CN1644763A - Composite coating containing carbon/molybdenum disulfide nanometer tube and its preparation - Google Patents
Composite coating containing carbon/molybdenum disulfide nanometer tube and its preparation Download PDFInfo
- Publication number
- CN1644763A CN1644763A CN 200510048951 CN200510048951A CN1644763A CN 1644763 A CN1644763 A CN 1644763A CN 200510048951 CN200510048951 CN 200510048951 CN 200510048951 A CN200510048951 A CN 200510048951A CN 1644763 A CN1644763 A CN 1644763A
- Authority
- CN
- China
- Prior art keywords
- composite
- carbon
- nano tube
- molybdenumdisulphide
- plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000002131 composite material Substances 0.000 title claims description 95
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims description 55
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 title claims description 55
- 229910052799 carbon Inorganic materials 0.000 title claims description 45
- 238000000576 coating method Methods 0.000 title claims description 17
- 239000011248 coating agent Substances 0.000 title claims description 15
- 229910052982 molybdenum disulfide Inorganic materials 0.000 title description 2
- 229910018104 Ni-P Inorganic materials 0.000 claims abstract description 27
- 229910018536 Ni—P Inorganic materials 0.000 claims abstract description 27
- 238000007747 plating Methods 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 17
- 239000000126 substance Substances 0.000 claims abstract description 13
- 239000002071 nanotube Substances 0.000 claims description 48
- 238000004070 electrodeposition Methods 0.000 claims description 8
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 8
- 150000002815 nickel Chemical class 0.000 claims description 8
- 239000001488 sodium phosphate Substances 0.000 claims description 7
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 7
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 6
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- 238000009713 electroplating Methods 0.000 claims description 4
- 239000004310 lactic acid Substances 0.000 claims description 4
- 235000014655 lactic acid Nutrition 0.000 claims description 4
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 4
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims description 3
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 3
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 3
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 3
- 239000001632 sodium acetate Substances 0.000 claims description 3
- 229960004249 sodium acetate Drugs 0.000 claims description 3
- 235000017281 sodium acetate Nutrition 0.000 claims description 3
- 239000001509 sodium citrate Substances 0.000 claims description 3
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 3
- 235000011152 sodium sulphate Nutrition 0.000 claims description 3
- XMVONEAAOPAGAO-UHFFFAOYSA-N sodium tungstate Chemical compound [Na+].[Na+].[O-][W]([O-])(=O)=O XMVONEAAOPAGAO-UHFFFAOYSA-N 0.000 claims description 3
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 claims description 3
- 229940038773 trisodium citrate Drugs 0.000 claims description 3
- 235000011054 acetic acid Nutrition 0.000 claims description 2
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 2
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 4
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 3
- 239000011733 molybdenum Substances 0.000 abstract description 3
- 238000012360 testing method Methods 0.000 abstract description 2
- 239000002041 carbon nanotube Substances 0.000 description 14
- 229910021393 carbon nanotube Inorganic materials 0.000 description 14
- 239000011159 matrix material Substances 0.000 description 7
- 238000005299 abrasion Methods 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 5
- 229910010271 silicon carbide Inorganic materials 0.000 description 5
- 229910000831 Steel Inorganic materials 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052976 metal sulfide Inorganic materials 0.000 description 3
- 239000002086 nanomaterial Substances 0.000 description 3
- 230000001052 transient effect Effects 0.000 description 3
- 229910000838 Al alloy Inorganic materials 0.000 description 2
- XMWRBQBLMFGWIX-UHFFFAOYSA-N C60 fullerene Chemical compound C12=C3C(C4=C56)=C7C8=C5C5=C9C%10=C6C6=C4C1=C1C4=C6C6=C%10C%10=C9C9=C%11C5=C8C5=C8C7=C3C3=C7C2=C1C1=C2C4=C6C4=C%10C6=C9C9=C%11C5=C5C8=C3C3=C7C1=C1C2=C4C6=C2C9=C5C3=C12 XMWRBQBLMFGWIX-UHFFFAOYSA-N 0.000 description 2
- 150000001721 carbon Chemical class 0.000 description 2
- 238000007772 electroless plating Methods 0.000 description 2
- 229910003472 fullerene Inorganic materials 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- ITRNXVSDJBHYNJ-UHFFFAOYSA-N tungsten disulfide Chemical compound S=[W]=S ITRNXVSDJBHYNJ-UHFFFAOYSA-N 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- ZKKLPDLKUGTPME-UHFFFAOYSA-N diazanium;bis(sulfanylidene)molybdenum;sulfanide Chemical compound [NH4+].[NH4+].[SH-].[SH-].S=[Mo]=S ZKKLPDLKUGTPME-UHFFFAOYSA-N 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Abstract
Description
Claims (4)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100489517A CN1322168C (en) | 2005-01-12 | 2005-01-12 | Composite coating containing carbon/molybdenum disulfide nanometer tube and its preparation |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2005100489517A CN1322168C (en) | 2005-01-12 | 2005-01-12 | Composite coating containing carbon/molybdenum disulfide nanometer tube and its preparation |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1644763A true CN1644763A (en) | 2005-07-27 |
CN1322168C CN1322168C (en) | 2007-06-20 |
Family
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Family Applications (1)
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CNB2005100489517A Expired - Fee Related CN1322168C (en) | 2005-01-12 | 2005-01-12 | Composite coating containing carbon/molybdenum disulfide nanometer tube and its preparation |
Country Status (1)
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CN (1) | CN1322168C (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101935829A (en) * | 2010-10-18 | 2011-01-05 | 上海应用技术学院 | Nanocomposite nickel-plated coating material and preparation method and application thereof |
CN103014809A (en) * | 2012-11-19 | 2013-04-03 | 无锡九条龙汽车设备有限公司 | Surface processing method of compact spinning negative pressure tube |
CN105405663A (en) * | 2015-10-30 | 2016-03-16 | 东南大学 | Electrochemical preparation method of MoS<2>/graphene composite counter electrode |
CN105967237A (en) * | 2016-05-10 | 2016-09-28 | 合肥工业大学 | Preparation method for inducing growth of molybdenum disulfide by means of graphene template |
CN111097381A (en) * | 2019-12-02 | 2020-05-05 | 镇江市高等专科学校 | Renewable modified activated carbon adsorbent and preparation method and application thereof |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1204699A (en) * | 1998-01-21 | 1999-01-13 | 李文铸 | Carbon nanometer pipe high wear-resistant compound cladding material on metal surface and preparation method thereof |
CN1142320C (en) * | 2001-07-18 | 2004-03-17 | 浙江大学 | Composite coating containing nanometer inorganic fullerene material and its prepn |
EP1486582A1 (en) * | 2003-06-13 | 2004-12-15 | Asulab S.A. | Low friction Micromechanical device |
-
2005
- 2005-01-12 CN CNB2005100489517A patent/CN1322168C/en not_active Expired - Fee Related
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101935829A (en) * | 2010-10-18 | 2011-01-05 | 上海应用技术学院 | Nanocomposite nickel-plated coating material and preparation method and application thereof |
CN103014809A (en) * | 2012-11-19 | 2013-04-03 | 无锡九条龙汽车设备有限公司 | Surface processing method of compact spinning negative pressure tube |
CN103014809B (en) * | 2012-11-19 | 2015-12-02 | 江苏高博智融科技有限公司 | A kind of surface treatment method of compact spinning negative pressure tube |
CN105405663A (en) * | 2015-10-30 | 2016-03-16 | 东南大学 | Electrochemical preparation method of MoS<2>/graphene composite counter electrode |
CN105405663B (en) * | 2015-10-30 | 2017-10-20 | 东南大学 | A kind of MoS2The electrochemical preparation method of/graphene combined counter electrode |
CN105967237A (en) * | 2016-05-10 | 2016-09-28 | 合肥工业大学 | Preparation method for inducing growth of molybdenum disulfide by means of graphene template |
CN111097381A (en) * | 2019-12-02 | 2020-05-05 | 镇江市高等专科学校 | Renewable modified activated carbon adsorbent and preparation method and application thereof |
Also Published As
Publication number | Publication date |
---|---|
CN1322168C (en) | 2007-06-20 |
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Legal Events
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
EE01 | Entry into force of recordation of patent licensing contract |
Assignee: Lin'an Hualong Friction Material Co., Ltd. Assignor: Zhejiang University Contract fulfillment period: 2009.3.18 to 2015.12.31 contract change Contract record no.: 2009330000902 Denomination of invention: Composite coating containing carbon/molybdenum disulfide nanometer tube and its preparation Granted publication date: 20070620 License type: Exclusive license Record date: 2009.5.11 |
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LIC | Patent licence contract for exploitation submitted for record |
Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2009.3.18 TO 2015.12.31; CHANGE OF CONTRACT Name of requester: LINAN HUALONG FICTION MATERIALS CO., LTD. Effective date: 20090511 |
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C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070620 Termination date: 20120112 |