CN1679487A - Aqueous composition based on alcohol, surfactant and solubilizing agent, article impregnated with this composition, and method for cleansing the hair - Google Patents

Aqueous composition based on alcohol, surfactant and solubilizing agent, article impregnated with this composition, and method for cleansing the hair Download PDF

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Publication number
CN1679487A
CN1679487A CNA2005100641425A CN200510064142A CN1679487A CN 1679487 A CN1679487 A CN 1679487A CN A2005100641425 A CNA2005100641425 A CN A2005100641425A CN 200510064142 A CN200510064142 A CN 200510064142A CN 1679487 A CN1679487 A CN 1679487A
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hair
weight
compositions
composition
substrate
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CN100342843C (en
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S·德科斯特
V·马塞
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LOreal SA
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LOreal SA
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8105—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • A61K8/8111—Homopolymers or copolymers of aliphatic olefines, e.g. polyethylene, polyisobutene; Compositions of derivatives of such polymers
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/10—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged one within the other, e.g. concentrically
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/31—Hydrocarbons
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/34—Alcohols
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/39—Derivatives containing from 2 to 10 oxyalkylene groups
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H3/00—Air heaters
    • F24H3/02—Air heaters with forced circulation
    • F24H3/06—Air heaters with forced circulation the air being kept separate from the heating medium, e.g. using forced circulation of air over radiators
    • F24H3/08—Air heaters with forced circulation the air being kept separate from the heating medium, e.g. using forced circulation of air over radiators by tubes
    • F24H3/087—Air heaters with forced circulation the air being kept separate from the heating medium, e.g. using forced circulation of air over radiators by tubes using fluid fuel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00—Details
    • F24H9/0052—Details for air heaters
    • F24H9/0057—Guiding means
    • F24H9/0068—Guiding means in combustion gas channels
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00—Details
    • F24H9/0052—Details for air heaters
    • F24H9/0073—Arrangement or mounting of means for forcing the circulation of air
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F24—HEATING; RANGES; VENTILATING
    • F24H—FLUID HEATERS, e.g. WATER OR AIR HEATERS, HAVING HEAT-GENERATING MEANS, e.g. HEAT PUMPS, IN GENERAL
    • F24H9/00—Details
    • F24H9/18—Arrangement or mounting of grates or heating means
    • F24H9/1854—Arrangement or mounting of grates or heating means for air heaters
    • F24H9/1877—Arrangement or mounting of combustion heating means, e.g. grates or burners
    • F24H9/1881—Arrangement or mounting of combustion heating means, e.g. grates or burners using fluid fuel
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D7/00—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall
    • F28D7/16—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation
    • F28D7/163—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing
    • F28D7/1638—Heat-exchange apparatus having stationary tubular conduit assemblies for both heat-exchange media, the media being in contact with different sides of a conduit wall the conduits being arranged in parallel spaced relation with conduit assemblies having a particular shape, e.g. square or annular; with assemblies of conduits having different geometrical features; with multiple groups of conduits connected in series or parallel and arranged inside common casing with particular pattern of flow or the heat exchange medium flowing inside the conduits assemblies, e.g. change of flow direction from one conduit assembly to another one
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/006—Antidandruff preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F28—HEAT EXCHANGE IN GENERAL
    • F28D—HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT
    • F28D21/00—Heat-exchange apparatus not covered by any of the groups F28D1/00 - F28D20/00
    • F28D2021/0019—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for
    • F28D2021/0035—Other heat exchangers for particular applications; Heat exchange systems not otherwise provided for for domestic or space heating, e.g. heating radiators

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  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Veterinary Medicine (AREA)
  • Mechanical Engineering (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Engineering & Computer Science (AREA)
  • Thermal Sciences (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Medicine (AREA)
  • Geometry (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

The present invention relates to a hair composition preferably intended for cleansing the hair, containing, in a cosmetically acceptable aqueous medium, at least one C2-C4 monoalcohol, at least one surfactant and at least one agent that solubilizes liposoluble compounds, and to a method for cleansing said hair using this composition. It also relates to a cosmetic article impregnated with this composition and to the use of this composition for cleansing the hair, and to a method for cleansing said hair using this composition or this article.

Description

Based on the Aquo-composition of alcohol, surfactant and solubilizing agent, with the method for the goods and the cleaning hair of said composition dipping
Technical field
The present invention relates to a kind of hair composition that is used to clean hair, in the acceptable aqueous medium of a kind of cosmetics, contain at least a C 2-C 4The reagent of monohydric alcohol, at least a surfactant and at least a solubilising fat-soluble compound; Also relate to a kind of method of using said composition cleaning hair simultaneously.
Background technology
Under the effect of the elimination of multiple factor such as natural greasy dirt, perspiration, squama, pollution, humidity etc., hair has the trend of some quality of forfeiture.These factors are deleterious for the visual appearance and the sense of touch of hair.Thereby greasy dirt (may be to pollute) can force down hair once more, has to make the hair coagulation become one trend.So hair is difficult to typing, have the sense of touch of glossy and wax sample beastly, this also is beastly.
These factors almost all are that inevitably influence degree is indefinite.For example, depend on the length of hair quality, hair and the hair style of employing.
In any case, get used to adopting shampoo to tackle these inconvenience.In fact, it is very effective adopting cleanser compositions to clean, and can remove the dirt and the dandruff.During hair becomes dry, can make hair return to the form of hope then.But the beneficial effect of shampoo can disappear after several days, and problem described above can reappear.Therefore, the trend that increases the hair washing number of times is arranged.
Hair washing, the water source is essential, especially hot water or warm water.
Shampoo Compositions is based on a large amount of surfactants, and these surfactants can produce inconvenience for example scalp irritation or eye.
Proposed to adopt " doing " shampoo to clean hair quickly and to avoid the hair of getting wet.This technology is absorbent granules is sprayed on the hair, effectively curries hair then with eliminating particle.But, be difficult to thoroughly remove those granules usually.The result is not very satisfactory.Hair is not ten minutes gloss and feels very coarse.
Summary of the invention
Purpose of the present invention particularly will overcome the above problems.
Even more accurately, the objective of the invention is to propose a kind of method that cleans hair, after using end, make hair have neutral sense of touch and neutral visual appearance.
Now, after having carried out considerable research at this theme, the applicant is all beyond one's expectations and is surprised to find, this purpose and other purposes, can be used for cleaning the liquid makeup compositions of hair by use, especially hair composition is realized, in the acceptable aqueous medium of a kind of cosmetics, said composition contains:
-with respect at least a C of 10 to 90 weight % of composition total weight 2-C 4Monohydric alcohol;
-with respect at least a surfactant of 0.01 to 5 weight % of composition total weight, be selected from anion surfactant, both sexes and/or zwitterionic surfactant and non-ionic surface active agent;
-with respect to the reagent of a kind of solubilising fat-soluble compound of 0.01 to 5 weight % of composition total weight, it is different from surfactant, and is selected from straight or branched hydrocarbon, hydrogenation or unhydrided polyolefin, volatile siloxane and composition thereof;
-with respect to the water of 1 to 89.98 weight % of composition total weight.
The hair that adopts the present composition to clean has the characteristics of clean hair: the sensation of nature, glossy (oily outward appearance has disappeared), hair is elegant and bright and do not have the dandruff.In addition, more docile, submissiveer, the more suitable cunning of hair.And abnormal flavour beastly has been eliminated in this processing.
Thereby a theme of the present invention also is the cosmetic use that is used to clean hair of cosmetic composition defined above.
A theme of the present invention also is a kind of method that cleans hair, and described method is characterised in that compositions defined above is applied to exsiccant hair, and hair is become dry.
C 2-C 4Monohydric alcohol is a straight or branched.They especially are selected from ethanol, isopropyl alcohol and the tert-butyl alcohol.
The concentration range of alcohol is preferably 10 to 50 weight % with respect to composition total weight, more preferably 10 to 25 weight %.
As non-ionic surface active agent, preferably use alkyl poly glucoside, particularly have alkyl polyglucoside (the APGs) (C of the alkyl that contains 6-30 carbon atom 6-C 30Alkyl polyglucoside), preferably contain 8-16 carbon atom, for example decyl glucoside (C 9/ C 11Alkyl polyglucoside (1,4)), as Kao Chemicals company with title MYDOL 10 product solds, Henkel company with title PLANTAREN 2000 UP or PLANTACARE 2000 UP product solds and Seppic company with title ORAMIX NS 10 product solds; Caprylyl/capryl (capryl) glucoside, as Seppic company with title ORAMIX CG110 product sold; The lauryl glucoside, as Henkel company with title PLANTAREN 1200 N and PLANTACARE 1200 product solds; Coco-Glucoside, as Henkel company with title PLANTACARE 818/UP product sold.
As anion surfactant, as the anionic derivative that can use carboxylate, amino acid derivativges, alkyl sulfate, alkyl ether sulfate, sulfonate, isethionate, taurate, sulfosuccinate, alkyl sulfoethanoic acid. salt, phosphate ester salt and alkyl phosphate salt, polypeptide, alkyl polyglucoside, fatty acid soaps and composition thereof.
As carboxylate, as the salt (as alkali salt) that can mention the N-acylamino acid; (C 8-C 20) alkyl amido ether carboxylate (ACEs), as lauryl acylamino-ether carboxylic acid sodium (3EO), Kao Chemicals company sells with title AKYPO FOAM 30; (C 8-C 20) alkyl ether carboxy acid salt, as (6EO) lauryl ether carboxylic acid sodium (65/25/10 C of oxyethylation 12-C 14-C 16), Kao Chemicals company sells with title AKYPOSOFT 45 NV; The lauryl ether carboxylic acid (available from the AKYPO RLM 45 of KAO company) that comprises the ethylene oxideization of 4.5 EO; Polyoxyethyleneization and carboxy methylation olive oil fatty acid, as Biologia ETecnologia company with title OLIVEM 400 product solds; (6EO) tridecyl ether carboxylic acid sodium of ethylene oxideization, Nikkol company sells with title NIKKOL ECTD-6NEX; 2-(2-hydroxy alkoxy base) sodium acetate, Sanyo company sells with title BEAULIGHT SHAA.Preferred (the C that uses 8-C 20) alkyl amido ether carboxylic acid and (C 8-C 20) alkyl ether carboxylic acid and salt thereof.
Amino acid derivativges, as being selected from sarcosinate, acyl sarcosinates particularly, as sodium lauroyl sarcosine, Ciba company sells with title SARKOSYL NL 97 or Seppic company sells with title ORAMIXL30, myristoyl-N-methylaminoacetic acid sodium, and Nikkol company sells with title NIKKOL SARCOSINATE MN, palmitoyl sarcosine sodium, Nikkol company sells with title NIKKOL SARCOSINATE PN; Alanine salt, as N-lauroyl-N-methyl acylamino-Sodium L-alaninate, Nikkol company sells with title SODIUMNIKKOL ALANINATE LN 30 or Kawaken company sells with title ALANONE ALE, with N-lauroyl-methylalanine triethanolamine, Kawaken company sells with title ALANONE ALTA; The N-acyl glutamate, as single cocoyl glutamic acid triethanolamine, Ajinomomoto company sells and the lauroyl glutamate triethanolamine with title ACYLGLUTAMATE CT-12, and Ajinomoto company sells with title ACYLGLUTAMATE LT-12; Aspartate, as the mixture of N-lauroyl aspartic acid triethanolamine and N-myristoyl aspartic acid triethanolamine, Mitsubishi company sells with title ASPARACK LM-TS2; Citrate, and composition thereof.
As glycine derivative, can mention N-cocoyl Glycine sodium and N-cocoyl glycine potassium, as Ajinomoto company with title AMILITE GCS-12 and AMILITE GCK-12 product sold.
As alkyl ether sulfate, as mentioning sodium laureth sulfate (70/30 C 12-C 14) (2.2 EO), Henkel company sells with title SIPON AOS 225 or TEXAPON N702 PATE; Zetesol AP (70/30 C 12-C 14) (3EO), Henkel company sells with title SIPON LEA 370; Or C 12-C 14Alkyl ether (9EO) ammonium sulfate, Rhodia Chimie company sells with title RHODAPEXAB/20.
As sulfonate, as mentioning alpha-alkene sulfonate, as alpha-olefin sodium sulfonate (C 14-C 16), Stepan company sells with title BIO-TERGE AS-40, and Witco company sells with title WITCONATE AOSPROTEGE and SULFRAMINE AOS PH 12, or Stepan company sells with title BIO-TERGE AS-40CG; Secondary alkene sulfonic acid sodium, Clariant company sells with title HOSTAPUR SAS 30; Or the straight chained alkyl aromatic sulfonate, as sodium xylene sulfonate, Manro company is with title MANROSOL SXS30, and MANROSOL SXS40 and MANROSOL SXS93 sell.
As isethionate, can mention acyl-hydroxyethyl sulfonate, as the cocoyl sodium isethionate, as Jordan company with title JORDAPON CIP product sold.
As taurate, can mention the sodium salt of palm-kernel oil N-methyltaurine, Clariant company sells with title HOSTAPON CT PATE; N-acyl group-N methyl taurine salt, as N-cocoyl-N methyl taurine sodium, Clariant company is with title HOSTAPON LT-SF, or Nikkol company sells with title NIKKOL CMT-30-T; PMT sodium, Nikkol company sells with title NIKKOLPMT.
As sulfosuccinate, as mentioning (3EO) lauryl (70/30 C of ethylene oxideization 12-C 14) pure single sulfosuccinate, Witco company sells with title SETACIN 103 SPECIAL and REWOPOLSB-FA 30 K4; C 12-C 14The disodium salt of half 2-Sulfosuccinic acid of alcohol, Zschimmer Schwarz company sells with title SETACIN F SPECIAL PASTE; The amino disodium sulfosuccinate of (2EO) oleoyl of ethylene oxideization, Henkel company sells with title STANDAPOL SH 135; (5EO) lauramide list sulfosuccinate of ethylene oxideization, Sanyo company sells with title LEBON A-5000; (10EO) lauryl citric acid list disodium sulfosuccinate salt of ethylene oxideization, Witco company sells with title REWOPOL SB CS 50; Or castor oil acid single ethanol amide list sulfosuccinate, Witco company sells with title REWODERMS 1333.
As phosphate ester salt and alkyl phosphate salt, as mentioning alkylphosphonate and dialkyl phosphate salt, as the lauryl monophosphates, Kao Chemicals company sells with title MAP 20; The potassium salt of 1-isobutyl-3,5-dimethylhexylphosphoric acid, the mixture of monoesters and diester (being mainly diester), Cognis company sells with title CRAFOLAP-31; The mixture of octyl group phosphate monoester and diester, Cognis company sells with title CRAFOL AP-20; (7mol EO) the 2-butyl octyl phosphate monoester of ethoxylation and the mixture of diester, Condea company sells with title ISOFOL127 EO-PHOSPHATE ESTER; Single (C 12-C 13) potassium salt or the triethanolamine salt of alkyl phosphate, Uniqema company sells with title ARLATONE MAP 230K-40 and ARLATONE MAP 230T-60; Or the lauryl potassium phosphate, Rhodia Chimie company sells with title DERMALCARE MAP XC-99/09.
For example, the polypeptide that can obtain by aliphatic chain and cereals aminoacid especially Semen Tritici aestivi aminoacid and the amino acid whose condensation of Herba bromi japonici.As polypeptide, as mentioning the potassium salt of hydrolysis lauroyl wheat protein, Croda company sells with title AMINOFOAMWOR; The triethanolamine salt of hydrolysis cocoyl soybean protein, Maybrook company sells with title MAY-TEIN; The amino acid whose sodium salt of Herba bromi japonici lauroyl, Seppic company sells with title PROTEOLOAT; Be grafted to the collagen hydrolysate on the coconut fatty acid, DeutscheGelatine company sells with title GELIDERM 3000; Or with the soybean protein of hydrogenated coconut acylating acid, Seppic company sells with title PROTEOL VS 22.
Citrate, tartrate, sulfosuccinate, carbonic ester and glycerin ether that anion alkyl polyglucoside derivant can particularly be obtained by alkyl polyglucoside.As mentioning the sodium salt of cocoyl polyglucoside (1,4) tartrate, Cesalpinia company sells with title EUCAROLAGE-ET; The disodium salt of cocoyl polyglucoside (1,4) sulfosuccinate, Seppic company sells with title ESSAI 512 MP; The sodium salt of cocoyl polyglucoside (1,4) citrate, Cesalpinia company is with title EUCAROLAGE-EC Sell.Other anion polysaccharide derivant can be dodecyl-D-galactoside alduronic acid sodium, and Soliance company sells with title SODIUM DODECYL-D-GALACTOSIDE URONATE.
As both sexes and zwitterionic surfactant, as mentioning (C 8-C 20) alkyl betaine, N-(C 8-C 20) alkyl amido betanin and derivant thereof, glycine derivative, sulfobetaines, (C 8-C 20) alkyl polyaminocarboxylate, (C 8-C 20) alkyl both sexes acetate and composition thereof.
As betanin, as mentioning coco betaine, as Henkel company with title DEHYTON AB-30 product sold; Lauryl betaine, as Clariant company with title GENAGEN product sold; (10EO) lauryl betaine of ethylene oxideization, as Shin Nihon Rica company with title LAURYLETHER (10EO) BETAIN product sold; Or (10EO) stearyl betaine of ethylene oxideization, as Shin Nihon Rica company with title STEARYLETHER (10EO) BETAINE product sold.
In N-alkyl amido betanin and derivant thereof, as mentioning cocoamidopropyl, Sanyo company sells with title LEBON 2000 HG, or Albright ﹠amp; Wilson company sells with title EMPIGENBB; Or lauramido propyl betaine, Witco company sells with title REWOTERICAMB12P.
As sulfobetaines, can mention cocoyl acylamino-propyl hydroxy sulfobetaines, Croda company sells with title CROSULTAINEC-50.
As alkyl polyaminocarboxylate (APACs), can mention cocoyl polyaminocarboxylic acid sodium, Akzo Nobel company sells with title AMPHOLAK 7 CX/C and AMPHOLAK 7 CX; Stearyl polyamidoamines carboxylic acid sodium, Akzo Nobel company sells with title AMPHOLAK 7 TX/C; The carboxymethyl oil base gathers propylamine sodium, and Akzo Nobel company sells with title AMPHOLAK XO7/C.
As alkyl both sexes acetate, as mentioning N-disodium N-cocoyl-N-carboxymethoxyl ethyl-N-carboxymethyl ethylenediamine (CTFA title: cocoyl both sexes two acetic acid disodiums), as Rhodia Chimie company with title MIRANOL C2M CONCENTRE NP product sold; With N-sodium N-cocoyl-N-ethoxy-N-carboxymethyl ethylenediamine (CTFA title: cocoyl both sexes cerinic acid sodium).
Compositions also can comprise these surfactant mixtures.
The preferred both sexes of surfactant and/or zwitterionic surfactant, alkyl polyglucoside and have the anion surfactant of at least one carboxyl.
The character of various surfactants and concentration are selected so that compositions can not produce foam when being applied to hair.
Preferably, the surfactant concentrations scope is 0.01 to 2 weight % with respect to composition total weight, 0.05 to 1 weight % more preferably, even 0.075 to 0.5 weight % more preferably.
The reagent of solubilising fat-soluble compound is not surfactant.(the HLB=hydrophile-lipophile balance value is in the intended scope of Griffin less than 3 for the HLB value of these chemical compounds; Referring to J.Soc.Cosm.Chem.1954 (vol.5), pp249-256; Balance between hydrophilic and the lipophile).
The reagent of solubilising fat-soluble compound is preferably volatile.
For purpose of the present invention, term " volatility " refers to that under atmospheric pressure boiling point is lower than any chemical compound of 290 ℃.
Preferably have 8-16 the carbon atom and the hydro carbons of side chain preferably.More preferably C 10-C 14Isoparaffin.
Polyolefin is poly-alpha-olefin particularly, more especially:
-hydrogenation or unhydrided polybutene class, preferred hydrogenation or unhydrided polyisobutylene.
The preferred molecular weight that uses is less than 1000 isobutylene oligomer.
Example as the poly-alpha-olefin that uses within the scope of the present invention, can mention polyisobutylene more especially, Presperse Inc company sells with title PERMETHYL 99A, 101A, 102A, 104A (n=16) and 106A (n=38), or alternative ICI company is with title ARLAMOLHD (n=3) product sold (n refers to the degree of polymerization)
-hydrogenation or unhydrided poly decene class.
As this series products that Ethyl Corp. company sells with title ETHYLFLO, reach ICI company with title ARLAMOL PAO product sold.
Volatile siloxane is more special to be selected from boiling point at 60 ℃ to 260 ℃ siloxanes, even more special being selected from:
(i) have 3-7, the annular siloxane of preferred 4-5 silicon atom.For example octamethylcy-clotetrasiloxane, particularly Union Carbide with title " VPLATILE SILICONE 7207 " or Rhodia Chimie with " SILBIONE 70045 V2 " product sold; Or decamethylcyclopentaandoxane, Union Carbide sells with " SILBIONE 70045 V5 " with " VPLATILE SILICONE 7158 " or Rhodia Chimie, and composition thereof.
The straight chain volatile siloxane that (ii) has 2-9 silicon atom, and its viscosity in the time of 25 ℃ is less than or equal to 5 * 10 -6m 2/ s.For example, decamethyl tetrasiloxane, particularly Toray Sihcone company are with title " SH200 " product sold.Be published in Cosmetics and Toiletries, Vol.91, Jan.76,27-32-Todd ﹠amp; The paper of Byers " the volatile siloxane liquid (Volatile Silicone Fluidsfor Cosmetics) that is used for cosmetics " is also described the siloxanes that belongs to this type of.
The concentration range of the reagent of solubilising fat-soluble compound is preferably 0.1 to 3 weight % with respect to composition total weight, more preferably 0.5 to 1.5 weight %.
Compositions also can contain the conventional auxiliary agent that uses, for example organic solvent in this area, hydrophilic or lipophilic thickening agent and gellant, softening agent, antioxidant, opacifier, stabilizing agent, chelating agen, aromatic, screening agent, quintessence oil, dyestuff, pigment, vitamin, provitamin, dandruff removing agent, be used to clean the seborrhea activating agent of sebum too much on the hair, remove the antimicrobial that may have microorganism thereon from hair, anti-alopecia agent, promote the activating agent of natural on-off cycles of hair growth, hydrophilic or lipophilic activating agent, the optional lipid capsule that is encapsulated with one or more active agents, or cosmetics or normally used any other composition of dermatological field.Compositions also randomly contains antiseptic.The consumption of various compositions can be with reference to the conventional amount used of this area in the present composition.Certainly, the use amount of these auxiliary agents must not be disturbed the cleaning of the present invention to hair.For example, the amount ranges of these auxiliary agents is 0.01 to 30 weight % with respect to composition total weight.
Compositions also can contain the additive that is selected from antiseptic, pH regulator agent and aromatic.
The viscosity of cosmetic composition of the present invention is more preferably less than 1000mPas preferably less than 1500mPas.Use a kind of Rheomat RM180 device to measure viscosity in room temperature (about 25 ℃).
The pH of the present composition is generally 2 to 12, and preferred 3 to 8.
The present composition preferably contains the water with respect to composition weight 40 to 89 weight %, is more particularly 50 to 85 weight %, even more preferably 60 to 85 weight %, preferred 70 to 85 weight %.
Compositions of the present invention can be by the well-known technology preparation of those skilled in the art.
Can use tip, sprayer unit, the distribution comb of hands, applicator, said composition is used in the insoluble substrate that preferred use is impregnated with said composition.
The applicant finds to use insoluble substrate to use said composition to have useful especially effect.
Therefore, according to a preferred version of the present invention, compositions of the present invention also can be used to the insoluble substrate of steep water to constitute goods, especially for the towelette or the glove of cleaning hair.The water-insoluble substrate can contain single or multiple lift and can be selected from textile material, non-woven material, foamed materials, sponge or raw cotton, can be thin slice, sphere or thin film.Can be based on the non-woven substrate of natural origin (Caulis et Folium Lini, Pilus Caprae seu Ovis, Cotton Gossypii, silk) fiber or synthetic source (cellulose derivative, viscose, polythene derivative, polyester such as polyethylene terephthalate, polyolefin such as polyethylene or polypropylene, polyamide such as nylon, acrylic acid derivative) fiber especially." nonwoven adhesive bonding method and the material " of Ridel, the nonwoven world (Nonwoven World) (1987) have done general description to these non-woven materials.Can obtain these substrates by the common process method of preparation non-woven material.
When substrate is non-woven material, preferably use thick non-woven material, its do not curl balling-up and enough firmly be unlikely to cracked and be applied to not balling-up on the skin.At least on one side, it must have absorbability, softness, particularly can remove cosmetics from eye.Suitable non-woven material, as mentioning that BBA company is with title Ultraloft 15285-01, Ultraloft 182-008, these products that Ultraloft 182-010 and Ultraloft 182-016 sell, Freudenberg company is with title Vilmed M1519 Blau, these products that Vilmed M1550N and 112-132-3 sell, Jacob Holm Industries company is with title Norafin 11601-010B product sold, Tharreau company is with title Aquadim VE50 G1NL (non-woven fabrics) product sold, and Uni Flockage company is with the flocking non-woven material of title Univel 109 and Univel 119 sale.
And this substrate can contain one or more layers with identical or different character, and has elasticity and flexibility and other and be suitable for the character of expecting instructions for use.For example, described as WO-A-99/13861, substrate can contain and has different elastic two parts; Or described as WO-A-99/25318, substrate can contain the monolayer with different densities; Or described as WO-A-98/18441, substrate can contain the two-layer of differing texture.
This goods preferably constitute glove, but also can be other forms (for example, towelettes).
Therefore a theme of the present invention also is a kind of goods that contain water-insoluble substrate and above institute definitions section compound, and said composition is flooded described substrate.
A theme of the present invention also is the application that the preparation of above institute definitions section compound is used to clean the goods of hair.
According to another aspect of the present invention, prepare a kind of disposable cosmetic product, it contains the substrate of the above defined liquid makeup compositions dipping of at least a usefulness, described substrate is permeable and contains at least a first kind fiber and at least a second fibrid, the hydrophilic of second fibrid is different from the hydrophilic of first kind fiber, arrange the described first kind fiber and second fibrid so that the first surface of substrate demonstrates than substrate second surface, the reverse side of first surface just, bigger hydrophilic, described first surface is that the outer surface of substrate makes it can contact processed surface, particularly hair.
For a kind of like this goods, the gain of cosmetic treatment effect can obtain significant raising by allowing more the compositions of these goods of dipping of volume to be discharged into treatment surface.
Term " permeable " refers to that described make-up composition can see through the whole thickness of substrate.Therefore, unlike some goods of the above prior art of quoting, goods of the present invention do not contain the impermeable barrier that may constitute barrier when useful described compositions is flooded to said composition.
Certainly, substrate is water-insoluble, and just at least in the whole useful life of product, its integrity is not flooded the influence that the aqueous cosmetics composition of this substrate exists substantially.
Advantageously, substrate is a single layer substrates." single layer substrates " refers to that all fibres of forming this substrate is interconnected to term in same connection procedure.At last, in the thickness of this substrate, it is uneven that two types fiber distributes, and according to a side, it is characterized by:
The major part of-first kind fiber is on the first surface of substrate;
The major part of-the second fibrid is on the second surface of substrate and between two surfaces;
The relative quantity of-first kind fiber increases progressively curvilinear motion relatively according to one, and this slope of a curve has and the relative opposite symbol of slope of a curve that increases progressively corresponding to the second fibrid relative quantity.
Such structure is different from and wherein forms different layers and independent bookbinding respectively, then by heat bonding, and thermal weld or ultrasonic its mutual adherent multiple structure that makes.
Advantageously, the first surface of substrate has a kind of release index (RISP1) under static pressure, and the substrate second surface has a kind of release index (RISP2) under static pressure, and the ratio of RISP1/RISP2 is more than or equal to 1.5.
Discharge index (RISP) under the static pressure:
The test that describes below can be used for measuring the release index (RISP) of two surfaces under static pressure with the goods of above defined cosmetic product dipping.RISP has determined to be immersed in the amount of liquid in the carrier, and this liquid two surfaces from carrier under the effect of static pressure discharge, and therefore discharge index and shown whether two surfaces there are differences on discharging.
Because consumer's common posture that adopts during using these goods is to use first surface wiping his or his the skin or the hair of these goods, another surface of described goods contacts with palmistry, so wish to measure the amount of liquid that is discharged simultaneously by two surfaces of this carrier.
For this reason, (Kimberley-Clark sells with trade name Wypall L30 (with reference to 7303), and basic weight is 50g/m with two napkin type absorbing materials 2) accurately be weighed into one of percentage gram with Mettler Toledo PR5002 balance.The thin slice of absorbing material at least should be the same with tested goods big, and is preferred bigger so that cover at least two centimetres of the outward flanges of carrier.
First is placed on the glass plate, and its size is the same big with those tested goods at least.Tested goods are placed on first Wypall L30.Second Wypall L30 is placed on the top.
A surface area amasss the metallic plate of 3.7kg that equate, heavy at least with tested product surface, be placed on this molectron.After one minute, remove metallic plate, each sheet Wypall L30 is weighed.
Mass discrepancy calculating according to Wypall L30 before and after the test impregnated in every liquid weight among the Wypall L30.This liquid weight is equivalent to two surperficial amount of liquid that discharge from carrier, is designated as respectively to represent the RISP1 and the representative that have than super hydrophilic surface to have the RISP2 that hangs down hydrophilic surface.
The ratio of RISP1 and RSP2 has shown the difference of two surfaces on discharging of towelette.
Gained RISP1/RSP2 ratio is the meansigma methods of measuring four goods.
Favourable, the RISP1/RSP2 ratio range is 1.5 to 15, and is preferred 2.5 to 10, more preferably 2.5 to 7.
Significantly, when these goods be hollow and when especially being designed to the form of glove, two that form these goods is isolating, therefore on separated, test.
Substrate:
The preferred water jet adhesive method of the conventional preparation non-woven material that uses that adopts prepares substrate.
The first step is the fibroreticulate production with different hydrophilic.These fleeces can be by prepared in various methods well known by persons skilled in the art, can be by carrying out combing with fibrous nodules, or become successive filametntary form by extruded polymer, or by the preparation of air-flow method.
The most hydrophilic fleece and least hydrophilic fleece are placed on the conveyer belt and below the multiple row High-Pressure Water and are transmitted, and High-Pressure Water bonds together fiber.Therefore these High-Pressure Waters make three directions of fiber in the fibre structure scope rearrange, and cause the overlapping of fiber, do not use any chemical adhesive and they are combined.Usually, fleece is by the multiple row current, and the pressure of these current generally raises gradually from first row to last string.This technology is called as the waterpower bonding.
In addition, substrate can be embossed, with drawn lace decoration, calendering or direct printing, or stand that any line is terminal to be handled.Thereby, favourable, be a surface of described carrier particularly by hot calendering, especially least hydrophilic surface provides fissility.
Should be noted that though formed two fleeces according to this special process, final substrate only contains one deck.The observed stratified risk of department has been eliminated in the multiple structure for preparing in above list of references.
The most hydrophilic fiber can be selected from Cotton Gossypii, cellulose or viscose fiber.
Least hydrophilic fiber is optional from polypropylene, polyester, polyamide or polyethylene fibre.
According to another aspect of the present invention, prepare a kind of disposable cosmetic product, it contains at least a substrate with liquid makeup compositions dipping, described substrate is permeable and contains at least a first kind fiber and at least a second fibrid, the hydrophilic of second fibrid is different from first kind fiber, arrange the described first kind fiber and second fibrid so that the first surface of substrate, the outer surface of second surface just, demonstrate second surface than substrate, first reverse side just, bigger hydrophilic, described goods contain at least one hollow or female, and described hollow or female are used for:
I) hold processed surface so that the inner surface of described surface and these goods contacts;
Ii) or hold all or part of of hands, so that the outer surface of these goods and processed surface engage.
The such hollow or the goods of depression can be designed to glove, mitten, sliding sleeve (slipper), the form of fingerstall, overseas cap, helmet or head-shield.
Can by will be at least " two " assemble up along edge separately or the folding edge that will fold substrate then of a slice fixedly obtained such hollow product.
When hollow or female were used to hold all or part of of hands, for outer surface and the processed surface that makes these goods engages, the outer surface of hollow or female was the most hydrophilic surface.
Advantageously, with this substrate with described cosmetic composition dipping to containing 100% to 1000% with respect to the weight of not flooding substrate, preferred 150% to 800%, the more preferably degree of 150% to 400% weight combinations thing.
The specific embodiment
Following embodiment makes can more detailedly understand the present invention, but in fact to the present invention without any restriction.If do not mention especially, shown in amount for weight %.
In the following examples that provide as non-limitative illustration, provided according to concrete compositions of the present invention (AM refers to active material).
Embodiment 1: the hair cleaning glove:
Below described Cleasing compositions be impregnated on the Sandler non-woven material ref.03/02/1001 with 200% amount.
Composition quality %
Water is in right amount to 100%
Ethanol 16%AM
The two acetic acid disodiums of cocoyl both sexes
(MIRANOL C2M CONC derives from RHODIA CHIMIE) 0.2%AM
C 11-C 12(ISOPARH derives from EXXONMOBIL to isoparaffin
CHEMICAL) 1％
Aromatic, antiseptic are an amount of
An amount of pH7 of pH agent
Sandler non-woven material ref.03/02/1001 obtains by the waterpower Method for bonding, by at one lip-deep 100% viscose fiber and fibrous at another polypropylene of lip-deep 100% (PP).It cuts into the shape of mitten or glove, at inner edgewise edge welding polypropylene fibre face to define the insertable pocket of hands.
On the hair that other day cleans, massage head half with the glove that contain the present composition.About 30 seconds of massage hair makes hair become dry then in the open.
Hair become in after, the hair on the left side (the present invention) is cleaner more elegant than the untreated hair in the right.The hair on the left side (the present invention) has had more pleasant sensation before handling.
Hair feels more suitable cunning, brighter, submissiveer.It is more plentiful and be easier to molding.
Embodiment 2: the hair cleaning glove:
Below described Cleasing compositions be impregnated on the Sandler non-woven material ref.03/02/1001 with 200% amount.
Composition quality %
Water is in right amount to 100%
Denatured ethyl alcohol (93.1%AM is in water) 20%
The two acetic acid disodiums of cocoyl both sexes
(MIRANOL C2M CONC derives from RHODIA CHIMIE) 0.2%AM
Parleam 5%
Aromatic is an amount of
An amount of pH7 of pH agent
Sandler non-woven material ref.03/02/1001 obtains by the waterpower Method for bonding, by at one lip-deep 100% viscose fiber and fibrous at another polypropylene of lip-deep 100% (PP).It cuts into the shape of mitten or glove, at inner edgewise edge welding polypropylene fibre face to define the insertable pocket of hands.
Embodiment 3: the hair cleaning glove:
Below described Cleasing compositions be impregnated on the Sandler non-woven material ref.03/02/1001 with 200% amount.
Composition quality %
Water is in right amount to 100%
Ethanol 16%
The lauryl ether carboxylic acid that contains 4.5mol oxirane
(KAO RLM 45 derives from Kao) 0.4%AM
C 11-C 12(ISOPAR H derives from isoparaffin
EXXON?MOBIL?CHEMICAL) 1％
Aromatic, antiseptic are an amount of
An amount of pH7 of pH agent
Hair feels more suitable cunning, brighter, submissiveer.It is more plentiful and be easier to molding.

Claims (16)

1, cosmetic hair composition, contain in the acceptable aqueous medium of a kind of cosmetics:
-with respect at least a C of 10 to 90 weight % of composition total weight 2-C 4Monohydric alcohol;
-with respect at least a surfactant of 0.01 to 5 weight % of composition total weight, be selected from anion surfactant, both sexes and/or zwitterionic surfactant and non-ionic surface active agent;
-with respect to the reagent of a kind of solubilising fat-soluble compound of 0.01 to 5 weight % of composition total weight, this reagent is selected from straight or branched hydrocarbon, hydrogenation or unhydrided polyolefin, volatile siloxane and composition thereof;
-with respect to the water of 1 to 89.98 weight % of composition total weight.
2, according to the compositions of claim 1, it is characterized in that C 2-C 4Monohydric alcohol is selected from ethanol, isopropyl alcohol and the tert-butyl alcohol.
3,, it is characterized in that the concentration range of monohydric alcohol is 10 to 50 weight % with respect to composition total weight, more preferably 10 to 25 weight % according to the compositions of above-mentioned any claim.
4,, it is characterized in that surfactant is selected from both sexes and/or zwitterionic surfactant, alkyl polyglucoside and has the anion surfactant of at least one carboxylate groups according to the compositions of above-mentioned any claim.
5,, it is characterized in that both sexes and/or zwitterionic surfactant are selected from alkyl both sexes acetate according to the compositions of above-mentioned any claim.
6,, it is characterized in that anion surfactant is selected from (C according to the compositions of above-mentioned any claim 8-C 20) alkyl amido ether carboxylic acid and (C 8-C 20) alkyl ether carboxylic acid and salt thereof.
7,, it is characterized in that the surfactant concentrations scope for respect to 0.01 to 2 weight % of composition total weight, 0.05 to 1 weight % more preferably, even 0.1 to 0.5 weight % more preferably according to the compositions of above-mentioned any claim.
8,, it is characterized in that the concentration range of solubilising reagent is 0.1 to 3 weight % with respect to composition total weight, more preferably 0.5 to 1.5 weight % according to the compositions of above-mentioned any claim.
9, each compositions of claim 1-8 is used to prepare the purposes of cleaning head hair products.
10, disposable use cosmetic product contains at least a substrate with any defined liquid makeup compositions dipping among the claim 1-8.
11, disposable use cosmetic product, contain at least a substrate with any defined liquid makeup compositions dipping among the claim 1-8, described substrate is permeable and contains at least a first kind fiber and at least a second fibrid, the hydrophilic of second fibrid is different from the hydrophilic of first kind fiber, arrange the described first kind fiber and second fibrid so that the first surface of substrate demonstrates than substrate second surface, the reverse side of first surface just, bigger hydrophilic, described first surface is that the outer surface of substrate makes it can contact processed surface, particularly hair.
12,, it is characterized in that described substrate is a single layer substrates according to the cosmetic product of claim 11.
13, according to each cosmetic product of claim 10-12, it is characterized in that reaching with respect to the weight of not flooding substrate and contain 100% to 1000% with the substrate of described cosmetic composition dipping, preferred 150% to 800%, the more preferably degree of 150% to 400% compositions.
14, each make-up composition of claim 1-8 is used to clean the purposes of hair.
15, the method for cleaning hair is characterized in that each compositions of claim 1-8 is applied to dried hair.
16, the method for cleaning hair is characterized in that each goods of claim 10-13 are applied to dried hair.
CNB2005100641425A 2004-03-08 2005-03-07 Aqueous composition based on alcohol, surfactant and solubilizing agent, article impregnated with this composition, and method for cleansing the hair Expired - Fee Related CN100342843C (en)

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FR0450465A FR2867066B1 (en) 2004-03-08 2004-03-08 AQUEOUS COMPOSITION BASED ON ALCOHOL, SURFACTANT AND SOLUBILIZING AGENT, ARTICLE IMPREGNATED WITH SAID COMPOSITION AND METHOD FOR CLEANING THE HAIR

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CN103416943A (en) * 2012-05-18 2013-12-04 林炳松 Method and tool for rapidly cleaning hair
CN103476388A (en) * 2011-04-15 2013-12-25 莱雅公司 Composition comprising a nonionic surfactant, a polycondensate of ethylene oxide and of propylene oxide and a monoalcohol

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CN103857375B (en) * 2011-08-19 2016-03-16 荷兰联合利华有限公司 Hair cleaning cover box

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CN103476388A (en) * 2011-04-15 2013-12-25 莱雅公司 Composition comprising a nonionic surfactant, a polycondensate of ethylene oxide and of propylene oxide and a monoalcohol
CN103416943A (en) * 2012-05-18 2013-12-04 林炳松 Method and tool for rapidly cleaning hair

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