CN1709961A - Dry-blend-process poly vinyl chloride slushing powder and its production method - Google Patents
Dry-blend-process poly vinyl chloride slushing powder and its production method Download PDFInfo
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- CN1709961A CN1709961A CN 200510016921 CN200510016921A CN1709961A CN 1709961 A CN1709961 A CN 1709961A CN 200510016921 CN200510016921 CN 200510016921 CN 200510016921 A CN200510016921 A CN 200510016921A CN 1709961 A CN1709961 A CN 1709961A
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Abstract
The invention belongs to macromolecule modified material relating to a kind of PVC vitreous enamel plastic powder material and its producing method. The powder material is vitreous enamel powder material used for instrument panel outer cover, which is made by dry-mix method with PVC as parent metal and added several kinds of auxiliary agents. Tested according to the TL52296 Standard of Volkswagen AG., after heating stored for 500 hours at 120 Deg. C, its performance is: breaking strength changing rate 24.3, (which is 77.0% of imported products, and no more than 45% of standard), break elongation rate 70.9%, (which is 22.6% of imported products, and no more than 30% of standard).
Description
Technical field
The invention belongs to macromolecule modified material field, relating to a kind of is base-material with the polyvinyl chloride, adds the polyvinyl chloride slushing powder that multiple auxiliary agent makes and the preparation method of this slushing powder.
Background technology
In recent years, the particularly middle high gear car development of China's automobile industry is very fast.For cooperating the needs of introduction of production line production domesticization, the needed polymer slushing powder of high gear car instrument plate covering in the research and development has become the important topic of researching and developing unit and manufacturing enterprise.At present, be not reported about relating to above information with essence.After it is reported that maximum in the world production firm France atropic company adopts batch mixing, carry out mixing extruding with single-screw machine, and in pulverizing under-100 ℃ of liquid nitrogen deeps approximately, then through collection products such as screening, aftertreatment (see Fig. 1, but its concrete prescription being still unclear).This technique process is longer, and energy consumption is more high.Described slushing powder generally adopts polyvinyl chloride (PVC) base-material.
Summary of the invention
Purpose of the present invention provides car instrument plate covering needed PVC slushing powder in order to cooperate the needs of production domesticization; Another object of the present invention is to solve the deficiency that exists in the existing production technique, provides a kind of dry mix to produce the method for PVC slushing powder.
The objective of the invention is to be achieved by the following technical solutions
A kind of dry mix PVC slushing powder, it is characterized in that: it is made by following raw materials in weight portion and auxiliary agent, and it consists of:
Polyvinyl chloride resin 100 Palamall 654 70 calcium-zinc composite stabilizing agents 2～5
Carbon black 1 ACR201 3～5 octyl stearates 3～5
External lubricant 1～2 PVC sticks with paste resin 8～10
The production method of described PVC slush moulding material, it is required granularity that carbon black is ground; Carry out the raw material metering by the design proportioning; Carry out batch mixing by given prescription, it is characterized in that: start cold mixed stills when the still temperature reaches 120 ℃, high when mixing still temperature rise to 125～135 ℃ in cold mixed still blowing, and material is put to hopper natural ageing 24 hours when being cooled to 90 ℃; Then, above-mentioned work in-process after ageing again through aftertreatment, screening, are collected 80～120 order products.
The present invention compares with French atropic company production technique, and Production Flow Chart is short, and simple to operate, energy consumption obviously reduces.Its product detects according to Volkswagen's TL52296-94 standard, after 120 ℃ of following heat are deposited 500 hours, its breaking tenacity velocity of variation is 24.3% (imported product 77.0%, standard-required≤45%), tension set decline 70.9% (imported product 22.6%, standard-required≤30%).See the following form according to its detailed results of above-mentioned standard detection.
Epidermis test ((pressing TL52296-94)) defective performance (red) synopsis
| Item | Standard | Jiization | Import (existing production) |
| Anti-dry friction | Surface tinctorial pattern gloss no change 〉=4 grades | Visible abrasion mark, 3 grades are arranged | Visible abrasion mark, 2-3 level are arranged |
| The washing composition of anti-dipping friction | Red | Red | |
| 102# gasoline | Surface tinted gloss no change, 〉=4 grades | Qualified | Qualified |
| Sherwood oil | Surface tinted gloss no change, 〉=4 grades | Qualified | Qualified |
| Dehydrated alcohol | Surface tinted gloss no change, 〉=4 grades | Qualified | Qualified |
| Smell C3 | ??C1≤2 ??C2≤3 ??C3≤3 | ??3.0 ??3.0 ??4.5 | ??3.0 ??3.0 ??4.0 |
| 500 hours, 120 ℃ of weathering tests | Red | Red | |
| Tensile strength changes | ??≤45％ | ??24.3％ | ??77％ |
| Tension set changes | ??≤30％ | ??70.9％ | ??22.6％ |
Description of drawings
Fig. 1 France atropic company technological process of production schematic block diagram
Fig. 2 technological process of production schematic block diagram of the present invention
Embodiment
Now with embodiment the present invention is described below in conjunction with the accompanying drawings.
Embodiment
See Fig. 2, PVC slushing powder of the present invention production is made up of following process:
1. carbon black grinds: the carbon black that has prepared on three-roll grinder grinds three times, makes its fineness≤30um;
2. material metering: 100 parts polyvinyl chloride resins, ACR201 (multipolymer of methyl methacrylate and propylene hydrocarbon acid esters) are dropped into high mixing in the stills for 3～5 parts, start and stir after 1 minute, in still, add 2～5 parts of calcium-zinc composite stabilizing agents under stirring, and after 1 minute, add 1 part of ground carbon black again;
3. batch mixing: when the still temperature reaches 35 ℃, continue in still, to add 20 parts of plasticizer P alamall 654 (hexanodioic acid polyhydroxy-alcohol derive Reoplex), 1～3 part of internal lubricant octyl stearate; When rising to 60 ℃, temperature adds 50 parts in above-mentioned softening agent, 2 parts of internal lubricants again; 1～2 part of the external lubricant that when temperature rises to 80 ℃, adds metering again.
4. when the still temperature reaches 120 ℃, start cool mixed still, high mix the still temperature when rising to 125～135 ℃ in cold mixed still blowing, and lower the temperature and material put into hopper 90 ℃ the time, ageing is 24 hours under the state of nature; (can see the present invention and the French atropic company production process from accompanying drawing 1 and Fig. 2 maximum different, be exactly the present invention saved that single screw rod is extruded and-100 ℃ under deep cooling pulverize two step processes) then,
5. with above-mentioned aged work in-process, drop into height and mix in the still, start the low shutdown after 1 minute that mixes, add PVC and stick with paste 8～10 parts of resins in still, continue to stir, blowing entered vibratory screening apparatus and sieves collection 80～120 order products when the still temperature reached 40 ℃.From natural ageing 24 hours, as if prolong and produce the used time, but in fact, when carrying out second batch of aftertreatment, the ageing work in-process material that is equipped with for this approval is ready to, and do not need the people and follow the tracks of operation, so the present invention's while saving of labor again.
Raw material and auxiliary agent that the present invention is used are all bought from the market.
Claims (2)
1, a kind of dry-blend-process poly vinyl chloride slushing powder is characterized in that: it is made by following raw materials in weight portion and auxiliary agent, and it consists of:
Polyvinyl chloride (PVC) RESINS 100 Palamall 654 70 calcium-zinc composite stabilizing agents 2～5
Carbon black 1 ACR201 3～5 octyl stearates 3～5
External lubricant 1～2 pvc resin paste grade 8～10.
2, the production method of polyvinyl chloride slush moulding material as claimed in claim 1 grinds to form desired particle size with carbon black; Carry out the raw material metering by the design proportioning; Carry out batch mixing by given proportioning, it is characterized in that: the still temperature reaches 120 ℃ and starts cold mixed still, high when mixing the still temperature rise as for 125～135 ℃ in cold mixed still blowing, and material is put to hopper when being cooled to 90 ℃, nature ageing 24 hours is collected 80～120 order products again through the work in-process after the ageing after aftertreatment, screening.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100169218A CN1326934C (en) | 2005-06-29 | 2005-06-29 | Dry-blend-process poly vinyl chloride slushing powder and its production method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100169218A CN1326934C (en) | 2005-06-29 | 2005-06-29 | Dry-blend-process poly vinyl chloride slushing powder and its production method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1709961A true CN1709961A (en) | 2005-12-21 |
| CN1326934C CN1326934C (en) | 2007-07-18 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100169218A Expired - Fee Related CN1326934C (en) | 2005-06-29 | 2005-06-29 | Dry-blend-process poly vinyl chloride slushing powder and its production method |
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| CN (1) | CN1326934C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977510A (en) * | 2012-12-11 | 2013-03-20 | 苏州工业园区润佳工程塑料有限公司 | Slush molding PVC (Poly Vinyl Chloride) material for instrument panel covering and preparation method of slush molding PVC material |
| CN103497448A (en) * | 2013-09-30 | 2014-01-08 | 中国科学院长春应用化学研究所 | Polyvinyl chloride slush moulding powder material and preparation method and application thereof |
| CN105085941A (en) * | 2015-08-17 | 2015-11-25 | 山东大学 | Technique for uniformly dispersing inorganic particles in special material for PVC (polyvinyl chloride) slush molding and product thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100341114B1 (en) * | 1999-12-30 | 2002-06-20 | 권문구 | Composition of flame retardant sheath material and cable using the above composition |
| CN1485366A (en) * | 2002-09-28 | 2004-03-31 | 上海赛克力塑料厂 | Environment protection insulated fire-retardant termiteproof cable sheath material made of polyethylene and method for production thereof |
| DE10305562A1 (en) * | 2003-02-10 | 2004-08-26 | Sasol Germany Gmbh | Ester mixtures based on branched alcohols and / or branched acids and their use as a polymer additive |
-
2005
- 2005-06-29 CN CNB2005100169218A patent/CN1326934C/en not_active Expired - Fee Related
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977510A (en) * | 2012-12-11 | 2013-03-20 | 苏州工业园区润佳工程塑料有限公司 | Slush molding PVC (Poly Vinyl Chloride) material for instrument panel covering and preparation method of slush molding PVC material |
| CN102977510B (en) * | 2012-12-11 | 2014-11-12 | 苏州润佳工程塑料股份有限公司 | Slush molding PVC (Poly Vinyl Chloride) material for instrument panel covering and preparation method of slush molding PVC material |
| CN103497448A (en) * | 2013-09-30 | 2014-01-08 | 中国科学院长春应用化学研究所 | Polyvinyl chloride slush moulding powder material and preparation method and application thereof |
| CN103497448B (en) * | 2013-09-30 | 2016-10-12 | 中国科学院长春应用化学研究所 | A kind of polrvinyl chloride slush moulding powder material and preparation method thereof and application thereof |
| CN105085941A (en) * | 2015-08-17 | 2015-11-25 | 山东大学 | Technique for uniformly dispersing inorganic particles in special material for PVC (polyvinyl chloride) slush molding and product thereof |
| CN105085941B (en) * | 2015-08-17 | 2017-10-27 | 山东大学 | The dispersed process of inorganic particulate in PVC slush mouldings PP Pipe Compound and product |
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| Publication number | Publication date |
|---|---|
| CN1326934C (en) | 2007-07-18 |
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