanced Polymer Systems, trade name Microsponge and Polytrap, polytetrafluorethylepowder powder is as deriving from Shamrock Technologies, Inc. those, trade name FluoroPLURE and HydroPURE, with the silicone resin granule of GE Silicones, comprise Tospearl 105 with trade name Tospearl sale, 120,130,145,3120 and 240.Ganzpearl GS-0605 crosslinked polystyrene (deriving from Presperse) also is useful.
The non-limiting example of hybrid particles comprises Ganzpearl GSC-30SR (sericite and crosslinked polystyrene mixed-powder), SM-1000, SM-200 (Muscovitum and silicon dioxide mixed-powder, derive from Presperse) and FluroTOUCH 135C and 235C (polyethylene and politef, derive from Shamrock Technologies, Inc).
In one embodiment of the invention, the granule that is used for compositions is a hollow particle.In preferred embodiments, hollow particle is to have sealed fluidic flexible microsphere.This microsphere is a hollow on the structure, yet they also can comprise various fluids, and it comprises liquids and gases and their isomer.Gas includes but not limited to butane, pentane, air, nitrogen, oxygen, carbon dioxide and dimethyl ether.If be used, liquid only is partly to fill microsphere.Liquid comprises water and any compatible solvent.Liquid also can comprise vitamin, aminoacid, protein and protein derivatives, herbaceous plant extract, pigment, dyestuff, antimicrobial, chelating agen, UV absorbent, fluorescent whitening agent, silicone compounds, spice, normally water miscible wetting agent, normally water-insoluble additional conditioner and their mixture.In one embodiment, the material that is wrapped is preferably water-soluble component.In another embodiment, the material that is wrapped is preferably selected from the component of vitamin, aminoacid, albumen, protein derivatives, herbaceous plant extract and their mixture.In another embodiment, entrapped material is preferably selected from vitamin E, general benzyl ethyl ether, pantothenylol, Radix Polygoni Multiflori extract and their mixture.
Granule of the present invention can have surface charge or their surperficial available organic or inorganic material as for example surfactant, polymer and inorganic material-modified.Particle composites also is useful.The non-limiting example of the complex of the microsphere that gas is sealed is DSPCS-I2
TM(silica modified ethylene/methacrylate copolymer microsphere body) and SPCAT-I2
TM(ethylene of Talcum modification/methacrylate copolymer microsphere body).All derive from Kobo Products, Inc..
Particulate surface can be charged by the static development, perhaps with directly various or charged by the connection of short, long or the ionic group that branched alkyl group connects.Can be anionic, cationic, zwitterionic or amphoteric on the surface charge property.
The particulate wall of the present invention can be formed by thermoplastic.This thermoplastic can be to be selected from following at least a polymer of monomers or copolymer: acrylate, methacrylate, styrene, substituted phenylethylene, unsaturated dihalide, acrylonitrile, methacrylonitrile.This thermoplastic can comprise amide, ester, urethane, urea, ether, carbonic ester, acetal, sulfide, phosphate ester, phosphonate ester and siloxanes and be connected base.Hollow particle can comprise 1% to 60% derived from 1, the constitutional repeating unit of 1-dichloroethylene, the constitutional repeating unit of 20% to 90% derived from propylene nitrile and 1% to 50% constitutional repeating unit derived from (methyl) acrylic monomers, its percentage ratio and (by weight) equal 100.(methyl) acrylic monomers is, for example, and acrylic acid methyl ester. or methylmethacrylate, especially methylmethacrylate.Preferably, granule is made up of at least a polymer of monomers or the copolymer that is selected from vinylidene chloride expansion or non-expansion, acrylic acid, styrene and (methyl) acrylonitrile.More preferably, this granule is made up of the copolymer of acrylonitrile and methacrylonitrile.
Also can use by deriving from ester for example vinyl acetate or lactic acid vinyl acetate, or the acid for example polymer of itaconic acid, citraconic acid, maleic acid or fumaric acid and the granule that copolymer is formed.In this respect, referring to Japanese patent application JP-A-2-112304, its complete disclosure is introduced the present invention for your guidance.
The suitable particulate non-limiting example of commercially available acquisition is that (particle size range is that about 30 to 50 μ m and density are about 42kg/m to 551 DE
3), (particle size range is that about 15 to 25 μ m and density are about 60kg/m to 551 DE 20
3), (particle size range is that about 20 to 40 μ m and density are 60kg/m to 461 DE
3), (particle diameter is that about 50 to 80 μ m and density are about 42kg/m to 551 DE 80
3), (particle size range is that about 35 to 55 μ m and density are about 30kg/m to 091 DE
3), all these are all with trade mark EXPANCEL
TMSell by Akzo Nobel.Other is suitable for particulate embodiment of the present invention is with trade mark DUALITE
And MICROPEARL
TMThe series microsphere is sold, and derives from Pierce ﹠amp; Stevens Corporation.Especially preferred hollow particle is 091 DE and 551 DE 50.Hollow particle of the present invention or exist with exsiccant or hydrate state.Aforementioned particles is nontoxic and non-stimulated to skin.
Being useful on hollow particle of the present invention can pass through, and for example, is described in European patent EP-56,219, EP-348,372, EP-486,080, EP-320,473, EP-112,807 and United States Patent (USP) 3, method preparation in 615,972, the complete disclosure of each patent is introduced the present invention for your guidance.
Alternatively, the wall that is useful on hollow particle of the present invention can be formed by inorganic material.This inorganic material can be silicon dioxide, soda lime borosilicate glass, silicon dioxide-alumina porcelain or alkaline aluminosilicate pottery.The suitable low-density of commercially available acquisition, the non-limiting example of inorganic particle are H50/10,000 EPX (particle size range is about 20 to 60 μ m), S38 (particle size range is about 15 to 65 μ m), W-210 (particle size range is about 1 to 12 μ m), W-410 (particle size range is about 1 to 24 μ m), W-610 (particle size range is about 1 to 40 μ m), G-200 (particle size range is about 1 to 12 μ m), G-400 (particle size range is about 1 to 24 μ m), G-600 (particle size range is about 1 to 40 μ m), all these is with trade mark 3M
TMScotchlite
TMGlass Bubbles, 3M
TMZeeospheres
TMCeramic microspheres and 3M
TMZ-Light Spheres
TMCeramic microspheres is sold.Also Silica shells (mean diameter 3 μ m) usefully derives from KOBO Products, and LUXSIL
TM(3-13 μ m average diameter) derives from PQCorporation.
Preferably, the wall that is useful on hollow particle of the present invention is flexible." flexible " used in the present invention meaning is meant that hollow particle is easy to compression.Hollow particle will regain their initial volume when pressure descends.Flexible hollow particle can be under the pressure of using or the thermal expansion that causes owing to temperature change and the contraction shape that changes them.Therefore, granule may expand under heat effect.
Granule of the present invention can be permeable or impermeable." permeable " meaning of using as the present invention is meant that they allow liquid or gas to pass through under specified criteria.Preferably, most of granule will keep their structural intergrity among the present invention in the normal use of compositions.More preferably, all granules keep their structural intergrity in the normal use of compositions basically.
Preferred granule also will have physical property, the be not combined typical process appreciable impact of thing of described character.Preferably, fusing point is used greater than about 70 ℃ granule.Also more preferably, fusing point is used greater than 80 ℃ granule and more preferably, fusing point is used greater than about 95 ℃ granule.As used in the present invention, fusing point will be meant the temperature when granule is transformed into remarkable distortion of liquid or fluid state or generation or physical property change.In addition, many granules of the present invention are crosslinked or have crosslinked skin covering of the surface.These granules do not show clearly fusing point.As long as they are stable under processing that is used to make compositions and condition of storage, cross-linked particles also is useful.
Granule of the present invention preferably has 0.1 μ m or bigger particle diameter.More preferably, this granule has the particle diameter greater than about 0.5 μ m.In addition, granule of the present invention preferably has the particle diameter less than 300 μ m.More preferably, this granule has the particle diameter of diameter less than about 80 μ m.Also more preferably, granule is the about 1 μ m of diameter to about 70 μ m even more preferably about 2 μ m to about 65 μ m, also more preferably about 2 μ m are to about 60 μ m.
For the specific purposes of compositions, exemplary particles content is chosen.For example, when the color beneficial effect was sent in expectation, meeting the granules of pigments of expecting tone can be impregnated in.When expectation hair volume or typing during beneficial effect, the granule that can give friction can be used to reduce disintegrating and subsiding of Hairsetting.When conditioning or slide when being expectation, suitable platelet or spherical particle can be impregnated in.Grain type and content fix within technical staff's the technical ability really.Generally recognized as safe, list in C.T.F.A. cosmetic composition handbook, sixth version, Cosmetic and Fragrance Assn., Inc., the granule among the Washington D.C. (1995) can be used, and introduces the present invention for your guidance.
In the present composition, preferably mix by weight at least 0.025% granule, more preferably at least 0.1%, also more preferably at least 0.2% even more preferably at least 0.5% granule by weight.In compositions of the present invention, preferably mix no more than by weight about 20% granule, more preferably no more than about 10%, also more preferably no more than 5% even more preferably no more than by weight 2% granule.
Preferably, granule is not a pharmaceutically active substance.More preferably, granule is not the anti-dandruff active substance.
C. additional component
The present composition can comprise further that one or more become known for hair-care or personal care product's optional components, condition be this optional components and solvent of the present invention at physics and chemically compatible, or can suitably damage stability, aesthetic property or the performance of product.The independent concentration of such optional components can be by the weight of compositions about 0.001% to about 10%.
The non-limiting example that is used for the optional components of the present composition comprises cationic polymer, conditioner (hydrocarbon ils, aliphatic ester, siloxanes), dandruff removing agent, suspending agent, viscosity modifier, dyestuff, nonvolatile solvent or diluent (water miscible and insoluble), pearlescent additive, foam booster, additional surfactants or nonionic cosurfactant, pediculicide, the pH regulator agent, spice, antiseptic, chelating agen, protein, skin active agent, sunscreen, UV absorbent and vitamin.
Detersive surfactant
The present composition preferably includes detersive surfactant.Detersive surfactant is included to provide clean-up performance for described compositions.Described detersive surfactant comprises anionic detersive surfactant, amphion or amphoteric detersive surfactants or their compositions successively.Such surfactant should be at physics or chemically compatible with solvent described in the invention, or should not damage stability, aesthetic property or the performance of product inadequately.
The suitable anionic detersive surfactant component that is used for the present composition comprises those that become known for hair-care or other personal care cleansing compositions.The anion surfactant component should be enough to provide the cleaning and the foaming effect of expectation in the compositions, and is generally by the weight of compositions about 5% to about 50%, preferred about 8% to about 30%, more preferably from about 10% to about 25% even more preferably from about 12% to about 22%.
The anion surfactant that preferably is applicable to the present composition is alkyl and alkyl ether sulfate.These materials have expression formula ROSO separately
3M and RO (C
2H
4O)
xSO
3M, wherein R has about 8 alkyl or alkenyls to about 18 carbon atoms, and x is the integer with value of 1 to 10, and M is cation, as ammonium, alkanolamine, as triethylamine, univalent metal, as sodium and potassium, and multivalent metal cation, as magnesium and calcium.The dissolubility of surfactant will depend on specific anionic detersive surfactant and selected cation.
In alkyl and alkyl ether sulfate, preferred R has about 8 to about 18 carbon atoms, more preferably from about 10 to about 16 carbon atoms even more preferably from about 12 to about 14 carbon atoms.This alkyl ether sulfate typically can be used as oxirane and has the about 8 condensation product preparations to the monohydric alcohol of about 24 carbon atoms.Alcohol can be syntheticly maybe can derive from oils and fats, as Oleum Cocois, palm-kernel oil, Adeps Bovis seu Bubali.Lauryl alcohol is preferred with the straight chain alcohol that derives from Oleum Cocois or palm-kernel oil.Such alcohol and about 0 to about 10, preferred about 2 to reacting ethylene oxides about 5, more preferably from about 3 mol ratios, and the mixture of gained molecular species has about 3 moles of ethylene oxide of for example average every mol of alcohol by sulphation and neutralization.
The concrete non-limiting example that can be used for the alkyl ether sulfate of the present composition comprises the sodium salt and the ammonium salt of cocos nucifera oil alkyl 2,2'-ethylenedioxybis(ethanol). ether sulfate, tallow alkyl 2,2'-ethylenedioxybis(ethanol). ether sulfate and tallow alkyl six ethylene oxide sulfate.Highly preferred alkyl ether sulfate is those of mixture that comprise independent chemical compound, wherein the chemical compound in described mixture have about 10 to the mean alkyl chain of about 16 carbon atoms long and about 1 average degree of ethoxylation to about 4 moles of ethylene oxide.
Other suitable anionic detersive surfactant is to meet formula [R
1-SO
3-M] the water soluble salt of organic sulfur acid reaction product, R wherein
1Be to have about 8 to about 24 carbon atoms, preferred about 10 straight chain or side chain, saturated, aliphatic hydrocarbyls to about 18 carbon atoms; And M is the foregoing cation of the present invention.The non-limiting example of such detersive surfactant is the hydrocarbon of methane series, comprise have about 8 to about 24 carbon atoms, preferred about 12 dissidents to about 18 carbon atoms-, new-and just-paraffin hydrocarbon and sulfonating agent such as SO
3, H
2SO
4The salt of organic sulfur acid reaction product, described product is according to known method of sulfonating, comprises bleaching and hydrolysis acquisition.The sulfonated C of alkali metal and ammonium salt preferably
10-C
18Just-paraffin hydrocarbon.
Still with the isethionic acid esterification with the product of the neutral fatty acid of sodium hydroxide, wherein, for example, this fatty acid derives from Oleum Cocois or palm-kernel oil to other suitable anionic detersive surfactant; The sodium of the fatty acid amide of methylamino esilate or potassium salt, wherein, for example, this fatty acid derives from Oleum Cocois or palm-kernel oil.Other similar anion surfactant is described in United States Patent (USP) 2,486, and in 921,2,486,922 and 2,396,278, it is described and introduces the present invention for your guidance.
Other anionic detersive surfactant that is applicable to the present composition is a succinate, embodiment comprises N-disodium octadecyl sulfosuccinate, lauryl disodium sulfosuccinate, lauryl 2-Sulfosuccinic acid diammonium, N-(1,2-dicarboxyl ethyl)-N-octadecyl 2-Sulfosuccinic acid four sodium, the diamyl ester of sodium sulfosuccinate, the dihexyl ester of sodium sulfosuccinate; Dioctyl ester with sodium sulfosuccinate.
Other suitable anionic detersive surfactant comprises having about 10 alkene sulfonates to about 24 carbon atoms.In the context of the invention, term " alkene sulfonate " is meant the chemical compound that can obtain like this: use the sulfur trioxide that does not cooperate with the alpha-olefin sulfonation, in subsequently under like this condition and acidic reaction mixture, so that any sulfone that forms in reaction is hydrolyzed to obtain corresponding hydroxyl-alkanesulfonic acid ester salt.This sulfur trioxide can be a liquid, also can be gas, and usually but not necessarily with the inert diluent dilution, for example when using with liquid form, uses liquid SO
2, dilution such as chlorohydrocarbon, perhaps when using, with air, nitrogen, gas SO with gas form
2Deng dilution.By its alpha-olefin that obtains alkene sulfonate is to have about 10 to about 24 carbon atoms, preferred about 12 one-alkene to about 16 carbon atoms.Preferably, they are linear olefin.Except real olefine sulfonate and a part of hydroxyl-paraffin sulfonate, alkene sulfonate also can comprise other material of trace, as the olefine disulfonate, this depends on the ratio of reaction condition, reactant, character and the impurity in the olefin feedstock and the side reaction in the sulfonation process of olefin feedstock.The non-limiting example of such alpha-alkene sulfonate mixture is described in United States Patent (USP) 3,332, and in 880, the introduction of the present invention is for reference.
Another kind ofly be applicable to that the anionic detersive surfactant of compositions is β-oxyalkyl chain alkyl sulfonate.These surfactants meet following formula
R wherein
1Be to have about 6 straight chained alkyls, R to about 20 carbon atoms
2Be to have about 1 low alkyl group, and M is as the foregoing water-soluble cationic of the present invention to about 3 carbon atoms, preferred 1 carbon atom.
The preferred anionic surfactants detersive surfactant that is used for the present composition comprises ammonium lauryl sulfate; lauryl polyethenoxy ether sodium sulfate; the triethylamine lauryl sulfate; triethylamine laureth sulfate; the triethanolamine lauryl sulfate; triethanolamine laureth sulfate; the monoethanolamine lauryl sulfate; monoethanolamine laureth sulfate; the diethanolamine lauryl sulfate; diethanolamine laureth sulfate; lauryl monoglyceride sodium sulfate; sodium lauryl sulfate; sodium laureth sulfate; lauryl potassium sulfate; the laureth potassium sulfate; sodium lauryl sarcosinate; sodium lauroyl sarcosine; the lauryl sarcosine; the cocoyl sarcosine; cocoyl ammonium sulfate; lauroyl ammonium sulfate; cocoyl sodium sulfate; lauroyl sodium sulfate; the cocoyl potassium sulfate; lauryl potassium sulfate; the triethanolamine lauryl sulfate; the triethanolamine lauryl sulfate; monoethanolamine cocoyl sulfate; the monoethanolamine lauryl sulfate; the tridecyl benzene sulfonic acid sodium salt; dodecylbenzene sodium sulfonate and their combination.
The suitable both sexes or the zwitterionic detersive surfactants that are used for the present composition comprise those that become known for hair-care or other personal care cleansing.The concentration of such amphoteric detersive surfactants is preferably about 0.5% to about 20%, preferred about 1% to about 10% by the weight of compositions.The suitable amphion or the non-limiting example of amphoteric surfactant are described in United States Patent (USP) 5,104, and among 646 people such as () the Bolich Jr., 5,106,609 people such as () Bolich Jr., it is described and introduces the present invention for your guidance.
Be applicable to that the amphoteric detersive surfactants in the present composition is well known in this area, and comprise those surfactants of the derivant that is described to the secondary and tertiary amine of aliphatic series widely, wherein aliphatic group can be a straight or branched, and one of them aliphatic substituent group comprises about 8 to about 18 carbon atoms, and an aliphatic substituent group comprises the anionic water-soluble group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical and phosphonate radical.Be used for preferred amphoteric detersive surfactants of the present invention and comprise N-cocamidopropyl ethyl-N hydroxyethyl acetate (cocoamphoacetate), N-cocamidopropyl ethyl-N hydroxyethyl diacetin (cocoamphodiacetate), N-lauroyl amido ethyl-N hydroxyethyl acetate, N-lauroyl amido ethyl-N hydroxyethyl diacetin (lauroamphodiacetate) and their mixture.
The zwitterionic detersive surfactants that is applicable to the present composition is well known in this area, and comprise those surfactants of the derivant that is described to quaternary ammonium, bony, sulfonium compound widely, wherein aliphatic group can be a straight or branched, comprise about 8 to about 18 carbon atoms with one of them aliphatic substituent group, and one of them aliphatic substituent group comprises anionic group, as carboxyl, sulfonate radical, sulfate radical, phosphate radical or phosphonate radical.Zwitterionic compound such as betanin are preferred.
The present composition can further comprise additional surfactant, with the aforesaid anionic detersive surfactant combination of components of the present invention.Suitable option list surface-active agent comprises non-ionic surface active agent.Any such surfactant that is used for hair-care or personal care product known in the art can be used, condition is that this optional additional surfactants also is at chemistry or physically compatible with the solvent of the present composition, or can suitably damage performance, aesthetic property or the stability of product.The concentration of the optional additional surfactants in the present composition can change according to the other factors of knowing in the existence of other component in the product design of the cleaning of expectation or frothing capacity, selected option list surface-active agent, expectation, the compositions and this area.
The non-limiting example of other anion, amphion, amphoteric or optional additional surfactants is described in McCutcheon ' s, Emulsifiers and Detergents, 1989 yearbooks, M.C.Publishing Co. publishes and United States Patent (USP) 3,929,678,2,658,072,2,438,091,2, in 528,378, it is described and introduces the present invention for your guidance.
Deposition aid
The present composition comprises and is used for particulate deposition aid.Deposition aid is included to effectively strengthen the deposition of aforementioned particulate components.Deposition aid can comprise water-insoluble, water-dispersible, nonvolatile liquid, and it is formed on the emulsive liquid particles in the compositions, cationic deposition polymer or their compositions.This deposition aid should with solvent of the present invention at physics and chemically compatible, perhaps should not damage stability, aesthetic property or the performance of product inadequately.The concentration of the deposition aid in the compositions should be enough to effectively strengthen the deposition of grain fraction, typically is about 0.05% to about 5%, preferred about 0.075% to about 2.5%, more preferably from about 0.1% to about 1.0% by the weight of compositions.
1) water-insoluble non-volatile liquid
The suitable water-insoluble non-volatile liquid deposition aid that is used for the present composition is that those are generally siloxanes (for example silicone oil, cationic silicone, polysiloxanes natural gum, high refractive siloxanes and silicone resin), organic oil (for example hydrocarbon ils, polyolefin and aliphatic ester) or their compositions, or those water-insoluble on-liquid reagent, its in aqueous surfactant substrate of the present invention, form liquid, dispersed particles." nonvolatile " is meant that this liquid (i.e. 1 atmospheric pressure, 25 ℃) under environmental condition shows very low or do not have remarkable vapour pressure, as this area is understood.The nonvolatile oily mater of water-insoluble preferably has about 250 ℃ or higher boiling point under environmental condition." water-insoluble " is meant this oily liquids in 0.1% concentration, at 25 ℃ water insoluble (distillatory or equivalents) down.
When the nonvolatile liquid deposition auxiliary agent of water-insoluble is used to when of the present invention, a part, preferably all non-platelets particle stabilizedly are disperseed therein.The stable dispersions of non-platelet granule in the liquid deposition auxiliary agent of describing as the present invention normally equably non-platelet granule is mixed into the liquid deposition auxiliary agent and with major part non-platelet granule remain on liquid, in the dispersed particles, described granule is to be formed by the liquid deposition auxiliary agent when in the aqueous surfactant substrate that is mixed into the present composition.The acquisition of stable dispersion liquid can be by selecting suitable viscosity, solubility characteristics and the particle diameter of water-insoluble non-volatile liquid deposition aid; Select the particulate suitable surface character of non-platelet, surface modification and particle diameter; Using suitable dispersant or its to make up realizes.
When the liquid deposition auxiliary agent was used in the present composition, liquid deposition auxiliary agent and the particulate relative quantity of non-platelet should be able to be enough to allow the particulate dispersion of non-platelet at this, did not negatively influence the degree of volume beneficial effect but can high not attend the meeting.In the time of in being used to the present composition, based on nonvolatile liquid deposition auxiliary agent of the water-insoluble of weight and the particulate ratio of non-platelet be lower than about 3: 1, preferably be lower than about 1.5: 1, more preferably less than about 1: 1.The concentration of water-insoluble, the nonvolatile liquid deposition auxiliary agent in the compositions typically is about 0.05% to about 5%, preferred about 0.075% to about 2.5%, more preferably from about 0.1% to about 1.0% by the weight of compositions.
A. siloxanes (silicone)
The suitable water-insoluble of the present composition, water-dispersible, nonvolatile liquid deposition auxiliary agent comprise insoluble siloxanes.Siloxane particles can comprise volatile siloxane, non-volatile siloxane or their compositions.Non-volatile siloxane preferably.If there is volatile siloxane, it will be typically incidental application they as the non-volatile siloxane material composition of commercially available acquisition such as the solvent or the carrier of siloxanes natural gum and resin.Siloxane particles can comprise the polysiloxane fluid conditioner, and also can comprise other composition, as silicone resin to improve the polysiloxane fluid deposition properties or to strengthen hair luster (especially when high index of refraction (for example being higher than about 1.46) when siloxanes is used (for example high phenylating siloxanes).
Suitable siloxanes and the non-limiting example that is used for the optional suspending agent of this siloxanes are described in the U.S. again in issued patents 34,584, United States Patent (USP) 5,104,646 and the United States Patent (USP) 5,106,609, and it is described and introduces the present invention for your guidance.The siloxanes that is used for the present composition preferably have under 25 ℃, record about 10,000 to about 3,000,000 centistoke, more preferably from about 50,000 to about 2,000,000 centistoke even 100,000 viscosity more preferably from about to about 1,500,000 centistoke.
Dispersive siloxane particles typically has the number average particle diameter of about 0.01 μ m to about 50 μ m.For the granule that is coated on hair, the number average particle diameter typically is about 0.01 μ m to about 4 μ m, preferred about 0.01 μ m to about 2 μ m, more preferably from about 0.01 μ m is to about 0.5 μ m.For the larger particles that is coated on hair, the number average particle diameter is about 4 μ m to about 50 μ m, preferred about 6 μ m to about 30 μ m, more preferably from about 9 μ m are to about 20 μ m, most preferably from about 12 μ m are to about 18 μ m.The suitable particle diameter of dispersive siloxane particles will depend on the particulate amount of non-platelet and the type of use.Having the siloxane particles that mean diameter is lower than about 5 μ m can more effectively deposit on the hair.The conditioner that it is believed that small sized particles is comprised in the coacervate, and this layer is through the compositions dilution, forms between anion surfactant component (as mentioned above) and cationic polymer component (as described below).
About the background information of siloxanes, comprise the part that polysiloxane fluid, natural gum and resin and siloxanes manufacturing are discussed, can be referring to " Encyclopedia of Polymer Science and Engineering ", the 15th volume, second edition, 204-308 page or leaf, John Wiley ﹠amp; Sons among the Inc. (1989), introduces the present invention for your guidance.
I. silicone oil
Siloxanes fluids comprises silicone oil, and it is flowable silicone material, and its viscosity that records under 25 ℃ is less than 1,000,000 li of pond.The suitable silicone oil that is used for the present composition comprises poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane, polyether siloxane copolymer and their mixture.Other insoluble non-volatile polysiloxane fluid with hair-conditioning character also can be used.
Siloxanes comprises poly-alkyl or poly-aryl siloxanes, and it meets following formula (III):
Wherein R is an aliphatic group, and preferred alkyl or alkenyl, or aryl, R can be that replace or unsubstituted, and x is 1 to about 8,000 integer.The suitable R group that do not replace that is used for the present composition includes but not limited to aliphatic series and aryl that alkoxyl, aryloxy, alkaryl, aralkyl, aryl alkenyl, alkylamino and ether replace, that hydroxyl replaces replaces with halogen.The suitable R group also comprises cationic amine and quaternary ammonium group.
Aliphatic group or aryl at the siloxanes chain substitution can have any structure, as long as the gained siloxanes at room temperature keeps fluid, be hydrophobic, when being coated on hair, its nonirritant, avirulence, harmless with other component compatibility in the compositions, chemically are being stable under normal use and condition of storage, be insoluble in the present composition, and can be deposited on the hair and conditioning hair.Two R groups on the silicon atom of each monomer siloxane unit can be represented identical or different group.Preferably, two identical groups of R group representative.
Preferred alkyl and alkenyl substitutents are C
1-C
5Alkyl and alkenyl, more preferably C
1-C
4, C most preferably
1-C
2Other aliphatic series part that comprises the group (as alkoxyl, alkaryl and alkylamino) of alkyl, alkenyl or alkynyl can be a straight or branched, and preferred C
1-C
5, more preferably C
1-C
4, even more preferably C
1-C
3, C most preferably
1-C
2As discussed above, the R substituent group also can comprise functional group's (for example alkylamino), and it can be primary, the second month in a season or tertiary amine or quaternary ammonium.These groups comprise one, two and trialkyl amino and alkoxy amino, and wherein aliphatic part chain length preferably as mentioned above.The R substituent group also can be by for example halogen (for example chlorine, fluorine and bromine), halogenated aliphatic group or aryl, hydroxyl (for example aliphatic group of hydroxyl replacement) and their the mixture replacement of other group.Suitable halo R group can comprise, for example, and three halos (preferred three fluoro) alkyl, as-R
1CF
3, R wherein
1Be C
1-C
3Alkyl.The embodiment of such polysiloxanes includes but not limited to poly-methyl 3,3,3-trifluoropropyl siloxane.
The suitable R group that is used for the present composition includes but not limited to methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.The non-limiting example of preferred siloxanes comprises polydimethylsiloxane, poly-di-ethyl siloxane and PSI.Especially preferred is polydimethylsiloxane.Other suitable R group comprises methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Three R groups at siloxane blocking can be represented identical or different group.
The non-volatile poly-alkylsiloxane fluid that can be used comprises, for example the low-molecular-weight polydimethylsiloxane.These siloxanes can be available from the Viscasil R and SF 96 series of General Electric company, DC 200 series of Dow Corning company.The polyoxyethylene alkyl aryl radical siloxane fluid that can be used also comprises, for example PSI.These siloxanes can be available from the SF 1075 aminomethyl phenyl liquid of for example General ElectricCompany, perhaps available from 556 cosmetics-stage liquid of Dow Corning company.The polyether siloxane copolymer that can be used comprises, the polydimethylsiloxane of polypropylene oxide modification (for example Dow Corning DC-1248) for example is although the mixture of ethylene oxide or ethylene oxide and propylene oxide also can be used.The concentration of ethylene oxide and polypropylene oxide must enough be hanged down to prevent the dissolubility in the compositions of water and the present invention's description.
Be applicable to that siloxanes that the alkyl amino of the present composition replaces includes but not limited to meet those of following general formula (IV):
Wherein x and y are integers.This polymer is also referred to as " amino-terminated polydimethylsiloxane ".
Ii. cationic silicone
The cationic silicone liquid that is applicable to the present composition includes but not limited to those of general molecular formula (V):
(R
1)
aG
3-a-Si-(-OSiG
2)
n-(-OSiG
b(R
1)
2-b)
m-O-SiG
3-a(R
1)
a
Wherein be hydrogen, phenyl, hydroxyl or C
1-C
8Alkyl, preferable methyl; A is 0 or integer with value of 1 to 3, preferred 0; B is 0 or 1, preferred 1; N is 0 to 1,999 number, preferred 49 to 149; M is 1 to 2,000 integer, preferred 1 to 10; N and m and be 1 to 2,000 number, preferred 50 to 150; R
1Be general molecular formula C
qH
2qThe univalent perssad of L, wherein q is that integer and the L with value of 2 to 8 is selected from following groups:
-N(R
2)CH
2-CH
2-N(R
2)
2
-N(R
2)
2
-N(R
2)
3A
-
-N(R
2)CH
2-CH
2-NR
2H
2A
-
R wherein
2Be hydrogen, phenyl, benzyl or saturated hydrocarbyl, preferably about C
1To about C
20Alkyl, and A
-It is the halogen ion.
The cationic silicone of especially preferred corresponding formula V is the polymer that is called " trimethyl silyl ammonia is for polydimethylsiloxane ", and it is as shown in the formula shown in (VI):
Other siloxanes cationic polymer that can be used for the present composition is represented with general formula (VII):
R wherein
3Be C
1-C
18The monovalence alkyl, preferred alkyl or alkenyl are as methyl; R
4Be alkyl, preferred C
1-C
18Alkylidene or C
10-C
18Alkylene oxide group, more preferably C
1-C
8Alkylene oxide group; Q
-Be the halogen ion, preferred chloride ion; R is 2 to 20, preferred 2 to 8 average statistics value; S is 20 to 200, preferred 20 to 50 average statistics value.The preferred polymer of this class is called UCARE SILICONE ALE 56
TM, derive from Union Carbide.
Iii. siloxanes natural gum
The preferred polysiloxane fluid that is used for the present composition is undissolved polysiloxanes natural gum.These natural gum are polysiloxane materials, and it is more than or equal to 1,000,000 li of pond 25 ℃ of viscosity that record.Siloxanes natural gum is described in United States Patent (USP) 4,152,416; Noll and Walter, " chemistry of siloxanes and technology " (Chemistry and Technology of Silicones), New York: Academic Press (1968); In General Electric Silicone Rubber Product Data Sheets SE 30, SE 33, SE 54 and SE 76, all these introduces the present invention for your guidance.Siloxanes natural gum will typically have and surpass approximately 200,000, and preferred about 200,000 to about weight average molecular weight of 1,000,000.The non-limiting example of the concrete siloxanes natural gum that is used for the present composition comprises polydimethylsiloxane, (polydimethylsiloxane) (ethylene methacrylic radical siloxane) copolymer, poly-(dimethyl siloxane) (diphenyl siloxane) (ethylene methacrylic radical siloxane) copolymer and their mixture.
Iv. high index of refraction siloxanes
Other the non-volatile insoluble silicone fluid deposition auxiliary agent that is applicable to the present composition is to be called those of " high index of refraction siloxanes ", it has at least about 1.46, preferably at least about 1.48, more preferably at least about 1.52, most preferably at least about 1.55 refractive index.It is about 1.70 that the refractive index of polysiloxane fluid will be usually less than, and typically is lower than about 1.60.In this context, polysiloxanes " fluid " comprises oil and natural gum.
The high refractive index polysiloxanes fluid comprises those of as above general formula (III) expression, and cyclic polysiloxanes, those of following facial (VIII) expression:
Wherein R as defined above and n be about 3 to about 7 number, preferred about 3 to about 5.
The substituent amount of the R that comprises aryl that the high refractive index polysiloxanes fluid comprises is enough to improve refractive index to aforesaid aspiration level.In addition, R and n must be chosen so that this material is nonvolatile.
The substituent group that comprises aryl comprise comprise alicyclic and heterocyclic five yuan and hexa-atomic aromatic ring those and comprise those of condensed five yuan or hexatomic ring.Aryl rings itself can be substituted or unsubstituted.Substituent group comprises aliphatic substituent group, and also can comprise alkoxy substituent, acyl substituent, ketone, halogen (for example Cl and Br), amine etc.The embodiment that comprises the group of aryl includes but not limited to aromatic hydrocarbons that replace or unsubstituted, as phenyl and phenyl derivatives, as has C
1-C
5The phenyl of alkyl or alkenyl substitutents.Concrete non-limiting example comprises allyl phenyl, aminomethyl phenyl and ethylphenyl, ethenylphenyl (being styryl) and phenyl alkynes (phenyl C for example
2-C
4Alkynes).Heterocyclic aryl includes but not limited to the substituent group derived from furan, imidazoles, pyrroles, pyridine etc.The substituent embodiment of fused aromatic rings includes but not limited to naphthalene, coumarin and purine.
Usually, the high refractive index polysiloxanes fluid will have at least about 15%, preferably at least about 20%, more preferably at least about 25% in addition more preferably at least about 35%, most preferably at least about 50% the substituent group degree that comprises aryl.Typically, the aryl substitution value will be lower than about 90%, more generally be lower than about 85%, be preferably about 55% to about 80%.
The aryl that the high refractive index polysiloxanes fluid also has because of them replaces the high surfaces tension force that causes.Generally speaking, polysiloxane fluid will have at least about 24 dyne/cm
2Surface tension, typically at least about 27 dyne/cm
2Surface tension for the purpose at this, gets by de Nouy ring strain instrumentation according to the method for testing CTM of Dow Corning company 0461 (on November 23rd, 1971).Capillary change can record according to above-mentioned method of testing or according to ASTM Method D 1331.
Preferred high refractive index polysiloxanes fluid has phenyl or phenyl derivatives substituent group (most preferably phenyl) and alkyl substituent, preferred C
1-C
4Alkyl (most preferable), hydroxyl or C
1-C
4Alkyl amino (especially-R
1NHR
2The combination of NH2, wherein each R
1And R
2Be C independently
1-C
3Alkyl, alkenyl and/or alkoxyl).High refractive index polysiloxanes derives from Dow Corning, Huls America and GeneralElectric.
When the high index of refraction siloxanes is used to the present composition, they preferably use in the solution with spreading agent such as silicone resin or surfactant, improve the gloss (after the drying) of sprawling and therefore strengthening the hair of handling with said composition to reduce surface tension fully.Usually, the consumption of spreading agent be enough to the fluidic surface tension of high refractive index polysiloxanes reduce at least about 5%, preferably at least about 10%, more preferably at least about 15% in addition more preferably at least about 20%, most preferably at least about 25%.Polysiloxane fluid/spreading agent mixture can improve hair luster to capillary reduction.
Spreading agent also can preferably reduce surface tension at least about 2 dyne/cm
2, preferably at least about 3 dyne/cm
2, even more preferably at least about 4 dyne/cm
2, most preferably at least about 5 dyne/cm
2
With the ratio that exists in the final products, the mixture surface tension of polysiloxane fluid and spreading agent preferably is less than or equal to about 30 dyne/cm
2, be more preferably less than or equal about 28 dyne/cm
2, most preferably be less than or equal to about 25 dyne/cm
2Typically, surface tension will be about 15 dyne/cm
2To about 30 dyne/cm
2, about 18 dyne/cm more typically
2To about 28 dyne/cm
2, the most about 20 dyne/cm
2To about 25 dyne/cm
2
Usually, the weight rate of height arylation polysiloxane fluid and spreading agent will be about 1000: 1 to about 1: 1, preferred about 100: 1 to about 2: 1, more preferably from about 50: 1 to about 2: 1, most preferably from about 25: 1 to about 2: 1.When fluorizated surfactant was used, the especially high polysiloxane fluid and the ratio of spreading agent were because the effect of these surfactants can be effective.Therefore, can use the ratio that was significantly higher than 1000: 1 through imagination.
The polysiloxane fluid that is applicable to the present composition is disclosed in United States Patent (USP) 2,826,551, United States Patent (USP) 3,964,500, United States Patent (USP) 4,364,837, British patent 849,433, " silicon compound " (SiliconCompounds), Petrarch Systems, among the Inc. (1984), all these introduces the present invention for your guidance.
V. silicone resin
Silicone resin can be included in the siloxanes of the present composition.These resins are highly cross-linked polymer siloxane systems.Crosslinked is by introducing with four functionalized silanes and functional or two functional or two kinds of silane fusion trifunctional in making the process of silicone resin.This will be conspicuous for those of ordinary skill in the art, and obtaining the needed degree of cross linking of silicone resin will become according to the concrete silane unit that mixes silicone resin.Usually, have enough content trifunctional with four functional silane monomer unit (with therefore, enough levels crosslinked) silicone material, they become rigidity or hard film after drying like this, are considered to silicone resin.The ratio of oxygen atom and silicon atom is the index of crosslinked level in the particular silicone material.The silicone resin that is applicable to the present composition has each silicon atom usually at least about 1.1 oxygen atoms.Preferably, the ratio of oxygen and silicon atom was at least about 1.2: 1.0.The silane that is used to make silicone resin include but not limited to monomethyl-, dimethyl-, trimethyl-, a phenyl-, diphenyl-, aminomethyl phenyl-, a vinyl-and methyl ethylene-chlorosilane, and tetrachloro silicane, wherein the silane of methyl-replacement is the most frequent use.Preferred resin derives from General Electric with GE SS4230 and GE SS4267.The silicone resin of commercially available acquisition provides with dissolved form in the volatile or nonvolatile polysiloxane fluid of low viscosity usually.Being used for silicone resin of the present invention should be provided and mix this compositions with so dissolved form, and this will be conspicuous to those of ordinary skill in the art.
Especially silicone material and silicone resin can be called the shorthand naming system of " MDTQ " name according to those of ordinary skills are known and be pointed out easily.Under this system, represent polysiloxanes according to the various siloxanyl monomers unit of existing composition polysiloxanes.Briefly, symbol M is represented a functional unit (CH
3)
3SiO
0.5D represents two functional unit (CH
3)
2SiO; T represents trifunctional units (CH
3) SiO
1.5Represent four functional unit SiO with Q
2Substituent group outside elementary cell symbol (for example M ', D ', T ' and Q ') the expression methyl, and must define particularly in each appearance place.Typical alternately substituent group includes but not limited to group such as vinyl, phenyl, amine, hydroxyl etc.Each unitary mol ratio is perhaps represented the sum (or its average) of each type units in the polysiloxanes with the symbol subscript, perhaps ratio and the binding molecule scale with concrete expression shows, thereby finished the description to the polysiloxanes material according to the MDTQ system.The T of higher relative molecular weight, Q, T ' and/or Q ' are higher levels of crosslinked to D, D ', M and/or M ' indication in the silicone resin.Yet as discussed above, total crosslinked level also can be indicated by oxygen silicon ratio.
The preferred silicone resin that is used for the present composition includes but not limited to MQ, MT, MTQ, MDT and MDTQ resin.Methyl is preferred siloxanes substituent group.Especially preferred silicone resin is MQ resin, wherein M: the Q ratio is about 0.5: 1.0 to about 1.5: 1.0, and the mean molecule quantity of silicone resin is about 1000 to about 10,000.
The weight rate that refractive index is lower than 1.46 non-volatile polysiloxane fluid and silicone resin component (when using) is preferably about 4: 1 to about 400: 1, more preferably from about 9: 1 to about 200: 1, most preferably from about 19: 1 to about 100: 1, especially when the polysiloxane fluid component is the mixture of aforesaid polydimethylsiloxane fluid or polydimethylsiloxane fluid and polydimethylsiloxane natural gum.Because silicone resin forms and siloxanes fluids in the present composition, i.e. the part of the phase that the liquid deposition auxiliary agent is identical is in determining compositions during content of siloxane, in the summation of fluid and resin should be included in.
B. organic oil
Water-insoluble in the present composition, the dispersible non-volatile liquid deposition aid of water also can comprise at least a organic oil as deposition aid, and it can use separately or unite use with other deposition aid such as siloxanes (as mentioned above) or cationic deposition polymer (as described below).The organic oil that is suitable as deposition aid of the present invention is preferably high viscosity, water-insoluble liquid, and it is selected from hydrocarbon ils, polyolefin, aliphatic ester and their mixture.Preferably about 10,000 centipoises of so organic oil viscosity that record under 25 ℃ are to about 300 ten thousand centipoises, preferred about 50,000 centipoises to about 200 ten thousand centipoises, more preferably from about 100,000 to about 1.5 hundred ten thousand centipoises.
I. hydrocarbon ils
The organic oil that is suitable as the dispersible nonvolatile liquid deposition auxiliary agent of water-insoluble, water of the present composition includes but not limited to have the hydrocarbon ils at least about 10 carbon atoms, as cyclic hydrocarbon, linear aliphatic hydrocarbon (saturated or unsaturated) and branched aliphatic hydrocarbons (saturated or unsaturated), comprise polymer and their mixture.The straight chain hydrocarbon ils is preferably about C
12To about C
19The side chain hydrocarbon ils comprises hydrocarbon polymer, typically will comprise more than 19 carbon atoms.
The concrete non-limiting example of these hydrocarbon ils comprises paraffin oil, mineral oil, saturated and unsaturated dodecane, saturated and unsaturated tridecane, the saturated and unsaturated tetradecane, saturated and unsaturated pentadecane, saturated and unsaturated hexadecane, polybutene, poly decene and their mixture.The branched chain isomer of these chemical compounds and the hydrocarbon of more senior chain length also can be used, and embodiment comprises highly branched, saturated or undersaturated alkane, as the methyl substituted isomer of height, the for example high methyl substituted isomer of hexadecane and icosane is as 2,2,4,4,6,6,8,8-dimethyl-10-methyl hendecane and 2,2,4,4,6,6-dimethyl-8-methylnonane derives from Permethyl Corporation.Hydrocarbon polymer such as polybutene and poly decene.Preferred hydrocarbon polymer is a polybutene, for example the copolymer of isobutene. and butylene.The material of the commercially available acquisition of this class is the L-14 polybutene, derives from Amoco Chemical Corporation.
The ii polyolefin
The organic oil that is used for the present composition as deposition aid also can comprise liquid polyolefin, more preferably liquid poly alpha olefin, hydrogenant liquid poly-alpha-olefin most preferably.Be used for polyolefin of the present invention and pass through C
4To about C
14Olefinic monomer, preferably about C
6To about C
12Polymerization and prepare.
The non-limiting example that is used to prepare the present invention's polyolefinic olefinic monomer comprises ethylene, propylene, 1-butylene, 1-amylene, 1-hexene, 1-octene, 1-decene, 1-dodecylene, 1-tetradecylene, branched chain isomer such as 4-methyl-1-pentene and their mixture.What also be suitable for preparing polyolefin liquid is refinery's raw material or the emission that comprises alkene.Preferred hydrogenation 'alpha '-olefin monomers include but not limited to the 1-hexene to cetene, 1-octene to 1-tetradecylene and their mixture.The suitable embodiment of this class material of commercially available acquisition is PureSyn 1000 that derives from Exxon Mobil ChemicalCompany and the PureSyn 3000 with the PureSyn trade name.
The iii aliphatic ester
Other the suitable organic oil that is used for the present composition as deposition aid includes but not limited to have the aliphatic ester of at least 10 carbon atoms.These aliphatic esters comprise the ester that has derived from the hydrocarbyl chain of fatty acid or alcohol (for example monoesters, polyol ester and two and tricarboxylic ester).Can comprise or have the other compatible functional group of covalent bonding at this alkyl of aliphatic ester, as amide and alkoxyl part (for example ethyoxyl or ehter bond etc.).
What be suitable for the present composition is to have about C
10To about C
22The alkyl of the fatty acid of aliphatic chain and alkenyl ester and have C
10To about C
22Alkyl and/or derived from alkyl and the alkenyl aliphatic alcohol carboxylate and their mixture of the aliphatic chain of alkenols.The specific embodiment of preferred aliphatic ester includes but not limited to the isostearic acid isopropyl ester, lauric acid hexyl ester, lauric acid dissident ester, hexadecanoic acid dissident ester, the hexadecanoic acid isopropyl ester, decyl oleate, Ceraphyl 140A, the stearic acid cetyl ester, stearic acid ester in the last of the ten Heavenly stems, the isostearic acid isopropyl ester, adipic acid dihexyl ester in the last of the ten Heavenly stems, lactic acid lauryl ester, lactic acid tetradecane alcohol ester, lactic acid spermaceti alcohol ester, stearic acid oleyl alcohol ester, oleic acid oleic alcohol ester, tetradecanoic acid oleyl alcohol ester, acetic acid Laurel alcohol ester, propanoic acid spermaceti alcohol ester and adipic acid oleyl alcohol ester.
Other aliphatic ester that is applicable to the present composition is the monocarboxylic acid ester as general formula R ' COOR, and wherein R ' and R are alkyl or alkenyl, and the carbon atom sum is 10 at least among R ' and the R, preferably at least 20.The monocarboxylic acid ester needn't comprise at least one chain that at least 10 carbon atoms are arranged; And the sum of aliphatic chain carbon atom must be at least 10.The concrete non-limiting example of monocarboxylic acid ester comprises isopropyl myristate, glycol stearate and isopropyl laurate.
Other is applicable to that the aliphatic ester of the present composition still is two and trialkyl and the alkenyl ester of carboxylic acid, as C
4-C
8Dicarboxylic ester (for example succinic acid, 1,3-propanedicarboxylic acid, adipic acid, caproic acid, enanthic acid and sad C
1-C
22Ester, preferred C
1-C
6Ester).Two and the trialkyl of carboxylic acid and the concrete non-limiting example of alkenyl ester comprise stearyl stearic acid 2-Methylpentadecane alcohol ester, diisopropyl adipate and citric acid three stearic alcohol esters.
Other is applicable to that the aliphatic ester of the present composition is to be called those of polyol ester.Such polyol ester comprises alkylidene diol ester, as ethylene glycol one and di fatty acid ester, diethylene glycol one and di fatty acid ester, Polyethylene Glycol one and di fatty acid ester, propylene glycol one and di fatty acid ester, the polypropylene glycol monooleate, polypropylene glycol 2000 monostearates, ethoxylation propylene glycol monostearate, glycerol one and di fatty acid ester, polyglycereol polyglycerol fatty acid ester, the ethoxylated glycerol monostearate, 1,3-butanediol monostearate, the 1,3 butylene glycol distearate, the polyoxyethylene polyols fatty acid ester, sorbitan fatty acid esters and polyoxyethylene sorbitan fatty acid esters.
Aliphatic ester or glyceride that other is applicable to the present composition include but not limited to monoglyceride, diglyceride and triglyceride, preferably glycerine diester and triglyceride, triglyceride most preferably.For the use in compositions of the present invention, glyceride is preferably long-chain carboxylic acid such as C
10-C
22The monoglyceride of carboxylic acid, diglyceride and triglyceride.From plant and animal fat and oily, for example Semen Ricini oil, safflower oil, Oleum Gossypii semen, Semen Maydis oil, olive oil, cod liver oil, almond oil, American Avocado Tree oil, Petiolus Trachycarpi oil, Oleum sesami, lanoline and Oleum Glycines can obtain this material.Artificial oil includes but not limited to triolein and three stearic acid glyceryl dilaurates.
Other aliphatic ester that is applicable to the present composition is a water-insoluble synthctic fat family ester.Some preferably synthetic esters meet following general formula (IX):
R wherein
1Be C
7-C
9Alkyl, alkenyl, hydroxy alkyl or hydroxyl alkenyl, preferred saturated alkyl, alkyl more preferably saturated, straight chain; N is the positive integer with value of 2 to 4, preferred 3; And Y is the alkyl or the alkenyl of alkyl, alkenyl, hydroxyl or carboxyl substituted, and it has about 2 to about 20 carbon atoms, and preferred about 3 to about 14 carbon atoms.Other preferably synthetic ester meets following general formula (X):
R wherein
2Be C
8-C
10Alkyl, alkenyl, hydroxy alkyl or hydroxyl alkenyl; Preferred saturated alkyl, more preferably saturated, straight chained alkyl; N and Y formula (X) as above defines.
The concrete non-limiting example that is used for the suitable synthctic fat family ester of the present composition as deposition aid comprises with trade name PureSyn and derives from those of Exxon Mobil Chemical Company, as PureSyn ME100 and PureSyn ME450.
2. cationic polymer
The present composition can comprise organic cationic polymer as particulate deposition aid, and it can use separately or combine with aforesaid water-insoluble, the dispersible non-volatile liquid deposition aid of water.The concentration of cationic polymer typically is by the weight of compositions about 0.05% to about 3%, preferred about 0.075% to about 2.0%, more preferably from about 0.1% to about 1.0% in the compositions.The cationic charge density that suitable cationic polymers has, under the pH of the compositions that desire is used, be at least about 0.4meq/gm, preferably at least about 0.9meq/gm, more preferably at least about 1.2meq/gm, more preferably at least about 1.5meq/gm in addition more preferably at least about 1.7meq/gm, also more preferably at least about 1.9meq/gm, but also preferably be lower than about 7meq/gm, more preferably less than about 5meq/gm even more preferably less than about 4.5meq/gm, wherein the pH of the compositions of desire use normally is extremely about pH9 of about pH3, and preferably about pH4 is to about pH8.The term " cationic charge density " that uses as the present invention be meant positive changes on the monomeric unit of forming polymer and as described in the ratio of molecular weight of monomeric unit.Cationic charge density multiply by polymer molecular weight and has determined positive charge positional number on given polymer chain.The mean molecule quantity of such suitable cationic polymers will be generally between about 10,000 and 1,000 ten thousand, preferably between about 50,000 and about 500 ten thousand, more preferably between about 100,000 and about 300 ten thousand.
The mean molecule quantity of such suitable cationic polymers will be generally between about 10,000 and 1,000 ten thousand, preferably between about 50,000 and about 500 ten thousand, more preferably between about 100,000 and about 300 ten thousand.
The suitable cationic polymers that is used for the present composition comprises the cation nitrogen moiety, as quaternary ammonium or the protonated amino part of cation.The protonated amino of cation can be primary, the second month in a season or tertiary amine (the preferred second month in a season or uncle), depends on the particular types and the selected pH of compositions.Any anionic counter ion can be united use with cationic polymer, as long as this polymer in the solvent that keeps dissolving at the coacervate of water, compositions or compositions in mutually and need only this counter ion and compositions at physics with chemically be compatible or can suitably damage properties of product, stability or aesthetic property.The non-limiting example of such counter ion comprises halide ion (for example chloride ion, fluorion, bromide ion, iodide ion), sulfate radical and methylsulfate.
The cation nitrogen moiety of cationic polymer is present in all as substituent group usually, or typically, is present on some monomeric units.Therefore, the cationic polymer that is used for the present composition comprises the homopolymer, copolymer, terpolymer of the monomeric unit (the non-cationic monomer that randomly is called spacer monomers with the present invention) that quaternary ammonium or cation amino replace etc.The non-limiting example of such polymer is described in CTFA Cosmetic Ingredient Dictionary, the third edition, Estrin, Crosley and Haynes compile (CTFA, Washington, D.C. (1982)) in, it is described and introduces the present invention for your guidance.
The non-limiting example of suitable cationic polymers comprises vinyl monomer and water solublity spacer monomers such as acrylamide, MAAm, alkyl and dialkyl group acrylamide, alkyl and dialkyl group MAAm, alkyl acrylate, methacrylate Arrcostab, vinyl caprolactone or the vinylpyrrolidone copolymers with cation protonated amines or quaternary ammonium functional group.The monomer that alkyl and dialkyl group replace preferably has C
1-C
7Alkyl, more preferably C
1-C
3Alkyl.Other suitable interval monomer comprises vinyl esters, vinyl alcohol (being made by the polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.
The protonated amino of suitable cation and the quaternary ammonium monomer that are used for being included in the cationic polymer of the present composition comprise by propenoic acid dialkyl aminoalkyl ester, the methacrylate dialkyl aminoalkyl ester, acrylic acid one alkylaminoalkyl, methacrylate one alkylaminoalkyl, trialkyl isobutene. acyl-oxygen base alkylammonium salt, trialkyl acryloxyalkyl ammonium salt, the vinyl compound that the diallyl quaternary ammonium salt replaces, with have cationic azo-cycle such as the pyridine of containing of ring-type, the vinyl quaternary ammonium monomer of imidazoles and quaternized ketopyrrolidine, for example alkyl vinyl imidazoles, alkylvinylpyridines, alkyl vinyl ketopyrrolidine salt.These monomeric moieties are low alkyl group preferably, as C
1, C
2Or C
3Alkyl.
Be applicable to that the vinyl monomer that amine of the present invention replaces comprises propenoic acid dialkyl aminoalkyl ester, methacrylate dialkyl aminoalkyl ester, dialkyl aminoalkyl acrylamide and dialkyl aminoalkyl MAAm, wherein this alkyl group is preferably C
1-C
7Alkyl, C more preferably
1-C
3Alkyl.
Other suitable cationic polymers that is used for the present composition comprises the copolymer (referring to the Polyquaternium-16 of the CTFA of industrial quarters) of l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (for example hydrochlorate), can trade name LUVIQUAT (for example LUVIQUAT FC370 and FC 905) commercially available as those from BASF Wyandotte Corp (Parsippany, N.J., USA); The copolymer of l-vinyl-2-pyrrolidone and methacrylate dimethylamino ethyl ester (referring to the Polyquaternium-11 among the CTFA of industrial quarters) derives from Gaf Corporation (Wayne as being purchased with trade name GAFQUAT (for example GAFQUAT 755N), N.J., USA) those; The polymer that comprises cation diallyl quaternary ammonium salt, comprise, the copolymer of dimethyl diallyl ammonium chloride homopolymer, acrylamide and dimethyl diallyl ammonium chloride (respectively referring to Polyquaternium among the CTFA of industrial quarters 6 and Polyquaternium 7) for example, as deriving from CalgonCorp. ((Pittsburgh with trade name MERQUAT, Pa., those of Merquat 100 USA) and Merquat 550; Amphoteric acrylic copolymer, comprise acrylic acid and dimethyl diallyl ammonium chloride copolymer (referring to the Polyquaternium among the CTFA of industrial quarters 22) as deriving from Calgon Corp. with trade name Merquat (for example Merquat 280 and 295), the terpolymer of acrylic acid and dimethyl diallyl ammonium chloride and acrylamide (referring to the Polyquaternium among the CTFA of industrial quarters 39) is as deriving from Calgon Corp. with trade name Merquat (for example Merquat 3300 and 3331).Terpolymer (referring to the Polyquaternium among the CTFA of industrial quarters 47) with acrylic acid and amino trimethyl ammonium chloride of methacryloyl and methacrylate hydrochlorate derives from Calgon Corp with trade name Merquat (for example Merquat 2001).The monomer that preferred cation replaces is dialkyl aminoalkyl acrylamide, dialkyl aminoalkyl MAAm and the compositions thereof that cation replaces.These preferred monomers meet following formula.
R wherein
1Be hydrogen, methyl or ethyl; Each R
2, R
3And R
4Independently for hydrogen or have about 1 to about 8 carbon atoms, preferred about 1 to about 5 carbon atoms, 1 short-chain alkyl more preferably from about to about 2 carbon atoms; N has about 1 to about 8, the integer of preferred about 1 to about 4 value; X is a counter ion.Be connected in R
2, R
3And R
4Nitrogen can be protonated amine (primary, the second month in a season or uncle), but preferably quaternary ammonium, wherein each R
2, R
3And R
4Be alkyl, its non-limiting example is a polyisobutylene acylamino-oxypropyl trimethyl ammonium chloride, derives from Rhone-Poulenc with trade name Polycare 133, Cranberry, N.J., U.S.A..
Other suitable cationic polymers that is used for compositions comprises polysaccharide polymer, as cationic cellulose derivative and cationic starch derivative.Suitable cationic polysaccharide polymer comprises those that meet following formula:
Wherein A is the anhydroglucose residue, as starch or cellulose anhydroglucose residue; R is alkylidene oxyalkylene, polyoxyalkylene or hydroxyl alkylidene or their compositions; R1, R2 and R3 are alkyl, aryl, alkylaryl, aryl alkyl, alkoxyalkyl or alkoxy aryl independently, each group comprises and is up to about 18 carbon atoms, and the total number of carbon atoms of each cationic moiety (being carbon number sum among R1, R2 and the R3) is preferably about 20 or still less; And X is an anionic counter ion mentioned above.
The preferred cation cellulosic polymer be hydroxyethyl-cellulose and leptodactyline substituted epoxide react salt, Polyquaternium 10 referring to industrial quarters (CTFA), PolymerLR, JR and KG series polymer with them derive from Amerchol Corp. (Edison, N.J., USA).The cationic cellulose of the type that other is suitable comprises the polymer quaternary ammonium salt of the epoxide that hydroxyethyl-cellulose and lauryl dimethyl ammonium salt replace, referring to the Polyquaternium 24 of industrial quarters (CTFA).These materials derive from Amerchol Corp. with trade name Polymer LM-200.
Other cationic polymer comprises the cationic guar gum derivant, as guar hydroxypropyl trimonium chloride, its specific embodiment comprises Jaguar series, commercially available from Rhone-Poulenc Incorporated and N-Hance series, commercially available from Hercules, the Aqualon Division of Inc..Any anionic counter ion can be used in combination with cationic guar gum, as long as that cationic guar gum keeps is water-soluble, be dissolved in the shampoo compositions or be dissolved in coacervate phase in the shampoo compositions, with if counter ion physics with chemically perhaps can suitably damage properties of product, stability or aesthetic property mutually with the solvent of compositions.Such counter ion ground non-limiting example comprises halogen ion (for example chloride ion, fluorion, bromide ion, iodide ion), sulfate radical, methylsulfate and their mixture.
Guar gum is galactomannan (melon ear) Gum derivatives that cation ground replaces.The guar gum that is used to prepare these guar gum derivatives is the seed that typically derives from melon ear plant with natural product.The guar gum molecule self is the straight chain mannan, and described straight chain is replacing branching on the mannose unit with a member galactose units at interval in rule.The mannose unit is interconnection by β (1-4) glycosidic bond.Galactose branching takes place by α (1-6) key.The cationic derivative of guar gum gets by the hydroxyl and the reaction of reactive quaternary ammonium compound of galactomannan.Cation group must be enough to provide the above-mentioned cationic charge density of needs at the structural substitution value of guar gum.
The suitable quaternary ammonium compound that is used to form the cationic guar gum polymer comprises those that meet following general formula (XII):
R wherein
1, R
2And R
3Be methyl or ethyl; R
4Be the epoxy alkyl of any following general formula (XIII):
Or R
4Be halohydrin group as general formula (XIV):
R wherein
5Be C
1-C
3Alkylidene; X is that chlorine or bromine and Z are aniones, as Cl
-, Br
-, I
-Or HSO
4 -
Represent by following general formula (XV) by the cationic guar gum polymer (cationic derivative of guar gum) that mentioned reagent forms:
Wherein R is a guar gum.Preferably, the cationic guar gum polymer is a guar hydroxypropyl trimonium chloride.
Other suitable cationic polymers comprises the plain ether of season nitrogen-containing fiber, and its some embodiment are described in United States Patent (USP) 3,962, and in 418, it is described and introduces the present invention for your guidance.Other suitable cationic polymers comprises the copolymer of cellulose, guar gum and the starch of etherificate, and its some embodiment are described in United States Patent (USP) 3,958, and in 581, it is described and introduces the present invention for your guidance.When using, cationic polymer of the present invention or be dissolved in compositions or be dissolved in complex coacervate phase in the compositions, described coacervate forms by cationic polymer and anionic detersive surfactant component mentioned above.The complex coacervate of cationic polymer also can form with other charge species in the compositions.
Coacervate forms and to depend on various standards, closes charge density, pH and the temperature that ratio, ionic forces (comprising the ionic forces modification, for example by adding salt), the cation of interactional ion component are closed anionic group as molecular weight, concentration of component.The influence of coacervate system and these parameters is described, people such as J.Caelles for example, " anion in the mixed system and cationic compound " (Anionic and CationicCompounds in Mixed Systems), Cosmetics﹠amp; Toiletries, the 106th volume, in April, 1991, the 49th to 54 page, C.J.van Oss, " cohesion; complex coacernation and flocculation " (Coacervation, Complex-Coacervation and Flocculation), J.Dispersion Science andTechnology, the the 9th (5,6) volume, 1988-89, the 561st to 573 page, and D.J.Burgess, " proximate analysis of coordination compound coacervate system " (Practical Analysis of Complex CoacervateSystems), J.of Colloid and Interface Science, volume 140, the first phase, in November nineteen ninety, in the 227th to 238, it is described and introduces the present invention for your guidance.
It is believed that cationic polymer especially advantageously is present in the coacervate phase in the compositions, or coating or form the coacervate phase from the hair washing on hair.Compound coacervate it is believed that easier depositing on the hair.Therefore, generally speaking preferably cationic polymer form coacervate mutually and be present in the compositions mutually or through dilution with coacervate.
The technology that is used to analyze coordination compound coacervate forming process is known in the art.For example, the micro analysis in the compositions of any selected dilution stage can be employed to confirm whether coacervate forms mutually.This coacervate will be identified mutually as the other emulsifying in the compositions mutually.During the use dyestuff can help to distinguish coacervate and be dispersed in said composition other is mutually insoluble.
Conditioner
Conditioner comprises any material that hair and/or skin is provided special conditioning beneficial effect.In Hiar treatment compositions, suitable conditioner is to send those of one or more beneficial effects, and these beneficial effects comprise gloss, flexibility, the compatibility, antistatic behaviour, wet process, anti-damage, arrangement property, main body and anti-greasy.The conditioner that is useful on the present composition typically comprises water-insoluble, the dispersible non-volatile liquid of water, and it forms emulsive liquid particles or is dissolved by the surfactant micella of (as mentioned above) in the anionic detersive surfactant component.The suitable conditioner that is used for compositions is the conditioner that those features are generally siloxanes (for example silicone oil, cationic silicone, siloxanes natural gum, high refraction siloxanes and silicone resin), organic conditioning oil (for example hydrocarbon ils, polyolefin and aliphatic ester) and its compositions, or those form the conditioner of liquid, dispersed particles in aqueous surfactant substrate of the present invention.Such conditioner should be at physics or chemically compatible with the solvent of compositions and should not damage stability, aesthetic property or the performance of product inadequately.
The concentration of the conditioner in the compositions should be enough to provide the conditioning beneficial effect of expectation, and this will be conspicuous to those of ordinary skill in the art.Such concentration can be according to factors such as the type of the particulate mean diameter of conditioning performance, conditioner of conditioner, expectation, other component and concentration and is changed.
Other conditioner
What also be applicable to the present composition is the conditioner that is described in the United States Patent (USP) 5,674,478 and 5,750,122 of P﹠G, and both introduce the present invention for your guidance in full.Also being applicable to of the present invention is that those are described in United States Patent (USP) 4,529,586 (Clairol), 4,507,280 (Clairol), 4,663,158 (Clairol), 4,197,865 (L ' Oreal), 4,217,914 (L ' Oreal), 4,381,919 (L ' Oreal) and 4, conditioner among 422,853 (L ' Oreal), all its are described and are introduced the present invention for your guidance.
Some are applicable to that the preferred silicone conditioning agent in the present composition comprises: Abil
S201 (polydimethylsiloxane/sodium PG-propyl group dimethicone thiosulfuric acid salt copolymer) derives from Goldschmidt; DC Q2-8220 (trimethyl silyl ammonia is for polydimethylsiloxane) derives from DowCorning; DC 949 (amino-terminated polydimethylsiloxane, hexadecyltrimethylammonium chloride and tridecyl polyoxyethylene ether-12) derives from Dow Corning; DC 749 (cyclomethicone and trimethylsiloxy esters of silicon acis) derives from Dow Corning; DC2502 (cetyl dimethyl siloxane) derives from Dow Corning; BC97/004 and BC 99/088 (aminofunctional siloxanes microemulsion) derive from Basildon Chemicals; GE SME253 and SM2115-D2_ and SM2658 and SF 1708 (aminofunctional siloxanes microemulsion) derive from General Electric; Silication meadowfoam seed oil derives from Croda; Be described in United States Patent (USP) 4 by GAF Corp., 834,767 (quaternary ammonium group lactams), BiosilTechnologies are described in United States Patent (USP) 5,854,319 (comprising amino acid whose reactive siloxane emulsion) and Dow Corning are described in United States Patent (USP) 4, those siloxanes in 898,585 (polysiloxanes), all describe introducing the present invention for your guidance.
The anti-dandruff active substance
The present composition also can comprise dandruff removing agent.The particulate non-limiting example of suitable anti-dandruff comprises: pyrithione, selenium sulfide, granule sulfur and their mixture.Pyrithione preferably.Such anti-dandruff granule should physics or chemically with compositions in solvent compatible and should not damage stability, aesthetic property or the performance of product inadequately.
1. pyrithione
Pyrithione anti-dandruff granule, especially 1-hydroxyl-2-pyrithione are the highly preferred granule dandruff removing agents that is used for the present composition.The particulate concentration of pyrithione anti-dandruff typically is about 0.1% to about 4%, preferred about 0.1% to about 3%, most preferably from about 0.3% to about 2% by the weight of compositions.Preferred pyrithione comprises from heavy metal such as zinc, stannum, cadmium, magnesium, aluminum and zirconium, preferred zinc form those, more preferably the zinc salt of 1-hydroxyl-2-pyrithione (being called " zinc pyrithione " or " ZPT "), most preferably with the 1-hydroxyl-2-pyrithione of the particulate form of platelet, wherein the average-size that has of granule is for being up to about 20 μ, preferably about 5 μ, 2.5 μ most preferably from about.By other cation, the salt that forms as sodium also is applicable to the present invention.The pyrithione dandruff removing agent for example is disclosed in United States Patent (USP) 2,809,971; 3,236,733; 3,753,196; 3,761,418; 4,345,080; 4,323,683; In 4,379,753 and 4,470,982, all these documents all are incorporated herein by reference.Can think that when with ZPT during as the dandruff removing agent granule in the compositions of the present invention, the growth of hair or regrowth can be strengthened or regulate or both, perhaps trichomadesis can reduce or be suppressed, and perhaps hair is with thickening or abundant.
2. selenium sulfide
Selenium sulfide is the granule dandruff removing agent that is applicable to the present composition, and its valid density counts about 0.1% to about 4%, preferred about 0.3% to about 2.5%, more preferably from about 0.5% to about 1.5% by the weight of compositions.Selenium sulfide is considered to have the chemical compound of one mole of selenium and two molar sulphur usually, although it also is general molecular formula Se
xS
yCirculus, x+y=8 wherein.The average particulate diameter of selenium sulfide is recorded by preceding laser light scattering device (e.g.Malvern 3600 instrument), preferably less than 10 μ m typically less than 15 μ m.The selenium sulfide chemical compound for example is disclosed in United States Patent (USP) 2,694,668; 3,152,046; 4,089,945; With 4,885, in No. 107, all these documents all are incorporated herein by reference.
3. sulfur
Sulfur also can be used as the granule dandruff removing agent in the present composition.The valid density of granule sulfur is about 1% to about 4%, preferred about 2% to about 4% of said composition weight.
Wetting agent
The present composition can comprise wetting agent.Wetting agent of the present invention is selected from polyhydric alcohol, water soluble alkoxylated non-ionic polymers and their mixture.When being used for when of the present invention, wetting agent is preferably in by the amount of the weight of compositions about 0.1% to about 20%, more preferably from about 0.5% to about 5% amount is used.
Can be used for polyhydric alcohol of the present invention and comprise glycerol, sorbitol, propylene glycol, butanediol, hexanediol, ethoxylated glucose, 1,2-hexanediol, hexanetriol, dipropylene glycol, erithritol, trehalose, two glycerol, xylitol, maltose alcohol, maltose, glucose, fructose, sodium chondroitin sulfate, hyaluronate sodium, adenylic acid sodium, sodium lactate, ketopyrrolidine carbonate, glycosamine, cyclodextrin and their mixture.
Can be used for water soluble alkoxylated non-ionic polymers of the present invention and comprise Polyethylene Glycol and polypropylene glycol, be called those of PEG-200, PEG-400, PEG-600, PEG-1000 and their mixture as those CTFA names with molecular weight about 1000.
Be applicable to that commercially available wetting agent of the present invention comprises: trade name STAR
TMSUPEROL
TMGlycerol derive from P﹠G, CRODEROL GA7000
TMDerive from Universal Ltd., PRECERIN
TMSeries derives from Unichema, the identical NOF that derives from chemical name of trade name; Trade name LEXOLPG-865/855
TMPropylene glycol derive from Inolex, 1,2-PROPYLENE GLYCOL USP derives from BASF; Trade name LIPONIC
TMThe sorbitol of series derives from Lipo, SORBO
TM, ALEX
TM, A-625
TMAnd A-641
TMDerive from ICI and UNISWEET 70
TM, UNISWEET CONC
TMDerive from UPI; Dipropylene glycol derives from BASF with identical trade name; Trade name DIGLYCEROL
TMDiglycerol derive from Solvay GmbH; Xylitol derives from Kyowa and Eizai with identical trade name; Maltose alcohol derives from Hayashibara with trade name MALBIT, and sodium chondroitin sulfate derives from Freeman and Bioiberica with identical trade name and trade name ATOMERGIC SODIUMCHONDROITIN SULFATE derives from Atomergic Chemetals; Hyaluronate sodium derives from Active Organics with trade name ACTIMOIST, and AVIAN SODIUM HYALURONATE series derives from Intergen, and HYALURONIC ACID Na derives from Ichimaru Pharcos; Adenylic acid sodium derives from Asahikasei with identical trade name, Kyowa and Daiichi Seiyaku; Sodium lactate derives from Merck, Wako and Showa Kako with identical trade name, and cyclodextrin derives from American Maize with trade name CAVITRON, and RHODOCAP series derives from Rhone-Poulenc and DEXPEARL derives from Tomen; Derive from Union Carbide with Polyethylene Glycol with trade name CARBOWAX series.
Suspending agent
The present composition also can comprise suspending agent, its concentration can effectively suspend hollow particle or other water-insoluble material, with dispersive form in compositions or be used to change the viscosity of compositions.Such concentration is to about 10%, preferred about 0.3% to about 5.0% by the weight of compositions about 0.1%.
Can be used for suspending agent of the present invention and comprise anionic polymer and non-ionic polymers.Can be used for of the present invention is the crosslinked acrylic acid polymer of polyvinyl such as CTFA carbomer by name, the cellulosic polymer of cellulose derivative and modification such as methylcellulose, ethyl cellulose, hydroxyethyl-cellulose, hydroxypropyl emthylcellulose, NC Nitroncellulose, cellulose sodium sulfate, sodium carboxymethyl cellulose, crystalline cellulose, cellulose powder, polyvinylpyrrolidone, polyvinyl alcohol, guar gum, hydroxypropyl guar gum, xanthan gum, arabic gum, Tragacanth, galactan, carob glue, the guar gum resin, karaya, carrageenin, pectin, agar, the WENBO seeds of trees (Cydonia oblonga Mill), starch (Oryza sativa L., corn, Rhizoma Solani tuber osi, Semen Tritici aestivi), alginate jelly (algae extract), microbial polymer such as glucosan, succinoglucan, Pullulan (pulleran), polymer such as carboxymethyl starch based on starch, the methyl hydroxypropyl starch, polymer such as sodium alginate based on alginic acid, the alginic acid propylene glycol ester, acrylate polymer such as sodium polyacrylate, polyethyl acrylate, polyacrylamide, polymine and inorganic water-soluble substances such as speckle take off bentonite, Magnesiumaluminumsilicate, LAPONITE, Strese Hofmann's hectorite. and anhydrous silicic acid.
Molecular weight is higher than about 1000 poly alkylene glycol and can be used for the present invention.Can use material with following formula:
R in the formula
95Be selected from H, methyl and their mixture.Work as R
95During for H, these materials are polymers of ethylene oxide, and they are also referred to as poly(ethylene oxide), polyethylene glycol oxide and Polyethylene Glycol.Work as R
95During for methyl, these materials are the polymer of expoxy propane, and they are also referred to as poly(propylene oxide), polypropylene oxide and polypropylene glycol.Work as R
95During for methyl, also can understand the isomer of all places that can have resulting polymers.In said structure, x
3Has about 1500 to about 120,000 meansigma methods, preferred about 3,000 to about 100,000, more preferably from about 5,000 to about 50,000.Other useful polymer comprises polypropylene glycol and blended polyethylene-polypropylene glycol or polyoxyethylene-polyoxypropylene copolymer.Can be used for polyethylene glycol polymer of the present invention is PEG-2M, wherein R
95Equaling H and x3 has about 2,000 meansigma methods (PEG-2M is also referred to as Polyox WSR
N-10, it is with PEG-2,000 derives from Dow/Amerchol); PEG-5M, wherein R
95Equaling H and x3 has about 5,000 meansigma methods (PEG-5M is also referred to as Polyox WSR
N-35 and Polyox WSR
N-80, all with PEG-5,000 and Polyethylene Glycol 300,000 derive from Dow/Amerchol); PEG-7M, wherein R
95Equaling H and x3 has about 7,000 meansigma methods (PEG-7M is also referred to as Polyox WSR
N-750 derives from Dow/Amerchol); PEG-9M, wherein R
95Equaling H and x3 has about 9,000 meansigma methods (PEG9-M is also referred to as Polyox WSR
N-3333 derives from Dow/Amerchol); PEG-14M, wherein R
95Equaling H and x3 has about 14,000 meansigma methods (PEG-14M is also referred to as Polyox WSR
N-3000 derives from Dow/Amerchol); PEG-45M, wherein R
95Equaling H and x3 has about 45,000 meansigma methods (PEG-45M is also referred to as Polyox WSR
N-60K derives from Dow/Amerchol); And PEG-90M, wherein R
95Equaling H and x3 has about 90,000 meansigma methods (PEG-90M is also referred to as Polyox WSR
-301, derive from Dow/Amerchol).
The viscosity modifier that highly is of value to commercially available acquisition of the present invention comprises carbomer, commodity are called Carbopol 934, Carbopol 940, Carbopol 950, Carbopol 980, Carbopol 981, Carbopol ETD 2010, Carbopol ETD 2050, Carbopol Ultrez 10 and Carbopol AquaSF-1, all Noveon that derive from, Inc., acrylates/stearyl polyoxyethylene ether-20 methacrylate copolymers, trade name ACRYSOL 22, derive from Rohm and Hass, the ninth of the ten Heavenly Stems oxygen ethylhydroxyethylcellulose, trade name AMERCELL POLYMER HM-1500, derive from Amerchol, methylcellulose, trade name BENECEL, hydroxyethyl-cellulose, trade name NATROSOL, hydroxypropyl cellulose, trade name KLUCEL, the cetyl hydroxyethyl-cellulose, trade name POLYSURF 67, all these is provided by Hercules, based on the polymer of oxirane and/or expoxy propane, trade name CARBOWAX PEGs, POLYOX WASRs and UCON FLUIDS, all these is provided by Amerchol.
Other optional suspending agent comprises the crystallite suspending agent, and it can be classified as acyl derivative, long-chain amine oxide and their mixture.These suspending agents are described in United States Patent (USP) 4,741, and in 855, it is described and introduces the present invention for your guidance.These preferred suspending agents comprise having about 16 ethylene glycol fatty acids to about 22 carbon atoms.More preferably ethylene glycol stearate, monoesters and distearate, but especially comprise the distearate that is lower than about 7% monostearate.Other suitable suspending agent comprise the alkanolamide of fatty acid, preferably have about 16 to about 22 carbon atoms, 16 to 18 carbon atoms more preferably from about, its preferred embodiment comprises stearic acid one glycollic amide, Stearic acid diethanolamine salt, stearic acid one isopropanol amide and stearic acid one glycollic amide stearate.Other long acyl derivant comprises the long-chain ester (for example geoceric acid stearyl alcohol ester, cetin etc.) of long-chain fatty acid; The long-chain ester of long chain alkanol amide (for example stearoyl diethanolamine distearate, stearoyl monoethanolamine stearate); And glyceride (for example glycerol distearate, trihydroxy stearin, tribehenin), its commercially available acquisition embodiment is Thixin R, derives from Rheox, Inc..Except the preferred material of listing above, long acyl derivant, long-chain carboxylic acid's glycol ester, long-chain amine oxide and long-chain carboxylic acid's alkanolamide can be used as suspending agent and use.
Other long acyl derivant that is suitable as the suspending agent use comprises N; N-dialkyl acylamino-benzoic acid and its water soluble salt (for example Na, K); especially the N of this class; N-two (hydrogenation) C.sub.16, C.sub.18 and Adeps Bovis seu Bubali acylamino-benzoic acids; it is commercially available from Stepan Company (Northfield; Ill., USA).
The embodiment of the suitable long-chain amine oxide that uses as suspending agent comprises alkyl (C.sub.16-C.sub.22) dimethyl amine oxide, for example stearyl dimethyl amine oxide.
Other suitable suspending agent comprises the primary amine of the fatty alkyl part with at least 16 carbon atoms, embodiment comprises palmitamide or 18-amine., with the secondary amine with two fatty alkyl parts that at least 12 carbon atoms are arranged respectively, embodiment comprises two palmityl amines or two (h-tallow base) amine.Other suitable suspending agent also comprises two (h-tallow base) phthalic amides and crosslinked maleic anhydride-methyl ethylene ether copolymer.
Other optional components
The present composition also can comprise vitamin and aminoacid, as: water soluble vitamins, as vitamin B1, B2, B6, B12, C, pantothenic acid, general benzyl ethyl ether, pantothenylol, biotin and their derivant; Water-soluble amino acid is as agedoite, alanine, indole, glutamic acid and their salt; The water-insoluble vitamin is as vitamin A, D, E and their derivant; Water-insoluble aminoacid is as tyrosine, tryptamines and their salt.
The present composition also can comprise pigment material, as inorganic, nitroso, monoazo, bisazo, carotenoid, tritan., triarylmethane, xanthene; Xanthene, quinoline oxazine, azine, anthraquinone, indigo system, the thionine indigoid, quinacridone, phthalocyanine, plant, natural pigment, comprise: water-soluble component, as dyestuff: Acid Red 18 with following C.I. title, 26,27,33,51,52,87,88,92,94,95, Acid Yellow 1,3,11,23,36,40,73, FoodYellow 3, Food Green 3, Food blue 2, Food Red 1,6, Acid Blue 5,9,74, Pigment Red 57-1,53 (Na), Basic Violet 10, Solvent Red 49, Acid orange 7,20,24, Acid Green 1,3,5,25, Solvent Green 7, Acid Violet 9,43; Water-msoluble ingredients, the dyestuff that for example has following C.I. title: Pigment Red 53 (Ba), 49 (Na), 49 (Ca), 49 (Ba), 49 (Sr), 57, Solvent Red 23,24,43,48,72,73, SolventOrange 2,7, Pigment Red 4,24,48,63 (Ca) 3,64, Vat Red 1, Vat blue 1,6, Pigment Orange 1,5,13, Solvent Yellow 5,6,33, Pigment Yellow 1,12, Solvent Green 3, Solvent Violet 13, Solvent Blue 63, Pigment Blue 15, titanium dioxide, the copper chlorophyllin coordination compound, ultramarine, aluminium powder, bentonite, calcium carbonate, barium sulfate, bismuth trihydride, calcium sulfate, carbon black, bone ash, chromic acid, cobalt blue, gold, ferrum oxide, hydrated ferric oxide, ferric ferrocyanide, magnesium carbonate, magnesium phosphate, silver and zinc oxide.
The present composition also can comprise antimicrobial, it is useful as cosmetics insecticide and dandruff removing agent, comprising: the hot pyrrole copper of water-soluble component such as hydroxyl first ethanolamine, and water-msoluble ingredients is as 3,4,4 '-neko (triclosan), triclocarban and Zinc Pyrithione.
The present composition also can comprise chelating agen, as: 2,2 '-two pyridine amine; 1,10-phenanthroline { o-phenanthroline }; Two-2-pyridyl ketone; 2,3-two (2-pyridine radicals) pyrazine; 2,3-two (2-pyridine radicals)-5,6-dihydro pyrazine; 1,1 '-carbonyl dimidazoles; 2,4-two (5,6-diphenyl-1,2,4-triazine-3-yl) pyridine; 2,4,6-three (2-pyridine radicals)-1,3,5-triazines; 4,4 '-dimethyl-2,2 '-bipyridyl (dipyridyl); 2; Two-2-pyridine radicals Biformyl 2,2 '-pyridil}; 2-(2-pyridine radicals) benzimidazole; 2,2 '-the Lian pyrazine; 3-(2-pyridine radicals)-5,6-diphenyl-1,2,4-triazine; 3-(4-phenyl-2-pyridine radicals)-5-phenyl-1,2, the 4-triazine; 3-(4-phenyl-2-pyridine radicals)-5,6-diphenyl-1,2,4-triazine; 2,3,5,6-four-(2 '-pyridine radicals)-pyrazine; 2, dipicolimic acid 2; 2,4, the 5-trihydroxy-pyrimidine; Phenyl 2-pyridine radicals ketoxime; 3-amino-5,6-dimethyl-1,2,4-triazine; 6-hydroxyl-2-phenyl-3 (2H)-2H-Pyridazin-3-one; 2,4-pteridine glycol { lumazine}; 2,2 '-bipyridyl; With 2, the 3-dihydroxy-pyridine.
Friction testing
After present composition processing, hair will preferably show about 1 to about 2 coefficient of friction.More preferably, hair will show about 1.05 to about 1.8 coefficient of friction.Also more preferably, hair will show about 1.1 to about 1.7 coefficient of friction.Even more preferably, hair will show about 1.2 to about 1.6 coefficient of friction.Coefficient of friction is determined according to following method:
The friction that this method is measured the untreated relative hair of handling bunch changes.(about 4.6mm * 3.1mm), heavy 73g+/-5% is with the nylon wire covering of about 105 micron pore size to claim overweight " coaster ", it is connected in device for measuring force, on Instron, with the hair bunch (approximately 25cm (10 inch) long) of constant speed traction by 20g, the one end is clamped.
The hair that uses is white people's hairs, and it is formed 20 gram hairs bunch, and 25cm (10 inches) is long, and it is cleaned to remove any external dirt.Then, this hair bunch is allowed in the room equilibrate overnight of constant temperature at 75 ℃/50% relative humidity (RH).
Hair bunch quilt is by following processing: send out pre-wetted bunch under mobile tap water.Excessive water is extracted and sent out bunch to be hung on the clothes hanger.For the leave product, the test products of 1.5cc is administered to hair bunch surface then and is rubbed into sends out bunches about 30 to 40 seconds.For rinse-off products, test products is applied to wet hair with the dosage of 0.1g/g and massaged/be coated with soap bubble about 30 seconds, about flow velocity about 5.7 liters/minute (1.5 gallon per minute) rinsings 30 seconds down, repeats this method to finish a cycle of treatment subsequently.Then, send out and bunch be dried and the aforementioned processing circulation repeats 3 circulations altogether.After the processing, send out and bunch to hang on the clothes hanger again and be positioned between constant-temperature house (75 ℃/50%RH) equilibrate overnight.
This to be measured bunch clamps on the horizontal checkout frame and combing 2 to 3 times determines that with hair direction and removal tangle.Then coaster is connected and be positioned on the hair bunch.Friction records with forward direction (towards the tip of hair) on three independent send out bunch, measures tension force (typically recording by gram) simultaneously by the speed drawing coaster with about 1cm/ second.Each power measured value is at the average apart from least 10 values of record of 5cm at least after " coaster " reaches constant speed.Every bunch of minimum measurement three times.Coefficient of friction is determined divided by the average ratio of the friction of untreated hair bunch by the friction of processed hair bunch.
The trichoesthesia test
After the present composition is handled, hair will preferably show and be lower than about 8 " trichoesthesia ".More preferably, hair is lower than demonstration about 7 " trichoesthesia ".Also more preferably, hair is lower than demonstration about 6 " trichoesthesia ".Even more preferably, hair is lower than demonstration about 5 " trichoesthesia "." trichoesthesia " determined according to following method:
The hair of handling bunch is by at least 5 panelists' assessments of training, and sends out bunch to feel to do.20 grams, 25cm (10 inches) is long, and the friction testing that white people's hair bunch as the present invention describe is described by with present composition processing with feel evaluated for coating amount.0 to 10 grade is used to the grade of hair that authentication process crosses bunch.The hair of the very clean sensation of grade " 0 " expression.Grade " 10 " expression is to the very coated sensation of hair.The grade terminal point is based on by the hair of following processing bunch:
0=Pantene
TMClarifying Shampoo handles
10=0.75cc comprise (Sipernet 22LS, PemulenTR-1 gel (the deriving from B.F.Goodrich) granule Degussa) friction 30 seconds in hair bunch of 2.0% silicon dioxide.
Every kind of compositions to be tested is used three different send out bunch.The panelist assesses that each handled send out bunch and marking by average to draw total " trichoesthesia " grade.
Using method
The present composition uses with the usual manner that is used to clean hair or skin and volumeization, conditioning, typing and other beneficial effect of the present invention are provided.The compositions that being used to of effective dose cleaned hair or skin is coated on hair or skin, and it preferably by water-wet, rinses then.Such effective dose is generally about 1g to about 50g, and preferably about 1g is to about 20g.Be coated on hair typically comprise rub compositions in hair so that most of or all hairs contact with compositions.
The method of this cleaning hair and skin comprises the steps: a) with water-wet hair and/or skin, and b) compositions of using effective dose is in hair and/or skin, and c) water is from hair and/or skin rinse composition.These steps can repeat repeatedly up to cleaning that obtains expecting and volume beneficial effect.
Various aspects of the present invention and various embodiment that this paper lists have many advantages.In preferred embodiments, the present composition deposits many granules on the hair fiber of user.Granule can be the discrete little aggregation deposition with the discrete entities of different shape and form or individual particle.Entity that these are discrete or aggregation provide structure for the hair fiber surface and strengthen friction between hair fiber.The friction that increases has reduced relative slip mutual between the hair fiber and the auxiliary hair volume or the main body of building and keeping expectation.The result is that compositions can provide the hair volume of increase and main body, bounce-back, full, elasticity and structure.Various embodiments of the present invention have emphasized that to the hair care product needs it can provide the hair outward appearance volume of increase and keep good trichoesthesia simultaneously.
The following example has further described and has proved the preferred embodiment in the scope of the invention.Embodiment only is for the purpose of describing, and should not be construed as the limitation of the invention condition, is possible because under the condition that does not deviate from its scope it is carried out many changes.
Embodiment
The compositions of describing among the following embodiment has been described the specific embodiments of the present composition, but is not intended to its qualification.Under the condition that does not deviate from spirit and scope of the invention, the technical staff can carry out other change.The embodiment of these examples of the present composition provides hair cleaning and volume beneficial effect.
The compositions of describing in the following examples is by conventional formulation and mixed method preparation, and embodiment is following illustrated.Except as otherwise noted, the amount of all examples is listed with percentage by weight, side by side except microcomponent, as diluent, antiseptic, colored solutions, imaginary composition, medicinal plants etc.
The present composition can use conventional preparation and hybrid technology preparation.When the fusing of solid surfactant or wax component or dissolving when being essential, these can be added into the surfactant pre-composition, or the surfactant of certain part, for example under about 72 ℃, mix also heating with the melting solid component.Mixture can mix remaining ingredient then randomly by shearing dismembyator processing and cooling then.Solid particulate components can or preferably be added to after cooling in the final mixture before handling through high shear grinding.Compositions typically has about 2000 to about 20, the final viscosity of 000cps.The viscosity of compositions can be passed through conventional method, comprises adding sodium chloride on demand or ammonium xylene sulfonate is regulated.Therefore, institute's series preparation comprises listed component and any microcomponent relevant with this component.
(1) polymer KG30M derives from Amerchol
(2) cationic guar gum, charge density 1.8meq/g, molecular weight is about 200 ten thousand, and Aqualon provides
(3) Polycare 133, derive from Rhodia
(4) Polyox WSR N-3000 derives from Union Carbide
(5) derive from Witco
(6) Viscasil 330M derives from General Electric Silicones
(7) Sipernat 22LS derives from Degussa
(8) Tospearl 240, derive from GE Silicones
(1) polymer KG30M derives from Amerchol[charge density=1.9meq/g, molecular weight 1,250,000]
(7) Sipernat 22LS derives from about 4 microns of Degussa[particle diameter, about 175 meters squared per gram of concrete surface area]
(8) Tospearl 240, derive from about 4 microns of GE Silicones[particle diameter, about 35 meters squared per gram of concrete surface area]
(9) cationic cellulose, Amerchol provide [the about 2.4meq/g of charge density, molecular weight about 2,000,000]
(10) cationic cellulose, Amerchol provide [the about 2.4meq/g of charge density, molecular weight about 350,000]
(11) HMW MAPTAC (Rhodia) [the about 4.5meq/g of charge density, molecular weight about 860,000]
(12) Polyox WSR-301 derives from Dow Chemical Company
(13) Carbopol Ultrez 10, derive from Noveon, Inc.
(14) Thixin R derives from Rheox, Inc.
(15) derive from about 12 microns of KOBO Products Inc.[particle diameter, about 750 meters squared per gram of concrete surface area
(16) derive from KOBO Products Inc, [about 3 microns of particle diameter, about 60 meters squared per gram of concrete surface area
(1) polymer KG30M derives from Amerchol[charge density=1.9meq/g, molecular weight about 1,250,000]
(6) Viscasil 330M derives from General E1ectric siloxanes company
(7) Sipernat 22LS derives from about 4 microns of Degussa[particle diameter, about 175 meters squared per gram of concrete surface area]
(8) Tospearl 240, derive from about 4 microns of GE Silicones[particle diameter, about 35 meters squared per gram of concrete surface area]
(9) cationic cellulose, Amerchol provide [the about 2.4meq/g of charge density, molecular weight about 2,000,000]
(10) cationic cellulose, Amerchol provide [the about 2.4meq/g of charge density, molecular weight about 350,000]
(12) Polyox WSR-301 derives from Dow Chemical Company
(13) Carbopol Ultrez 10, derive from Noveon, Inc.
(14) Thixin R derives from Rheox, Inc.
(15) derive from about 12 microns of KOBO Products lnc.[particle diameter, about 750 meters squared per gram of concrete surface area
(17) Dow Corning
2-1865 microemulsion (Dow Corning)
(18) Dow Corning
1664 emulsions (Dow Corning)
(19) Sipernat 360, derive from about 15 microns of Degussa Corp.[particle diameter, about 50 meters squared per gram of concrete surface area
(20) SP-10 derives from KOBO Products, about 10 microns of Inc[particle diameter]
(21) cationic guar gum, Aqualon provide [the about 2.4meq/g of charge density, molecular weight about 600,000]
(22) (15) derive from about 12 microns of KOBO Products Inc.[particle diameter, about 30 meters squared per gram of concrete surface area
To should be appreciated that to be that embodiment of the present invention and embodiment only are in order being described, under the situation that does not deviate from scope of the present invention, will to be given those skilled in the art by hint according to its various changes and change.
Claims (10)
1. be used to improve the compositions of the outward appearance volume of hair, described compositions comprises:
A) liquid-carrier,
B) mean diameter is less than 300 microns granule;
Wherein, after described compositions-treated, described hair demonstrates about 1 to about 2 coefficient of friction and has trichoesthesia grade at least about 8.
2. wherein there is the described granule at least about 0.1 percentage by weight in compositions as claimed in claim 1.
3. wherein there is the described granule at least about 0.5 percentage by weight in the described compositions of each claim as described above.
4. the described compositions of each claim as described above, wherein said particulate mean diameter is less than about 70 microns.
5. the described compositions of each claim as described above, wherein said particulate mean diameter is less than about 60 microns.
6. the described compositions of each claim as described above, wherein, after described compositions-treated, described hair demonstrates about 1.05 to about 1.8 coefficient of friction.
7. the described compositions of each claim as described above, wherein, after described compositions-treated, described hair has the trichoesthesia grade at least about 7.
8. the described compositions of each claim as described above, wherein, after described compositions-treated, described hair demonstrates about 1.1 to about 1.7 coefficient of friction and has trichoesthesia grade at least about 6.
9. the described compositions of each claim as described above, wherein, described particle grain size about 5 to the scope of about 60 μ m.
10. nurse the method for hair by the described compositions of each claim as described above of using safe and effective amount.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US32677801P | 2001-10-03 | 2001-10-03 | |
| US60/326,778 | 2001-10-03 | ||
| US60/328,156 | 2001-10-10 | ||
| US60/387,131 | 2002-06-07 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1735396A true CN1735396A (en) | 2006-02-15 |
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ID=36077476
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02818794 Pending CN1735396A (en) | 2001-10-03 | 2002-10-03 | Composition for improving hair volume |
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| CN (1) | CN1735396A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102762191A (en) * | 2009-09-15 | 2012-10-31 | 陶氏环球技术有限责任公司 | Silicone deposition aid for personal care compositions |
-
2002
- 2002-10-03 CN CN 02818794 patent/CN1735396A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102762191A (en) * | 2009-09-15 | 2012-10-31 | 陶氏环球技术有限责任公司 | Silicone deposition aid for personal care compositions |
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