CN1734620A - Hard disk driver magnet and its preparation method - Google Patents
Hard disk driver magnet and its preparation method Download PDFInfo
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- CN1734620A CN1734620A CN 200510026659 CN200510026659A CN1734620A CN 1734620 A CN1734620 A CN 1734620A CN 200510026659 CN200510026659 CN 200510026659 CN 200510026659 A CN200510026659 A CN 200510026659A CN 1734620 A CN1734620 A CN 1734620A
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- hard disk
- disk driver
- driver magnet
- magnet
- annulus
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Abstract
The invention discloses a hard disk activator magnet, which is characterized by the following: the terminal tolerance of round and one-shot forming magnet equals to or is less than +/-0.03mm; the outside or inside diameter roundness and the axiality of circular ring is less than 0.03mm; coating the magnet surface with macromolecular polymeric substance of good anti-corrosion stock; detecting the magnet by public GB/T18880 method.
Description
Technical field
The present invention relates to a kind of hard disk driver magnet, particularly a kind of surface has the hard disk driver magnet of anticorrosive protective seam.
Background technology
Hard disk drive is components and parts important in the computing machine, not only will have reliable performance, also needs to have stronger corrosion resistance, so that can be in the relatively medium-term and long-term use of rugged environment.
Hard disk driver magnet is one of part of hard disk drive most critical, and the quality of its performance has directly determined the quality of hard disk drive.At present, the material of hard disk driver magnet is selected bonding rare earth magnet for use or is contained in the bonded permanent magnet of rare earth element and adds ferromagnetic oxide powder, aluminium-nickel-cobalt magnetic powder, metallic element powder etc., or other magnetic material.Document J.J.Croat, (AMM company), Luo Yang, " rare earth magnet is as the present situation and the prediction of bonding NdFeB magnet industry " of IEEE director TC-15 writing; Japan bonded permanent magnet industry association farmland on a plateau English timbo well wins own " today of bonded permanent magnet and tomorrow "; Bi Chao, Zheng Guangde, the Zhang Xinyu Singapore data storage research institute opportunities and challenges of development one permanent magnetic material of device " hard disk tend to act "; Sevi Gaiffi, the disclosed technology of the bright MQI of horse bezoar " the manufacture craft performance and the economic target of NdFeB bonded permanent magnet ", the bonding rare earth magnet material is divided into Agglutinate neodymium-iron-boron, rare earth ferroalloy nitride, (SmCo is meant Sm to the bonding SmCo
2Co
17Or SmCo
5), the compound of wherein one or more.
The disclosed technology of above-mentioned document; its hard disk driver magnet once-forming is bigger to the tolerance of final finished; generally greater than ± 0.03mm; the detailed technology of protective seam is not all described on the surface simultaneously; therefore; when in hard disk driver magnet has the environment of Korrosionsmedium, using, might cause hard disk drive operation irregularity, performance to descend, finally influence the operate as normal of hard disk.
Therefore,, make the hard disk driver magnet can either operate as normal, can resist the erosion of extraneous Korrosionsmedium again how at the surface coverage layer protective layer of hard disk driver magnet, be relevant department very expectation.
Summary of the invention
One of technical issues that need to address of the present invention are to disclose a kind of hard disk driver magnet, to overcome the above-mentioned defective that prior art exists, satisfy the needs of the parties concerned;
Two of the technical issues that need to address of the present invention are the preparation methods that disclose described hard disk driver magnet, so that suitability for industrialized production.
Hard disk driver magnet of the present invention is annular magnetic, and its relative dimensions is as follows:
The outside dimension of annulus: 35~4mm, outside dimension once-forming to the tolerance of final finished is ± 0.03mm;
The internal diameter size of annulus: 33~2mm, internal diameter size once-forming to the tolerance of final finished is ± 0.03mm;
The height dimension of annulus: 0.5-6mm height dimension once-forming to the tolerance of final finished is ± 0.03mm;
The once-forming of annulus is to the circularity of the external diameter of final finished: less than 0.03mm;
The once-forming of annulus is to the right alignment of final finished: less than 0.03mm;
The once-forming of annulus is to the circularity of the internal diameter of final finished: less than 0.03mm.
The magnetic property of hard disk driver magnet:
Maximum magnetic energy product (BH) max:56-112kJ/m
3
The magnetic magnetic pole number of poles of magnet is 2 n times, n=1-128;
The material of hard disk driver magnet is selected bonding rare earth magnet for use, is divided into Agglutinate neodymium-iron-boron, rare earth ferroalloy nitride, (SmCo is meant Sm to the bonding SmCo
2Co
17Or SmCo
5), the compound of wherein one or more; Or the bonding rare earth magnet material one or more compound and the potpourri of ferromagnetic oxide powder, aluminium-nickel-cobalt magnetic powder or metallic element powder etc.The preparation method of above-mentioned physical dimension and material and magnet is at document J.J.Croat, (AMM company), Luo Yang, " rare earth magnet is as the present situation and the prediction of bonding NdFeB magnet industry " of IEEE director TC-15 writing; Japan bonded permanent magnet industry association farmland on a plateau English timbo well wins own " today of bonded permanent magnet and tomorrow "; Bi Chao, Zheng Guangde, the Zhang Xinyu Singapore data storage research institute opportunities and challenges of development one permanent magnetic material of device " hard disk tend to act "; Sevi Gaiffi in the bright MQI of horse bezoar " the manufacture craft performance and the economic target of the NdFeB bonded permanent magnet " document, all has disclosed report, and the present invention repeats no more.
According to the present invention, also comprise the corrosion-resistant material layer that is coated in magnet surface.
Said corrosion-resistant material is a high molecular polymer;
Preferred high molecular polymer is selected from a kind of or its potpourri in epoxy resin, poly-fluororesin, linear phenolic resin or the aldehyde ketone resin, and the thickness of corrosion-resistant material layer is 2-30 μ m;
The preparation method of hard disk driver magnet of the present invention comprises the steps:
The first step: permanent magnetic powder and compound binding agent are mixed with, the percentage by weight of mixing, permanent magnetic powder 58~99.5%, compound binding agent 0.5~42%, evenly mix at normal temperatures and pressures, make the mixture powder of permanent magnetic powder and compound binding agent, size 2~500 μ of mixture powder;
Compound binding agent is selected from one or more in phenolics, epoxy resin, liquid crystalline resin, polyamide (nylon), polyphenylene sulfide, the fluorine resin.
Second step: the shaping of hard disk driver magnet: at normal temperature and pressure is 2~20 tons/centimetre
2Condition under compression moulding, solidified 1~120 minute down at 80~230 ℃ again, make a kind of hard disk driver magnet.
The 3rd step: high molecular polymer is dissolved in organic solvent, and in the solvent, the mass concentration of Molecularly Imprinted Polymer is 20~80%, adopts spraying or electrophoresis in the hard disk driver magnet surface, and oven dry or air dry get final product under 10~260 ℃ temperature then.
Said organic solvent is selected from a kind of in acetone, n-butanols, ethyl acetate or the paraldehyde;
Because hard disk driver magnet of the present invention, size once-forming to the tolerance of final finished is ± 0.03mm, or less than 0.03mm, surface-coated one deck high molecular polymer, therefore, has stronger corrosion resistivity, adopt GB/T 18880 disclosed test methods, it is detected, the humidity resistance and the solvent resistance of the hard disk driver magnet after the coating are good, do not corrode, can satisfy the needs of the parties concerned.
Embodiment
Embodiment 1
Hard disk driver magnet, its material is Agglutinate neodymium-iron-boron, and is circular, its relative dimensions: the outside dimension of annulus: 28mm, the internal diameter size of annulus: 26mm, the height dimension of annulus: 4.5mm, the circularity of the external diameter of annulus: less than 0.03mm, right alignment: less than 0.03mm;
The circularity of the internal diameter of annulus: less than 0.03mm.
The magnetic property of hard disk driver magnet:
Maximum magnetic energy product (BH) max:80kJ/m
3
The magnetic magnetic pole number of poles of magnet is 24;
The manufacture method of hard disk driver magnet:
The first step: permanent magnetic powder and compound binding agent are mixed with, permanent magnetic powder 97.5%, and compound binding agent 2.5% evenly mixes at normal temperatures and pressures, makes the mixture powder of permanent magnetic powder and compound binding agent, mean grain size size 100 μ of mixture powder;
Second step: the shaping of hard disk driver magnet: at normal temperature and pressure is 12 tons/centimetre
2Press in compression moulding, solidified 10 minutes down at 200 ℃ again, make a kind of hard disk driver magnet.
Epoxy resin is dissolved in the ethyl acetate, and the mass concentration of epoxy resin is 45%, adopts and is sprayed at the hard disk driver magnet surface, dries then to get final product under 190 ℃ temperature.
The thickness of erosion shield is 20 μ m.
Adopt IEC, GB, JIS magnetic detection standard disclosed method to detect, the magnetic property of hard disk driver magnet is as follows: maximum magnetic energy product (BH) max:80kJ/m
3The magnetic number of poles of magnet is 24;
Adopt GB/T 18880 disclosed test methods, its corrosion resistance is detected, its result is as follows:
The humidity resistance of 60 ℃ * 95%RH: do not corrode in 300 hours;
Hard disk driver magnet after the coating is environmental baseline 25 ℃ * 100 hours, in pure water, 10% salt solution, 4.0% NaOH aqueous solution, ethanol, propyl alcohol, trichloroethanes, machine oil, gasoline, neutral detergent, and weight no change, size no change, magnetic no change, microscopic examination outward appearance are rustless.
Embodiment 2
Hard disk driver magnet, its material are that Agglutinate neodymium-iron-boron is dosed 1% SmCo magnetic, and be circular, its relative dimensions:
The outside dimension of annulus: 9.4mm, the internal diameter size of annulus: 7.1mm, the height dimension of annulus: 1.2mm;
Hard disk driver magnet adopts electrophoresis, deposition condition 60 ℃ * 20 minutes, and condition of cure got final product in 180 ℃ * 1 hour;
Adopt IEC, GB, JIS standard disclosed method to detect, the magnetic property of hard disk driver magnet is as follows: maximum magnetic energy product (BH) max:96kJ/m
3The magnetic magnetic pole number of poles of magnet is 12;
Adopt the disclosed test method of GB/T 18880 standards that its corrosion resistance is detected, its result is as follows:
The humidity resistance of 60 ℃ * 95%RH: do not corrode in 300 hours;
Hard disk driver magnet after the coating is in environmental baseline, in pure water, 10% salt solution, 4.0% NaOH aqueous solution, ethanol, propyl alcohol, trichloroethanes, machine oil, gasoline, neutral detergent, weight no change, size no change.
Claims (8)
1. a hard disk driver magnet is annular magnetic, it is characterized in that, its relative dimensions is as follows:
The outside dimension of annulus: 35~4mm, outside dimension once-forming to the tolerance of final finished is ± 0.03mm;
The internal diameter size of annulus: 33~2mm, internal diameter size once-forming to the tolerance of final finished is ± 0.03mm;
The height dimension of annulus: 0.5-6mm height dimension once-forming to the tolerance of final finished is ± 0.03mm;
The once-forming of annulus is to the circularity of the external diameter of final finished: less than 0.03mm;
The once-forming of annulus is to the right alignment of final finished: less than 0.03mm;
The once-forming of annulus is to the circularity of the internal diameter of final finished: less than 0.03mm.
The magnetic property of hard disk driver magnet:
Maximum magnetic energy product (BH) max:56-112kJ/m
3
The magnetic magnetic pole number of poles of magnet is 2 n times, n=1~128.
2. hard disk driver magnet according to claim 1 is characterized in that, also comprises the corrosion-resistant material layer that is coated in magnet surface.
3. hard disk driver magnet according to claim 2 is characterized in that, said corrosion-resistant material is a high molecular polymer.
4. hard disk driver magnet according to claim 3 is characterized in that, high molecular polymer is selected from a kind of or its potpourri in epoxy resin, poly-fluororesin, linear phenolic resin or the aldehyde ketone resin.
5. hard disk driver magnet according to claim 4 is characterized in that, the thickness of corrosion-resistant material layer is 2~30 μ m.
6. according to the preparation method of each described hard disk driver magnet of claim 1~5, it is characterized in that, comprise the steps:
The first step: permanent magnetic powder and compound binding agent are mixed with, the percentage by weight of mixing, permanent magnetic powder 58~99.5%, compound binding agent 0.5~42%, evenly mix at normal temperatures and pressures, make the mixture powder of permanent magnetic powder and compound binding agent, size 2~500 μ of mixture powder;
Second step: the shaping of hard disk driver magnet: be compression moulding under 2~20 tons/centimetre 2 the condition at normal temperature and pressure, solidified 1~120 minute down at 80~250 ℃ again, make a kind of hard disk driver magnet.
7. method according to claim 6 is characterized in that, compound binding agent is selected from one or more in phenolics, epoxy resin, liquid crystalline resin, polyamide (nylon), polyphenylene sulfide, the fluorine resin.
8. method according to claim 6, it is characterized in that, also comprised for the 3rd step: high molecular polymer is dissolved in organic solvent, in the solvent, the mass concentration of Molecularly Imprinted Polymer is 20~80%, adopt spraying or electrophoresis in the hard disk driver magnet surface, oven dry or air dry get final product under 20~280 ℃ temperature then.
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CNB2005100266595A CN100403434C (en) | 2005-06-10 | 2005-06-10 | Hard disk driver magnet and its preparation method |
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CNB2005100266595A CN100403434C (en) | 2005-06-10 | 2005-06-10 | Hard disk driver magnet and its preparation method |
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CN1734620A true CN1734620A (en) | 2006-02-15 |
CN100403434C CN100403434C (en) | 2008-07-16 |
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CNB2005100266595A Expired - Fee Related CN100403434C (en) | 2005-06-10 | 2005-06-10 | Hard disk driver magnet and its preparation method |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102005278A (en) * | 2010-11-11 | 2011-04-06 | 湖南航天稀土磁有限责任公司 | Miniature bonding permanent magnet and production method thereof |
CN101299364B (en) * | 2008-03-13 | 2012-07-18 | 上海爱普生磁性器件有限公司 | Agglutinate rare earth magnet for blue laser optical disc drive as well as preparing method thereof |
CN107619603A (en) * | 2017-11-08 | 2018-01-23 | 绵阳美胜邦科技有限公司 | A kind of corrosion-resistant high toughness polyphenyl thioether rare earth composite material and preparation method thereof |
CN107958764A (en) * | 2017-11-07 | 2018-04-24 | 安徽艾贤磁体器件科技有限公司 | A kind of computer CPU radiator fan ultra-thin Agglutinate neodymium-iron-boron magnet and preparation method thereof |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0834165B2 (en) * | 1987-12-23 | 1996-03-29 | セイコーエプソン株式会社 | Rare earth / iron resin-bonded magnet |
JPH01245504A (en) * | 1988-03-28 | 1989-09-29 | Seiko Epson Corp | Rare earth-iron based resin-bonded magnet |
TW338167B (en) * | 1995-10-18 | 1998-08-11 | Seiko Epson Corp | Rare-earth adhesive magnet and rare-earth adhesive magnet components |
CN1595555A (en) * | 2004-06-28 | 2005-03-16 | 广州金南磁塑有限公司 | A rare-earth bonded magnet and method for manufacturing same |
-
2005
- 2005-06-10 CN CNB2005100266595A patent/CN100403434C/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101299364B (en) * | 2008-03-13 | 2012-07-18 | 上海爱普生磁性器件有限公司 | Agglutinate rare earth magnet for blue laser optical disc drive as well as preparing method thereof |
CN102005278A (en) * | 2010-11-11 | 2011-04-06 | 湖南航天稀土磁有限责任公司 | Miniature bonding permanent magnet and production method thereof |
CN102005278B (en) * | 2010-11-11 | 2012-05-23 | 湖南航天稀土磁有限责任公司 | Miniature bonding permanent magnet and production method thereof |
CN107958764A (en) * | 2017-11-07 | 2018-04-24 | 安徽艾贤磁体器件科技有限公司 | A kind of computer CPU radiator fan ultra-thin Agglutinate neodymium-iron-boron magnet and preparation method thereof |
CN107619603A (en) * | 2017-11-08 | 2018-01-23 | 绵阳美胜邦科技有限公司 | A kind of corrosion-resistant high toughness polyphenyl thioether rare earth composite material and preparation method thereof |
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CN100403434C (en) | 2008-07-16 |
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Address after: 201807 No. 3210 Chengbei Road, Jiading Industrial Zone, Shanghai, Jiading District Patentee after: SHANGHAI SAN HUAN MAGNETICS CO., LTD. Address before: 201800 No. 18 Chengbei Road, Shanghai, Jiading District Patentee before: Shanghai Epson Magnetics Co., Ltd. |
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CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080716 Termination date: 20210610 |
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CF01 | Termination of patent right due to non-payment of annual fee |