CN1703187A - Hair conditioning composition comprising thickening polymer and cationic surfactant - Google Patents
Hair conditioning composition comprising thickening polymer and cationic surfactant Download PDFInfo
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- CN1703187A CN1703187A CN 200380101234 CN200380101234A CN1703187A CN 1703187 A CN1703187 A CN 1703187A CN 200380101234 CN200380101234 CN 200380101234 CN 200380101234 A CN200380101234 A CN 200380101234A CN 1703187 A CN1703187 A CN 1703187A
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Abstract
Disclosed is a hair conditioning composition comprising: (a) a thickening polymer system selected from the group consisting of a cationic thickening polymer, a nonionic thickening polymer, and mixtures thereof; (b) cationic surfactant system selected from the group consisting of one cationic surfactant, a mixture of two or more cationic surfactants, and a mixture of a cationic surfactant and a nonionic surfactant; and (c) an aqueous carrier; wherein the composition is substantially free of a water-insoluble high melting point oily compound and an anionic compound. Preferably, the conditioning composition further contains a silicone compound selected from the group consisting of a water-soluble silicone compound, a silicone nanoemulsion with an average particle diameter of less than 220nm, and mixtures thereof. The conditioning composition of the present invention has a suitable rheology for conditioning compositions and provides conditioning benefits. The conditioning composition of the present invention is especially suitable for rinse-off use.
Description
Invention field
The present invention relates to hair care composition, described compositions comprises thickening polymer system, cationic surfactant system and is substantially free of the compositions of water-insoluble high-melting-point oiliness compound and anionic compound.Care composition of the present invention has the rheological behavior that is applicable to care composition, and the conditioning beneficial effect is provided.Care composition of the present invention especially is fit to the washing-off type purposes.
Background of invention
Develop the whole bag of tricks and come conditioning hair.The usual method that the conditioning beneficial effect is provided is by using conditioner, as cationic surfactant and polymer, hard fat compounds of group, low melting point oil, silicone compounds, and their mixture.These conditioners of known great majority can provide various conditioning beneficial effects.For example, when using with some hard fat compounds of group, it is believed that some cationic surfactant can provide gel-type vehicle, this substrate has the rheological behavior that is suitable for care composition and is suitable for providing multiple conditioning beneficial effect, especially when being used for hair care product, twine as the wet smooth feeling of sending out, flexibility and minimizing, and flexibility and moist feeling during trichoxerosis.
Need in the conditioning beneficial effect that keeps gel-type vehicle, use other method rather than form above-mentioned gel-type vehicle, obtain to be suitable for the rheological behavior of care composition.
In addition, also known, most of above-mentioned conditioners can make compositions become opaque.Therefore, need care composition to have clarifying product appearance, promptly transparent or semitransparent product appearance.
In addition, also known, most of above-mentioned conditioners can force down hair.For those wished maintenance or the increase relief consumer of hair (consumer thinner as hair), it was undesirable that hair forces down.Therefore, need a kind of hair care composition, it can not force down hair when the conditioning beneficial effect is provided.
Also need a kind of care composition, when said composition was used with the rinse-off products form, it can make consumer feel to be easy to rinsing when the conditioning beneficial effect is provided.When the flushing hair, the conditioner composition that comprises above-mentioned gel-type vehicle also provides competent smooth feeling.Therefore, need a kind of care composition, it can be easy to leave hair and produce clean feel when the flushing hair, can deposit the conditioner of q.s simultaneously on hair.
Described based on preamble, need a kind of care composition, it can be when providing conditioning beneficial effect, an especially wet flexibility and reducing to twine, by using other method rather than forming gel-type vehicle, have the rheological behavior that is suitable for care composition, wherein said gel-type vehicle is made up of cationic surfactant and hard fat compounds of group.Also need above-mentioned care composition when above-mentioned rheological behavior and conditioning beneficial effect are provided, be suitable for providing further beneficial effect, as clarifying product appearance, do not force down hair, and be easy to the rinsing sense.
Can provide whole advantage of the present invention and beneficial effect without any prior art.
Summary of the invention
The present invention relates to hair care composition, said composition comprises by weight:
(a) about 0.01% to about 10% thickening polymer system (thickening polymersystem), it is selected from cationic thickening polymer, nonionic thickening polymer, and their mixture;
(b) about 0.05% to about 10% cationic surfactant system, it is selected from a kind of cationic surfactant, the mixture of the mixture of two or more cationic surfactants and cationic surfactant and non-ionic surface active agent; With
(c) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound and anionic compound.
The invention still further relates to hair care composition, said composition comprises by weight:
(a) about 0.5% to about 5% thickening polymer system, it is selected from cationic thickening polymer, nonionic thickening polymer, and their mixture;
(b) about 0.25% to about 7% cationic surfactant system, it is selected from a kind of cationic surfactant, the mixture of the mixture of two or more cationic surfactants and cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds, it is selected from the water-soluble silicon siloxane compound, and mean diameter is less than the siloxanes nanoemulsions of 220nm, and their mixture; With
(d) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound and anionic compound.
The invention further relates to hair care composition, said composition comprises by weight:
(a) about 0.5% to about 5% nonionic thickening polymer;
(b) about 0.25% to about 7% cationic surfactant system, it is selected from a kind of cationic surfactant, the mixture of the mixture of two or more cationic surfactants and cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds, it is selected from the water-soluble silicon siloxane compound, and mean diameter is less than the siloxanes nanoemulsions of 220nm, and their mixture; With
(d) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound, anionic compound and cationic thickening polymer.
By reading following detailed and appending claims, can understand these and other feature, aspect and advantage of the present invention better.
Detailed Description Of The Invention
Although this description it is believed that by following explanation to understand the present invention better with by particularly pointing out and clearly claimed claims of the present invention are drawn a conclusion.
In this article, " comprise " and be meant and add other step of not influencing final result and other composition.This term comprise term " by ... form " and " basically by ... composition ".
Except as otherwise noted, all percent than, umber and ratio all in the gross weight of the present composition.All relate to the above-mentioned weight of ingredients listed all in activity substance content, and therefore do not comprise the carrier or the by-product that may be included in the commercially available material.
Herein, " mixture " will comprise the simple combination of material and make up issuable any chemical compound by them.
Compositions
The present invention relates to hair care composition, said composition comprises by weight:
The present invention relates to hair care composition (compositions A), said composition comprises by weight:
(a) about 0.01% to about 10% thickening polymer system, it is selected from cationic thickening polymer, nonionic thickening polymer, and their mixture;
(b) about 0.05% to about 10% cationic surfactant system, it is selected from the mixture of a kind of cationic surfactant, two or more cationic surfactants and the mixture of cationic surfactant and non-ionic surface active agent; With
(c) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound and anionic compound.
The invention still further relates to hair care composition (compositions B), said composition comprises by weight:
(a) about 0.5% to about 5% thickening polymer system, it is selected from cationic thickening polymer, nonionic thickening polymer, and their mixture;
(b) about 0.25% to about 7% cationic surfactant system, it is selected from a kind of cationic surfactant, the mixture of two or more cationic surfactants, and the mixture of cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds (silicone compound), it is selected from the water-soluble silicon siloxane compound, and mean diameter is less than the siloxanes nanoemulsions of 220nm, and their mixture; With
(d) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound and anionic compound.
The invention further relates to hair care composition (compositions C), said composition comprises by weight:
(a) about 0.5% to about 5% nonionic thickening polymer;
(b) about 0.25% to about 7% cationic surfactant system, it is selected from a kind of cationic surfactant, the mixture of the mixture of two or more cationic surfactants and cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds, it is selected from the water-soluble silicon siloxane compound, and mean diameter is less than the siloxanes nanoemulsions of 220nm, and their mixture; With
(d) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound, anionic compound and cationic thickening polymer.
Care composition of the present invention has the rheological behavior that is suitable for care composition, and the conditioning beneficial effect is provided, and the especially wet flexibility of sending out is twined with reducing.It is believed that, combination by cation and nonionic thickening polymer and cationic surfactant, compositions of the present invention can be when providing conditioning beneficial effect (the especially wet flexibility of sending out is twined with minimizing), the rheological behavior that is suitable for care composition is provided, and does not have the gel-type vehicle of forming by cationic surfactant and hard fat compounds of group.
Care composition of the present invention is suitable for providing further beneficial effect when above-mentioned rheological behavior and conditioning beneficial effect are provided, as clarifying product appearance, do not force down hair, and be easy to the rinsing sense.Therefore, compositions of the present invention also can provide clarifying product appearance except above-mentioned rheological behavior and conditioning beneficial effect are provided.Compositions of the present invention can provide above-mentioned rheological behavior and conditioning beneficial effect, does not force down hair simultaneously.In addition, when using with the rinse-off products form, compositions of the present invention can provide to be easy to the rinsing sense when above-mentioned rheological behavior and conditioning beneficial effect are provided.
In the present invention, compositions " is substantially free of water-insoluble high-melting-point oiliness compound " and is meant, described compositions comprise 1.0% or still less, preferred 0.5% or still less, more preferably 0.1% or still less, more preferably 0% water-insoluble high-melting-point oiliness compound also.The water-insoluble high-melting-point oiliness compound of this paper be fusing point when being at least about 25 ℃ and 25 ℃ in the water dissolubility less than about 1g/100g water, preferably less than about 0.5g/100g water, be more preferably less than those of about 0g/100g water.This water-insoluble high-melting-point oiliness compound comprises, for example, aliphatic alcohol such as spermol and stearyl alcohol, fatty acid such as stearic acid, fatty alcohol derivative and derivative of fatty acid such as cetin, hydrocarbon such as wax, steroidal compounds such as cholesterol, and their mixture.
In the present invention, compositions " is substantially free of anionic compound " and is meant, said composition comprise 1% or still less, preferred 0.5% or still less, more preferably 0% anionic compound.The anionic compound of this paper comprises anion surfactant and anionic polymer.
In the present invention, compositions C is substantially free of cationic thickening polymer.Compositions " is substantially free of cationic thickening polymer " and is meant, said composition comprise 1.0% or still less, preferred 0.5% or still less, more preferably 0.1% or still less, more preferably 0% cationic thickening polymer also.
In the present invention, compositions preferably clear or translucent, and more preferably transparent.In the present invention, compositions is being meant of " transparent ", the transmittance of said composition greater than about 30%, be preferably greater than about 50%, more preferably greater than about 80%.Available any standard spectrophotometer is compared with deionized water and to be measured transmittance.In the present invention, compositions is being meant of " transparent ", and compositions has (i) turbidity simultaneously less than about 3,000NTU (Nephelometric turbidity unit) and (ii) transmittance less than 50%, preferably less than about 30%.The available Hach 2100N laboratory transmissometer with the Formazin standard calibration available from Hach Company comes measuring N TU value.
Preferably, compositions A also comprises silicone compounds, and wherein said silicone compounds is preferably selected from the water-soluble silicon siloxane compound, and mean diameter is less than the siloxanes nanoemulsions of 220nm, and their mixture.
Said composition also can comprise wetting agent, as Polyethylene Glycol.Said composition also can comprise defoamer.
Thickening polymer
Compositions of the present invention comprises thickening polymer.Can be used for thickening polymer of the present invention and be and to provide those of suitable viscosity and rheological properties to compositions, so that the appropriate viscosity that the present composition had is about 1,000 to about 100,000mPa.s (cP), preferred about 1,000 to about 50,000mPa.s (cP), more preferably from about 2,000 to about 50,000mPa.s (cP),, 000mPa.s (cP) also more preferably from about 5,000 to about 20.The viscosity of this paper can suitably be measured with the shear rate of 2s-1 with Brookfield RVT down at 26.7 ℃.
Compositions of the present invention comprise about by weight 0.01% to about 10%, preferred about 0.05% to about 8%, more preferably from about 0.1% to about 5%, also more preferably from about 0.5% to about 4% even more preferably from about 0.6% to about 3%, total thickening polymer of preferred about 1.0% to about 2.5% highly.
Multiple thickening polymer can be used in the compositions of the present invention.Can be used for thickening polymer of the present invention and comprise, for example, cellulose and derivant thereof are as the cellulose ether and the quaternised cellulose of cellulose ether, hydrophobically modified; Guar gum comprises cationic guar gum and nonionic guar gum; Cross linked polymer is as nonionic cross linked polymer and cationic crosslinked polymer; And acrylate polymer, as sodium polyacrylate, polyvinyl acrylate and polyacrylamide.Can be used for thickening polymer of the present invention can comprise to use the following polymer of name of product " cationic conditioning polymer " announcement of appearance design.In various thickening polymers, compositions of the present invention comprises cationic thickening polymer, nonionic thickening polymer, or their mixture.
In a preferred embodiment, according to the conditioning beneficial effect that is provided, compositions of the present invention comprises the thickening polymer system, and described polymeric system comprises the mixture of cationic thickening polymer and nonionic thickening polymer.Above-mentioned thickened systems is a cationic system.In the present invention, " cationic system " refers to this system and comprises at least a cationic thickener.In above-mentioned preferred cationic thickened systems, said composition is substantially free of anionic compound, as anion surfactant and anionic polymer.In the present invention, compositions " is substantially free of anionic compound " and is meant, said composition comprise 1% or still less, preferred 0.5% or still less, more preferably 0% anionic compound.
In a further preferred embodiment, compositions of the present invention comprises the nonionic thickening polymer, and said composition is substantially free of cationic thickening polymer.
Can be used for thickening polymer of the present invention or system has improved and compatibility cation opsonizing agent (as cationic surfactant).
Guar gum polymer (guar polymer)
In this compositions, the preferred guar gum polymer that uses in various thickening polymers.
Can be used for cation substitution value that cationic guar gum polymer of the present invention had and be preferably about 0.05, and the molecular weight that is had is preferably about 100,000 to about 3,000,000, more preferably from about 1,000,000 to about 2,400,000 to about 0.3.In the present invention, the cation substitution value is the integer that is obtained from following formula: the hydroxyl value that cation replaces is divided by all hydroxyl values before replacing.Can be used for commercially available cationic guar gum polymer of the present invention comprises, for example, (molecular weight is about 1,500,000 available from the Rhaball Gum CG-M 8M of Rhodia with trade name Jaguar Excel, the cation substitution value is about 0.15), (molecular weight is about 1 available from the Rhaball Gum CG-M 8M of Rhodia with trade name Jaguar CHJ, 000,000 to about 1,500,000, the cation substitution value is about 0.25).By weight, the content of this cationic guar gum polymer in compositions is preferably about 0.1% to 4%, more preferably 0.3% to 2%.
Can be used for the molecular weight that nonionic guar gum polymer of the present invention had and be preferably about 500,000 to about 4,000,000, more preferably from about 1,000,000 to about 4,000,000, also more preferably from about 1,600,000 to about 3,000,000 even more preferably from about 1,900,000 to about 2,800,000.Can be used for commercially available nonionic guar gum polymer of the present invention and comprise, for example, molecular weight is about 2,000,000 and with trade name Jaguar HP-105 the sort of available from Rhodia.By weight, the content of this nonionic guar gum polymer in compositions is preferably about 0.1% to 3%, more preferably from about 0.3% to 2.5%.
Cationic surfactant system
Compositions of the present invention comprises cationic surfactant system.By weight, the content of cationic surfactant system in compositions be about 0.05% to about 10%, preferred about 0.25% to about 7%, more preferably from about 0.3% to about 5%, also more preferably from about 0.4% to about 3%.
Cationic surfactant system is selected from the mixture of mixture, cationic surfactant and the non-ionic surface active agent of a kind of cationic surfactant, two or more cationic surfactants.When compositions comprises the thickening polymer system, wherein said system comprises cationic thickening polymer and nonionic thickening polymer, and described cationic surfactant system is preferably the mixture of a kind of cationic surfactant or two or more cationic surfactants.In compositions C, cationic surfactant system is preferably the mixture of two or more cationic surfactants, or the mixture of cationic surfactant and non-ionic surface active agent.
Cationic surfactant
In compositions of the present invention, in the described below multiple cationic surfactant, preferably use monoalkyltrimethyl ammonium salts.Can be used for monoalkyltrimethyl ammonium salts of the present invention and contain those of 12 to 28 carbon atoms, preferred 16 to 22 carbon atoms for alkyl wherein.Can be used for monoalkyltrimethyl ammonium salts of the present invention and comprise, for example, cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride.
Can be used for cationic surfactant of the present invention and comprise, for example, those of general molecular formula (I):
At least one R wherein
71, R
72, R
73And R
74Be selected from aliphatic group or have aromatics, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxy alkyl, aryl or alkylaryl, remaining R up to about 22 carbon atoms with 8 to 30 carbon atoms
71, R
72, R
73And R
74Be independently selected from and have 1 to the aliphatic group of about 22 carbon atoms or have aromatics, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxy alkyl, aryl or alkylaryl up to about 22 carbon atoms; X is into salt anionic as being selected from those of halogen (as chloride ion, bromide ion), acetate, citrate, lactate, glycolate, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl azochlorosulfonate group.Except carbon atom and hydrogen atom, aliphatic group also can comprise ehter bond and other group such as amino.Than the aliphatic group of long-chain, as have about 12 carbon atoms or more those, can be saturated or unsaturated.Work as R
71, R
72, R
73And R
74Be independently selected from C
1To about C
22During alkyl, be preferred.The non-limiting example that can be used for cationic surfactant of the present invention comprises the material with following CTFA name: quaternary ammonium-8, quaternary ammonium-14, quaternary ammonium-18, quaternary ammonium-18 dimethyl sulfate, quaternary ammonium-24, and their mixture.
In the middle of the cationic surfactant of general formula (I), preferably those comprise the alkyl that at least one has at least 16 carbon atoms in molecule.The non-limiting example of above-mentioned preferred cationic surfactants comprises: INCROQUAT TMC-80 ECONOL TM22, it can, for example, with trade name GenamineKDMP available from Clariant, with trade name INCROQUAT TMC-80 available from Croda and with trade name ECONOL TM22 available from Sanyo Kasei; The cetyl trimethyl ammonium chloride, its can, for example, with trade name CTAC 30KC available from KCI and with trade name CA-2350 available from Nikko Chemicals; The stearyl trimethyl ammonium chloride, its can, for example, with trade name Genamine STACP available from Clariant; The myristyl dimethyl benzyl ammonium chloride, its can, for example, with trade name Incroquat O-50 available from Croda; The hydrogenated tallow alkyl trimethyl ammonium chloride; dialkyl group (14-18) alkyl dimethyl ammonium chloride; two tallow alkyl alkyl dimethyl ammonium chlorides; dihydro tallow alkyl alkyl dimethyl ammonium chloride; VARISOFT TA100; Varisoft 432PPG; two (docosyl/eicosyl) alkyl dimethyl ammonium chloride; two docosyl alkyl dimethyl ammonium chlorides; the stearyl dimethyl benzyl ammonium chloride; stearyl propylene glycol phosphate ester alkyl dimethyl ammonium chloride; stearoyl amido propyl dimethyl benzyl ammonium chloride; stearoyl amido propyl dimethyl (myristyl acetate) ammonium chloride; with chlorination N-(stearoyl cholamine base formoxyl methyl) pyridine.
The cationic surfactant that preferably also has hydrophilic replacement, wherein at least one substituent group comprises one or more aromatics, ether, ester, amide or amino part, wherein R that show as substituent group in the group chain or coupling part
71To R
74At least one contains one or more hydrophilic segments in the group, and described hydrophilic segment is selected from alkoxyl (preferred C
1To C
3Alkoxyl), polyoxyalkylenes (preferred C
1To C
3Polyoxyalkylenes), alkyl amido, hydroxy alkyl, Arrcostab, and their combination.Preferably, the cationic conditioning surfactant of this hydrophilic replacement contains 2 to about 10 nonionic hydrophilic segments that are positioned at above-mentioned scope.Highly preferred hydrophilic replacement cationic surfactant comprises dialkyl group acylamino-ethyl-hydroxyethyl ammonium salt, dialkyl group acylamino-ethyl di-ammonium salts, two alkanoyl ethyl-hydroxyethyl ammonium salts, two alkanoyl second di-ammonium salts, and their mixture; For example commercially available: VARISOFT110 with following trade name, VARISOFT222, VARIQUAT K1215 and VARIQUAT638 (available from WitcoChemical), MACKPRO KLP, MACKPRO WLW, MACKPRO MLP, MACKPRO NSP, MACKPRO NLW, MACKPRO WWP, MACKPRO NLP, MACKPRO SLP (available from McIntyre), ETHOQUAD 18/25, ETHOQUAD O/12PG, ETHOQUAD C/25, ETHOQUAD S/25 and ETHODUOQUAD (available from Akzo), DEHYQUAT SP (available from Henkel) and ATLAS G265 (available from ICI Americas).Also be preferred in the said composition available from the babassu base acylamino-propyl group alkyl ammomium chloride of Croda with trade name Incroquat BA-85.
Amine is suitable for as cationic surfactant.The primary, the second month in a season and uncle's fatty amine also are available.Especially available is to have the about 12 uncle's amidoamines to about 22 carbon atom alkyls.Exemplary uncle's amidoamines comprises: the amino propyl group dimethylamine of stearoyl, the amino propyl group diethylamide of stearoyl, the amino ethyl diethylamide of stearoyl, the amino ethyl dimethyl amine of stearoyl, palmityl aminopropyl dimethyl amine, palmityl aminopropyl diethylamide, palmityl amino-ethyl diethylamide, palmityl amino-ethyl dimethyl amine, docosane acylamino-propyl-dimethyl amine, docosane acylamino-propyl group diethylamide, docosane acylamino-ethyl diethylamide, docosane acylamino-ethyl dimethyl amine, eicosane acylamino-propyl-dimethyl amine, eicosane acylamino-propyl group diethylamide, eicosane acylamino-ethyl diethylamide, eicosane acylamino-ethyl dimethyl amine, diethylamino ethyl stearmide.Stearic amine, dihydroxy ethyl stearic amine and the eicosyl docosyl amine that dimethyl stearic amine, dimethyl Semen sojae atricolor amine, Semen sojae atricolor amine, tetradecylamine, tridecyl amine, ethyl stearic amine, N-Adeps Bovis seu Bubali propane diamine, ethoxylation (having 5 moles of ethylene oxide) are arranged of Shi Yonging also.Available amine is disclosed in people's such as Nachtigal the United States Patent (USP) 4,275,055 among the present invention.These amine also can be united use with acid, as l-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, l-glutamic acid hydrochloride, maleic acid, and their mixture; More preferably l-glutamic acid, lactic acid, citric acid.Preferably with any one the part neutralization in these acid, wherein amine is about 1: 0.3 to about 1: 2, more preferably from about 1: 0.4 to about 1: 1 with the mol ratio of acid to amine herein.
Non-ionic surface active agent
Can be used for non-ionic surface active agent of the present invention is that the HLB value is those of about 8 to about 20, preferred about 10 to about 18, more preferably from about 12 to about 15.In various non-ionic surface active agents, it is highly preferred that the ethylene glycol ether of aliphatic alcohol.In the middle of them, especially preferred is Ceteth-10, pareth-12 and Laureth-9.
Aqueous carrier
Compositions of the present invention comprises aqueous carrier.According to selecting the content and the kind of carrier with required other characteristic of the compatibility of other component and product.
Preferably, aqueous carrier is water basically.The preferred deionized water that uses.The characteristic required according to product also can be used the water of the natural origin that comprises mineral cation.Usually, compositions of the present invention comprises about 20% to about water of 99%, preferred about 40% to about 98% and more preferably from about 50% to about 98%.
The pH value of the present composition is preferably about 3 to about 9, more preferably from about 3 to about 7.For obtaining required pH, can comprise buffer agent and other pH regulator agent.
Silicone compounds
Preferably, compositions of the present invention comprises silicone compounds.The consumption of this paper silicone compounds by the weight of described compositions be preferably about 0.1% to about 20%, more preferably from about 0.15% to about 10%, also more preferably from about 0.2% to about 5%.
The silicone compounds that can be used for this paper is preferably about 0.0001 (100) to about 2m 25 ℃ of viscosity that had down
2/ s (2,000,000cSt).Can use glass capillary tube viscometer to measure viscosity, described in the Dow Corning Corporate Test Method CTM0004 on July 20th, 1970.
In various silicone compounds, preferably be selected from those of water-soluble silicon siloxane compound, siloxanes nanoemulsions and their mixture in the compositions of the present invention.In the present invention, " water solublity " silicone compounds is meant, the dissolubility of 25 ℃ of following silicone compounds in water is 0.05g/100g water at least, preferably 0.1g/100g water, more preferably 0.2g/100g water at least at least.In the present invention, " water solublity " silicone compounds refers to that also in the presence of surfactant, silicone compounds is water-soluble.Dimethicone copolyol, amino-terminated dimethicone copolyol and quaternized siloxanes can be water miscible, and this depends on the alcoxylates chain in their structures and the content of quaternized ammonium groups.Can be used for commercially available water-soluble silicon siloxane compound of the present invention comprises, for example, (the INCI name is called PEG-12 methyl ether/Lauroxy PEG-5 amido propyl polydimethylsiloxane for dimethicone copolyol (commodity are called Silicone DC-5330) and amide groups dimethicone copolyol, buy with trade name Silicone BY16-906), and amino-terminated polydimethylsiloxane (the INCI name is called the amino-terminated polydimethylsiloxane of two (C13-15 alkoxyl) PG, buy with trade name DC2-8500), all available from Dow Corning.In the present invention, " nanoemulsions " of silicone compounds is meant, in compositions, the mean diameter of described emulsion is 220nm or littler, preferred 100nm or littler, more preferably 50nm or littler to silicone compounds with dispersed as emulsions.The silicone compounds that can be used for commercially available nanoemulsions form of the present invention comprises, for example, and with the siloxanes nanoemulsions of trade name Silicone DC-8177 available from Dow Corning; With the quaternized siloxanes nanoemulsions of trade name DC5-7133 available from Dow Corning; With the amino-terminated polydimethylsiloxane nanoemulsions of trade name XS65-B6413 available from General Electric; With with trade name DC2-8168 and DC2-8194 amino-terminated polydimethylsiloxane nanoemulsions available from Dow Corning.
Can be used for highly preferred water-soluble silicon siloxane compound of the present invention is the amide groups polydimethylsiloxane with hydrophobically modified of following formula:
R wherein
1, R
2, R
4Be respectively the C1-C3 alkyl, preferred ethyl; R
3For having 8 to 22 carbon atoms, preferred 10 to 20 carbon atoms, more preferably 12 to 16 carbon atoms even the more preferably alkyl of 12 carbon atoms; R
5Be H or C1-C3 alkyl, preferable methyl; R
6Be OH or CH
3, preferable methyl; N is 1 to 10 integer, highly preferred 5; M is 2 to 20 integer, highly preferred 12; N+m=3 to 30, preferred 5 to 25, more preferably 8 to 20, even more preferably 17; X is 200 to 500, preferred 300 to 400 integer; Y is 5 to 40, preferred 10 to 30 integer; And z is 0, or 1 to 30, preferred 5 to 20 integer.Can be used for commercially available hydrophobically modified amide groups dimethicone copolyol of the present invention and comprise, for example, with trade name BY16-906 available from those of Dow Corning.
Other siloxanes hair-conditioning characteristic also can be used for said composition.Above-mentioned siloxanes comprises, for example, and poly-alkylsiloxane (as available from TSF 451 series of General Electric Company with available from the polydimethylsiloxane of the Dow Corning SH200 series of DowCorning); Poly-aryl siloxanes; The polyoxyethylene alkyl aryl radical siloxane; Polyether siloxane copolymer; The amino siloxanes (as with the amino-terminated polydimethylsiloxane of trade name BY16-872) that replaces available from Dow Corning; Quaternized siloxanes (as with trade name UCAR SILICONE ALE 56 available from Union Carbide and with trade name Ultrasil Q-Plus available from those of Noveon); And their mixture.
Cationic conditioning polymer
Hair care composition of the present invention also can further comprise cationic conditioning polymer.The common weight average molecular weight that has of cationic polymer herein is at least about 5,000, the typical case is at least about 10,000, and less than about 100,000,000, preferably, its molecular weight is about 100,000 to about 200 ten thousand.The cationic polymer that can be used for this paper can comprise to use name of product " thickening polymer " the announcement polymer as above of appearance design.
The content of cationic conditioning polymer in compositions is preferably about 0.01% to about 10%, more preferably from about 0.05% to about 5% by weight.
In compositions of the present invention, cationic conditioning polymer is preferably water miscible." water solublity " cationic polymer is meant that can fully be dissolved in water down at 25 ℃ is the polymer of 0.05% water (distilled water or equivalent) solution to form the clarifying basically concentration of naked eyes.Preferred polymer can fully dissolve to form clear solutions basically, and its concentration is 0.1%, more preferably 0.2%.
This cationic polymer has nitrogenous cationic moiety usually, as quaternary ammonium ion or cation amino part, and their mixture.According to the concrete kind and the pH value of compositions, cationic amine can be primary, the second month in a season or tertiary amine.Usually, preferred secondary amine and tertiary amine, especially preferred tertiary amine.The vinyl monomer that amine replaces can amine the form polymerization, can randomly change into ammonium then by quaterisation.Amine also can be quaternized similarly after forming polymer.For example, the tertiary amine degree of functionality can by with formula be R
88The reactant salt of X and quaternized, wherein R
88Be short-chain alkyl, preferred C
1-C
7Alkyl, more preferably C
1-C
3Alkyl, and X is for becoming salt anionic as defined above.Any anionic counter-ion can be used in this cationic polymer, as long as it meets the water solubility standard.Suitable counter ion counterionsl gegenions comprise halide ion (for example CI, Br, I or F, preferably Cl, Br or I), sulfate radical and methyl ester sulfate radical.Because this tabulation is not unique, therefore can also use other counter ion counterionsl gegenions.
Suitable cationic conditioning polymer comprises, for example: l-vinyl-2-pyrrolidone and 1-vinyl-3-methylimidazole salt (as, chloride salt) copolymer is (industrial by Cosmetic, Toiletry, and Fragrance Association, " CTFA " is called polyquaternary ammonium salt-16), as with trade name LUVIQUAT available from BASF Wyandotte Corp. (Parsippany, NJ, USA) those (as, LUVIQUAT FC 370); The copolymer of l-vinyl-2-pyrrolidone and dimethylamino methyl ethyl acrylate (being called polyquaternary ammonium salt-11 by CTFA) industrial, as with trade name GAFQUAT available from GafCorporation (Wayne, NJ, USA) those (as, GAFQUAT 755N); The polymer of cation diallyl quaternary ammonium ion, comprise, the copolymer of dimethyl diallyl ammonium chloride homopolymer and acrylamide and dimethyl diallyl ammonium chloride for example, be called polyquaternary ammonium salt-6 and polyquaternary ammonium salt-7 at industrial (CTFA), polyquaternary ammonium salt-7 comprises with trade name Merquat550 available from those of OndeoNalco; Polyisobutylene acyl group amido propyl trimethyl ammonia chloride, as with trade name Polycare133 available from those of Rhone-Poulenc; And with trade name Synthalen CR, Synthalen CU and Synthalen CN polyquaternary ammonium salt-37 available from 3V Sigma.
The cationic conditioning polymer that this paper is also suitable comprises cationic cellulose derivative.Can be used for cationic cellulose derivative of the present invention and comprise, for example, the epoxide reaction that hydroxyethyl-cellulose and trimethyl ammonium replace and the salt that generates, it is known as polyquaternary ammonium salt 10 at industrial (CTFA), with their polymer JR
And LR
Series available from Amerchol Corp. (Edison, NJ, USA), and with trade name Celquat SC-230M available from National Starch ﹠amp; Chemical; The epoxide reaction that hydroxyethyl-cellulose and lauryl dimethyl ammonium replace and the polymeric quaternary ammonium salts that generates is called polyquaternary ammonium salt 24 at industrial (CTFA), with trade name Polymer LM-200
Available from Amerchol Corp. (Edison, NJ, USA); With with trade name Celquat H-100 available from National Starch ﹠amp; The polyquaternary ammonium salt of Chemical-4.
Other suitable cationic conditioning polymer comprises the cationic guar gum derivant, as with their Jaguar series available from the Rhaball Gum CG-M 8M of Rhodia.
Wetting agent
Compositions of the present invention also comprises wetting agent.Wetting agent of the present invention is selected from polyhydric alcohol, water soluble alkoxylated non-ionic polymers, and their mixture.The consumption of this paper wetting agent is preferably about 0.1% to about 20%, more preferably from about 0.5% to about 5% by the weight of described compositions.
Can be used for polyhydric alcohol of the present invention and comprise glycerol, sorbitol, propylene glycol, butanediol, hexene ethylene glycol, ethoxylated glucose, 1,2-hexanediol, hexanetriol, dipropylene glycol, erithritol, trehalose, diglycerol, xylitol, maltose alcohol, maltose, glucose, fructose, sodium chondroitin sulfate, hyaluronate sodium, adenylic acid sodium, sodium lactate, ketopyrrolidine carbonate, glycosamine, cyclodextrin, and their mixture.
The water soluble alkoxylated non-ionic polymers that can be used for this paper comprises molecular weight up to about 10,000 Polyethylene Glycol and polypropylene glycol, for example those of CTFA called after PEG-4, PEG-8, PEG-12, PEG-20, PEG-150, and their mixture.
Annexing ingredient
Compositions of the present invention can comprise other annexing ingredient, described annexing ingredient can be selected by those skilled in the art according to the required characteristic of end product, and it is suitable for making said composition in beauty treatment or aestheticly more can accept, and perhaps provides additional use beneficial effect for them.Usually, the independent consumption of above-mentioned other annexing ingredient by the weight of described compositions count about 0.001% to about 10%, preferably up to about 5%.
Various other annexing ingredients can be formulated in the compositions of the present invention.These compositions comprise: other conditioner, as hydrolytic collagen (with trade name Peptein2000 available from Hormel), vitamin E (with trade name Emix-d available from Eisai), pantothenylol (available from Roche), pantoyl ethylether (available from Roche); Non-ionic surface active agent is as tristerin (available from StepanChemicals), hydrolysis of keratin, protein, plant extract and nutrient substance; Emollient is as PPG-3 myristyl ether (with trade name Varonic APM available from Goldschmidt), trimethyl amylalcohol hydroxyethyl ether, PPG-11 stearyl ether (with trade name Varonic APS available from Goldschmidt), stearyl heptanoate (with trade name Tegosoft SH available from Goldschmidt), Lactil (sodium lactate, PCA sodium, glycine, fructose, urine, nicotiamide, inositol, the mixture of sodium benzoate and lactic acid) (available from Goldschmidt), the ethylhexyl cetylate (with trade name Saracos available from Nishin Seiyu and with trade name Tegosoft OP available from Goldschmidt); The hair fixed polymer is as both sexes fixed polymer, stationary cation polymer, anion fixed polymer, nonionic fixed polymer and silicone grafted copolymer; Antiseptic is as benzyl alcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; The pH regulator agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is usually as potassium acetate and sodium chloride; Coloring agent is as any FD﹠amp; C or D﹠amp; The C dyestuff; Hair oxidation (bleaching) agent is as hydrogen peroxide, perborate and persulfate; The hair Reducing agent is as thioglycolate salt; Spice; And sequestering agent, as disodiumedetate; Ultraviolet and infrared shield agent and absorbent are as ethylhexyl salicylate; The dandruff agent is as arsenic sulfur zinc and salicylic acid; Visible particle (with trade name Unisphere and Unicerin available from Induchem AG[Switzerland]); And defoamer, as with trade name XS63-B8929 available from those of GE-Toshiba Silicone.
Product form
Hair care composition of the present invention can be rinse-off products or leave product form, can be transparent, translucent or opaque, and can be mixed with various product forms, includes but not limited to cream, gel, emulsion, mousse and spray.
Care composition of the present invention especially is fit to the washing-off type purposes.Above-mentioned composition preferably follows these steps to use:
(i) after shampoo is sent out, the care composition of effective dose is applied on the hair with conditioning hair; Know
(ii) wash hair then.
Embodiment
The following example has further described and has illustrated the embodiment in the category of the present invention.These embodiment that given only are illustrative, and may not be interpreted as limitation of the present invention, because under the condition that does not deviate from spirit and scope of the invention, can carry out various changes to it.Unless limit in addition below, composition is all with chemical name or CTFA name identification.
Form (percentage by weight %)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | |
| Cationic guar gum-1 *1 | ??0.7 | ??0.7 | ??0.7 | ??0.5 | ??1.0 | ??0.7 | ??- |
| Cationic guar gum-2 *2 | ??0.8 | ??- | ??- | ??0.2 | ??0.7 | ??- | ??1.1 |
| Cationic guar gum-3 *3 | ??- | ??- | ??1.2 | ??- | ??- | ??- | ??- |
| Nonionic guar gum *4 | ??- | ??0.8 | ??- | ??- | ??- | ??- | ??- |
| Hydroxyethyl ethylcellulose *5 | ??- | ??- | ??0.8 | ??0.8 | ??- | ??- | ??- |
| The cetyl hydroxyethyl-cellulose *6 | ??- | ??- | ??- | ??- | ??- | ??0.75 | ??- |
| Polyquaternary ammonium salt-7 *7 | ??- | ??- | ??- | ??- | ??- | ??- | ??0.7 |
| The cetyl trimethyl ammonium chloride *8 | ??1.0 | ??1.0 | ??1.0 | ??1.0 | ??- | ??- | ??- |
| The stearyl trimethyl ammonium chloride *9 | ??- | ??- | ??- | ??- | ??1.0 | ??1.0 | ??1.0 |
| Dimethicone copolyol *10 | ??2.0 | ??2.0 | ??2.0 | ??- | ??- | ??2.0 | ??2.0 |
| The amide groups dimethicone copolyol *11 | ??- | ??- | ??- | ??2.0 | ??- | ??- | ??- |
| The siloxanes nanoemulsions *12 | ??- | ??- | ??- | ??- | ??0.6 | ??- | ??- |
| ??PEG-12 *13 | ??3.0 | ??3.0 | ??3.0 | ??3.0 | ??3.0 | ??3.0 | ??- |
| ??PEG-150 *14 | ??- | ??- | ??- | ??- | ??0.7 | ??- | ??- |
| Defoamer *15 | ??0.1 | ??0.1 | ??0.1 | ??0.1 | ??- | ??0.1 | ??0.1 |
| Methylchloroisothiazandnone/Methylisothiazolinone *16 | ??0.025 | ??0.025 | ??0.025 | ??0.025 | ??0.025 | ??0.025 | ??0.025 |
| Methyl parahydroxybenzoate | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
| Disodiumedetate | ??0.1 | ??0.1 | ??0.1 | ??0.1 | ??0.1 | ??0.2 | ??0.1 |
| Spice | ??0.25 | ??0.25 | ??0.1 | ??0.1 | ??0.1 | ??0.1 | ??0.1 |
| Deionized water | ----------is in right amount to 100%----------- | ||||||
Form (percentage by weight %)
| Embodiment 8 | Embodiment 9 | Embodiment 10 | Embodiment 11 | Embodiment 12 | Embodiment 13 | Embodiment 14 | |
| Cationic guar gum-1 *1 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??0.7 | ??- |
| Nonionic guar gum *4 | ??0.9 | ??0.9 | ??1.0 | ??1.0 | ??0.9 | ??0.9 | ??0.9 |
| Polyquaternary ammonium salt-37 *17 | ??- | ??- | ??- | ??- | ??- | ??- | ??0.7 |
| The cetyl trimethyl ammonium chloride *8 | ??1.0 | ??1.0 | ??1.0 | ??1.0 | ??0.5 | ??1.0 | ??0.8 |
| The myristyl dimethyl benzyl ammonium chloride *18 | ??- | ??- | ??- | ??- | ??1.0 | ??- | ??- |
| Babassu base acylamino-propyl group alkyl ammomium chloride *19 | ??- | ??- | ??- | ??- | ??- | ??1.0 | ??- |
| The amide groups dimethicone copolyol *11 | ??4.0 | ??- | ??3.0 | ??3.0 | ??3.0 | ??4.0 | ??4.0 |
| Amide groups dimethicone copolyol-2 *20 | ??- | ??2.0 | ??- | ??- | ??- | ??- | ??- |
| Quaternized siloxanes nanoemulsions *21 | ??- | ??- | ??1.0 | ??- | ??- | ??- | ??- |
| Amino-terminated polydimethylsiloxane nanoemulsions *22 | ??- | ??- | ??- | ??1.0 | ??- | ??- | ??- |
| Quaternized siloxanes *23 | ??- | ??- | ??- | ??- | ??2.0 | ??- | ??- |
| Defoamer *15 | ??- | ??0.075 | ??- | ??- | ??- | ??- | ??- |
| The pantoyl benzyl ethyl ether *24 | ??- | ??- | ??- | ??- | ??- | ??0.05 | ??- |
| Pantothenylol *25 | ??- | ??- | ??- | ??- | ??- | ??0.05 | ??- |
| Methylchloroisothiazandnone/Methylisothiazolinone *16 | ??0.033 | ??0.033 | ??0.033 | ??0.033 | ??0.033 | ??0.033 | ??0.033 |
| Methyl parahydroxybenzoate | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
| Disodiumedetate | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 |
| Spice | ??0.25 | ??0.25 | ??0.25 | ??0.25 | ??0.25 | ??0.25 | ??0.25 |
| Deionized water | ----------is in right amount to 100%---------- | ||||||
Form (percentage by weight %)
| Embodiment 15 | Embodiment 16 | Embodiment 17 | Embodiment 18 | Embodiment 19 | Embodiment 10 | Embodiment 21 | |
| Cationic guar gum-1 *1 | ??0.5 | ??- | ??- | ??- | ??- | ??- | ??- |
| Nonionic guar gum *4 | ??1.2 | ??1.6 | ??1.7 | ??1.7 | ??1.7 | ??1.6 | ??1.6 |
| Polyquaternary ammonium salt-37 *17 | ??- | ??- | ??- | ??- | ??- | ??- | ??- |
| The cetyl trimethyl ammonium chloride *8 | ??0.5 | ??0.5 | ??0.3 | ??0.5 | ??0.7 | ??0.5 | ??0.5 |
| The myristyl dimethyl benzyl ammonium chloride *18 | ??1.0 | ??1.0 | ??0.3 | ??- | ??1.0 | ??1.0 | ??1.0 |
| Babassu base acylamino-propyl group alkyl ammomium chloride *19 | ??- | ??- | ??- | ??1.0 | ??- | ??- | ??- |
| Palmityl acylamino-oxypropyl trimethyl ammonium chloride *26 | ??- | ??0.3 | ??0.9 | ??- | ??- | ??- | ??- |
| Ceteth-10 *27 | ??- | ??- | ??- | ??- | ??1.0 | ??1.0 | ??- |
| The amide groups dimethicone copolyol *11 | ??4.0 | ??2.0 | ??4.0 | ??4.0 | ??6.0 | ??3.0 | ??3.0 |
| Amide groups dimethicone copolyol-2 *20 | ??- | ??2.0 | ??- | ??- | ??- | ??- | ??- |
| Quaternized siloxanes nanoemulsions *21 | ??- | ??- | ??- | ??- | ??- | ??1.0 | ??- |
| Amino-terminated polydimethylsiloxane nanoemulsions-2 *28 | ??- | ??- | ??- | ??- | ??- | ??- | ??- |
| Amino-terminated polydimethylsiloxane nanoemulsions-3 *29 | ??- | ??- | ??- | ??- | ??- | ??- | ??1.0 |
| Defoamer *15 | ??- | ??0.075 | ??- | ??- | ??- | ??- | ??- |
| Methylchloroisothiazandnone/Methylisothiazolinone *16 | ??0.033 | ??0.033 | ??0.033 | ??0.033 | ??0.033 | ??0.033 | ??0.033 |
| Methyl parahydroxybenzoate | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 | ??0.2 |
| Disodiumedetate | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 | ??0.13 |
| Spice | ??0.25 | ??0.25 | ??0.25 | ??0.25 | ??0.25 | ??0.25 | ??0.25 |
| Deionized water | ----------is in right amount to 100%----------- | ||||||
Compositions (percentage by weight %)
| Embodiment 22 | Embodiment 23 | |
| Cationic guar gum-1 *1 | ??- | ??- |
| Nonionic guar gum *4 | ??1.6 | ??1.4 |
| Polyquaternary ammonium salt-37 *17 | ??- | ??0.3 |
| The cetyl trimethyl ammonium chloride *8 | ??0.5 | ??0.5 |
| The myristyl dimethyl benzyl ammonium chloride *18 | ??1.0 | ??0.8 |
| Babassu base acylamino-propyl group alkyl ammomium chloride *19 | ??- | ??- |
| Palmityl acylamino-oxypropyl trimethyl ammonium chloride *26 | ??- | ??- |
| Ceteth-10 *27 | ??- | ??1.0 |
| The amide groups dimethicone copolyol *11 | ??2.0 | ??4.0 |
| Amide groups dimethicone copolyol-2 *20 | ??- | ??- |
| Quaternized siloxanes nanoemulsions *21 | ??- | ??- |
| Amino-terminated polydimethylsiloxane nanoemulsions-2 *28 | ??2.0 | ??- |
| Amino-terminated polydimethylsiloxane nanoemulsions-3 *29 | ??- | ??- |
| Defoamer *15 | ||
| Methylchloroisothiazandnone/Methylisothiazolinone *16 | ??0.033 | ??0.033 |
| Methyl parahydroxybenzoate | ??0.2 | ??0.2 |
| Disodiumedetate | ??0.13 | ??0.13 |
| Spice | ??0.25 | ??0.25 |
| Deionized water | In right amount to 100% | |
The definition of component
*1 cationic guar gum-1: Rhaball Gum CG-M 8M, molecular weight are about 1,500,000, and the cation substitution value is 0.15, with trade name Jaguar Excel available from Rhodia
*2 cationic guar gums-2: Rhaball Gum CG-M 8M, molecular weight are about 2,200,000, and the cation substitution value is 0.25, with trade name Jaguar C-17 available from Rhodia
*3 cationic guar gums-3: Rhaball Gum CG-M 8M, molecular weight are about 1,000,000 to about 1,500,000, and the cation substitution value is about 0.25, with trade name Jaguar CHJ available from Rhodia
*4 nonionic guar gums: Jaguar HP-105, molecular weight are about 2,000,000, available from Rhodia
*5 hydroxyethyl ethylcelluloses: Elfacos CD481, available from Akzo Nobel
*6 cetyl hydroxyethyl-cellulose: Polysurf67 are available from Aqualon
*7 polyquaternary ammonium salt-7:Merquat550 are available from Ondeo Nalco
*8 cetyl trimethyl ammonium chlorides: CTAC 30KC, available from KCI
*9 stearyl trimethyl ammonium chlorides: Genamine STACP, available from Clariant
*10 dimethicone copolyols: the PEG/PPG-15/15 polydimethylsiloxane, with trade name Silicone DC-5330 available from Dow Corning
*11 amide groups dimethicone copolyols: siloxanes BY16-906, available from Dow Corning
*12 siloxanes nanoemulsions: siloxanes DC-8177, available from Dow Corning
*13PEG-12: available from Dow Chemical
*14PEG-150:Crothix is available from Croda
*15 defoamer: XS63-B8929 is available from GE-Toshiba Silicone
*16 methylchloroisothiazandnone/Methylisothiazolinone: Kathon CG, available from Rohm﹠amp; Haas
*17 polyquaternary ammonium salt-37: available from 3V Sigma, commodity are called Synthalen CR
*18 myristyl dimethyl benzyl ammonium chlorides: with trade name Incroquat O-50 available from Croda
*19 babassus bases acylamino-propyl group alkyl ammomium chloride: with trade name Incroquat BA-85 available from Croda
*20 amide groups dimethicone copolyols-2: with trade name DC2-8500 available from Dow Corning
*21 quaternized siloxanes nanoemulsions: with trade name DC5-7133 available from Dow Corning
*22 amino-terminated polydimethylsiloxane nanoemulsions: with trade name XS65-B6413 available from General Electric
*23 quaternized siloxanes: with trade name Ultrasil Q-Plus available from Noveon
*24 pantoyl ethylethers: available from Roche
*25 pantothenylol: available from Roche
*26 palmityl acylamino-oxypropyl trimethyl ammonium chloride: Varisoft PATC, available from Degussa
*27 ceteths-10: available from Nikko
*28 amino-terminated polydimethylsiloxane nanoemulsions-2:DC2-8168 are available from DowCorning
*29 amino-terminated polydimethylsiloxane nanoemulsions-3:DC2-8194 are available from DowCorning
Preparation method
As implied above, the hair care composition of " embodiment 1 " to " embodiment 23 " can prepare with any conventional method well known in the art.They can suitably be prepared as follows:
At room temperature polymeric material is scattered in the water, vigorous stirring is mixed, and is heated to 50 ℃ to 70 ℃ then.Under agitation, cationic surfactant and (if comprising) non-ionic surface active agent, wetting agent and other temperature-resistant component are joined in this mixture.Then mixture is cooled to below 40 ℃, then under agitation, remaining ingredient such as siloxanes, spice, antiseptic and defoamer (if comprising) is joined in this mixture.
Embodiment 1 to 23 is the hair care compositions of the present invention that are particularly useful for the washing-off type purposes.These embodiment have many advantages.For example, " embodiment 1 " to the compositions of " embodiment 23 " has the rheological behavior that is suitable for care composition, and the conditioning beneficial effect is provided, and especially wet flexibility of sending out and minimizing are twined." embodiment 1 " to the compositions of " embodiment 23 " has transparent or semitransparent outward appearance.The compositions of " embodiment 1 " to " embodiment 23 " can provide above-mentioned rheological behavior and conditioning beneficial effect when not forcing down hair.When using with the rinse-off products form, the compositions of " embodiment 1 " to " embodiment 23 " can provide above-mentioned rheological behavior with the conditioning beneficial effect in, provide to be easy to the rinsing sense.
Claims (20)
1. hair care composition, described compositions comprises by weight:
(a) about 0.01% to about 10% thickening polymer system, described system is selected from cationic thickening polymer, nonionic thickening polymer, and their mixture;
(b) about 0.05% to about 10% cationic surfactant system, described system is selected from the mixture of a kind of cationic surfactant, two or more cationic surfactants, and the mixture of cationic surfactant and non-ionic surface active agent; With
(c) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound and anionic compound.
2. hair care composition as claimed in claim 1, wherein said compositions is transparent or semitransparent.
3. hair care composition as claimed in claim 1, wherein said compositions is transparent.
4. hair care composition as claimed in claim 1, wherein said cationic thickening polymer are the cationic guar gum polymer, and described nonionic thickening polymer is a nonionic guar gum polymer.
5. hair care composition as claimed in claim 4, the molecular weight of wherein said cationic guar gum polymer are about 100,000 to about 3,000,000, and the molecular weight of described nonionic guar gum polymer is about 1,000,000 to about 4,000,000.
6. hair care composition as claimed in claim 4, wherein said thickening polymer comprises: by the described cationic guar gum polymer of the weight of described compositions about 0.1% to about 4%; And by the described nonionic guar gum polymer of the weight of described compositions about 0.1% to about 3%.
7. hair care composition as claimed in claim 1, described compositions comprise about 0.6% to about 3% described thickened systems.
8. hair care composition as claimed in claim 1, wherein said cationic surfactant is a monoalkyltrimethyl ammonium salts.
9. hair care composition as claimed in claim 8, wherein said cationic surfactant have the monoalkyl chain that contains 16 to 22 carbon atoms.
10. hair care composition as claimed in claim 1, described compositions also comprise about 0.1% to about 20% silicone compounds.
11. hair care composition as claimed in claim 10, wherein said silicone compounds are selected from water-soluble silicon siloxane compound, the mean diameter siloxanes nanoemulsions less than 220nm, and their mixture.
12. hair care composition as claimed in claim 11, wherein said silicone compounds is the water-soluble silicon siloxane compound, it is selected from PEG-12 methyl ether/Lauroxy PEG-5 amido propyl polydimethylsiloxane, the amino-terminated polydimethylsiloxane of two (C13-15 alkoxyl) PG, and their mixture.
13. hair care composition as claimed in claim 1, described compositions also comprise about 0.1% to about 20% wetting agent.
14. hair care composition as claimed in claim 1, described compositions also comprise about 0.01% to about 10% cation hair-conditioning polymer.
15. hair care composition as claimed in claim 1, the viscosity of described compositions are about 2,000 to about 50,000mPas.
16. hair care composition as claimed in claim 1, described compositions are the compositions that is used for the washing-off type purposes.
17. the method for a conditioning hair, described method comprises the following steps:
(i) after shampoo is sent out, the hair care composition as claimed in claim 1 of effective dose is applied on the hair; With
(ii) wash described hair then.
18. hair care composition, described compositions comprises by weight:
(a) about 0.5% to about 5% thickening polymer system, described system is selected from cationic thickening polymer, nonionic thickening polymer, and their mixture;
(b) about 0.25% to about 7% cationic surfactant system, described system is selected from the mixture of a kind of cationic surfactant, two or more cationic surfactants, and the mixture of cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds, described chemical compound are selected from water-soluble silicon siloxane compound, the mean diameter siloxanes nanoemulsions less than 220nm, and their mixture; With
(d) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound and anionic compound.
19. hair care composition, described compositions comprises by weight:
(a) about 0.5% to about 5% nonionic thickening polymer;
(b) about 0.25% to about 7% cationic surfactant system, described system is selected from the mixture of a kind of cationic surfactant, two or more cationic surfactants, and the mixture of cationic surfactant and non-ionic surface active agent;
(c) about 0.1% to about 10% silicone compounds, described chemical compound are selected from water-soluble silicon siloxane compound, the mean diameter siloxanes nanoemulsions less than 220nm, and their mixture; With
(d) aqueous carrier;
Wherein said compositions is substantially free of water-insoluble high-melting-point oiliness compound, anionic compound and cationic thickening polymer.
20. hair care composition as claimed in claim 19, wherein said nonionic thickening polymer are nonionic thickening guar gum polymer.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US41771002P | 2002-10-10 | 2002-10-10 | |
| US60/417,710 | 2002-10-10 | ||
| US60/476,706 | 2003-06-06 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1703187A true CN1703187A (en) | 2005-11-30 |
Family
ID=32393291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200380101234 Pending CN1703187A (en) | 2002-10-10 | 2003-10-08 | Hair conditioning composition comprising thickening polymer and cationic surfactant |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1703187A (en) |
| CA (1) | CA2444206A1 (en) |
Cited By (6)
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| CN103842387A (en) * | 2011-07-21 | 2014-06-04 | 罗地亚运作公司 | Guar hydroxypropyltrimethylammonium chloride and uses thereof in hair treatment compositions |
| CN105636649A (en) * | 2013-10-18 | 2016-06-01 | 荷兰联合利华有限公司 | Hair care composition |
| CN106232098A (en) * | 2013-12-11 | 2016-12-14 | 赫尔克里士公司 | The not personal care cleansing compositions of containing sulfate |
| CN106414690A (en) * | 2014-06-18 | 2017-02-15 | 罗地亚经营管理公司 | Method of use of composition comprising a quaternary ammonium compound, a cationic polysaccharide and a nonionic polysaccharide |
| CN110505865A (en) * | 2017-04-13 | 2019-11-26 | 宝洁公司 | Product composition comprising discrete particle and aqueous base composition |
| CN114209608A (en) * | 2021-12-28 | 2022-03-22 | 中山中研化妆品有限公司 | Emulsion and method for producing the same |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107847767A (en) * | 2015-04-23 | 2018-03-27 | 宝洁公司 | Hair-care care composition |
-
2003
- 2003-10-08 CN CN 200380101234 patent/CN1703187A/en active Pending
- 2003-10-09 CA CA 2444206 patent/CA2444206A1/en not_active Abandoned
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103842387B (en) * | 2011-07-21 | 2017-04-26 | 罗地亚运作公司 | Guar hydroxypropyltrimethylammonium chloride and uses thereof in hair treatment compositions |
| CN103842387A (en) * | 2011-07-21 | 2014-06-04 | 罗地亚运作公司 | Guar hydroxypropyltrimethylammonium chloride and uses thereof in hair treatment compositions |
| CN107266597A (en) * | 2011-07-21 | 2017-10-20 | 罗地亚运作公司 | Guar hydroxypropyl trimonium chloride and its purposes in hair treatment compositions |
| CN105636649A (en) * | 2013-10-18 | 2016-06-01 | 荷兰联合利华有限公司 | Hair care composition |
| CN106232098A (en) * | 2013-12-11 | 2016-12-14 | 赫尔克里士公司 | The not personal care cleansing compositions of containing sulfate |
| CN106414690A (en) * | 2014-06-18 | 2017-02-15 | 罗地亚经营管理公司 | Method of use of composition comprising a quaternary ammonium compound, a cationic polysaccharide and a nonionic polysaccharide |
| CN106459836A (en) * | 2014-06-18 | 2017-02-22 | 罗地亚经营管理公司 | Composition comprising a quaternary ammonium compound, a cationic polysaccharide, a nonionic polysaccharide and a fragrance material or perfume |
| CN106661513A (en) * | 2014-06-18 | 2017-05-10 | 罗地亚经营管理公司 | Method for preparing stable composition with perfume |
| CN106459835A (en) * | 2014-06-18 | 2017-02-22 | 罗地亚经营管理公司 | Composition comprising quaternary ammonium compound, cationic polysaccharide and nonionic polysaccharide |
| CN110505865A (en) * | 2017-04-13 | 2019-11-26 | 宝洁公司 | Product composition comprising discrete particle and aqueous base composition |
| CN110505865B (en) * | 2017-04-13 | 2023-04-14 | 宝洁公司 | Product composition comprising discrete particles and an aqueous base composition |
| CN114209608A (en) * | 2021-12-28 | 2022-03-22 | 中山中研化妆品有限公司 | Emulsion and method for producing the same |
| CN114209608B (en) * | 2021-12-28 | 2023-09-29 | 中山中研化妆品有限公司 | Emulsion and preparation method thereof |
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