CN1687337A - Clean compound ester type high temperature chain oil and preparation method - Google Patents
Clean compound ester type high temperature chain oil and preparation method Download PDFInfo
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- CN1687337A CN1687337A CN 200510024898 CN200510024898A CN1687337A CN 1687337 A CN1687337 A CN 1687337A CN 200510024898 CN200510024898 CN 200510024898 CN 200510024898 A CN200510024898 A CN 200510024898A CN 1687337 A CN1687337 A CN 1687337A
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Abstract
The present invention discloses a clean compounded ester type high-temperature chain oil and its preparation method. Its composition includes (by wt%) 40-90% of pentaerythritol compounded ester, 10-50% of benzenetetracarboxylic acid ester, 1-5% of high-temperature antioxidant, 1-5% of extreme pressure/anti-scuff agent and 0.02-0.5% of corrosion-resisting agent. Besides, said invention also provides the concrete steps of its preparation method, and provides its application range.
Description
Technical field
The present invention relates to a kind of composition, high-temperature chain oil and concocting method thereof especially are applicable to the low evaporation of equipment chain greasisngs such as heat setting machine, baking finish line, high temperature oven, the clean compound ester type high temperature chain oil that detergency is good.
Background technology
At present, the used chain oils of the high temperature oven of known dyeing heat setting machine, baking finish line and other industries is formed polyether-type, pentaerythritol ester type or the trimellitate type of mostly being.The polyether-type high-temperature chain oil has the good characteristics of lubricity, but its Applicable temperature is lower, generally is applied to the lubricated of the heat setting machine chain of setting temperature below 180 ℃; Tetramethylolmethane ester type high temperature chain oil Applicable temperature can reach 250 ℃, but at high temperature vaporization losses is bigger; Trimellitate type chain oils high temperature detergency ideal, but have the defective of poor lubricity.
Summary of the invention
The purpose of this invention is to provide a kind of clean compound ester type high temperature chain oil and concocting method thereof that can be applicable to heat setting machine, baking finish line and baking oven, not only Applicable temperature can reach 260 ℃, and has the characteristics that vaporization losses is little, coking is few, detergency is good under hot environment.
Technical scheme of the present invention is: a kind of clean compound ester type high temperature chain oil, by following component by weight percentage composition be: dipentaerythritol complex ester 40～90%, Pyromellitic Acid ester 10～50%, high-temperature antioxidant 1～5%, extreme pressure/antiwear agents 1～5%, corrosion inhibitor 0.02～0.5%.Wherein, described high-temperature antioxidant is an amine type oxidation inhibitor compound; Described extreme pressure/antiwear agents is at least a kind of or its mixture in thiophosphatephosphorothioate, the phosphoric acid ester; Described corrosion inhibitor is two benzotriazoles.The base oil of forming high-temperature chain oil adopts the dipentaerythritol complex ester, and adjusts viscosity with the Pyromellitic Acid ester, to reach suitable base oil viscosity requirement; Additive is selected efficient high-temperature antioxidant, extreme pressure/antiwear agents and corrosion inhibitor for use.
The base oil that the present invention selects for use: dipentaerythritol complex ester base oil structure is shown in (A); 40 ℃ of kinematic viscosity of Pyromellitic Acid ester are 40～180mm
2/ s.
N=7～11 R=C
6～C
9Alkyl
The additive that the present invention selects for use: high-temperature antioxidant is an amine type oxidation inhibitor compound; Extreme pressure/wear preventive additive is thiophosphatephosphorothioate, phosphoric acid ester or its mixture; The rut preventives that adopts is two benzotriazoles.
Each set of dispense of the present invention is such as following table:
| Title | Weight part (%) |
| Base oil: bipentaerythrite complex ester Pyromellitic Acid ester additive: high-temperature antioxidant extreme pressure/antiwear agents corrosion inhibitor | ? ????40～90 ????10～50 ? ????1～5 ????1～5 ????0.02～0.5 |
Allocation process in turn includes the following steps:
(1) high-temperature antioxidant, extreme pressure/wear preventive additive, corrosion inhibitor and the heating of Pyromellitic Acid ester and stirring are warming up to 90～100 ℃, insulation 0.5～1h makes the solid materials dissolving fully;
(2) add the dipentaerythritol complex ester again, 70～80 ℃ of temperature controls continue to stir 1h;
(3) be cooled to below 50 ℃ and filter with 500 order industrial filter cloths.
Wherein, dipentaerythritol complex ester weight percentage (%) is: 40,45,50,60,61,62,63,64,65,66,67,68,69,70,71,72,73,74,75,76,77,78,79,80,85,90:
Pyromellitic Acid ester weight percentage (%) is: 10,20,30,40,50;
High-temperature antioxidant weight percentage (%) is: 1,1.5,2,2.5,3,3.5,4,4.5,5;
Extreme pressure/antiwear agents weight percentage (%) is: 1,1.5,2,2.5,3,3.5,4,4.5,5:
Corrosion inhibitor weight percentage (%) is: 0.02,0.05,0.08,0.1,0.15,0.2,0.25,0.3,0.35,0.4,0.45,0.5
Superiority of the present invention is: prepared high-temperature chain oil is 260 ℃ and lubricating with lower chain applicable to envrionment temperature.Because the dipentaerythritol complex ester base oil high high-temp stability that adopts is good, can reduces lubricating oil and use consumption.Cooperate high performance amine type oxidation inhibitor compound, high temperature produces greasy filth down, coking is few, can keep the chain cleaning for a long time.Specific dipentaerythritol complex ester base oil has extremely excellent oilness, helps the chain wear protection, and can reduce the equipment operation energy consumption.
Description of drawings
Preparation process figure of the present invention.
Embodiment
Each composition weight percentage composition (%) is
Embodiment 1 embodiment 2
Dipentaerythritol complex ester 65.3 73.9
Pyromellitic Acid ester 30.0 20.0
Amine type oxidation inhibitor 2.5 3.0
Triphenyl-thiophosphate 2.0 3.0
Two benzotriazoles 0.2 0.1
In embodiment 1: 40 ℃ of kinematic viscosity of dipentaerythritol complex ester are 650～800mm
2/ s; 40 ℃ of kinematic viscosity of Pyromellitic Acid ester are 80～95mm
2/ s; Oxidation inhibitor is the mixture of alkylated diphenylamine and alkylation N-phenyl-a-naphthylamine.
Allocating technology is shown in figure preparation process figure of the present invention:
(1) amine type oxidation inhibitor, triphenyl-thiophosphate, two benzotriazole and the heating of Pyromellitic Acid ester and stirring are warming up to 90～100 ℃, insulation 0.5～1h makes the solid materials dissolving fully;
(2) add the dipentaerythritol complex ester more successively, 70～80 ℃ of temperature controls continue to stir 1h;
(3) be cooled to below 50 ℃ and filter with 500 order industrial filter cloths.
In embodiment 2: 40 ℃ of kinematic viscosity of dipentaerythritol complex ester are 500～650mm
2/ s; 40 ℃ of kinematic viscosity of Pyromellitic Acid ester are 80～95mm
2/ s; Oxidation inhibitor is the mixture of alkylated diphenylamine and alkylation N-phenyl-a-naphthylamine.
The preparation method is with embodiment 1.
Claims (7)
1, a kind of clean compound ester type high temperature chain oil, by following component by weight percentage composition make: dipentaerythritol complex ester 40～90%, Pyromellitic Acid ester 10～50%, high-temperature antioxidant 1～5%, extreme pressure/antiwear agents 1～5%, corrosion inhibitor 0.02～0.5%.Wherein, described high-temperature antioxidant is an amine type oxidation inhibitor compound; Described extreme pressure/antiwear agents is at least a kind of or its mixture in thiophosphatephosphorothioate, the phosphoric acid ester; Described corrosion inhibitor is two benzotriazoles.
2, clean compound ester type high temperature chain oil according to claim 1 is characterized in that dipentaerythritol complex ester structure is:
CH
2 n[COO-CH
2-C (CH
2OOCR)
2CH
2OCH
2C (CH
2OOCR)
3]
2Wherein, n=7～11
R=C
6～C
9Alkyl.
3, clean compound ester type high temperature chain oil according to claim 1 is characterized in that 40 ℃ of kinematic viscosity of Pyromellitic Acid ester are 40～180mm
2/ s.
4, clean compound ester type high temperature chain oil according to claim 1 and 2 is characterized in that 40 ℃ of kinematic viscosity of dipentaerythritol complex ester are 500～800mm
2/ s.
5, clean compound ester type high temperature chain oil according to claim 1 is characterized in that amine type oxidation inhibitor compound is the mixture of alkylated diphenylamine and alkylation N-phenyl-a-naphthylamine.
6, a kind of clean compound ester type high temperature chain oil according to claim 1 is characterized in that extreme pressure/antiwear agents is triphenyl-thiophosphate or tritolyl phosphate.
7, the concocting method of a kind of clean compound ester type high temperature chain oil according to claim 1, it is characterized in that may further comprise the steps successively: (1) is warming up to 90～100 ℃ with high-temperature antioxidant, extreme pressure/antiwear agents, corrosion inhibitor and the heating of Pyromellitic Acid ester and stirring, and insulation 0.5～1h makes the solid materials dissolving fully; (2) add the dipentaerythritol complex ester more successively, 70～80 ℃ of temperature controls continue to stir 1h; (3) be cooled to below 50 ℃ with 500 order industrial filter cloths and filter, make finished product.
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| Application Number | Priority Date | Filing Date | Title |
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| CN200510024898A CN100580069C (en) | 2005-04-06 | 2005-04-06 | Clean compound ester type high temperature chain oil and preparation method thereof |
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| CN200510024898A CN100580069C (en) | 2005-04-06 | 2005-04-06 | Clean compound ester type high temperature chain oil and preparation method thereof |
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|---|---|
| CN1687337A true CN1687337A (en) | 2005-10-26 |
| CN100580069C CN100580069C (en) | 2010-01-13 |
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| CN200510024898A Expired - Fee Related CN100580069C (en) | 2005-04-06 | 2005-04-06 | Clean compound ester type high temperature chain oil and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117609B (en) * | 2006-08-04 | 2010-05-12 | 中国石油天然气股份有限公司大连润滑油研究开发中心 | High-temperature chain oil and preparation method thereof |
| CN102311855A (en) * | 2011-08-16 | 2012-01-11 | 中国人民解放军空军油料研究所 | Aviation lubricating oil composition |
| CN102311854A (en) * | 2011-08-16 | 2012-01-11 | 中国人民解放军空军油料研究所 | Preparation method of aviation lubricant composition |
| CN102417851A (en) * | 2011-10-17 | 2012-04-18 | 中国石油化工股份有限公司 | High temperature chain oil composition and preparation method thereof |
| CN103100660A (en) * | 2013-03-01 | 2013-05-15 | 上海金兆节能科技有限公司 | Mold releasing agent of aluminum alloy casting crystallizer, and preparation method thereof |
| CN103409209A (en) * | 2013-08-12 | 2013-11-27 | 上海海联润滑材料科技有限公司 | Synthetic high temperature chain oil |
| CN109326434A (en) * | 2018-12-06 | 2019-02-12 | 张磊 | A kind of transformer rubber coating machine automatic feed/discharge discharging guiding device |
| CN109536252A (en) * | 2018-11-24 | 2019-03-29 | 天津斯博特润滑科技有限公司 | A kind of peace and quiet high-temperature oxidation resistant chain oils of low volatility and its concocting method |
| CN109536253A (en) * | 2018-11-24 | 2019-03-29 | 天津斯博特润滑科技有限公司 | A kind of peace and quiet high-temperature corrosion-resistance chain oils of low volatility and its concocting method |
| CN109943403A (en) * | 2019-04-23 | 2019-06-28 | 中国石油化工股份有限公司 | A kind of high-temperature chain oil composition and preparation method thereof |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018094176A1 (en) | 2016-11-17 | 2018-05-24 | Zschimmer & Schwarz, Inc. | Lubricant composition for high-temperature applications |
-
2005
- 2005-04-06 CN CN200510024898A patent/CN100580069C/en not_active Expired - Fee Related
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101117609B (en) * | 2006-08-04 | 2010-05-12 | 中国石油天然气股份有限公司大连润滑油研究开发中心 | High-temperature chain oil and preparation method thereof |
| CN102311855A (en) * | 2011-08-16 | 2012-01-11 | 中国人民解放军空军油料研究所 | Aviation lubricating oil composition |
| CN102311854A (en) * | 2011-08-16 | 2012-01-11 | 中国人民解放军空军油料研究所 | Preparation method of aviation lubricant composition |
| CN102311854B (en) * | 2011-08-16 | 2013-04-24 | 中国人民解放军空军油料研究所 | Preparation method of aviation lubricant composition |
| CN102311855B (en) * | 2011-08-16 | 2013-04-24 | 中国人民解放军空军油料研究所 | Aviation lubricating oil composition |
| CN102417851A (en) * | 2011-10-17 | 2012-04-18 | 中国石油化工股份有限公司 | High temperature chain oil composition and preparation method thereof |
| CN103100660A (en) * | 2013-03-01 | 2013-05-15 | 上海金兆节能科技有限公司 | Mold releasing agent of aluminum alloy casting crystallizer, and preparation method thereof |
| CN103409209A (en) * | 2013-08-12 | 2013-11-27 | 上海海联润滑材料科技有限公司 | Synthetic high temperature chain oil |
| CN103409209B (en) * | 2013-08-12 | 2014-12-24 | 上海海联润滑材料科技有限公司 | Synthetic high temperature chain oil |
| CN109536252A (en) * | 2018-11-24 | 2019-03-29 | 天津斯博特润滑科技有限公司 | A kind of peace and quiet high-temperature oxidation resistant chain oils of low volatility and its concocting method |
| CN109536253A (en) * | 2018-11-24 | 2019-03-29 | 天津斯博特润滑科技有限公司 | A kind of peace and quiet high-temperature corrosion-resistance chain oils of low volatility and its concocting method |
| CN109326434A (en) * | 2018-12-06 | 2019-02-12 | 张磊 | A kind of transformer rubber coating machine automatic feed/discharge discharging guiding device |
| CN109943403A (en) * | 2019-04-23 | 2019-06-28 | 中国石油化工股份有限公司 | A kind of high-temperature chain oil composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN100580069C (en) | 2010-01-13 |
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Denomination of invention: Clean compound ester type high temperature chain oil and preparation method Effective date of registration: 20140403 Granted publication date: 20100113 Pledgee: Ningbo commercial bank, Limited by Share Ltd, Shanghai branch Pledgor: Nake Lubricating Technology Co., Ltd., Shanghai Registration number: 2014310000016 |
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Date of cancellation: 20151202 Granted publication date: 20100113 Pledgee: Ningbo commercial bank, Limited by Share Ltd, Shanghai branch Pledgor: Nake Lubricating Technology Co., Ltd., Shanghai Registration number: 2014310000016 |
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Granted publication date: 20100113 Termination date: 20190406 |