CN1680659A - Paper-like film and its use - Google Patents
Paper-like film and its use Download PDFInfo
- Publication number
- CN1680659A CN1680659A CN 200410030672 CN200410030672A CN1680659A CN 1680659 A CN1680659 A CN 1680659A CN 200410030672 CN200410030672 CN 200410030672 CN 200410030672 A CN200410030672 A CN 200410030672A CN 1680659 A CN1680659 A CN 1680659A
- Authority
- CN
- China
- Prior art keywords
- film
- paper
- quasi
- double
- paper membrane
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000000843 powder Substances 0.000 claims abstract description 11
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 238000007639 printing Methods 0.000 claims abstract description 5
- 239000005083 Zinc sulfide Substances 0.000 claims abstract description 4
- 229920001225 polyester resin Polymers 0.000 claims abstract description 4
- 239000004645 polyester resin Substances 0.000 claims abstract description 4
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 4
- 229910052712 strontium Inorganic materials 0.000 claims abstract description 4
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 claims abstract description 4
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000012528 membrane Substances 0.000 claims description 18
- 229920002545 silicone oil Polymers 0.000 claims description 11
- -1 D Polymers 0.000 claims description 7
- 229920002521 macromolecule Polymers 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- 229910052693 Europium Inorganic materials 0.000 claims description 4
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 4
- OGPBJKLSAFTDLK-UHFFFAOYSA-N europium atom Chemical compound [Eu] OGPBJKLSAFTDLK-UHFFFAOYSA-N 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- 239000007822 coupling agent Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052692 Dysprosium Inorganic materials 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- KBQHZAAAGSGFKK-UHFFFAOYSA-N dysprosium atom Chemical compound [Dy] KBQHZAAAGSGFKK-UHFFFAOYSA-N 0.000 claims description 2
- 239000003973 paint Substances 0.000 claims description 2
- 150000001336 alkenes Chemical class 0.000 claims 1
- 230000001680 brushing effect Effects 0.000 claims 1
- 238000003851 corona treatment Methods 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000001125 extrusion Methods 0.000 abstract description 4
- 238000010345 tape casting Methods 0.000 abstract description 3
- 239000002131 composite material Substances 0.000 abstract description 2
- 229920005672 polyolefin resin Polymers 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 abstract description 2
- 230000007547 defect Effects 0.000 abstract 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 abstract 1
- 238000002156 mixing Methods 0.000 description 8
- 229920000915 polyvinyl chloride Polymers 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 6
- 239000010410 layer Substances 0.000 description 5
- 229920003023 plastic Polymers 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 239000004604 Blowing Agent Substances 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- 150000002632 lipids Chemical class 0.000 description 2
- 229920006267 polyester film Polymers 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical class CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000007127 saponification reaction Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
- Luminescent Compositions (AREA)
Abstract
The invention discloses a paper-like film and application thereof, in particular to a paper-like film which is prepared from raw materials such as light-storing and emitting powder and used for double-sided recording and application thereof, belonging to the field of chemical industry. The defects that the known luminescent paper simulating film cannot record on two sides and has narrow use range and the like are overcome; the invention adopts polyolefin or polyester resin, strontium metaaluminate or zinc sulfide luminescent powder, methyl silicone oil or silicone, high molecular wax, titanium dioxide and other components, which are mixed in proportion and then put into an extruder, and the composite extrusion method or tape casting method is adopted for operation, and corona treatment is used when the product comes out, thus obtaining the paper-like film. The paper-like film with the composition can be used for double-sided writing and drawing on the film by various pens, and can also be used for double-sided printing on the film by equipment such as a printer and the like; the paper-like film can self-illuminate without light source, and can display the characters and images on the film.
Description
Invention field: the invention discloses a kind of quasi-paper membrane and uses thereof, particularly a kind ofly be used for quasi-paper membrane of double-sided recording modes and uses thereof, belong to chemical field with what hold that raw materials such as luminescent powder make.
Background technology: quasi-paper membrane is meant to mould Dai Mu through the come out general name of a class plastic sheeting close with the plain paper performance of blowing or curtain coating.It is raw material that present known quasi-paper membrane mainly adopts plastics, and the goods of making can not reclaim, and easily pollute; Mainly added in process of production such as the lower lipid solvent of boiling points such as propane, butane, ethane, dichloroethanes as blowing agent; On using, the quasi-paper membrane based article is mainly used in foaming wallpaper and plastics adhesive sticker posting in time coil paper; Have luminescent properties, can be used for the two-sided quasi-paper membrane of writing and printing does not still have report at present.
Summary of the invention: the object of the present invention is to provide a kind of luminous quasi-paper membrane that can double-sided recording modes and uses thereof.The present invention includes following composition on forming:
A. polyolefin or polyester resin,
B. use rare earth elements europium or use rare earth elements europium and the meta-aluminic acid strontium or the light-accumulative luminous powder of zinc sulphide of the agent activated by dysprosium of living altogether,
C. methyl-silicone oil or silicone,
D. macromolecule wax,
E. titanium aluminate class coupling agent,
F. titanium dioxide or calcium carbonate,
G. boric acid,
H. dimethylbenzene;
The weight ratio of above-mentioned each component was followed successively by 1.0: 0.9: 0.1: 0.01: 0.05: 0.01: 0.01: 0.005;
Put into extruder after above-mentioned composition mixed in proportion, the heating work temperature of extruder is controlled between 50～320 ℃, adopt compound extruding method or The tape casting to operate; Use corona treatment when goods come out, can obtain the light-accumulative luminous quasi-paper membrane of double-sided recording modes.Having adopted the luminous quasi-paper membrane of above-mentioned composition, is raw material with the TPO or the polyester resin of environment-friendly type, the recyclable utilization of its goods, environmentally safe; Silicone oil or silicone be meeting and luminescent powder generation saponification in raw material mixing temperature-rise period, forms micro-pore (bubble) performance and is better than lower boiling lipid solvent-borne type blowing agent; Changed the original melt index of plastics by adding, made the processing temperature of product be tending towards reasonable more through meta-aluminic acid strontium or zinc sulfide luminescent powder after silicone oil, the titanium aluminate class coupling agent treatment; The change of melt index makes the more present known quasi-paper membrane of pliability, resistance to water and drug-resistant, insulating properties of the luminous quasi-paper membrane of double-sided recording modes have a greater degree of improvement, and can destroy as paper; Through two-sided corona treatment, increased the printing ink adsorptivity of light-accumulative luminous quasi-paper membrane, can be directly enterprising line operate of quasi-paper membrane and difficult the correction; The light-accumulative luminous quasi-paper membrane of the double-sided recording modes of making can use various classes to write on film and paint, and also can use equipment such as ink-jet printer to print on film and the special-purpose digital the same effect of printing; And can be luminous voluntarily under the situation of dull thread source, with literal on the film or clear picture display.
Specific embodiments: below provided three embodiment the present invention made further instructions.
Embodiment 1, compound extruding method.Get light-accumulative luminous powder 450 grams, polyvinyl resin 500 gram silicone oil 15 grams, macromolecule wax 100 grams are put into the internal layer hopper after mixing; Get titanium dioxide 300 gram, polyvinyl resin 500 grams, silicone oil 5 grams are put into outer hopper through after mixing, 60～260 ℃ of temperature by compound die head film extrusion, corona treatment simultaneously, film thickness 0.1～3mm.
Embodiment 2, three layers of compound extruding method.Get light-accumulative luminous powder 450 grams, polyvinyl resin 500 gram silicone oil 15 grams, macromolecule wax 100 grams are put into the internal layer hopper after mixing; Get titanium dioxide 300 grams, polyvinyl resin 500 grams, silicone oil 5 grams are put into the middle level hopper through after mixing; Get high-quality luminescent powder 450 gram, polyvinyl resin 500 gram silicone oil 15 grams, macromolecule wax 100 grams are put into outer hopper after mixing, 60～260 ℃ of temperature by compound die head film extrusion, corona treatment simultaneously, film thickness 0.15～3mm.
Embodiment 3, MULTILAYER COMPOSITE are extruded The tape casting.Get the single-layer and transparent polyester film as the top layer film, get light-accumulative luminous powder 450 grams, polyvinyl resin 500 gram silicone oil 15 grams, macromolecule wax 100 grams are put into the internal layer hopper after mixing; Get titanium dioxide 300 grams, polyvinyl resin 500 grams, silicone oil 5 grams are put into the middle level hopper through after mixing; By compound die head film extrusion, simultaneously the single-layer and transparent polyester film is unreeled gluing 60～260 ℃ of temperature, through pressure roller pressing walk flat, corona treatment, film forming rolling.Film thickness 0.2～3mm.
Claims (2)
1, a kind of quasi-paper membrane is characterized in that including following composition:
A, alkene or polyester resin,
B, with rare earth elements europium or use rare earth elements europium and the meta-aluminic acid strontium or the light-accumulative luminous powder of zinc sulphide of the agent activated by dysprosium of living altogether,
C, basic silicone oil or silicone,
D, macromolecule wax,
E, titanium aluminate class coupling agent,
F, titanium dioxide or calcium carbonate,
G, boric acid,
H, dimethylbenzene;
The weight ratio of above-mentioned each component was followed successively by 1.0: 0.9: 0.1: 0.01: 0.05: 0.01: 0.01: 0.005.
2, a kind of quasi-paper membrane is characterized in that: can use various classes to write and paint in that quasi-paper membrane is two-sided, also can use equipment such as printer, air brushing machine to carry out duplex printing on film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410030672 CN1680659A (en) | 2004-04-05 | 2004-04-05 | Paper-like film and its use |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410030672 CN1680659A (en) | 2004-04-05 | 2004-04-05 | Paper-like film and its use |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1680659A true CN1680659A (en) | 2005-10-12 |
Family
ID=35067382
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410030672 Pending CN1680659A (en) | 2004-04-05 | 2004-04-05 | Paper-like film and its use |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1680659A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254493A (en) * | 2013-04-08 | 2013-08-21 | 上海东升新材料有限公司 | Noctilucent stone paper, its preparation method and application |
-
2004
- 2004-04-05 CN CN 200410030672 patent/CN1680659A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103254493A (en) * | 2013-04-08 | 2013-08-21 | 上海东升新材料有限公司 | Noctilucent stone paper, its preparation method and application |
| CN103254493B (en) * | 2013-04-08 | 2015-07-29 | 上海东升新材料有限公司 | Noctilucent stone paper and its preparation method and application |
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| DD01 | Delivery of document by public notice |
Addressee: Li Hanjun Document name: Notification before expiration of term |
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Addressee: Li Hanjun Document name: Deemed as a notice of withdrawal |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |