CN1709811A - Chemical-adding, coagulating and precipitating + ABR reactor + aerobic fluidized bed for treating industrial waste water - Google Patents

Chemical-adding, coagulating and precipitating + ABR reactor + aerobic fluidized bed for treating industrial waste water Download PDF

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Publication number
CN1709811A
CN1709811A CNA200510020979XA CN200510020979A CN1709811A CN 1709811 A CN1709811 A CN 1709811A CN A200510020979X A CNA200510020979X A CN A200510020979XA CN 200510020979 A CN200510020979 A CN 200510020979A CN 1709811 A CN1709811 A CN 1709811A
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Prior art keywords
waste water
sludge
bed
abr
filler
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CNA200510020979XA
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Chinese (zh)
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罗良
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Chengdu Weizhuo Environment Sci & Tech Co Ltd
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Chengdu Weizhuo Environment Sci & Tech Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies
    • Y02W10/37Wastewater or sewage treatment systems using renewable energies using solar energy

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Abstract

The invention is mainly used to treat the waste water from high difficulty printing profession, the leather making meatpacking industry's production, which can realize recycling and second-use of the effective resources in production of waste water, and falls the waste water pollution degree to smallest. According to my company in the many years engineering design and the actual movement experience, we summarizes it that suits for the printing, leather making industrial production waste water processing, which has own characteristic of the industrial production waste water processing craft: Adds the coagulation precipitates the ABR reactor + aerobic fluid bed water leakage and achieves the synthesis discharge standard GB8978 - 1996 - best of the standards.

Description

Chemical-adding, coagulating and precipitating+ABR reactor+device+aerobic fluidized bed for treating industrial waste water
Technical field: environment-protective process
Chemical-adding, coagulating and precipitating+ABR reactor+device+aerobic fluidized bed for treating industrial waste water technical applications: manufacture wastewater treatments such as dyeing, process hides processing industry
Technical background
Chemical-adding, coagulating and precipitating+ABR reactor+device+aerobic fluidized bed for treating industrial waste water technical background:
It is the bigger trade effluent of domestic intractability that dyeing, process hides processing industry are concentrated the industrial production waste water of industry park, under the at present domestic situation that rationally reaches feasibility in Technological Economy, general water outlet after treatment can only reach the industry secondary standard, brings pollution to physical environment.
This project research topic is that traditional dyeing waste water treatment process is being improved, adopt flocculating settling+ABR reactor+aerobic fluidized bed art breading waste water, make the waste water after the processing reach the industry first discharge standard, and in operational process, reduce running cost and working strength, reduce pollution physical environment.
Handling water later must not directly drink.
In the patent of invention retrieval following invention is arranged: (seeing Appendix)
1, circulation system at hot does not stop and cleans prefilming agent and clean prefilming method
2, the treatment process and the device thereof that contain pollutents such as of animal or plant nature waste oil
3, combined treatment process under the background of circulating water leakage and treatment facility thereof
4, the micro-control biological enzyme type kitchen tools cabinet of keeping a public place clean
5, bioenzyme picture-dismounting liquid and take off the method for mounting
6, a kind of method that improves the catalase storage stability of microbial method preparation
7, textile auxiliary agent, preparation method and the purposes of the biochemical pre-treatment of a kind of cellulosic fibre and BLENDED FABRIC thereof
8, a kind of enzyme activation prepares alkali soluble fibre element method
9, utilize the biological enzymolysis way to produce paper pulp
10, all cotton woven fabric biological enzyme pad continuously, the decatize pre-treating technology
11, the continuous destarch of a kind of all cotton woven fabric biological enzyme, concise-bath method pre-treating technology
12, all cotton woven fabric amylase, polygalacturonase, proteolytic enzyme pad-the steam method pre-treating technology continuously
13, the using method of biological cleanser in circulating water system
14, timber finishing material biological enzyme pre-treating process
15, use the production method of hemp yarn and natural colorful cotton yarn interlace stitch woven garment
16, a kind of skin care towel and manufacture method
17, cotton and BLENDED FABRIC thereof printing and dyeing pre-treatment-bathe the method continuous production processes
18, a kind of cotton or wash/cotton fabrics biological enzyme pads-the steam method pre-treating technology continuously
19, a kind of cotton or wash/cotton fabrics oxidation dipping interrupter method pre-treating technology
20, a kind of without phosphorus fabric detergent with sequential quadruple detersive power
21, the preparation of water-based biological enzyme newsprinting paper deinking agent
22, a kind of method for disinfection and sterilization of apparatus and cleaning and sterilizing sterilizing device thereof
23, native cellulose fibre pretreating biological enzyme process
Summary of the invention:
Chemical-adding, coagulating and precipitating+ABR reactor+device+aerobic fluidized bed processing industrial production waster water process summary of the invention:
In for many years engineering design and practical operating experiences, sum up the printing-dyeing waste water treatment process that is fit to this type of wastewater treatment, has own characteristic according to my company:
Chemical-adding, coagulating and precipitating+ABR reactor+device+aerobic fluidized bed
Embodiment:
The core process unit of technology is an ABR reactor and aerobic fluidized bed, at the characteristics of printing and dyeing, process hides processing waste water, require each printing and dyeing, leather-making enterprises must be before waste water enters water drain with batik waste water, high basicity waste water, trivalent chromium, sulfide content is high or contain other waste water in the poisonous and hazardous contamination index of Sewage Plant biological process carries out effective pre-treatment and enter the water drain desired value with what reach that sewage work requires.The concrete technical process of sewage work is as follows:
Former water → pH adjusts pond → equalizing tank → lift pump → mechanical waterpower separation sieve → (dosing) → coagulative precipitation tank → ABR hydrolysis (acidifying) pond → aerobic biological fluid-bed → settling tank → oxidation contact tank → discharging
The technology point brief description is as follows:
ABR hydrolysis (acidifying) reactor utilizes the principle of acidication and the work characteristics design of upflow anaerobic sludge blanket process.The ABR principle utilizes first and second stage of anaerobic biological to reach raising wastewater biochemical function, and the purpose of the organic contamination of effectively degrading can be avoided producing the Security Control Problem that methane causes system, and control is oversimplified; Utilize the sludge absorption ability of flow lifting type Sludge Bed and the purpose that higher contaminant removal capacity reaches efficient removal pollutent simultaneously, make and handlingly to improve greatly.
The ABR reactor is managed simultaneously according to economical rationality and simply is easy to the principle controlled, maximizes favourable factors and minimizes unfavourable ones the practical technique of a kind of simple economy of can yet be regarded as.The ABR reactor is economical and effective on contaminant removal efficiency not only, adopts the ABR reactor can effectively reduce the mud generation of Sewage treatment systems simultaneously, reduces system sludge and handles load.
Aerobic biological fluid-bed employing filler fluidization technique, the compatible advantage of activated sludge process with embrane method, it is simpler that system is controlled.This fluidized-bed design simultaneously adopts novel solid open column shape filler as bio-carrier, this technology has been avoided a plurality of problems such as the fluidisation power, demoulding, filler life-span, filler loss of current control techniques difficulty, the filler of traditional fluidization water distribution, effectively reduce power charge, simplified operating process, management puzzlements such as sludge bulking can not appear in a large amount of mud backflow facilities of its non-activity mud method simultaneously.This technology is oversimplified control, low cost makes the organism fluidization bed technique become the practical art that can be widely used in the every profession and trade wastewater treatment.
Fluidization technique makes the contact probability of the microbial film of filling surface and organic pollutant in the waste water and air higher, and these characteristics have been inherited the advantage of activated sludge process.The embrane method technology makes the interior biomass of reaction tank abundanter, and be difficult for running off, make system keep higher anti impulsion load ability, the embrane method technology can be carried out biological segmentation simultaneously, sewage forms concentration gradient with classification, obtain contaminant degradation effect comprehensively and effectively in the different stages in different coenocorrelations, this performance has been given full play to the strong point of embrane method.
Aerobic biological fluid-bed volumetric loading reaches 1.0kgBOD in the actual motion 5/ m 3.d about, simultaneously because biochemical system has possessed the high processing ability, so prime dosing coagulation precipitation dispensing amount significantly reduces, and the integrated water processing cost is reduced greatly.
Remove efficiency analysis
Figure A20051002097900041
Remove efficient ??15% ??- ??30% ??-
The dosing coagulating sedimentation Water inlet ??1700 ??300 ??700 ??500
Remove efficient ??50% ??30% ??80% ??90%
The ABR reaction tank Water inlet ??850 ??210 ??140 ??50
Remove efficient ??40% ??- ??- ??-
Aerobic fluidized bed Water inlet ??510 ??210 ??- ??-
Remove efficient ??82% ??90% ??- ??-
Settling tank Water inlet ??91.8 ??21 ??140 ??50
Remove efficient ??- ??- ??70% ??-
The oxidation contact
Water outlet ??≤100 ??≤25 ??≤70 ??50
Sewage treatment process
◆ sewage treatment process
To produce a certain amount of mud in sewage work's biological wastewater treatment process, contain a certain amount of organism in this part mud, if the mishandling water body that enters again also with the dissolved oxygen in the consume water, causes secondary pollution.Therefore, sludge treatment is one of important content of Sewage Plant, and the processing requirements that general sewage disposal produces mud is as follows:
Reduce the organism in the mud, make mud realize stabilization;
Reduce sludge volume, reduce traffic capacity;
Utilization is to realize recycling sludge;
Sludge of sewage treatment plants is handled generally two kinds of forms, and the one, digestion reconcentration dehydration earlier, the 2nd, direct thickening.Because this engineering treatment scale is less, because of Digestive tract is generally used for large-scale wastewater treatment plant, and investment is high, and control is complicated, and therefore the security requirement height is considered to adopt direct thickening technology that mud is subtracted to hold usually and handled.
◆ the mud concentration technology
Mud concentrates mode, and to mainly contain that gravity concentrates, air supporting concentrates, machinery concentrates etc. several.The concentrated employing of gravity is more, and air supporting concentrates and the concentrated employing of machinery is less, but the trend that increases is arranged this year.Air supporting concentrates and to be used in the dephosphorization process morely, and its facility investment is many, and power consumption is higher, management, safeguards trouble, and investment is big, and is not suitable for this engineering.It is more that machinery concentrates an external application, generally need import equipment, so facility investment is bigger, and after sale service is difficult to guarantee.And traditional gravity concentrates, and effect stability is reliable, can satisfy this engine request fully.
Therefore, this engineering mud concentrates and recommends to adopt the gravity concentration technology.
◆ dewatering technology of mud is selected
Mud after concentrating is because water content is still very high, bulky, and it is easily corrupt smelly, be unfavorable for transportation and disposal,, can reduce the water ratio of mud like this so need carry out processed, reduce the volume of mud, reduce transportation cost, concentrated back mud commonly used can utilize the content of material to increase (as agricultural fertile part, the calorific value that burns etc.), and is beneficial to the follow-up disposal and the utilization of mud.Mud dewatering method commonly used has two kinds of nature mummification and mechanical dehydrations, and seasoning is to utilize a kind of usual way of elements (as sun power) with sludge dehydrating and drying, and commonly used is sludge drying bed traditionally.This method is applicable to that weather is relatively drier, occupation of land takes it easy and the area of environmental health conditions permit, in the less employing of Sewage Plant.Mechanical dehydration is the method that generally adopt present countries in the world.Dewatering machine commonly used has vacuum filter, plate-and-frame filter press, belt filter press and centrifuge.In this year, bowl centrifuge and belt filter press are developed rapidly, are used widely in countries in the world as the main machine of sludge dewatering.
The more three kinds of modes that have are used in sludge dewatering at present, the one, plate-and-frame filter press, the 2nd, centrifuge, the 3rd, belt filter press, see that with regard to dehydrating effect the water ratio of plate-and-frame filter press dehydrated sludge is minimum, can reach 70%-75%, centrifuge and belt filter press are suitable, and water ratio can reach about 75-80%.With regard to construction costs, sheet frame: centrifugal: belt=100: 70: 40.Therefore, the cost performance of belt filter press is best.
Through above-mentioned comparison, and the running condition of domestic dehydration type, this engineering adopts belt filter press.
◆ the sludge disposal mode
Mud disposal options commonly used has burning, landfill or is used for soil improvement.
Contain chemical agent because dyeing waste water produces mud more, should not consider that temporarily transporting outward landfill disposes as soil improvement or incineration disposal.
Water outlet and integrated wastewater discharge standard GB8978-1996 primary standard specific targets after printing and dyeing arrangement industry, the process hides processing industry production wastewater treatment are as follows:
CODcr≤70-85mg/L
BOD5≤20mg/L
SS≤50mg/L
PH<6-9
Colourity<50

Claims (3)

1. chemical-adding, coagulating and precipitating+ABR reactor+device+aerobic fluidized bed for treating industrial waste water.After it is characterized in that industrial production waste water is by the materialization of dosing coagulating sedimentation, enter the ABR reactor,, make the waste water after the processing reach the industry first discharge standard again by aerobic biological fluid-bed.
2. according to the described waster water process of claim 1, it is characterized in that ABR hydrolysis (acidifying) reactor utilizes the principle of acidication and the work characteristics design of upflow anaerobic sludge blanket process.The ABR principle utilizes first and second stage of anaerobic biological to reach raising wastewater biochemical function, and the purpose of the organic contamination of effectively degrading can be avoided producing the Security Control Problem that methane causes system, and control is oversimplified; Utilize the sludge absorption ability of flow lifting type Sludge Bed and the purpose that higher contaminant removal capacity reaches efficient removal pollutent simultaneously, make and handlingly to improve greatly.
3. according to the described waster water process of claim 1, aerobic biological fluid-bed employing filler fluidization technique, the compatible advantage of activated sludge process with embrane method, it is simpler that system is controlled.This fluidized-bed design simultaneously adopts novel solid open column shape filler as bio-carrier, this technology has been avoided a plurality of problems such as the fluidisation power, demoulding, filler life-span, filler loss of current control techniques difficulty, the filler of traditional fluidization water distribution, effectively reduce power charge, simplified operating process, management puzzlements such as sludge bulking can not appear in a large amount of mud backflow facilities of its non-activity mud method simultaneously.
CNA200510020979XA 2005-05-26 2005-05-26 Chemical-adding, coagulating and precipitating + ABR reactor + aerobic fluidized bed for treating industrial waste water Pending CN1709811A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464424A (en) * 2010-11-05 2012-05-23 天津滨海鼎昇环保科技工程有限公司 Coagulation-filtration synergistic biological treatment method of carbide slag wastewater
CN102503049A (en) * 2011-11-24 2012-06-20 苏州科技学院 Process for treating recalcitrant printing and dyeing wastewater by using reactor
CN102807299A (en) * 2011-05-31 2012-12-05 中国科学院大连化学物理研究所 Method for treatment and reuse of dimethyl ether production waste water, and special apparatus thereof
CN104803542A (en) * 2014-01-26 2015-07-29 北京林业大学 Integrated treatment and reuse technology of esterification wastewater
CN106045027A (en) * 2016-05-31 2016-10-26 绍兴水处理发展有限公司 Process of hydrolytic acidification of printing and dyeing wastewater through ABR reactor
CN108892314A (en) * 2018-07-10 2018-11-27 浙江合众环保科技有限公司 A kind of cellulose ether wastewater treatment method

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102464424A (en) * 2010-11-05 2012-05-23 天津滨海鼎昇环保科技工程有限公司 Coagulation-filtration synergistic biological treatment method of carbide slag wastewater
CN102464424B (en) * 2010-11-05 2013-06-12 天津滨海鼎昇环保科技工程有限公司 Coagulation-filtration synergistic biological treatment method of carbide slag wastewater
CN102807299A (en) * 2011-05-31 2012-12-05 中国科学院大连化学物理研究所 Method for treatment and reuse of dimethyl ether production waste water, and special apparatus thereof
CN102807299B (en) * 2011-05-31 2014-05-07 中国科学院大连化学物理研究所 Special apparatus for treatment and reuse of dimethyl ether production waste water
CN102503049A (en) * 2011-11-24 2012-06-20 苏州科技学院 Process for treating recalcitrant printing and dyeing wastewater by using reactor
CN104803542A (en) * 2014-01-26 2015-07-29 北京林业大学 Integrated treatment and reuse technology of esterification wastewater
CN106045027A (en) * 2016-05-31 2016-10-26 绍兴水处理发展有限公司 Process of hydrolytic acidification of printing and dyeing wastewater through ABR reactor
CN108892314A (en) * 2018-07-10 2018-11-27 浙江合众环保科技有限公司 A kind of cellulose ether wastewater treatment method

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