The suction means that is used for vacuum insulation panel
Technical field
The present invention relates to a kind of vacuum suction device, especially keep a kind of suction means that is used for vacuum insulation panel of degree of vacuum in the thermal baffle vacuum jacket.
Background technique
Because vacuum insulation panel has good insulation and environmental-protecting performance, progressively is widely used in field of thermal insulation such as oil, chemical industry, building, refrigerators.But vacuum insulation panel tends to along with the prolongation of time degree of vacuum be descended, and directly has influence on the thermal insulation property of vacuum insulation panel, traces it to its cause, and mainly is residual CO, CO in the chuck
2, O
2, H
2, H
2O or organic steam, or they are by thermal-protective material, or discharge in the material by the manufacturing thermal baffle, or enter in the chuck by the welding zone seepage, want to keep the degree of vacuum in the vacuum insulation panel, used getter material should have the characteristics that do not need thermal activation.
In view of the above, gondola SAES Getters S.p.A. proposes the international application that name is called " equipment and the manufacture method thereof of keeping vacuum in insulating jacket " on July nineteen ninety-five 3, its international application no is: PCT/IT95/00110, and enter China on January 6th, 1997, its China Patent No. is ZL95193987.4, this patent disclosure adopt that to disclose a kind of be getter material with Ba-Li getter alloy pressed powder, be placed on container bottom, and the equipment of in insulating jacket, keeping vacuum that is covered fully by one deck desiccant material, desiccant material has been selected barium oxide, strontium oxide strontia and phosphorous oxides, they can and prevent from metal oxide containing precious metals to cover on the getter material after extrded material from mixing.The equipment of keeping vacuum in this insulating jacket can CO absorption, CO
2, H particularly
2, but the rate of adsorption is relatively low, and the ability of adsorb organic compound gas is very limited.
Gondola SAES Getters S.p.A. proposed name to Patent Office of the People's Republic of China again on August 6th, 1996 and has been called " combination layer of getter material and charging appliance thereof " application for a patent for invention, its patent No. is: ZL96109371.4, this patent disclosure the mixture of Metal Palladium of oxide M O and≤2% (weight) of the transition metal selected in the oxide of a kind of oxide, copper or their mixture with cobalt be H under getter material and the room temperature
2The O vapor pressure is lower than the absorbent material of 1 handkerchief, and the suction device of being made up of them, and wherein absorbent material contacts with external environment condition.Compare in the ZL95193987.4 of first to file patent with the said firm, though improved CO, CO
2And H
2Adsorptive power, and can adsorb organic compound gas, become closely undue in order to prevent absorbent material between the powder because of the absorption of moisture makes, cause gas to pass through difficulty, add alumina powder in the absorbent material, because aluminium oxide belongs to inert material, its effect in absorbent material is single.Because absorbent material is exposed in the air all the time, in the technological preparation time, getter material just is in air-breathing working state, has consumed gettering ability, and effective gettering ability of charging appliance is descended.
Summary of the invention
The objective of the invention is to: at the suction means of present maintenance vacuum insulation panel degree of vacuum, especially China Patent No. is that the rate of adsorption that exists of ZL95193987.4 is relatively low, and the ability of adsorb organic compound gas is very limited, and the aluminium oxide in the ZL96109371.4 absorbent material belongs to inert material, its effect in absorbent material is single, practical problem in that the internal cause absorbent material exposure of technological preparation time descends effective gettering ability of charging appliance provides a kind of suction means that is used for vacuum insulation panel.
The object of the present invention is achieved like this: a kind of suction means that is used for vacuum insulation panel, comprise carrier, absorbent material, separating materials and getter alloy, it is characterized in that: also comprise organic gas-absorbing layer and anti-expanding material, mix the back by absorbent material and anti-expanding material and form air-permeable layer, getter alloy, organic gas absorbed layer and air-permeable layer layering successively place carrier from inside to outside, wherein, the interlayer of getter alloy and organic gas absorbed layer is provided with separating materials.
Described carrier is the cylindrical staving that adopts metal or plastic production, and its diameter is 10~80mm and open-top; To top layering setting successively, the air-permeable layer outside is for being located at the protective film of carrier top bead by the bottom of carrier for described getter alloy, organic gas absorbed layer and air-permeable layer.
The perforate simultaneously of the bottom of described carrier; Described getter alloy places the middle part of carrier, and organic gas absorbed layer, air-permeable layer are provided with to the top and the bottom layering of carrier successively, places the air-permeable layer outside of carrier upper and lower end to be respectively the protective film that is located at carrier top or bottom bead.
Described organic gas absorbed layer is the strong oxidizer absorbed layer; Absorbent material in the air-permeable layer and anti-expanding material proportions of ingredients are 1~150: 1; Described getter alloy is the barium lithium alloy, or the barium sodium alloy, and their powder compaction is become the porous muffin; Described separating materials is a screen cloth, or mesh grid, or filter paper.
Described strong oxidizer comprises: potash bichromate, or sodium dichromate, or natrium nitrosum, or cobalt oxide, and their powder compaction become the porous muffin; Absorbent material comprises in the air-permeable layer: magron, or U-Ramin MC, or calcium oxide, or phosphorous oxide; Anti-expanding material comprises in the air-permeable layer: molecular sieve, or zeolite, or active carbon, or silica; After mixing in proportion, the powder of absorbent material and anti-expanding material is pressed into the porous muffin.
The invention has the advantages that: because the open-top of carrier, or the perforate simultaneously of open-top bottom, make its working surface that bigger exposed surface area be arranged, the rate of adsorption improves relatively; The organic gas absorbed layer of setting up has improved the adsorptive power to the organic gas that may form in the vacuum insulation panel; Mix in the absorbent material such as molecular sieve, or zeolite, or active carbon, or the anti-expanding material of silica and so on forms air-permeable layer, these anti-expanding materials not only can utilize the porous breathable performance of himself, and the restriction absorbent material expands and keeps gas to pass through, and guarantee that strong oxidizer absorbed layer and getter material absorb the validity of gas, and gas also had certain adsorptive power, improved gettering efficiency greatly.
Description of drawings
Fig. 1 is an example structure schematic representation that the present invention relates to;
Fig. 2 is another example structure schematic representation that the present invention relates to;
The reference drawing of Fig. 3 air-breathing working state for the present invention enters.
Among the figure: 1, carrier, 2, the organic gas absorbed layer, 3, separating materials, 4, getter alloy, 5, air-permeable layer, 6, protective film.
Embodiment
Accompanying drawing discloses several specific embodiments related to the present invention without limitation, and the present invention is further illustrated below in conjunction with embodiment.
As seen from Figure 1: the present invention includes: carrier 1, absorbent material, separating materials 3 and getter alloy 4; also comprise organic gas-absorbing layer 2, anti-expanding material and protective film 6; absorbent material and anti-expanding material mix the back and form air-permeable layer 5; getter alloy 4, organic gas absorbed layer 2 and air-permeable layer 5 layering successively place carrier 1 from inside to outside; wherein, getter alloy 4 is provided with separating materials 3 with the interlayer of organic gas absorbed layer 2.Described carrier 1 is the cylindrical staving that adopts metal or plastic production, and its diameter is 10~80mm, and protective film 6 places the bead of the carrier 1 in air-permeable layer 5 outsides.In the present embodiment; carrier 1 is to adopt metal to make; its diameter is 60mm and open-top, and to top layering setting successively, air-permeable layer 5 outsides are the protective film 6 that is located at carrier 1 top bead by the bottom of carrier 1 for described getter alloy 4, organic gas absorbed layer 2 and air-permeable layer 5.
As seen from Figure 2, the difference of it and Fig. 1 is: described carrier 1 open-top not only, and bottom perforate simultaneously; Described getter alloy 4 places the middle part of carrier 1, and organic gas absorbed layer 2, air-permeable layer 5 are provided with to the top and the bottom layering of carrier 1 successively, place air-permeable layer 5 outsides of carrier upper and lower end to be respectively the protective film 6 that is located at carrier 1 top or bottom bead.
The reference drawing of Fig. 3 air-breathing working state for the present invention enters, the difference of it and Fig. 2 only is: air-permeable layer 5 outsides are not located at the protective film 6 of carrier 1 top or bottom bead.As seen, as long as throw off the protective film 6 that is located at air-permeable layer 5 outsides, suction means will enter air-breathing working state automatically.In practical operation, also can directly suction means be put into interlayer; interlayer is being carried out in the vacuum exhaust process; when interlayer forms certain vacuum; protective film 6 just can explosion under the effect of suction means inside and outside differential pressure; make air-permeable layer 5 be directly exposed to confined space in the interlayer, suction means will enter air-breathing working state automatically.
During concrete enforcement, described organic gas absorbed layer 2 is the strong oxidizer absorbed layer, and strong oxidizer can be selected: potash bichromate, or sodium dichromate, or natrium nitrosum, or cobalt oxide, and the powder compaction with them in the use becomes the porous muffin; Absorbent material in the air-permeable layer 5 and anti-expanding material proportions of ingredients are 1~150: 1, and absorbent material can be selected in the air-permeable layer 5: magron, or U-Ramin MC, or calcium oxide, or phosphorous oxide; Anti-expanding material can be selected in the air-permeable layer 5: molecular sieve, or zeolite, or active carbon, or silica; In the use, the powder of absorbent material and anti-expanding material is pressed into the porous muffin after should mixing in proportion; Described getter alloy 4 can be selected barium lithium alloy or barium sodium alloy, and the powder compaction with them in the use becomes the porous muffin; Described separating materials 3 can be selected screen cloth, or mesh grid, or filter paper; Protective film 6 can be selected laminated film or metallic thin film.