CN1645524A - Preparation and products of high temperature resistant and corrosionproof electric cables with polyfluorinated ethylene isolation - Google Patents

Preparation and products of high temperature resistant and corrosionproof electric cables with polyfluorinated ethylene isolation Download PDF

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Publication number
CN1645524A
CN1645524A CN 200510007212 CN200510007212A CN1645524A CN 1645524 A CN1645524 A CN 1645524A CN 200510007212 CN200510007212 CN 200510007212 CN 200510007212 A CN200510007212 A CN 200510007212A CN 1645524 A CN1645524 A CN 1645524A
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Prior art keywords
perfluoroethylene
insulation
propylene
control cable
temperature resistant
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CN 200510007212
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CN100366643C (en
Inventor
郑保祯
郑玉顺
李继涛
周玉宝
孙章栓
郑俊忠
杨俊娟
于恩楼
王桂芝
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HEBEI NEW BAOFENG WIRE & CABLE Co.,Ltd.
Hejian City Real Estate Development Co.,Ltd. Tianbao lear
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HEJIAN TIANBAOLIER CABLE CO Ltd
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Abstract

The method includes following steps: drawing wire; annealing; extruding insulation; over sparkling; cabling; lapping; extruding outside protection. The length-to-diameter of extruder used in extruded insulation step is 25-30. The temperature of extrude is 300-400deg.C and tubular type extruded die is adopted. The draw ration is 30-100 and the screw revolution speed is 20-70 turns /min.

Description

Preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable and products thereof
One, invention field
The present invention relates to preparation method of a kind of control cable and products thereof, preparation method of the high-temperature resistant anti-corrosive control cable that more particularly insulate and products thereof about a kind of perfluoroethylene-propylene.
Two, background technology
Along with the high speed development of China's industry, the electric automatization degree is in the popularization and application of every profession and trade, and in continuous increase, some special factories and miness and industry also need to use a large amount of control cable to the plastic insulation control cable at the industrial scope of application and consumption.But the plastic insulation control cable of GB9330 defined also is not suitable for these special industries and some special environment occasions.
There is following problem in actual use in the general control cable:
1, the overload capacity and the short circuit thermal capacity of general control cable (as the cable of models such as KVV, KYJV) are little, and the long-term work temperature is 70 ℃ or 90 ℃, can not bear higher ambient temperature; Polyvinyl chloride insulation is heated and can shrinks simultaneously, and thermal circulation performance is poor, influences the fail safe of circuit working.
2, the general control cable laying is when having the place of greasy dirt, steam, because the existence of oil and chemical substance, its insulating barrier can swelling, so that aging, be full of cracks, loses mechanical and physical performance and causes scrapping of electric wire.
3, general control cable insulation mechanical strength is relatively low, easily by gouge, damage and cause the energising accident.
4, when the general control cable has moisture content to immerse, the insulating dielectric layer loss increases, and insulation resistance descends, and influences electric wire useful life.
5, the general control cable-flame retardant is relatively poor, add fire retardant after, electrical insulating property reduces, and produces a large amount of poisonous and harmful smog during burning, and environment, equipment and personnel's life is all had great harm.
Three, summary of the invention
The purpose of this invention is to provide preparation method of a kind of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable with good heat resistance energy, fire resistance and acid and alkali resistance antiseptic property and good electrical insulation properties and products thereof.
Above purpose of the present invention and other purposes will and be described and further embody by following detailed description.
The preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable of the present invention, comprise wire drawing, annealing, extruded insulation, cross spark, stranding, wrapped and extrude the outer step of protecting, the draw ratio of extruder is 20-35 in the wherein said extruded insulation step, extrusion temperature is 300-400 ℃, adopt tubular molding tool, draw ratio is 30-100, and screw speed is 20-70 rev/min.
Further, in the preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable of the present invention, the draw ratio of extruder is 25-35 in the described extruded insulation step, extrusion temperature is 300-380 ℃, adopt tubular molding tool, draw ratio is 30-80, and screw speed is 30-60 rev/min.
Be preferably, in the preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable of the present invention, the draw ratio of extruder is 25-30 in the described extruded insulation step, extrusion temperature is 340-380 ℃, adopt tubular molding tool, draw ratio is 40-60, and screw speed is 30-50 rev/min.
In the preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable of the present invention, big drawing machine or Medium drawing mach ine are adopted in described wire drawing, and drawing speed is the 6.6-25 meter per second; The pot annealing stove is adopted in described annealing, and the conductor annealing temperature is 400-550 ℃, and temperature retention time is 4-5.5 hour, should vacuumize earlier before the annealing, charges into nitrogen then, carries out thermal annealing after charging again; The described spark of crossing adopts the power frequency spark machine, and the pass of test voltage U and insulation thickness δ is when δ≤0.4 millimeter, the U=4 kilovolt; When 0.4 millimeter≤δ≤0.6 millimeter, the U=6 kilovolt; When 0.6 millimeter≤δ≤1.0 millimeter, the U=10 kilovolt; Described stranding band adopts asbestos cord to fill, and the alkali-free glass fibre band is wrapped, and laying up pitch is not more than 20 times of external diameters.
Further, big drawing machine or Medium drawing mach ine, drawing speed: big drawing machine 6.6-16.5 meter per second, Medium drawing mach ine 15-25 meter per second are adopted in wire drawing; 1 millimeter 21.15 millimeters of the filament diameters of conductor, 1.5 millimeters 21.40 millimeters of the filament diameters of conductor, 2.5 millimeters 21.80 millimeters of the filament diameters of conductor, 4 millimeters 22.27 millimeters of the filament diameters of conductor, 6 millimeters 22.78 millimeters of the filament diameters of conductor.Should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again, adopt the pot annealing stove, the conductor annealing temperature of diameter below 1.0 millimeters: 450 ± 10 ℃, temperature retention time is 4-4.5 hour; The conductor annealing temperature of diameter more than 1.0 millimeters: 500 ± 10 ℃, temperature retention time is 4.5-5.5 hour.
Perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable of the present invention, the outside at copper conductor coats the perfluoroethylene-propylene insulating material, fill with asbestos cord between perfluoroethylene-propylene insulating material and alkali-free glass fibre band, the shell of product is the perfluoroethylene-propylene sheath.
In the present invention, conductor should meet the requirement of GB/T3956 in the used main raw material(s) of product, insulation adopts that exhaustive fluorinated ethylene propylene is mixing to form, band adopts the alkali-free glass fibre band, for the structure composition that makes cable keeps consistency, the alkali-free glass fibre band adopts the aluminium borosilicate glass composition, and the thermal endurance of material and the thermal endurance of cable adapt, and exhaustive fluorinated ethylene propylene is mixing forms in the sheath employing.
The long-term permission working temperature of perfluoroethylene-propylene of the present invention insulation control cable is more than 200 ℃, not only can be in hot environment operate as normal, and can improve the ampacity of cable greatly; And because perfluoroethylene-propylene can acid and alkali resistance and various chemicals, thereby product has fabulous antiseptic property and intensity height, hardness is big, can prevent the damage of mechanical external force; Be preferably, perfluoroethylene-propylene insulation control cable is because perfluoroethylene-propylene molecule adhesion is big, in known macromolecule key, the C-F key is one of the most firm key, insulation layer structure is closely knit, can effectively prevent the immersion of external water juice, greasy dirt and moisture, and the oxygen index of product is up to more than 95%, combustion hardly, its fire resistance is that other material is incomparable.
Rated voltage 450/750V perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable (KFF of the present invention 46Series), after putting on market, because this series of products excellent performance is heat-resisting good with anti-corrosive properties, be specially adapted to industry and factories and miness such as petrochemical industry, power station, smeltery and waste water treatment plant, after the user used, effect was fine, has higher rating.Detect through national authority department Shanghai Electrical Cable Research Institute, properties of product are apparently higher than the common plastics control cable that insulate, particularly in heat resistance, fire resistance, common plastics insulation control cable is incomparable especially for acid and alkali resistance antiseptic property and good aspects such as electrical insulation properties.
Because perfluoroethylene-propylene has certain corrosiveness to metal material, so the production equipment of processing perfluoroethylene-propylene must be through particular processing or with special made.The melt temperature of exhaustive fluorinated ethylene propylene is higher on the other hand, and the processing temperature scope is extremely narrow, and is high to the material requirement of temperature control system and screw rod, machine barrel and head.Adopt the main process equipments of making from the Zinc-lithium alloy material of Japanese import such as screw rod, machine barrel and head in the present invention.
Four, description of drawings
Fig. 1 is the schematic diagram of product of the present invention.
In Fig. 1, meet 1 and represent copper conductor, symbol 2 is represented the perfluoroethylene-propylene insulating material, and symbol 3 is represented asbestos cord, and symbol 4 is represented the alkali-free glass fibre band, and symbol 5 is represented the perfluoroethylene-propylene sheath.
Perfluoroethylene-propylene insulation high-temperature-resistant anticorrosion control cable of the present invention is outside copper conductor Side coats the perfluoroethylene-propylene insulating materials, at perfluoroethylene-propylene insulating materials and alkali-free glass Fill with asbestos cord between the fiber band, the shell of product is the perfluoroethylene-propylene sheath.
By the following specific examples further illustrate the invention, but embodiment only is used for explanation, Can not limit the scope of the invention.
In the present invention, if not refer in particular to, all part, percentages are unit of weight, all Equipment and raw material etc. all can be buied from market or the industry is commonly used.
Five, embodiment
Example 1:
The main process equipments such as screw rod, machine barrel and head that the main employing Zinc-lithium alloy material that adopts Japan to make is by the following method made prepare perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable:
Wire drawing: big drawing machine is adopted in wire drawing, and drawing speed is 7.0 meter per seconds, 1 millimeter 21.15 millimeters of the filament diameters of conductor;
Annealing: should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again, adopt the pot annealing stove, the conductor annealing temperature: 450 ± 10 ℃, temperature retention time is 4-4.5 hour;
Extruded insulation: the draw ratio of extruder is 22, and extrusion temperature is 320 ℃, adopts tubular molding tool, and draw ratio is 35, and screw speed is 25 rev/mins.
Cross spark: adopt the power frequency spark machine, the pass of test voltage U and insulation thickness δ is when δ≤0.4 millimeter, the U=4 kilovolt;
Stranding, wrapped and extrude outer protecting: the stranding band adopts asbestos cord to fill, and the alkali-free glass fibre band is wrapped, and laying up pitch is 5 times of external diameters.
Example 2:
The main process equipments such as screw rod, machine barrel and head that the main employing Zinc-lithium alloy material that adopts Japan to make is by the following method made prepare perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable:
Wire drawing: big drawing machine is adopted in wire drawing, and drawing speed is 16.5 meter per seconds, 1 millimeter 21.15 millimeters of the filament diameters of conductor;
Annealing: should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again, adopt the pot annealing stove, the conductor annealing temperature: 450 ± 10 ℃, temperature retention time is 4-4.5 hour;
Extruded insulation: the draw ratio of extruder is 35, and extrusion temperature is 390 ℃, adopts tubular molding tool, and draw ratio is 90, and screw speed is 70 rev/mins.
Cross spark: adopt the power frequency spark machine, the pass of test voltage U and insulation thickness δ is when δ≤0.4 millimeter, the U=4 kilovolt;
Stranding, wrapped and extrude outer protecting: the stranding band adopts asbestos cord to fill, and the alkali-free glass fibre band is wrapped, and laying up pitch is 10 times of external diameters.
Example 3
The main process equipments such as screw rod, machine barrel and head that the main employing Zinc-lithium alloy material that adopts Japan to make is by the following method made prepare perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable:
Wire drawing: big drawing machine is adopted in wire drawing, and drawing speed is 10.0 meter per seconds, 1.5 millimeters 21.40 millimeters of the filament diameters of conductor;
Annealing: should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again, adopt the pot annealing stove, the conductor annealing temperature: 450 ± 10 ℃, temperature retention time is 4-4.5 hour;
Extruded insulation: the draw ratio of extruder is 28, and extrusion temperature is 350 ℃, adopts tubular molding tool, and draw ratio is 60, and screw speed is 50 rev/mins.
Cross spark: adopt the power frequency spark machine, the pass of test voltage U and insulation thickness δ is when δ≤0.4 millimeter, the U=4 kilovolt;
Stranding, wrapped and extrude outer protecting: the stranding band adopts asbestos cord to fill, and the alkali-free glass fibre band is wrapped, and laying up pitch is 14 times of external diameters.
Example 4
The main process equipments such as screw rod, machine barrel and head that the main employing Zinc-lithium alloy material that adopts Japan to make is by the following method made prepare perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable:
Wire drawing: Medium drawing mach ine is adopted in wire drawing, and drawing speed is 25 meter per seconds, 2.5 millimeters 21.80 millimeters of the filament diameters of conductor;
Annealing: should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again, adopt the pot annealing stove, the conductor annealing temperature: 500 ± 10 ℃, temperature retention time is 4.5-5.5 hour
Extruded insulation: the draw ratio of extruder is 25, and extrusion temperature is 400 ℃, adopts tubular molding tool, and draw ratio is 40, and screw speed is 60 rev/mins.
Cross spark: adopt the power frequency spark machine, the pass of test voltage U and insulation thickness δ is when 0.4 millimeter≤δ≤0.6 millimeter, the U=6 kilovolt;
Stranding, wrapped and extrude outer protecting: the stranding band adopts asbestos cord to fill, and the alkali-free glass fibre band is wrapped, and laying up pitch is 20 times of external diameters.
Example 5
The main process equipments such as screw rod, machine barrel and head that the main employing Zinc-lithium alloy material that adopts Japan to make is by the following method made prepare perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable:
Wire drawing: Medium drawing mach ine is adopted in wire drawing, and drawing speed is 20 meter per seconds, 6 millimeters 22.78 millimeters of the filament diameters of conductor;
Annealing: should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again, adopt the pot annealing stove, the conductor annealing temperature: 500 ± 10 ℃, temperature retention time is 5.5 hours.;
Extruded insulation: the draw ratio of extruder is 23, and extrusion temperature is 370 ℃, adopts tubular molding tool, and draw ratio is 65, and screw speed is 40 rev/mins.
Cross spark: adopt the power frequency spark machine, the pass of test voltage U and insulation thickness δ is when when 0.6 millimeter≤δ≤1.0 millimeter, the U=10 kilovolt;
Stranding, wrapped and extrude outer protecting: the stranding band adopts asbestos cord to fill, and the alkali-free glass fibre band is wrapped, and laying up pitch is 15 times of external diameters.

Claims (8)

1, a kind of preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable, it is characterized in that comprising wire drawing, annealing, extruded insulation, cross spark, stranding, wrapped and extrude the outer step of protecting, the draw ratio of extruder is 20-35 in the wherein said extruded insulation step, extrusion temperature is 300-400 ℃, adopt tubular molding tool, draw ratio is 30-100, and screw speed is 20-70 rev/min.
2, the preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable according to claim 1, the draw ratio that it is characterized in that extruder in the described extruded insulation step is 25-35, extrusion temperature is 300-380 ℃, adopt tubular molding tool, draw ratio is 30-80, and screw speed is 30-60 rev/min.
3, the preparation method of perfluoroethylene-propylene insulation high-temperature resistant anti-corrosive control cable according to claim 1, the draw ratio that it is characterized in that extruder in the described extruded insulation step is 25-30, extrusion temperature is 340-380 ℃, adopt tubular molding tool, draw ratio is 40-60, and screw speed is 30-50 rev/min.
4, according to the preparation method of the described perfluoroethylene-propylene insulation of one of claim 1-3 high-temperature resistant anti-corrosive control cable, it is characterized in that described wire drawing employing big drawing machine or Medium drawing mach ine, drawing speed is the 6.6-25 meter per second.
5, according to the preparation method of the described perfluoroethylene-propylene of one of claim 1-3 insulation high-temperature resistant anti-corrosive control cable, it is characterized in that described annealing employing pot annealing stove, the conductor annealing temperature is 400-550 ℃, temperature retention time is 4-5.5 hour, should vacuumize earlier before the annealing, charge into nitrogen then, carry out thermal annealing after charging again.
6, according to the preparation method of the described perfluoroethylene-propylene of one of claim 1-3 insulation high-temperature resistant anti-corrosive control cable, it is characterized in that the described spark of crossing adopts the power frequency spark machine, the pass of test voltage U and insulation thickness δ is when δ≤0.4 millimeter, the U=4 kilovolt; When 0.4 millimeter≤δ≤0.6 millimeter, the U=6 kilovolt; When 0.6 millimeter≤δ≤1.0 millimeter, the U=10 kilovolt.
7, according to the preparation method of the described perfluoroethylene-propylene insulation of one of claim 1-3 high-temperature resistant anti-corrosive control cable, it is characterized in that described stranding band adopts asbestos cord to fill, the alkali-free glass fibre band is wrapped, and laying up pitch is not more than 20 times of external diameters.
8, according to the described perfluoroethylene-propylene insulation of one of claim 1-3 high-temperature resistant anti-corrosive control cable, it is characterized in that coating the perfluoroethylene-propylene insulating material in the outside of copper conductor, fill with asbestos cord between perfluoroethylene-propylene insulating material and alkali-free glass fibre band, the shell of product is the perfluoroethylene-propylene sheath.
CNB2005100072123A 2005-02-04 2005-02-04 Preparation and products of high temperature resistant and corrosionproof electric cables with polyfluorinated ethylene isolation Expired - Fee Related CN100366643C (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102157249A (en) * 2011-04-13 2011-08-17 广东昌宝通讯电缆电线有限公司 Production process of low-smoke high-fireproof performance network wire
CN103050185A (en) * 2012-08-31 2013-04-17 上海福尔欣线缆有限公司 Fluorine insulating wire and manufacturing method and applications thereof
CN104900312A (en) * 2015-06-05 2015-09-09 常熟市鑫华电子科技有限公司 Special round control flexible cable for fan motors
CN105139969A (en) * 2015-08-28 2015-12-09 马鞍山市兴隆铸造有限公司 Cable sheath manufacturing method
CN107248427A (en) * 2017-05-31 2017-10-13 迈特诺(马鞍山)特种电缆有限公司 A kind of production method of EMUs high fire-retardance fire-resisting cable
CN112309648A (en) * 2020-09-15 2021-02-02 源鑫线缆有限公司 Manufacturing method of fluoroplastic insulated power cable

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* Cited by examiner, † Cited by third party
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CN2200223Y (en) * 1994-09-23 1995-06-07 天津市安琪尔特种线缆有限责任公司 Fluorinated plastic insulation and sheath fire-proof control cable
CN1272984C (en) * 2002-10-29 2006-08-30 张志洪 Glass fiber mica alloy heat generating wire cable
CN1530966A (en) * 2003-01-24 2004-09-22 孙跃明 Wire cable and manufacturing method thereof
CN2613034Y (en) * 2003-04-18 2004-04-21 安徽华星电缆集团有限公司 Fire resistant cable

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102157249A (en) * 2011-04-13 2011-08-17 广东昌宝通讯电缆电线有限公司 Production process of low-smoke high-fireproof performance network wire
CN102157249B (en) * 2011-04-13 2012-11-28 广东昌宝通讯电缆电线有限公司 Production process of low-smoke high-fireproof performance network wire
CN103050185A (en) * 2012-08-31 2013-04-17 上海福尔欣线缆有限公司 Fluorine insulating wire and manufacturing method and applications thereof
CN103050185B (en) * 2012-08-31 2015-07-22 上海福尔欣线缆有限公司 Fluorine insulating wire and manufacturing method and applications thereof
CN104900312A (en) * 2015-06-05 2015-09-09 常熟市鑫华电子科技有限公司 Special round control flexible cable for fan motors
CN105139969A (en) * 2015-08-28 2015-12-09 马鞍山市兴隆铸造有限公司 Cable sheath manufacturing method
CN107248427A (en) * 2017-05-31 2017-10-13 迈特诺(马鞍山)特种电缆有限公司 A kind of production method of EMUs high fire-retardance fire-resisting cable
CN112309648A (en) * 2020-09-15 2021-02-02 源鑫线缆有限公司 Manufacturing method of fluoroplastic insulated power cable

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