CN1699528A - Universal antifriction lubricating oil additives and method for preparing same - Google Patents
Universal antifriction lubricating oil additives and method for preparing same Download PDFInfo
- Publication number
- CN1699528A CN1699528A CN 200510010036 CN200510010036A CN1699528A CN 1699528 A CN1699528 A CN 1699528A CN 200510010036 CN200510010036 CN 200510010036 CN 200510010036 A CN200510010036 A CN 200510010036A CN 1699528 A CN1699528 A CN 1699528A
- Authority
- CN
- China
- Prior art keywords
- parts
- universal
- lubricating oil
- particle diameter
- molybdenumdisulphide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000654 additive Substances 0.000 title claims abstract description 35
- 239000010687 lubricating oil Substances 0.000 title claims abstract description 31
- 238000000034 method Methods 0.000 title abstract description 5
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 claims abstract description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 28
- 239000010439 graphite Substances 0.000 claims abstract description 28
- 239000002253 acid Substances 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 16
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 13
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 239000002612 dispersion medium Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 41
- 239000002199 base oil Substances 0.000 claims description 23
- 239000006185 dispersion Substances 0.000 claims description 15
- 229920002367 Polyisobutene Polymers 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 12
- 235000021355 Stearic acid Nutrition 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 7
- 239000008117 stearic acid Substances 0.000 claims description 7
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 7
- 229910021382 natural graphite Inorganic materials 0.000 claims description 5
- 239000008187 granular material Substances 0.000 claims description 4
- 230000001404 mediated effect Effects 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 abstract description 5
- 238000002156 mixing Methods 0.000 abstract description 2
- 229910052982 molybdenum disulfide Inorganic materials 0.000 abstract description 2
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000004898 kneading Methods 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 239000010936 titanium Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 description 16
- 230000000694 effects Effects 0.000 description 6
- -1 phosphorous acid titanic acid ester Chemical class 0.000 description 6
- 239000008186 active pharmaceutical agent Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000003921 oil Substances 0.000 description 5
- 239000000446 fuel Substances 0.000 description 4
- 239000013538 functional additive Substances 0.000 description 4
- 239000010721 machine oil Substances 0.000 description 4
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 239000002362 mulch Substances 0.000 description 3
- 229920013639 polyalphaolefin Polymers 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 101100407037 Oryza sativa subsp. japonica PAO6 gene Proteins 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000000994 depressogenic effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000314 lubricant Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012528 membrane Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229920001083 polybutene Polymers 0.000 description 2
- 230000008439 repair process Effects 0.000 description 2
- 239000004173 sunset yellow FCF Substances 0.000 description 2
- XQVCBOLNTSUFGD-UHFFFAOYSA-N 3-chloro-4-methoxyaniline Chemical compound COC1=CC=C(N)C=C1Cl XQVCBOLNTSUFGD-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- RFBLTNQEHOBXPG-UHFFFAOYSA-N [Zn].[Ni].[Sn].[Cu] Chemical compound [Zn].[Ni].[Sn].[Cu] RFBLTNQEHOBXPG-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 239000012208 gear oil Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000010720 hydraulic oil Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N pentanoic acid group Chemical group C(CCCC)(=O)O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 230000003019 stabilising effect Effects 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The invention provides a universal antifriction lubricating oil additives and method for preparation, wherein the addition agent is prepared from (by weight portion) graphite 5-10 parts, molybdenum disulfide 1-4 parts, titanium acid ester coupling agent 0.1-0.9 part, dispersing agent 8-20 parts, dispersion medium 65-90 parts, the preparation method comprises the steps of disintegrating, mixing, kneading and high pressure homogeneity.
Description
Technical field
The invention belongs to lubricating oil additive, particularly a kind of universal antifriction lubricating oil additives and preparation method.
Background technology
In service in mechanical means, must take of the generation of various lubricant methods to reduce friction and to wear and tear, wherein the most frequently used and the most simple and effective method is to adopt lubricating oil to be lubricated.In research and practical application, find that adopt lubricating oil merely, its lubricant effect still is difficult to satisfy the requirement of many application scenarios.In recent years, the preparation and the utilisation technology of metallic substance have obtained significant progress, have reached the level of suitability for industrialized production gradually.Nearest result of study finds that the metallic particles material improves additive as lubricating oil and has a good application prospect, so be born following some technology and products based on this kind novel material.As: US patentN0.4,204,968 disclose a kind of lubricating oil additive, interpolation material copper and lead that it is main, but plumbous adding causes environmental pollution; US patent No.5,523,006 discloses another kind of lubricating oil additive, interpolation material adonic that it is main and copper nickel Zinc-tin alloy, its particle surface has coated one deck polymeric membrane, reduced particulate anti-attrition and supporting capacity, above-mentioned metal alloy almost can't fuse with the iron and steel body because of the relation of crystalline structure, so this kind additive does not almost have repairing effect.In addition, owing to polymeric membrane very easily breaks in friction, the rapid oxidation of its inner metal of back of breaking, thus cause additive to lose efficacy.
Summary of the invention
The objective of the invention is to overcome the deficiency in the present technology, a kind of universal antifriction lubricating oil additives and preparation method are provided.
Technical scheme of the present invention is summarized as follows:
Universal antifriction lubricating oil additives, (below be weight) is made of following component by weight, graphite granule, particle diameter accounts for more than 70% less than 1.0 μ m, 5～10 parts of content; Molybdenumdisulphide, particle diameter accounts for 95% less than 1.5 μ m, 1～4 part of content; 0.1～0.9 part of titanate coupling agent; 8～20 parts of dispersion agents; 65～90 parts in dispersion medium.
Above-mentioned preferred version is: graphite granule, and particle diameter accounts for more than 70% less than 1.0 μ m, 7～9 parts of content; Molybdenumdisulphide, particle diameter accounts for 95% less than 1.5 μ m, 1.5～3 parts of content; 0.2～0.6 part of titanate coupling agent; 10～15 parts of dispersion agents; 75～80 parts in dispersion medium.
Wherein: titanate coupling agent is triisopropyl phosphorous acid metatitanic acid fat or triisopropyl stearic acid metatitanic acid fat; Dispersion agent is two succimides of polyisobutene or the many succimides of polyisobutene; Dispersion medium is 150SN, 150BS base oil; The graphite raw material that uses is to originate in China Nanshu Graphite Mine, Shandong Prov., graphite is hexagonal, coefficient of friction is 0.05～0.19, be phosphorus sheet, Stability Analysis of Structures, what carbon atom was firm combines, survivable, the layer with the interlayer bonding force a little less than, be subjected to shear action to be easy to slippage, good filling, repair are arranged on attrition surface, easily form mulch film in the metallic surface, reach the anti-attrition effect; Its structure of molybdenumdisulphide is the same with graphite, also is hexagonal, and how thin that no matter grinds is, and it has certain laminate structure, and under the pressure friction there is very strong avidity the metallic surface, bears pressure is 3.45 * 10
9Pa, the parts of coating molybdenumdisulphide can turn round under no oily situation, and the moment reaction takes place in molybdenumdisulphide and metallic surface under certain temperature and pressure, generates the extremely low solid film of coefficient of friction, prevents the metallic surface sintering that rubs mutually.
According to the above-mentioned characteristic of graphite and molybdenumdisulphide, two kinds of materials are mixed, manufacture the lubricating oil universal antifriction additive of excellent property through titanate coupling agent surface-active-treatment, dispersion agent dispersion, high-pressure homogeneous processing.Its concrete preparation method may further comprise the steps:
A, graphite is pulverized, particle diameter accounts for more than 70% less than the particle of 1.0 μ m, and maximum particle diameter is no more than 6 μ m;
B, with molybdenumdisulphide pulverize, particle diameter accounts for more than 90% less than the particle of 1.5 μ m;
C, get graphite that a, b step obtain and molybdenumdisulphide with weight part by 3～10: 1～5 mixed;
D, the mixture of c is added 6-14 part base oil earlier, add 0.1～0.9 part in titanate coupling agent triisopropyl phosphorous acid metatitanic acid fat or triisopropyl stearic acid metatitanic acid fat again, make that solid particles surface is active to be handled, and in kneader, mediated 20-50 minute;
E, in the mixture of d, add 65～90 parts of the two succimides of dispersion agent polyisobutene or 8～20 parts of the many succimides of polyisobutene and base oils, uniform particles is dispersed in the base oil, in order to obtain stable solid-liquid phase dispersion, once high-pressure homogeneous under 50～70Mpa, promptly obtain the universal antifriction lubricating oil additives finished product.
Lubricating oil additive of the present invention be with graphite and molybdenumdisulphide blending dispersion in lubricating oil, contain the graphite and the molybdenumdisulphide of the fine particle of suspended dispersed.Graphite has fills up, repairs coarse metallic surface, plays the anti-attrition effect.Thermal chemical reaction takes place in molybdenumdisulphide under high-temperature and high-pressure conditions, generate the metal mulch film, antifriction effect is outstanding, and has an anti-extreme pressure energy, after the film that generates had both made and had been worn, can continuously add to again on the metallic surface of friction by the molybdenumdisulphide that in liquid, suspends, continue to play lubricated, also play simultaneously effects such as energy-saving and environmental protection, anti-attrition, speedup.
Embodiment
The present invention will be further described below in conjunction with embodiment:
Embodiment 1
A, natural graphite is pulverized, particle diameter is that the particle of 0.4～1.0 μ m accounts for more than 70%, and maximum particle diameter is no more than 6 μ m;
B, with molybdenumdisulphide pulverize, the particle of particle diameter 0.6～1.5 μ m accounts for more than 90%;
The molybdenumdisulphide of c, 5 parts in graphite getting a step and b step mixes for 1.2 parts;
D, the mixture that the c step is obtained add 8 parts of base oils earlier, add 0.2 part in titanate coupling agent triisopropyl phosphorous acid metatitanic acid fat again, and mediate 20 minutes in kneader;
E, add 65 parts of 12 parts of the two succimides of dispersion agent polyisobutene and 150BS base oils in the said mixture through mediate handling, homogeneous once promptly obtains the universal antifriction lubricating oil additives finished product under the high pressure of 55Mpa.
Embodiment 2
A, content is pulverized at the natural graphite more than 99.5%, particle diameter is that the particle of 0.6～1 μ m accounts for more than 70%, and maximum particle diameter is no more than 6 μ m;
B, extract molybdenumdisulphide from natural brightness ore deposit, molybdenumdisulphide content accounts for the particle that it is pulverized, particle diameter is 0.8～1.5 μ m more than 90% more than 98%;
C, get 7 parts in a step graphite and b step 2 moly-sulfide mixes for 2.5 parts;
D, the mixture that the c step is obtained add 10 parts of base oils earlier, add 0.3 part in triisopropyl stearic acid metatitanic acid fat again, and mediate 30 minutes in kneader;
E, in said mixture, adding 75 parts of 15 parts of the many succimides of polyisobutene and 150SN base oils, at the high pressure homogenizer mesohigh homogeneous of 60Mpa once, promptly obtaining the universal antifriction lubricating oil additives finished product through mediate handling.
Embodiment 3
A, content is pulverized at the natural graphite more than 99.5%, particle diameter is that the particle of 0.8～1.0 μ m accounts for more than 70%, and maximum particle diameter is no more than 6 μ m;
B, extract molybdenumdisulphide from natural brightness ore deposit, molybdenumdisulphide content accounts for the particle that it is pulverized, the particle diameter yardstick is 1.0～1.5 μ m more than 90% more than 98%;
The molybdenumdisulphide of c, 8 parts in graphite getting a step and b step mixes for 3 parts;
D, the mixture that the c step is obtained add 12 parts of base oils earlier, add 0.4 part in titanate coupling agent triisopropyl phosphorous acid metatitanic acid fat again, and mediate 30 minutes in kneader;
E, in said mixture, adding 80 parts of 18 parts of the two succimides of dispersion agent polyisobutene and 150BS base oils, at the high pressure homogenizer mesohigh homogeneous of 65Mpa once, promptly obtaining the universal antifriction lubricating oil additives finished product through mediate handling.
Embodiment 4
A, content is pulverized at the natural graphite more than 99.5%, particle diameter is that the particle of 1 μ m accounts for more than 70%, and maximum particle diameter is no more than 6 μ m;
B, extract molybdenumdisulphide from natural brightness ore deposit, molybdenumdisulphide content accounts for the particle that it is pulverized, particle diameter is 1.5 μ m more than 90% more than 98%;
The molybdenumdisulphide of c, 8.5 parts in graphite getting a step and b step mixes for 1.7 parts;
D, the mixture that the c step is obtained add 10 parts of base oils earlier, add 0.55 part in titanate coupling agent triisopropyl stearic acid metatitanic acid fat again, and mediate 30 minutes in kneader;
E, in said mixture, adding 20 parts of 10 parts of the many succimides of polyisobutene, 50 parts of 150SN base oils and 150BS base oils, at the high pressure homogenizer mesohigh homogeneous of 60Mpa once, promptly obtaining the lubricating oil additive finished product through mediate handling.
Embodiment 5
By general mediation technology, in Mixer pot, add base oil and functional additive, add again and press embodiment 1～4 resulting any universal antifriction lubricating oil additives, the homogeneous method is handled under the 60Mpa high pressure, making it solid, liquid is uniformly dispersed mutually, form not stratified, non-setting stabilising system, promptly obtain extraordinary antifriction lubricating oil.Concrete consumption is as follows:
(1) special gasoline machine oil API SJ SAE15W/40
The universal antifriction additive wherein contains for 1.0 parts: 0.07 part in graphite
0.03 part of molybdenumdisulphide
0.04 part of triisopropyl phosphorous acid titanic acid ester
0.15 part of two succimide
8.0 parts of LZL9800C (functional additive)
8.0 parts of OCPA (viscosity index improver second third glue)
0.4 part of PPT148 (pour point depressant polyacrylic ester)
47.5 parts of 10 centistokes(cst)s (isomerizing hydrogenation base oil)
34.91 parts of 5 centistokes(cst)s (isomerizing hydrogenation base oil)
(2) special diesel oil machine oil API CF-4 SAE/40
The universal antifriction additive wherein contains for 1.0 parts: 0.07 part in graphite
0.03 part of molybdenumdisulphide
0.04 part of triisopropyl phosphorous acid titanic acid ester
0.15 part of two succimide
8.0 parts of T613
0.25 part of PDT148
73.5 parts of 500SN (base oil)
8.06 parts of 150BS (base oil)
9.0 parts of H1275 (functional additive)
(3) extraordinary synthetic gasoline machine oil API SJ SAE5W/40
The universal antifriction additive wherein contains for 0.6 part: 0.04 part in graphite
0.02 part of molybdenumdisulphide
0.03 part of triisopropyl phosphorous acid titanic acid ester
0.08 part of the many succimide of polyethylene
9.5 parts of RO55004 (functional agent)
7.0 parts of T251 (viscosity index improver)
30.09 parts of PAO8# (polyalphaolefin synthetic oil)
45.3 parts of PAO6# (polyalphaolefin synthetic oil)
8.0 parts of E110 (synthetic dibasic acid esters oil)
(4) semi-synthetic special gasoline machine oil API SH SAE5W/40
The universal antifriction additive wherein contains for 0.5 part: 0.03 part in graphite
0.02 part of molybdenumdisulphide
0.04 part of triisopropyl phosphorous acid titanic acid ester
0.07 part of mono alkenyl succimide
12.2 parts of H1204 (functional agent)
49.0 parts of PAO6# (polyalphaolefin synthetic oil)
22.19 parts of 10 centistokes(cst)s (isomerizing hydrogenation base oil)
8.0 parts of E110 (dibasic acid esters synthetic oil)
8.0 parts of T251 (viscosity index improver)
(5) gear oil API GL-5 SAE85W/90
The universal antifriction additive wherein contains for 0.5 part: 0.07 part in graphite
0.03 part of molybdenumdisulphide
0.03 part of tetra-sodium type monoalkoxytitanates
0.06 part of the many succimide of polybutene
4.8 parts of T320 (functional agent)
10.0 parts of T613 (viscosity index improver)
0.4 part of PPT148 (polypropylene ester pour point depressant)
68 parts of 500SN
15.71 parts of 150BS
(6) special greases
The universal antifriction additive wherein contains for 2 parts: 0.14 part in graphite
0.06 part of molybdenumdisulphide
0.08 part in triisopropyl phosphorous acid metatitanic acid fat
0.14 part of many pairs of succimide of polybutene
0.5 part of pentanoic
7.92 parts of 12-oxystearic acids
1.98 parts of stearic acid
LiOHH
21.48 parts of O
85.9 parts of 500SN
(7) extraordinary antiwear hydraulic oil
The universal antifriction additive wherein contains for 0.4 part: 0.04 part in graphite
0.03 part of molybdenumdisulphide
0.1 part of dispersion agent
10 parts of functional additives
89.5 parts of base oils
The above-mentioned lubricating oil that utilizes universal antifriction lubricating oil additives to make, in running of an engine, utilize shearing force with graphite and molybdenum disulfide-filled to piston ring, piston and cylinder wall surface, improved the mechanical seal of combustion chamber, the pressurized air and the fuel that have suppressed in compression and power stroke are missed in piston, and the efficiency of combustion of fuel is provided again simultaneously.So not only improved fuel economy (fuel economy), but also reduce exhaust emissions, protected environment owing to fill enough mulch films, when cold starting, prevented friction, wearing and tearing, can better protect engine parts.
Claims (6)
1, universal antifriction lubricating oil additives is characterized in that being made of following component by weight, graphite granule, and particle diameter accounts for more than 70% less than 1.0 μ m, 5～10 parts of content; Molybdenumdisulphide, particle diameter accounts for 95% less than 1.5 μ m, 1～4 part of content; 0.1～0.9 part of titanate coupling agent; 8～20 parts of dispersion agents; 65～90 parts in dispersion medium.
2, universal antifriction lubricating oil additives as claimed in claim 1 is characterized in that: graphite granule, and particle diameter accounts for more than 70% less than 1.0 μ m, 7～9 parts of content; Molybdenumdisulphide, particle diameter accounts for 95% less than 1.5 μ m, 1.5～3 parts of content; 0.2～0.6 part of titanate coupling agent; 10～15 parts of dispersion agents; 75～80 parts in dispersion medium.
3, universal antifriction lubricating oil additives as claimed in claim 1 or 2 is characterized in that titanate coupling agent is one of triisopropyl phosphorous acid metatitanic acid fat, triisopropyl stearic acid metatitanic acid fat.
4, universal antifriction lubricating oil additives as claimed in claim 1 or 2 is characterized in that dispersion agent is one of the two succimides of polyisobutene, the many succimides of polyisobutene.
5, universal antifriction lubricating oil additives as claimed in claim 1 or 2 is characterized in that dispersion medium is the base oil of 150SN, 150BS.
6, the preparation method of universal antifriction lubricating oil additives is characterized in that being prepared as follows by the component of claim 1:
A, natural graphite is pulverized, particle diameter accounts for more than 70% less than the particle of 1.0 μ m, and maximum particle diameter is no more than 6 μ m;
B, with molybdenumdisulphide pulverize, particle diameter accounts for more than 90% less than the particle of 1.5 μ m;
C, get graphite that a, b step obtain and molybdenumdisulphide with weight part by 3～10: 1～5 mixed;
D, the mixture of c is added 6-14 part base oil earlier, add 0.1～0.9 part in titanate coupling agent triisopropyl phosphorous acid metatitanic acid fat or triisopropyl stearic acid metatitanic acid fat again, and in kneader, mediated 20-50 minute;
E, in the mixture of d, add 65～90 parts of the two succimides of dispersion agent polyisobutene or 8～20 parts of the many succimides of polyisobutene and base oils, once high-pressure homogeneous under 50～70Mpa, promptly obtain the universal antifriction lubricating oil additives finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100100369A CN100519714C (en) | 2005-05-24 | 2005-05-24 | Universal antifriction lubricating oil additives and method for preparing same |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100100369A CN100519714C (en) | 2005-05-24 | 2005-05-24 | Universal antifriction lubricating oil additives and method for preparing same |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1699528A true CN1699528A (en) | 2005-11-23 |
| CN100519714C CN100519714C (en) | 2009-07-29 |
Family
ID=35475777
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100100369A Expired - Fee Related CN100519714C (en) | 2005-05-24 | 2005-05-24 | Universal antifriction lubricating oil additives and method for preparing same |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100519714C (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505522A (en) * | 2016-01-29 | 2016-04-20 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Lubricating oil additive containing nano diamond alkenes and preparation method of lubricating oil additive |
| CN107760424A (en) * | 2017-11-15 | 2018-03-06 | 无锡中科苏惠自动化技术有限公司 | A kind of automation equipment biological based lubricating oil and preparation method thereof |
| CN107815339A (en) * | 2017-11-15 | 2018-03-20 | 无锡中科苏惠自动化技术有限公司 | High wear-resisting automated machine equipment lubricating oil of tack and preparation method thereof |
| CN107937094A (en) * | 2017-11-15 | 2018-04-20 | 无锡中科苏惠自动化技术有限公司 | A kind of wear-resisting automated machine equipment lubricating grease of high adhesion and its preparation |
| CN108559581A (en) * | 2018-04-21 | 2018-09-21 | 高密市孚润达润滑油有限公司 | A kind of preparation method of molybdenum disulfide wear-resistant lubricating oil |
| CN109401815A (en) * | 2018-11-13 | 2019-03-01 | 吴鸿江 | Antiwear and antifriction composition, wear-resistant friction reducer and preparation method thereof |
| CN109749818A (en) * | 2018-12-29 | 2019-05-14 | 中国人民解放军空军勤务学院 | A kind of non-sulphur phosphorus organic titanium anti wear and friction reducing additives of environment-friendly type and preparation method thereof |
-
2005
- 2005-05-24 CN CNB2005100100369A patent/CN100519714C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105505522A (en) * | 2016-01-29 | 2016-04-20 | 郑州人造金刚石及制品工程技术研究中心有限公司 | Lubricating oil additive containing nano diamond alkenes and preparation method of lubricating oil additive |
| CN107760424A (en) * | 2017-11-15 | 2018-03-06 | 无锡中科苏惠自动化技术有限公司 | A kind of automation equipment biological based lubricating oil and preparation method thereof |
| CN107815339A (en) * | 2017-11-15 | 2018-03-20 | 无锡中科苏惠自动化技术有限公司 | High wear-resisting automated machine equipment lubricating oil of tack and preparation method thereof |
| CN107937094A (en) * | 2017-11-15 | 2018-04-20 | 无锡中科苏惠自动化技术有限公司 | A kind of wear-resisting automated machine equipment lubricating grease of high adhesion and its preparation |
| CN108559581A (en) * | 2018-04-21 | 2018-09-21 | 高密市孚润达润滑油有限公司 | A kind of preparation method of molybdenum disulfide wear-resistant lubricating oil |
| CN109401815A (en) * | 2018-11-13 | 2019-03-01 | 吴鸿江 | Antiwear and antifriction composition, wear-resistant friction reducer and preparation method thereof |
| CN109401815B (en) * | 2018-11-13 | 2021-06-22 | 吴鸿江 | Wear-resistant and friction-reducing composition, wear-resistant and friction-reducing agent and preparation method thereof |
| CN109749818A (en) * | 2018-12-29 | 2019-05-14 | 中国人民解放军空军勤务学院 | A kind of non-sulphur phosphorus organic titanium anti wear and friction reducing additives of environment-friendly type and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100519714C (en) | 2009-07-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1699528A (en) | Universal antifriction lubricating oil additives and method for preparing same | |
| CN100337983C (en) | A composite body of silicon carbide and binderless carbon and process for producing | |
| CN1314786C (en) | High alkali cleaning additive | |
| CN105647612A (en) | Lubricating grease containing a nanometer carbon material and a preparing method thereof | |
| CN1944607A (en) | High performance nano metal/mine ore powder composite self repairing agent and its preparing method | |
| WO2012080939A1 (en) | Grease composition | |
| WO2012080940A1 (en) | Grease composition | |
| CN1888036A (en) | Composite calcium-base lubricating grease and its prepn | |
| CN1165595C (en) | water-based mud extreme pressure lubricant | |
| CN102344846A (en) | Lubricating oil with negative wear self-repair function and preparation method thereof | |
| CN101338238B (en) | Internal combustion engine oil potentiator special for shipping | |
| CN101353606B (en) | Complex grease additive | |
| CN113817530A (en) | Drawing oil containing nano-particle additive | |
| CN1888037A (en) | Anticorrosive polyaniline thread grease and its prepn | |
| CN101503645B (en) | Cermet couplant and preparation thereof | |
| CN1923978A (en) | Ethanol modifier and application thereof | |
| CN1234826C (en) | Graphite lubricating oil and its preparing method | |
| CN1566294A (en) | Preparation of antiwear antifriction reparation lubricating oil additive using nano materials | |
| KR101336294B1 (en) | Lubricant composition and method of producing the same | |
| CN110734804A (en) | nanometer cutting oil and preparation method and application thereof | |
| CN102382711B (en) | Novel engine oil for diesel engine and preparation method thereof | |
| CN1831097A (en) | Antiwear and energy-saving lubricant oil | |
| CN101338242B (en) | Gear oil potentiator special for pumping unit | |
| CN108485764A (en) | A kind of wear-resisting vehicle lubricating oil and preparation method thereof | |
| CN103614182A (en) | Biological lubricating oil additive and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: DAQING RUNYUAN CHEMICAL CO., LTD. Free format text: FORMER OWNER: WU XINGHE Effective date: 20110831 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 163111 DAQING, HEILONGJIANG PROVINCE TO: 163316 DAQING, HEILONGJIANG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20110831 Address after: 163316 Daqing Development Zone, Heilongjiang Patentee after: Daqing Development Zone Run Yuan Chemical Co., Ltd. Address before: 163111 No. three, No. 99 Middle Road, Saertu District, Heilongjiang, Daqing Patentee before: Wu Xinghe |
|
| ASS | Succession or assignment of patent right |
Owner name: WU XINGHE Free format text: FORMER OWNER: DAQING RUNYUAN CHEMICAL CO., LTD. Effective date: 20120730 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 163316 DAQING, HEILONGJIANG PROVINCE TO: 163111 DAQING, HEILONGJIANG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20120730 Address after: 163111 No. three, No. 99 Middle Road, Saertu District, Heilongjiang, Daqing Patentee after: Wu Xinghe Address before: 163316 Daqing Development Zone, Heilongjiang Patentee before: Daqing Development Zone Run Yuan Chemical Co., Ltd. |
|
| ASS | Succession or assignment of patent right |
Owner name: HEILONGJIANG RUNYUAN CHEMICAL INDUSTRY CO., LTD. Free format text: FORMER OWNER: WU XINGHE Effective date: 20130426 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 163111 DAQING, HEILONGJIANG PROVINCE TO: 163316 DAQING, HEILONGJIANG PROVINCE |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20130426 Address after: 163316 room 407, B11, service outsourcing garden, hi tech Zone, Heilongjiang, Daqing Patentee after: Heilongjiang Run Yuan Chemical Co., Ltd. Address before: 163111 No. three, No. 99 Middle Road, Saertu District, Heilongjiang, Daqing Patentee before: Wu Xinghe |
|
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20090729 Termination date: 20200524 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |