CN1664152A - High-strength anti-corrosion steel plate for rail vehicle and its making method - Google Patents
High-strength anti-corrosion steel plate for rail vehicle and its making method Download PDFInfo
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- CN1664152A CN1664152A CN 200510012431 CN200510012431A CN1664152A CN 1664152 A CN1664152 A CN 1664152A CN 200510012431 CN200510012431 CN 200510012431 CN 200510012431 A CN200510012431 A CN 200510012431A CN 1664152 A CN1664152 A CN 1664152A
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Abstract
The invention relates to a high-strength corrosion-resistance steel plate used in railway car and preparation. The component of steel plate comprises 8.00-12.0wt% of Cr, 0.2-0.5 wt% of Ni, C<=0.10wt%, Si<=2.00wt%, Mn<=2.00wt%, P<=0.040wt%, S<=0.030wt% and iron. The invention comprises the following steps: casting billet with chemical composition of C<=0.10wt%, Si<=2.00wt%, Mn<=2.00wt%, P<=0.040wt%, S<=0.030wt%, Cr 8.00-12.0wt%, Ni 0.2-0.5wt% and iron; heating to 1200+/-30 degrees for keeping for 200 minutes; heating to 820+/-30 degrees and rolling to steel sheet; cooling to 650+/-30 degrees and coiling the steel sheet; metallic band keeping 700+/-10 degrees for 6-12h to anneal and after annealing process cooling by radiation. Annual erosion of the plate is less then 0.05 millimeters even without japanning process and the plate has good manufacturability.
Description
Technical field
The present invention relates to a kind of rail vehicle anti-corrosion steel plate and preparation method thereof.
Background technology
Because the circumstance complication of rail vehicle operation usually moves in the environment of awful weather, so the intensity and the erosion resistance of rail vehicle had higher requirement.The steel plate that existing rail vehicle is used is a weathering steel, the main trade mark has 09CuPCrNi, 09CuPTiRE, though weathering steel has higher erosion resistance, but handling the average annual etching extent in back in japanning still is 0.10 millimeter, in vicennial life cycle, must thicken 2 millimeters to the steel plate that rail vehicle is used as corrosion allowance like this, the steel of making rail vehicle have so not only been increased, and increased the own wt of rail vehicle, and reduce loading capacity, reduce travelling speed.
Summary of the invention
In order to overcome the above-mentioned deficiency of the weather-resistant steel plate that existing rail vehicle uses, the invention provides a kind of anti-corrosion steel plate and preparation method thereof, the rail vehicle that adopts steel plate of the present invention to make, under painted situation not, a year etching extent is reduced in 0.05 millimeter.
Technical scheme of the present invention is the content that increases chromium in the steel, improves the erosion resistance of steel; Reduce the content of carbon, nitrogen, improve the welding property of steel; Add an amount of nickel, improve the low-temperature flexibility of steel, add corresponding art breading again, thereby become erosion resistance, processibility, toughness, the good rail vehicle steel plate special of weldability.
The steel plate that rail vehicle of the present invention is used has following characteristics.
(1) Chemical Composition (weight percentage) of the steel plate used of rail vehicle of the present invention is:
| ??C | ??Si | Mn | ??P | ??S | ???Cr | ???Ni | Fe and unavoidable impurities |
| ??≤0.10 | ??≤2.00 | ≤2.00 | ??≤0.040 | ??≤0.030 | ???8.00～13.00 | ???0.2～3.0 | All the other |
According to performance requriements, can add content≤0.5% trace alloying element Nb, Ti.The mechanical property and the weldability that add Nb raising steel plate add Ti and improve the steel plate low-temperature impact.
(2) through Overheating Treatment, form ferrite, and a spot of low carbon martensite is arranged, form the duplex structure of ferrite+low carbon martensite.
Rail vehicle steel plate of the present invention contains a certain amount of nickel, different with other single-phase ferritic steel, it is austenite that high-temperature lower part is divided ferritic transformation, difference according to speed of cooling, this austenite can change the very thin ferrite of crystal grain in cooling, also can form needle type martensite, this needle type martensite is different from the martensite that forms under the normal condition, referring to Fig. 1, grain fineness number is 8 grades among the figure, is organized as ferrite, and lower carbon content is arranged in the dislocation atomic lattice, not to be in higher stressed condition, therefore have plasticity and toughness preferably.Contain 8.00～13.00% chromium, can self generate the chromic oxide protective membrane, even the chromic oxide protective membrane is damaged; as long as there is oxidation to exist on every side; this steel one deck chromic oxide protective membrane of just regenerating, the protection matrix is not corroded, and the erosion resistance of steel is unaffected.Because the content of carbon, nitrogen is lower, this steel is essentially ferritic structure under user mode, has avoided a large amount of nitride and carbide at grain boundary precipitate, has obviously improved the welding property of steel, and throat thickness can reach 30 millimeters.
The preparation method
A smelts steel billet
Adopt molten iron to become steel billet through VOD refining steel stove smelting continuous casting with Cr, Ni alloy and steel scrap at last through AOD or K-OBM-S converter, the composition of steel billet (weight percentage) is:
| C | ?Si | ?Mn | ?P | ?S | ???Cr | ???Ni | Fe and unavoidable impurities |
| ≤0.10 | ?≤2.00 | ?≤2.00 | ?≤0.040 | ?≤0.030 | ???8.00～13.00 | ???0.2～3.0 | All the other |
The B heating
In sealed heating furnace, steel billet is heated to 1200 ± 30 ℃, be incubated 200 minutes;
The C rolled sheet material
Adopt the technology of control finishing temperature, when being cooled to 820 ± 30 ℃, on hot-rolling finishing mill, be rolled into thick 3～8 millimeters, wide 1000～1300 millimeters steel plate.
D batches
The laminar flow cooling when steel plate is cooled to 650 ± 30 ℃, is rolled into steel plate the coil of strip of 1500～2000 millimeters of internal diameter 762 mm outer diameter after the hot rolling;
E thermal treatment
Is temperature that 650 ± 30 ℃ coil of strip is packed in the bell furnace of coal gas heating, at 700 ± 10 ℃, is incubated annealing in 6-12 hour, hangs away outer cover after the annealing, naturally cooling in air.
Steel plate after Overheating Treatment forms needle type martensite, and lower carbon content is arranged in the dislocation atomic lattice, has improved the plasticity and the toughness of steel plate, has obviously improved the welding property of steel.
The rail vehicle that adopts steel plate of the present invention to make, under painted situation not, a year etching extent is reduced in 0.05 millimeter.
Middle chromium content in the corrosion steel plate that rail vehicle of the present invention is used is higher, can self generate the chromic oxide protective membrane, improves the erosion resistance of steel, and under painted situation not, a year etching extent is reduced in 0.05 millimeter; Reduce the content of carbon, nitrogen, improve the welding property of steel; The low-temperature flexibility that adds an amount of nickel raising steel, and through anneal formation needle type martensite, lower carbon content is arranged in the dislocation atomic lattice, not to be in higher stressed condition, avoided a large amount of nitride and carbide at grain boundary precipitate, therefore have plasticity and toughness preferably, obviously improved the welding property of steel.
Description of drawings
Fig. 1 is the metallographic structure figure of the corrosion steel plate used of rail vehicle of the present invention.
Embodiment
The embodiment of corrosion steel plate that rail vehicle of the present invention is used and preparation method thereof is provided by following embodiment, but corrosion steel plate that rail vehicle of the present invention is used and preparation method thereof is not limited to following embodiment.
Steel plate embodiment one
The thickness of the steel plate that the rail vehicle of present embodiment is used is 4 millimeters, and is wide 1000 millimeters, and its chemical ingredients (weight percentage) is:
C?0.02％????Si?0.5％????Mn?1.0％????Cr?12.0％
Ni?0.5％????P≤0.040％??S≤0.030％
All the other are the component of unavoidable impurities and Fe.
During rolling postcooling to 650 ℃, in 700 ± 10 ℃ of insulations annealing in 8 hours, annealing back naturally cooling in air, the cooling back forms the ferrite steel plate with low carbon martensite, this steel plate is ferrite substantially, and its metallographic structure is the duplex structure of ferrite+low carbon martensite.
Steel plate embodiment two
The thickness of the steel plate that the rail vehicle of present embodiment is used is 5 millimeters, and is wide 1250 millimeters, and its chemical ingredients (weight percentage) is:
C?0.025％??Si?1.0％??Mn?1.3％????Cr?11.3％
Ni?0.3％???Nb?0.20???P≤0.040％??S≤0.030
All the other are the component of unavoidable impurities and Fe.
During rolling postcooling to 650 ℃, in 700 ± 10 ℃ of insulations annealing in 10 hours, annealing back naturally cooling in air, the cooling back forms the ferrite steel plate with needle type martensite, this steel plate is ferrite substantially, and its metallographic structure is the duplex structure of ferrite+low carbon martensite.
Steel plate embodiment three
The thickness of the steel plate that the rail vehicle of present embodiment is used is 6 millimeters, and is wide 1200 millimeters, and its chemical ingredients (weight percentage) is:
C?0.08％????Si?1.0％????Mn?1.0％??????Cr?10％
Ni?2.5％????Ti?0.40％???P≤0.040％????S≤0.030％
All the other are the component of unavoidable impurities and Fe.
During rolling postcooling to 650 ℃, in 700 ± 10 ℃ of insulations annealing in 6 hours, annealing back naturally cooling in air, the cooling back forms the ferrite steel plate with low carbon martensite, this steel plate is ferrite substantially, and its metallographic structure is the duplex structure of ferrite+low carbon martensite.
Preparation method embodiment one
That prepare is steel plate embodiment one
A smelts steel billet
Smelt continuous casting with three-steps process and become steel billet in converter, VOD refining furnace, the chemical ingredients of steel billet (weight percentage) is:
C?0.02％????Si?0.5％??????Mn?1.0％????Cr?12.0％
Ni?0.5％????P≤0.040％????S≤0.030％
All the other are the component of unavoidable impurities and Fe.
The B heating
In walking beam furnace, steel billet is heated to 1200 ℃, is incubated 200 minutes;
The C rolled sheet material adopts the technology of control finishing temperature, when being cooled to 820 ± 30 ℃, is being rolled into thick 3 millimeters, wide 1000 millimeters steel plate through hot-rolling finishing mill.
D batches
The cooling of employing laminar flow when steel plate is cooled to 650 ± 30 ℃, is rolled into coil of strip to steel plate;
E thermal treatment
Is temperature that 650 ± 30 ℃ coil of strip is packed in the bell furnace of coal gas heating, at 700 ± 10 ℃, is incubated annealing in 10 hours, hangs away outer cover after the annealing, naturally cooling in air.
Preparation method embodiment two
That prepare is steel plate embodiment two
A smelts steel billet
Smelt continuous casting with three-steps process and become steel billet in converter, VOD refining furnace, the chemical ingredients of steel billet (weight percentage) is:
C?0.025％???Si?1.0％???Mn?1.3％????Cr?11.3％
Ni?0.3％????Nb?0.20????P≤0.040％??S≤0.030
All the other are the component of unavoidable impurities and Fe.
Other step is identical with method and preparation method embodiment's one.
Preparation method embodiment three
That prepare is steel plate embodiment three
A smelts steel billet
Smelt continuous casting through converter, VOD refining furnace technology and become steel billet, the chemical ingredients of steel billet (weight percentage) is:
C?0.08％????Si?1.0％?????Mn?1.0％??????Cr?10％
Ni?2.5％????Ti?0.40％????P≤0.040％????S≤0.030％
All the other are the component of unavoidable impurities and Fe.
Other step is identical with method and preparation method embodiment's one.
Below with three embodiment of anti-corrosion steel plate of the present invention, compare with mechanical property, low-temperature flexibility and the erosion resistance of weathering steel.See Table 1 with mechanical property, the low-temperature flexibility contrast of weathering steel
Table 1
| Steel grade | Specification (millimeter) | Yield strength R P0.2(Mpa) | Tensile strength Rm (Mp) | Unit elongation A% | Impact Ak (40 ℃, V-type) J | Surface hardness HB |
| ?09CuPCrNi | ????6 | ?380 | ??485 | ??29.5 | ??18，19，22 | ?156 |
| ????6 | ?365 | ??505 | ??29.5 | ??31，18，18 | ?156 | |
| ?09CuPTiRE | ????12 | ?370 | ??475 | ??32.5 | ??57，60，48 | ?146 |
| ????12 | ?365 | ??475 | ??32.5 | ??119，57，84 | ?146 | |
| Steel plate embodiment one | ????4 | ?350 | ??495 | ??26 | ??31，30，32 | ?175 |
| ????4 | ?340 | ??485 | ??26.5 | ??32，31，29 | ?170 | |
| Steel plate embodiment two | ????5 | ?415 | ??575 | ??23.5 | ??47，44，43 | ?189 |
| ????5 | ?405 | ??550 | ??21.5 | ??32，43，38 | ?184 | |
| Steel plate embodiment three | ????6 | ?425 | ??580 | ??23 | ??31，34，37 | ?188 |
| ????6 | ?435 | ??595 | ??21.5 | ??41，38，39 | ?190 |
See Table 2 with the corrosion resistance nature contrast of weathering steel, adopt salt spray corrosion test, NaCl solution, concentration 50g/l, spraying continuously in 24 hours, 35 ℃ of temperature according to GB10125-88.Table 2
| Steel grade | Average weightless g | Corrosion rate % |
| ??09CuPCrNi | ????0.07322 | ????2.224 |
| ??09CuPTiRE | ????0.04713 | ????1.958 |
| Steel plate embodiment one | ????0.03465 | ????0.282 |
| Steel plate embodiment two | ????0.04265 | ????0.295 |
| Steel plate embodiment three | ????0.03894 | ????0.271 |
Find out by table 1, the rail vehicle of the present invention mechanical property ratio weathering steel height of anti-corrosion steel plate, table 2 as a result by corrosion test is found out, rail vehicle of the present invention only is 0.14 of a weathering steel with the corrosion rate of anti-corrosion steel plate, obviously than the erosion resistance height of existing rail vehicle with the anti-corrosion steel plate weathering steel.
Claims (4)
1, the high-strength anti-corrosion steel plate used of a kind of rail vehicle is characterized in that:
(1) Chemical Composition (weight percentage) is:
C≤0.10％????Si≤2.00％????Mn≤2.00％???P≤0.040％???S≤0.030％
Cr?8.00～12.0％????Ni?0.2～0.3％
All the other are the component of unavoidable impurities and Fe;
(2) be placed in the bell furnace, at 700 ± 10 ℃, be incubated annealing in 6-12 hour, annealing back naturally cooling in air forms the ferrite steel plate with low carbon martensite, and the metallographic structure of this steel plate is the duplex structure of ferrite+low carbon martensite.
2, rail vehicle anti-corrosion steel plate according to claim 1 is characterized in that: also add (weight percentage) content≤0.5% trace alloying element Nb or Ti in the steel plate.
3, the preparation method of the high-strength anti-corrosion steel plate used of a kind of rail vehicle, its preparation process is as follows successively:
A smelts steel billet
Adopt molten iron to become steel billet through VOD refining steel stove smelting continuous casting with Cr, Ni alloy and steel scrap at last through AOD or K-OBM-S converter, the composition of steel billet (weight percentage) is:
C≤0.10％????Si≤2.00％????Mn≤2.00％????P≤0.040％????S≤0.030％
Cr?8.00～12.0％????Ni?0.2～0.5％
All the other are the component of unavoidable impurities and Fe;
The B heating
In sealed heating furnace, steel billet is heated to 1200 ± 30 ℃, be incubated 200 minutes;
The C rolled sheet material
Adopt the technology of control finishing temperature, when being cooled to 820 ± 30 ℃, on hot-rolling finishing mill, be rolled into thick 3～8 millimeters steel plate;
D batches
The laminar flow cooling when steel plate is cooled to 650 ± 30 ℃, is rolled into coil of strip to steel plate after the hot rolling;
E thermal treatment
Is temperature that 650 ± 30 ℃ coil of strip is packed in the bell furnace of coal gas heating, at 700 ± 10 ℃, is incubated annealing in 6-12 hour, hangs away outer cover after the annealing, naturally cooling in air.
4, rail vehicle according to claim 3 is characterized in that: also add (weight percentage) content≤0.5% trace alloying element Nb or Ti in steel billet with the preparation method of anti-corrosion steel plate.
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| CNB2005100124310A CN100374608C (en) | 2005-03-29 | 2005-03-29 | High-strength anti-corrosion steel plate for rail vehicle and its making method |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538684B (en) * | 2008-09-23 | 2011-06-01 | 山西太钢不锈钢股份有限公司 | Stainless steel tube for brake system of rail vehicle and method for producing same |
| CN102954906A (en) * | 2011-08-19 | 2013-03-06 | 鞍钢股份有限公司 | Method for removing nickel steel hot acid etching oxides |
| CN103343295A (en) * | 2013-05-21 | 2013-10-09 | 马钢(集团)控股有限公司 | Sheet steel with high strength, high corrosion resistance and yield strength of 700 Mpa and production method thereof |
| CN107131371A (en) * | 2017-06-16 | 2017-09-05 | 广东工业大学 | A kind of swivel joint |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4301754C2 (en) * | 1993-01-23 | 1994-10-20 | Rexnord Kette Gmbh & Co Kg | Process for producing hot rolled steel strip with set strength |
| US6238493B1 (en) * | 1999-02-05 | 2001-05-29 | Bethlehem Steel Corporation | Method of making a weathering grade plate and product thereform |
| IT1317649B1 (en) * | 2000-05-19 | 2003-07-15 | Dalmine Spa | MARTENSITIC STAINLESS STEEL AND PIPES WITHOUT WELDING WITH IT PRODUCTS |
| JP4283425B2 (en) * | 2000-07-13 | 2009-06-24 | 新日鐵住金ステンレス株式会社 | Method for producing ferritic stainless steel sheet with excellent high temperature strength and magnetic properties |
| US6783610B2 (en) * | 2001-03-05 | 2004-08-31 | Amsted Industries Incorporated | Railway wheel alloy |
| JP4192576B2 (en) * | 2001-12-26 | 2008-12-10 | Ｊｆｅスチール株式会社 | Martensitic stainless steel sheet |
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2005
- 2005-03-29 CN CNB2005100124310A patent/CN100374608C/en active Active
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101538684B (en) * | 2008-09-23 | 2011-06-01 | 山西太钢不锈钢股份有限公司 | Stainless steel tube for brake system of rail vehicle and method for producing same |
| CN102954906A (en) * | 2011-08-19 | 2013-03-06 | 鞍钢股份有限公司 | Method for removing nickel steel hot acid etching oxides |
| CN102954906B (en) * | 2011-08-19 | 2015-05-06 | 鞍钢股份有限公司 | Method for removing nickel steel hot acid etching oxides |
| CN103343295A (en) * | 2013-05-21 | 2013-10-09 | 马钢(集团)控股有限公司 | Sheet steel with high strength, high corrosion resistance and yield strength of 700 Mpa and production method thereof |
| CN103343295B (en) * | 2013-05-21 | 2016-08-10 | 马钢(集团)控股有限公司 | The high intensity high-corrosion resistance steel board of a kind of yield strength 700MPa and production method thereof |
| CN107131371A (en) * | 2017-06-16 | 2017-09-05 | 广东工业大学 | A kind of swivel joint |
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| CN100374608C (en) | 2008-03-12 |
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Owner name: SHANXI TAIGANG STAINLESS STEEL CO., LTD. Free format text: FORMER OWNER: TAIYUAN IRON AND STEEL (GROUP) CO LTD Effective date: 20070706 |
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Effective date of registration: 20070706 Address after: 030003 No. 2, sharp lawn, Taiyuan City, Shanxi Province Applicant after: Shanxi Taigang Stainless Steel Co., Ltd. Address before: 030003 No. 2, sharp lawn, Taiyuan City, Shanxi Province Applicant before: Taiyuan Iron & Steel (Group) Co., Ltd. |
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