CN1699464A - Process for preparing nano Si3N4 / polytetrafluoroethylene antiwear composite materials - Google Patents
Process for preparing nano Si3N4 / polytetrafluoroethylene antiwear composite materials Download PDFInfo
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- CN1699464A CN1699464A CN 200510027063 CN200510027063A CN1699464A CN 1699464 A CN1699464 A CN 1699464A CN 200510027063 CN200510027063 CN 200510027063 CN 200510027063 A CN200510027063 A CN 200510027063A CN 1699464 A CN1699464 A CN 1699464A
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- polytetrafluoroethylene
- tetrafluoroethylene
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Abstract
The invention relates to a process for preparing nano Si3N4 / polytetrafluoroethylene antiwear composite materials, wherein the weight percentage of the constituents in the raw material being, polytetrafluoroethylene 75-95%, nano Si3N4 4-15%, 1-10% of accessory material which includes molybdenum disulphite and inorganic pigment. The preparing process comprises the steps of mixing the raw materials, mechanically agitating homogeneously, forming the mixed powder in stainless steel die arrangement, high temperature sintering, and mechanically processing.
Description
Technical field
The present invention relates to a kind of preparation method of matrix material, relate in particular to a kind of nanometer Si
3N
4The preparation method of/PTFE anti-wear composite material adopts nanometer Si
3N
4Particles filled tetrafluoroethylene can improve the hardness of teflon resin matrix, and then improves the mechanical property and the abrasion resistance properties of matrix material.
Background technology
Tetrafluoroethylene is the most potential antifriction material, though it is good to have a self-lubricating property, frictional coefficient is low, excellent specific property such as corrosion-resistant, low temperature resistant, but because of its bad mechanical property, linear expansivity is big, thermal conductivity is poor again, and abrasion loss is big, uses and be unsuitable for doing separately high-abrasive material.Common employing adds fillers such as fiber, particle, whisker it is carried out modification in tetrafluoroethylene, be prepared into ptfe composite, in the hope of when keeping its low-friction coefficient, obtain good wear resistance and high strength, high rigidity and dimensional stability.
Granular packing material is one of field of compound material packing material commonly used, and in recent years, the particle of nanoscale is used for filled composite materials has become one of domestic and international hot research field.Nano particle is used for filling thermoplastic resin's matrix, can improve its rigidity, hardness and dimensional stability, and can improve the wear resistance of material.
Someone studies and uses nanometer Si
3N
4Particles filled Resins, epoxy just can obtain good tribological property under the condition of very little filling consumption.
Chinese invention patent 200310109284.X discloses a kind of nano-material modified polytetrafluoroethyloil oil seals PP Pipe Compound composition and method of making the same, but its nano inoganic particle that adopts is Al
2O
3, SiO
2, ZnO, TiO
2, its main application is an oil sealing PP Pipe Compound composition, is a kind of sealing material, can not be applied to friction materials.
Chinese invention patent 02111929.5 discloses a kind of PTFE anti-wear composite material that contains carbon nanotube, has high wear resisting property.But what its packing material adopted is carbon nanotube, and carbon nanotube costs an arm and a leg, and is not suitable for producing in enormous quantities.
Summary of the invention
The objective of the invention is at the deficiencies in the prior art, a kind of nanometer Si is provided
3N
4The preparation method of/PTFE anti-wear composite material, advantage such as resulting composite products has good manufacturability, and mechanical property is good, and dimensional stabilizing is wear-resisting, and frictional coefficient is little.
For realizing such purpose, in the technical scheme of the present invention, elder generation is with tetrafluoroethylene, nanometer Si
3N
4, subsidiary material carry out mechanical blending according to a certain percentage, the powerful stirring put into mixed powder stainless steel mould compression moulding again, the blank with compression moulding carries out sintering then, by mechanical workout, makes nanometer Si again
3N
4/ ptfe composite sample or part.
Method concrete steps of the present invention are:
Earlier with tetrafluoroethylene, nanometer Si
3N
4, subsidiary material mix according to a certain percentage, carry out the powerful stirring of machinery then, after stirring mixed powder put into stainless steel mould compression moulding, pressure-controlling is about 40～50MPa, time is 30～50 minutes, pressurization and stress-relief process must slowly carry out, the blank of above-mentioned compression moulding is taken out gently, put into muffle furnace, carry out sintering: slowly be warming up to about 320 ℃ earlier, and then be warming up to about 380 ℃ with 30 ℃/hour speed, be incubated 5～6 hours, again by being machined into nanometer Si
3N
4/ ptfe composite sample or part.
Wherein, the weight percent of each material composition of matrix material is as follows:
Tetrafluoroethylene: 75%～95%,
Nanometer Si
3N
4: 4%～15%,
Subsidiary material: 1%～10%.
Wherein subsidiary material comprise molybdenumdisulphide, some mineral dyes etc.
Processing method of the present invention is simple, and prepared matrix material has advantages such as cost is low, and dimensional stability is good, and self lubricity is good, and is wear-resisting, and the life-span is long, compares with common ptfe composite, has better mechanical property and tribological property.
Embodiment
Below by specific embodiment technical scheme of the present invention is further described, but do not constitute limitation of the invention.
Embodiment 1:
Used starting material comprise: teflon resin, the SM021-F type that ShanghaiChlorine and Alkali Chemical Co Ltd produces; Nanometer Si
3N
4, average dimension is produced by Zhoushan nano material company limited below 20nm.
Each weight percentages of components of starting material is as follows:
Tetrafluoroethylene: 95%
Nanometer Si
3N
4: 4%
Subsidiary material: 1% (0.5% molybdenumdisulphide+0.5% medium chrome yellow medium yellow)
Above-mentioned starting material are carried out powerful mechanical stirring, then mixed powder is put into stainless steel mould compression moulding, pressure-controlling is about 40MPa, and the time is 50 minutes, and pressurization and stress-relief process slowly carry out, the blank of above-mentioned compression moulding is taken out gently, put into muffle furnace, carry out sintering: slowly be warming up to about 320 ℃ earlier, and then be warming up to about 380 ℃ with 30 ℃/hour speed, be incubated 5 hours, make nanometer Si
3N
4/ PTFE anti-wear composite material.Above-mentioned materials is machined into the matrix material sample of 20mm * 10mm * 10mm, on the M-2000 friction wear testing machine, records:
Frictional coefficient is 0.24, and the specific wear rate is 36.2 * 10
-6Mm
3/ N.m.
Embodiment 2:
Used starting material are with embodiment 1.
Each weight percentages of components of starting material is as follows:
Tetrafluoroethylene: 85%
Nanometer Si
3N
4: 10%
Subsidiary material: 5% (medium chrome yellow medium yellow of 3% molybdenumdisulphide+2%)
Above-mentioned starting material are carried out powerful mechanical stirring, then mixed powder is put into stainless steel mould compression moulding, pressure-controlling is about 50MPa, and the time is 30 minutes, and pressurization and stress-relief process slowly carry out, the blank of above-mentioned compression moulding is taken out gently, put into muffle furnace, carry out sintering: slowly be warming up to about 320 ℃ earlier, and then be warming up to about 380 ℃ with 30 ℃/hour speed, be incubated 6 hours, make nanometer Si
3N
4/ PTFE anti-wear composite material.Above-mentioned materials is machined into shock test sample and rub(bing)test sample.Shock test is carried out on universal testing machine, and friction-wear test is carried out on the M-2000 friction wear testing machine, test result:
Shock strength: 14.5kJ/m
2, frictional coefficient 2.7, specific wear rate 48.6 * 10
-6Mm
3/ N.m.
Embodiment 3:
The raw material that adopts is with embodiment 1.
Raw-material weight percent is as follows:
Tetrafluoroethylene: 75%
Nanometer Si
3N
4: 15%
Subsidiary material: 10% (medium chrome yellow medium yellow of 8% molybdenumdisulphide+2%)
Above-mentioned starting material are carried out powerful mechanical stirring, then mixed powder is put into stainless steel mould compression moulding, pressure-controlling is about 45MPa, and the time is 40 minutes, and pressurization and stress-relief process slowly carry out, the blank of above-mentioned compression moulding is taken out gently, put into muffle furnace, carry out sintering: slowly be warming up to about 320 ℃ earlier, and then be warming up to about 380 ℃ with 30 ℃/hour speed, be incubated 5 hours, make nanometer Si
3N
4/ PTFE anti-wear composite material.Above-mentioned materials is machined into the matrix material sample, on the M-2000 friction wear testing machine, records:
Frictional coefficient is 2.6, specific wear rate 42.7 * 10
-6Mm
3/ N.m.
Claims (1)
1, a kind of nanometer Si
3N
4The preparation method of/PTFE anti-wear composite material is characterized in that earlier tetrafluoroethylene, nanometer Si
3N
4, subsidiary material are mixed in proportion, mechanical stirring is even, then mixed powder is put into stainless steel mould compression moulding, pressure-controlling is at 40～50MPa, time is 30～50 minutes, and pressurization and stress-relief process slowly carry out, with the blank taking-up of above-mentioned compression moulding, put into muffle furnace and carry out sintering, earlier slowly be warming up to 320 ℃, and then be warming up to 380 ℃, be incubated 5～6 hours with 30 ℃/hour speed, again by mechanical workout, make nanometer Si at last
3N
4/ ptfe composite sample or part; Wherein, the weight percent of each material composition of matrix material is: tetrafluoroethylene: 75%～95%, and nanometer Si
3N
4: 4%～15%, subsidiary material molybdenumdisulphide and mineral dye: 1%～10%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100270637A CN1318503C (en) | 2005-06-23 | 2005-06-23 | Process for preparing nano Si3N4 / polytetrafluoroethylene antiwear composite materials |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2005100270637A CN1318503C (en) | 2005-06-23 | 2005-06-23 | Process for preparing nano Si3N4 / polytetrafluoroethylene antiwear composite materials |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1699464A true CN1699464A (en) | 2005-11-23 |
| CN1318503C CN1318503C (en) | 2007-05-30 |
Family
ID=35475717
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2005100270637A Expired - Fee Related CN1318503C (en) | 2005-06-23 | 2005-06-23 | Process for preparing nano Si3N4 / polytetrafluoroethylene antiwear composite materials |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1318503C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802154A (en) * | 2016-05-03 | 2016-07-27 | 苏州天擎电子通讯有限公司 | Wearproof antiskid type mobile phone protective shell |
| CN111073185A (en) * | 2019-12-04 | 2020-04-28 | 沈阳化工大学 | B4Preparation method of C/polytetrafluoroethylene composite material |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1148429C (en) * | 2001-07-09 | 2004-05-05 | 北京化工大学 | Anticorrossion antiwear ceramic paint |
| CN1176153C (en) * | 2002-05-30 | 2004-11-17 | 浙江大学 | Antiwear teflon composite material containing nano carbon tubes |
-
2005
- 2005-06-23 CN CNB2005100270637A patent/CN1318503C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105802154A (en) * | 2016-05-03 | 2016-07-27 | 苏州天擎电子通讯有限公司 | Wearproof antiskid type mobile phone protective shell |
| CN111073185A (en) * | 2019-12-04 | 2020-04-28 | 沈阳化工大学 | B4Preparation method of C/polytetrafluoroethylene composite material |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1318503C (en) | 2007-05-30 |
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| SE01 | Entry into force of request for substantive examination | ||
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Granted publication date: 20070530 Termination date: 20100623 |