CN1637130A - Thickener for surface active agent and detergent composition - Google Patents

Thickener for surface active agent and detergent composition Download PDF

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Publication number
CN1637130A
CN1637130A CNA2004101012159A CN200410101215A CN1637130A CN 1637130 A CN1637130 A CN 1637130A CN A2004101012159 A CNA2004101012159 A CN A2004101012159A CN 200410101215 A CN200410101215 A CN 200410101215A CN 1637130 A CN1637130 A CN 1637130A
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active agent
thickener
surface active
anion surfactant
type anion
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CN100558870C (en
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鸟井文仁
水田元就
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JAPAN OIL AND GREASE Ltd
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JAPAN OIL AND GREASE Ltd
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88—Ampholytes; Electroneutral compounds
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Emergency Medicine (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

The provides a thickening agent for surfactants expressing an excellent thickening effect on surfactants, in particular to acylamino acid type anionic surfactants or alkyliminodicarboxylate type amphoteric surfactants, and to provide a detergent composition containing the same and excellent in quality of foams and free from slimy feeling. The thickening agent for surfactant is expressed by general formula (1): R[1]O(EO)[x](BO)[y](EO)[z]H. In the formula, R[1] is a group selected from an 8-14C alkyl group, an alkenyl group or an acyl group, EO is an ethylene oxide group, BO is a butylene oxide group, x, y or z are each an average addition mole number and 0<=x<=3, 1<=y<=3, 0<=z<=3 and 0<=x+z<=3.

Description

Thickener for surface active agent and cleanser compositions
Technical field
The present invention relates to thickener for surface active agent and contain the cleanser compositions of this thickening material; particularly; relate to the good thickening effectiveness that demonstrates tensio-active agent; particularly to the very effective thickener for surface active agent of thickening of acyl amino acid type anion surfactant or alkyl imino dicarboxylic ester type amphoterics, and contain the good alveolar substance of having of this thickening material and can not produce the cleanser compositions of stick-slip sense.
Background technology
At present, tensio-active agent is used in the various uses and goods of industrial field widely.But the aqueous solution that contains tensio-active agent does not have suitable viscosity.Therefore, when being used for purposes such as sanitising agent when tensio-active agent,, this tensio-active agent is mixed use with various viscosity modifiers with the water equal solvent for reaching suitable viscosity.
The thickening material of tensio-active agent is known water-soluble polymers such as inorganic salt, Natvosol, xanthan gum such as sodium-chlor, fatty acid alkyl amide etc.Wherein, because of fatty acid alkyl amide not only has thickening effectiveness, and can also reach the foam enhancing effect, so be used widely with combinations-of surfactants such as sulfated alkyl ether type tensio-active agents.
But the thickening effectiveness of fatty acid alkyl amide is little, is difficult to thickening during with acyl amino acid type anion surface activity or the combination of basic iminodicarboxylic acid ester type amphoterics, has caused the problem of the storage stability of the mixed solution that contains tensio-active agent.And after being used for sanitising agent, stick-slip sense is arranged.Therefore, people wish to have a kind of good thickening effectiveness that demonstrates tensio-active agent, can be to the thickener for surface active agent of the effective thickening of tensio-active agent.
Use thickening material for making cleanser compositions have suitable viscosity; the alkyl sulphate type anion surfactant that often will be used to reach excellent cleaning capacity and use; sulfated alkyl ether type silver is from tensio-active agent; amide ether sulfate type anion surface activity base; acyl taurate type anion surfactant; the acyl glutamate type anion surfactant that sulfate type such as acyl group isethionic acid ester type anion surfactant or sulphonate type anion surfactant use with being used to reach good whipability; acyl group-Beta-alanine salt type anion surfactant; acyl sarcosine ester type anion surfactant; acyl amino acid type anion surfactants such as acylglycine ester type anion surfactant, or alkylamidoalkyl dicarboxylic ester type amphoterics and usefulness.
And use the cleanser compositions of fatty amines can enumerate the cleanser compositions (patent documentation 1 of acyl group alkyl tauride type anion surfactant and amine oxide and alkanolamine combination as tackifier; Japanese kokai publication sho 59-100198 communique); cleanser compositions (the patent documentation 2 of acyl group sarkosine type anion surfactant or acylglycine type anion surfactant and fatty acid alkyl amide combination; Japanese kokai publication hei 2-180811 communique); higher fatty acid salt; acyl group alkyl tauride type anion surfactant; the cleanser compositions of acyl group isethionic acid ester type anion surfactant or amide ether sulfate type anion surfactant and alkylolamide type nonionic surfactant combinations (patent documentation 3, Japanese kokai publication hei 7-138591 communique) etc.
The cleaning agent example that contains oxyalkylene derivative can enumerate use epoxy butane with the ethylene oxide polymerization more than 6 moles and must the cleanser compositions (patent documentation 4: TOHKEMY 2001-334139 communique), contain simultaneously the sulphation unrighted acid of poly-alkylene glycols fatty acid ester of the poly-alkylene glycols fatty acid ester of 1～5 mole of epoxy butane and 1～5 moles of ethylene oxide addition and 1～5 mole of epoxy butane and 6～20 moles of ethylene oxide additions or the composition (patent documentation 5: TOHKEMY 2003-226900 communique) etc. of soap of poly-alkylene glycols fatty acid ester. But the alveolar substance of these cleanser compositions and the stick-slip sense that is had thereof may not necessarily meet the demands.
Summary of the invention
The object of the present invention is to provide provides the thickening effectiveness that shows the tensio-active agent excellence, particularly to the effectively thickener for surface active agent of thickening of acyl amino acid type anion surfactant or alkyl imino dicarboxylic ester type amphoterics and contain the cleanser compositions that the alveolar substance of this thickening material is good, can not produce stick-slip sense.
The inventor etc. for address the above problem further investigate after, found that: the thickener for surface active agent by ad hoc structure can achieve the above object, and finishes the present invention in view of the above.
That is, main contents of the present invention are as described below.
The invention provides thickener for surface active agent with following general formula (1) expression,
R 1O(EO) x(BO) y(EO) zH?????(1)
In the formula, R 1Expression is selected from the group of alkyl, alkenyl and the acyl group of carbonatoms 8～14, EO representative ring oxidative ethane, and BO represents butylene oxide ring, x, y and z represent average addition mole number respectively, wherein, 0≤x≤3,1≤y≤3,0≤z≤3,0≤x+z≤3.
The present invention also provides the thickener for surface active agent with following general formula (2) expression,
R 1O(BO) yH????????????????(2)
In the formula, R 1Expression is selected from the group of alkyl, alkenyl and the acyl group of carbonatoms 8～14, and BO represents butylene oxide ring, and y represents average addition mole number, wherein, and 1≤y≤3.
The invention provides the above-mentioned thickener for surface active agent that contains 0.5～10 weight % and the tensio-active agent of 2～40 weight %, while the weight ratio of this thickener for surface active agent and this tensio-active agent is 1/30～1/2 cleanser compositions.
In a preferred embodiment, above-mentioned tensio-active agent is at least a tensio-active agent that is selected from sulfate type anion surfactant, sulphonate type anion surfactant, acyl amino acid type anion surfactant and the alkyl imino dicarboxylic ester type amphoterics.
The invention effect
Thickener for surface active agent of the present invention demonstrates the good thickening effectiveness to tensio-active agent, and is particularly very effective to the thickening of acyl amino acid type anion surfactant or alkyl imino dicarboxylic ester type amphoterics.And the cleanser compositions that is added with thickener for surface active agent of the present invention has good alveolar substance, and can not produce stick-slip sense.And cleanser compositions of the present invention does not also have pungency to skin.
Embodiment
Thickener for surface active agent of the present invention is the material with following general formula (1) expression,
R 1O(EO) x(BO) y(EO) zH???????????????????(1)
In the formula, R 1Expression is selected from the group of alkyl, alkenyl and the acyl group of carbonatoms 8～14, EO representative ring oxidative ethane, and BO represents butylene oxide ring, x, y and z represent average addition mole number respectively, wherein, 0≤x≤3,1≤y≤3,0≤z≤3,0≤x+z≤3.
In above-mentioned general formula (1), R 1Expression is selected from the group of alkyl, alkenyl and the acyl group of carbonatoms 8～14.Wherein, R 1In alkyl can enumerate octyl group, iso-octyl, nonyl, different nonyl, decyl, isodecyl, undecyl, different undecyl, dodecyl, Permethyl 99A. base, tridecyl, isotridecyl, tetradecyl, different tetradecyl etc.R 1In alkenyl can enumerate the tetradecene base.And R 1In acyl group can enumerate capryloyl, decanoyl, lauroyl, tetradecanoyl.R 1Be preferably the group of the alkyl, alkenyl and the acyl group that are selected from carbonatoms 8～12, more preferably the acyl group of carbonatoms 8～12.
R 1Carbonatoms 8 when above, can obtain having the thickener for surface active agent of excellent thickening effectiveness, the cleanser compositions that contains this thickening material can reach good alveolar substance.And carbonatoms is 14 when following, and the gained thickener for surface active agent can not cause worsening with the intermiscibility of tensio-active agent, can show excellent thickening effectiveness.And the cleanser compositions that contains above-mentioned thickening material can not produce stick-slip sense.
In above-mentioned general formula (1), the average addition mole number y of butylene oxide ring is 1～3, is preferably 1～2.Y is 1～3 o'clock, can obtain having the thickening material of excellent thickening effectiveness, and the cleanser compositions that contains this thickening material can reach good alveolar substance.Oxyethane average addition mole number x and z are 0≤x≤3,0≤z≤3,0≤x+z≤3, more preferably 0≤x≤2,0≤z≤2,0≤x+z≤2, more preferably x=z=0.X+z can obtain having the thickening material of excellent thickening effectiveness 3 when following, and the cleanser compositions that contains this thickening material can not produce stick-slip sense.
Especially thickener for surface active agent of the present invention can obtain more excellent thickening effectiveness when x=z=0, when adding in the cleanser compositions, can obtain can not producing the composition of stick-slip sense.This thickener for surface active agent is shown in following general formula (2):
R 1O(BO) yH??????????????????(2)
R in the formula 1, BO and y be identical with corresponding meaning in the general formula (1).
Manufacture method to thickener for surface active agent of the present invention is not particularly limited, for example can adopt the method for lipid acid and the esterification of polytetramethylene glycol polyoxyethylene glycol, or in the presence of level Four salt, Lewis acid or alkaline catalysts, make 1, the manufacture method such as method of 2-butylene oxide ring and oxyethane and alcohol or lipid acid addition reaction make.
Cleanser compositions of the present invention contains thickener for surface active agent (also being called (a) composition down) and the tensio-active agent (also being called (b) composition down) that is selected from above-mentioned general formula (1) or (2).
In cleanser compositions of the present invention, (a) content of composition is 0.5～10 weight %, is preferably 1～8 weight %.When (a) content of composition is in the scope of 0.5～10 weight %, can give the viscosity of cleanser compositions appropriateness, can obtain having good alveolar substance, and not have stick-slip sense, but also skin is not had irritating cleanser compositions.
In cleanser compositions of the present invention, (b) content of composition is 2～40 weight %, is preferably 5～30 weight %.The content that makes (b) composition then can obtain having the cleanser compositions of good alveolar substance more than or equal to 2 weight %; And make its content smaller or equal to 40 weight %, then can obtain can not producing the high-quality cleanser compositions of stick-slip sense.
(a) composition in the cleanser compositions and (b) content of composition be 1/30～1/2 than (a)/(b) represent with weight ratio, be preferably 1/20～1/4.When (a)/(b) more than or equal to 1/30 the time, the cleanser compositions that can obtain having good alveolar substance; And smaller or equal to 1/2 o'clock, the cleanser compositions that can obtain having good alveolar substance and can not produce stick-slip sense.
Cleanser compositions of the present invention does not have restriction especially to contained tensio-active agent ((b) composition); for obtaining the more fine cleanser compositions that has good alveolar substance and can not produce stick-slip sense, should (b) composition be preferably and be selected from least a in sulphonate type anion surfactant, acyl amino acid type anion surfactant and the alkyl imino dicarboxylic ester type amphoterics.This tensio-active agent divides to be an alkali metal salt, alkaline earth salt, ammonium salt, organic amine salt etc., for example, can be various salt such as lithium salts, sodium salt, sylvite, 1/2 calcium salt, 1/2 magnesium salts, ammonium salt, trolamine, diethanolamine, monoethanolamine.This tensio-active agent preferably has the alkyl or the acyl group of carbonatoms 8～22, for example can be lauryl, lauroyl, myristoyl, palmitoyl, stearyl-, oleoyl, fatty acid distribution of coconut oil residue, palm kernel oil fatty acid residue, tallow fatty acids residue etc.Owing to use the tensio-active agent of carbonatoms 8～22 can obtain having excellent alveolar substance, and do not have the cleanser compositions of stick-slip sense, so be preferred version.
Sulfate type anion surfactant of the present invention can be enumerated alkyl sulphate type anion surfactant, sulfated alkyl ether type anion surfactant and amido ether sulfate type anion surfactant etc.
Sulphonate type anion surfactant of the present invention can be enumerated acyl group alkyl taurine ester type anion surfactant, acyl group isethionic acid type anion surfactant, dialkyl sulfosuccinate amber acid type anion surfactant, alkyl sulfone type anion surfactant and amidosulfonic acid type anion surfactant.Be preferably acyl group alkyl taurine ester type anion surfactant and acyl group isethionic acid type anion surfactant.
Acyl amino acid type anion surfactant of the present invention can be enumerated acyl glutamate type anion surfactant, acyl group-Beta-alanine salt type anion surfactant, acyl sarcosinate type anion surfactant, acylglycine type anion surfactant and aspat type anion surfactant.Be preferably acyl glutamate type anion surfactant, acyl group-Beta-alanine salt type anion surfactant, acyl sarcosinate type anion surfactant and acylglycine type anion surfactant.
Alkyl imino dicarboxylic ester type amphoterics can be enumerated alkyl imino diacetate esters type amphoterics or alkyl imino dipropionate type amphoterics.
In cleanser compositions of the present invention, usually, the surplus except that above-mentioned (a) and (b) composition is a water.But also can add other composition or the additive that can be used in the cleanser compositions as required.Specifically can add for example hexadecanol, higher alcoholss such as stearyl alcohol, glycerine, polyvalent alcohols such as ethylene glycol, squalane, hydrocarbon ils such as paraffin, Jojoba oil, ester oils such as tetradecanoic acid octyl group dodecyl ester, cationic Polyvinylpyrolidone (PVP) derivative, the cationic macromolecular compounds such as multipolymer of dimethyl diallyl ammonium chloride and acrylamide, organosilicon derivates such as dimethyl siloxane-methyl (polyoxyethylene) silicone copolymers, sodium sulfate, inorganic salt such as salt of wormwood, L-glutamic acid, organic acid and salt thereof such as aspartic acid, p-Hydroxybenzoate, sanitass such as Phenoxyethanol, 5-methyl-2-isopropyl cyclohexanol, nourishing agents such as capsicum tincture (tonic), edetate, citric acid, sequestrants such as nitrilotriacetic acid trisodium.UV light absorber such as benzophenone derivates, benzotriazole derivatives, and pigment, spices etc.
Embodiment
Below, specify the present invention according to embodiment, but the present invention is not limited because of embodiment.
Modulation example 1: make thickener for surface active agent
Weighing dodecylic acid 1600g (8 moles) and be the tetramethyl ammonium chloride 16g of 1 weight part when being 100 weight parts with this dodecylic acid, the autocrave that adds 5 liters of volumes, be warming up to 125 ℃, at top pressure is under the condition of 0.45MPa, make it reaction, carry out 5 hours slaking with butylene oxide ring 749g (10.4 moles).Under 75 ℃, the condition of decompression, outgas again,, through dehydration, filtration, obtain butyleneglycol list dodecylate (A-1) (hydroxyl value 204mgKOH/g, the average addition mole number 1.0 of butylene oxide ring) again with 10% salt solution 2kg washing.The receipts amount is 2046g.The structure of A-1 is as shown in table 1.
Modulation example 2: make thickener for surface active agent
The sad 1152g of weighing (8 moles) and sad with this be the potassium hydroxide 58g of 5 weight parts when being 100 weight parts, add the autocrave of 5 liters of volumes, be warming up to 125 ℃, under the pressure of 0.49MPa, make it reaction, carry out 2 hours slaking with butylene oxide ring 749g (10.4 moles).Under 75 ℃, the condition of decompression, outgas again,,, obtain the butyleneglycol list octanoate (A-2) (hydroxyl value 244mgKOH/g, the average addition mole number 1.2 of butylene oxide ring) of structure shown in the table 1 again through dehydration, filtration with 10% saltcake water 2kg washing.The receipts amount is 1708g.
Modulation example 3～5: make thickener for surface active agent
The sad 1152g (8 moles) in using tetradecanoic acid 1670g (7.3 moles), dodecylic acid 760g (3.8 moles), dodecanol 1250g (6.7 moles) replacement modulation example 2 respectively, other operation is the same with modulation example 2, obtains butyleneglycol list tetradecanoate (A-3), butyleneglycol list dodecylate (A-4), the butyleneglycol monododecyl ether (A-5) of structure shown in the table 1 respectively.
Relatively modulate example 1～4
The sad 1152g (8 moles) in using butyric acid 590g (6.7 moles) (relatively modulating example 1), octadecanoic acid 2080g (7.3 moles) (relatively modulating example 2), dodecanol 300g (1.5 moles) (relatively modulating example 3) replacement modulation example 2 respectively, other is the same with modulation example 2, obtains the comparison composition C-1～C-3 of structure shown in the table 2.And except that replacing the butylene oxide ring 749g (10.4 moles) with the sad 1152g (8 moles) in dodecylic acid 1600g (8 moles) the replacement modulation example 2 with oxyethane 460g (10.5 moles), other operation is the same with modulation example 2, obtains the comparison composition C-4 of structure shown in the table 2.
Modulation example 6: make thickener for surface active agent
Weighing modulation example 1 gained A-1 composition 1375g (5 moles) and be the potassium hydroxide 69g of 5 weight parts when being 100 weight parts with this A-1 composition, the autocrave that adds 5 liters of volumes, be warming up to 135 ℃, at top pressure is under the condition of 0.49MPa, make it reaction, carry out 3 hours slaking with oxyethane 705g (16 moles).Again in 75 ℃, the decompression condition under outgas, then with acetate neutralization and filtration, obtain the polyoxyethylene glycol-butyleneglycol dodecylate (A-6) (hydroxyl value 139mgKOH/g, the average addition mole number of butylene oxide ring is 1.0, the average addition mole number of oxyethane is 2.9) of structure shown in the table 1.The receipts amount is 1920g.
Relatively modulate example 5
In modulation example 6, the consumption that removes oxyethane is the 2420g (55 moles), other with operate that to modulate example 6 the same, obtain the comparison composition C-5 of structure shown in the table 2.
Modulation example 7: make thickener for surface active agent
Weighing dodecanol 1119g (6.0 moles) and be the potassium hydroxide 56g of 5 weight parts when being 100 weight parts with this dodecanol, add the autocrave of 5 liters of volumes, be warming up to 125 ℃, under the pressure of 0.49MPa, make it reaction, carry out 2 hours slaking with butylene oxide ring 467g (6.5 moles).Again in 75 ℃, the decompression condition under the degassing 1 hour, with the acetate neutralization, filter again, obtain polyoxyethylene glycol butyleneglycol monododecyl ether (A-7) (hydroxyl value 157mgKOH/g, the average addition mole number 1.0 of butylene oxide ring, the average addition mole number 2.3 of oxyethane).The receipts amount is 1971g.The A-7 structure is as shown in table 1).
Table 1
(a) composition Structure R in the general formula (1) 1
The modulation example ??1 ??A-1 ??R 1O(BO) 1.0H Lauroyl
??2 ??A-2 ??R 1O(BO) 1.2H Capryloyl
??3 ??A-3 ??R 1O(BO) 1.1H Tetradecanoyl
??4 ??A-4 ??R 1O(BO) 2.2H Lauroyl
??5 ??A-5 ??R 1O(BO) 1.2H Dodecyl
??6 ??A-6 ??R 1O(BO) 1.0(EO) 2.9H Lauroyl
??7 ??A-7 ??R 1O(BO) 1.0(EO) 2.3H Dodecyl
Table 2
Compare composition Structure R in the general formula (1) 1
The modulation example ??1 ?C-1 ????R 1O(BO) 1.2H Butyryl radicals
??2 ?C-2 ????R 1O(BO) 1.1H Octadecanoyl
??3 ?C-3 ????R 1O(BO) 5.3H Lauroyl
??4 ?C-4 ????R 1O(BO) 1.1H Lauroyl
??5 ?C-5 ????R 1O(BO) 1.0(EO) 9.2H Lauroyl
Embodiment 1～16 and comparative example 1～11
(A-1～A-7 and C-1～C-5) and various tensio-active agents and water are estimated the viscosity of this mixture according to mixed shown in table 3 and the table 4 with following method with the thickener for surface active agent shown in table 1 and 2.Evaluation result as shown in Tables 3 and 4.
(1) viscosity
Said mixture is kept 25 ℃, under 100 seconds minute, use Brookfield viscometer ((strain) Tokyo gauge is made made) to measure viscosity.
Table 3
Embodiment
????1 ????2 ????3 ????4 ????5 ????6 ????7 ??8 ??9 ??10 ??11 ??12 ??13 ??14 ????15 ????16
Component content weight % Thickener for surface active agent A-1 ????3 ????- ????- ????- ????- ????- ????- ??6 ??15 ??5 ??7 ??2 ??4 ??5 ????3 ????6
A-2 ????- ????3 ????- ????- ????- ????- ????- ??- ??- ??- ??- ??- ??- ??- ????- ????-
A-3 ????- ????- ????3 ????- ????- ????- ????- ??- ??- ??- ??- ??- ??- ??- ????- ????-
A-4 ????- ????- ????- ????3 ????- ????- ????- ??- ??- ??- ??- ??- ??- ??- ????- ????-
A-5 ????- ????- ????- ????- ????3 ????- ????- ??- ??- ??- ??- ??- ??- ??- ????- ????-
A-6 ????- ????- ????- ????- ????- ????3 ????- ??- ??- ??- ??- ??- ??- ??- ????- ????-
A-7 ????- ????- ????- ????- ????- ????- ????3 ??- ??- ??- ??- ??- ??- ??- ????- ????-
Tensio-active agent Polyoxyethylene (EO=3) lauryl ether sulfate ????20 ????20 ????20 ????20 ????20 ????20 ????20 ??50 ??35 ??- ??- ??8 ??- ??17 ????- ????-
Coconut oil fat acid amide CAB ????- ????- ????- ????- ????- ????- ????- ??- ??- ??20 ??- ??7 ??12 ??- ????- ????-
The fatty acid distribution of coconut oil N-methyltaurine ????- ????- ????- ????- ????- ????- ????- ??- ??- ??- ??30 ??- ??8 ??7 ????- ????-
The fatty acid distribution of coconut oil Sodium Glutamate ????- ????- ????- ????- ????- ????- ????- ??- ??- ??- ??- ??- ??- ??- ????20 ????-
The lauryl iminodiacetic acid sodium ????- ????- ????- ????- ????- ????- ????- ??- ??- ??- ??- ??- ??- ??- ????- ????28
Purified Water ????77 ????77 ????77 ????77 ????77 ????77 ????77 ??44 ??50 ??75 ??63 ??83 ??76 ??71 ????77 ????66
Valuation Viscosity (mPas) ????1510 ????560 ????330 ????750 ????560 ????140 ????120 ??63400 ??42500 ??200 ??1280 ??7100 ??35240 ??3370 ????180 ????250
Table 4
Comparative example
????1 ????2 ????3 ????4 ????5 ????6 ????7 ????8 ????9 ????10 ????11
Component content weight % Thickener for surface active agent C-1 ????- ????- ????- ????- ????- ????3 ????- ????- ????- ????- ????-
C-2 ????- ????3 ????- ????- ????- ????- ????3 ????- ????- ????- ????-
C-3 ????- ????- ????3 ????- ????- ????- ????- ????3 ????- ????- ????-
C-4 ????- ????- ????- ????3 ????- ????- ????- ????- ????3 ????- ????-
C-5 ????- ????- ????- ????- ????3 ????- ????- ????- ????- ????3 ????-
Lauric acid diethyl amide ????- ????- ????- ????- ????- ????3 ????- ????- ????- ????- ????3
Tensio-active agent Polyoxyethylene (EO=3) lauryl ether sulfate ????20 ????- ????- ????- ????- ????20 ????20 ????20 ????20 ????20 ????-
Coconut oil fat acid amide CAB ????- ????20 ????- ????- ????- ????- ????- ????- ????- ????- ????-
Fatty acid distribution of coconut oil N-methyltaurine sodium ????- ????- ????30 ????- ????- ????- ????- ????- ????- ????- ????-
The fatty acid distribution of coconut oil Sodium Glutamate ????- ????- ????- ????20 ????- ????- ????- ????- ????- ????- ????20
The lauryl iminodiacetic acid sodium ????- ????- ????- ????- ????28 ????- ????- ????- ????- ????- ????-
Purified Water ????80 ????80 ????70 ????80 ????72 ????77 ????77 ????77 ????77 ????77 ????77
Estimate Viscosity (mPas) ????5 ????4 ????5 ????5 ????4 ????23 ????28 ????32 ????30 ????8 ????25
According to table 3, can confirm the thickener for surface active agent (A-1～A-7) various promoting agents are had thickening effectiveness of embodiment 1～16.
According to table 4 as can be known: in the comparative example 6, owing to use R 1The few comparison composition C-1 of carbonatoms of acyl group, so thickening effectiveness is poor; In the comparative example 7, owing to use R 1The many comparison composition C-2 of acyl group carbonatoms, so thickening effectiveness is poor; In the comparative example 8, owing to use the many comparison composition C-3 of addition mole number of butylene oxide ring, so thickening effectiveness is poor; In the comparative example 9, because use is without the comparison composition C-4 of butylene oxide ring addition, so thickening effectiveness is poor; In the comparative example 10, owing to use the many comparison composition C-5 of oxyethane addition mole number, so thickening effectiveness is poor; In comparative example 11, because use is as the lauric acid diethyl amide of fatty acid alkyl amide, so thickening effectiveness is poor.
Embodiment 17～32 and comparative example 12～20
Thickener for surface active agent shown in table 1 and 2 (a composition), tensio-active agent (b composition) and water are pressed mixed shown in table 5 and the table 6, obtain sanitising agent, use this sanitising agent, estimate alveolar substance and usability with following method.Evaluation result is shown in table 5 and table 6.
(2) alveolar substance
By the alveolar substance behind each 10 expertises usefulness 5g cleanser compositions cleaning health of men and women.Feel that bubble is fine and smooth and when flexible, be 2 points, feel that it is 1 point that bubble has when loose slightly, feel that bubble loosens and be 0 point when nonelastic, count according to 20 experts' total, with following three grades of method evaluations.
Alveolar substance is good: zero (adding up to point more than 30);
Alveolar substance is poor slightly: △ (adding up to point more than 20, less than 30 points);
Alveolar substance is poor: * (adding up to some less than 20 points).
(3) stick-slip sense
By the stick-slip sense behind each 10 expertises usefulness 5g cleanser compositions cleaning health of men and women.Being 2 points when not having stick-slip sense, is 1 point when slightly stick-slip sense being arranged, and stick-slip sense is strong, need are 0 point when cleaning for a long time, counts according to 20 experts' total, with following three grades of method evaluations.
No stick-slip sense: zero (adding up to point more than 30)
Stick-slip sense: △ (adding up to point more than 20, less than 30 points) is arranged slightly
Stick-slip sense is strong: * (adding up to some less than 20 points)
Table 5
Embodiment
??17 ????18 ??19 ??20 ??21 ??22 ??23 ??24 ??25 ??26 ??27 ??28 ??29 ??30 ??31 ??32
Composition weight % The a composition A-1 ??3 ????- ??- ??- ??- ??- ??- ??3 ??6 ??1 ??3 ??3 ??- ??- ??- ??-
A-2 ??- ????3 ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??1 ??- ??-
A-3 ??- ????- ??3 ??- ??- ??- ??- ??- ??- ??- ??- ??- ??1 ??- ??- ??-
A-4 ??- ????- ??- ??3 ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??4 ??-
A-5 ??- ????- ??- ??- ??3 ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??3
A-6 ??- ????- ??- ??- ??- ??3 ??- ??- ??- ??- ??- ??- ??- ??- ??- ??-
A-7 ??- ????- ??- ??- ??- ??- ??3 ??- ??1.5 ??2 ??- ??- ??- ??- ??- ??3
(a) become deal ??3 ????3 ??3 ??3 ??3 ??3 ??3 ??3 ??7.5 ??3 ??3 ??3 ??1 ??1 ??4 ??3
The b composition Lauryl sulfate ??20 ????- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??-
Polyoxyethylene (EO=3) lauryl ether sulfate ??- ????20 ??- ??- ??- ??20 ??- ??- ??- ??- ??- ??- ??- ??- ??- ??-
Polyoxyethylene fatty acid distribution of coconut oil monoethanolamine sodium sulfate ??- ????- ??20 ??- ??- ??- ??20 ??- ??- ??- ??8 ??- ??- ??- ??- ??-
Fatty acid distribution of coconut oil N-methyltaurine sodium ??- ????- ??- ??20 ??- ??- ??- ??20 ??30 ??- ??5 ??- ??- ??- ??- ??-
The fatty acid distribution of coconut oil isethionic acid ester ??- ????- ??- ??- ??20 ??- ??- ??- ??- ??20 ??- ??- ??- ??- ??- ??-
Coconut oil fat glutamatic acid trolamine ??- ????- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??30 ??- ??- ??- ??-
Lauroyl-Beta-alanine sodium ??- ????- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??25 ??- ??- ??-
Sodium N-lauroyl sarcosinate ??- ????- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??5 ??- ??-
The lauroyl Sodium glycocollate ??- ????- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??25 ??-
Lauroyl acetimidic acid sodium ??- ????- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??- ??15
(b) become deal ??20 ????20 ??20 ??20 ??20 ??20 ??20 ??20 ??30 ??20 ??13 ??30 ??25 ??5 ??25 ??15
Purified Water ??77 ????77 ??77 ??77 ??77 ??77 ??77 ??77 ??62.5 ??77 ??84 ??67 ??74 ??94 ??71 ??82
??????????????????a/b ??1/7 ????1/7 ??1/7 ??1/7 ??1/7 ??1/7 ??1/7 ??1/7 ??1/4 ??1/7 ??1/4 ??1/10 ??1/25 ??1/5 ??1/6 ??1/5
Estimate Alveolar substance ??○ ????○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○
Stick-slip sense ??○ ????○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○ ??○
Table 6
Comparative example
????12 ????13 ????14 ????15 ????16 ????17 ????18 ????19 ????20
Composition weight % The a composition A-1 ????0.5 ????5 ????5 ????- ????- ????- ????- ????- ????-
A-6 ????- ????- ????- ????- ????- ????- ????- ????- ????-
(a) become deal ????0.5 ????5 ????5 ????0 ????0 ????0 ????0 ????0 ????-
Compare a composition C-1 ????- ????- ????- ????3 ????- ????- ????- ????- ????-
C-2 ????- ????- ????- ????- ????3 ????- ????- ????- ????-
C-3 ????- ????- ????- ????- ????- ????3 ????- ????- ????-
C-4 ????- ????- ????- ????- ????- ????- ????3 ????- ????-
C-5 ????- ????- ????- ????- ????- ????- ????- ????3 ????-
The lauric acid diethanolamine ????- ????- ????- ????- ????- ????- ????- ????- ????3
The b composition Polyoxyethylene (EO=3) lauryl ether sulfate ????1 ????- ????- ????20 ????- ????- ????- ????20 ????-
Polyoxyethylene fatty acid distribution of coconut oil monoethanolamine sodium sulfate ????- ????50 ????- ????- ????20 ????- ????- ????- ????20
Fatty acid distribution of coconut oil N-methyltaurine sodium ????- ????- ????- ????- ????- ????20 ????- ????- ????-
The fatty acid distribution of coconut oil isethionic acid ester ????- ????- ????- ????5 ????- ????- ????20 ????- ????-
(b) become deal ????1 ????50 ????5 ????20 ????20 ????20 ????20 ????20 ????30
Purified Water ????98.5 ????45 ????90 ????77 ????77 ????77 ????77 ????77 ????77
????????????????????a/b ????1/2 ????1/10 ????1/1 ????0 ????0 ????0 ????0 ????0 ????0
Estimate Alveolar substance ????× ????△ ????× ????× ????× ????× ????× ????△ ????○
Stick-slip sense ????△ ????× ????△ ????× ????△ ????△ ????× ????× ????×
As shown in Table 5: the cleanser compositions of embodiments of the invention 17～32 is the cleanser compositions with excellent alveolar substance and usability.And the cleanser compositions of embodiment 17～32 is also very little to the pungency of skin
As shown in Table 6: in the comparative example 12 since (b) content of composition less than 2 weight %, so alveolar substance is poor; In the comparative example 13 and since (b) content of composition greater than 40 weight %, so usability is poor; In the comparative example 14, because (a)/(b) greater than 1/2, so alveolar substance is poor; In the comparative example 15, owing to used R 1The few comparison composition C-1 of acyl group carbonatoms, so alveolar substance difference and stick-slip sense is arranged; In the comparative example 16, owing to used R 1The many comparison composition C-2 of acyl group carbonatoms, so alveolar substance is poor; In the comparative example 17, owing to used the many comparison composition C-3 of addition mole number of butylene oxide ring, so alveolar substance is poor; In the comparative example 18, the comparison composition C-4 owing to having used without the butylene oxide ring addition so alveolar substance is poor, and has stick-slip sense; In the comparative example 19, owing to use the many comparison composition C-5 of oxyethane addition mole number, so usability is poor; In the comparative example 18, owing to used the lauric acid diethanolamine, so stick-slip sense is arranged; In comparative example 20, because use is as the lauric acid diethyl amide of fatty acid alkyl amide, so stick-slip sense is strong.
Industrial applicability
Even a small amount of interpolation of thickener of the present invention also demonstrates significant thickening effect, so be effective thickener for surface active agent; And in the time of in using it for cleanser compositions, can obtain having appropriate viscosity, alveolar substance is good, the cleanser compositions of no stick-slip sense.

Claims (4)

1. the thickener for surface active agent shown in the following general formula (1),
R 1O(EO) x(BO) y(EO) zH???????????(1)
In the formula, R 1Expression is selected from the group of alkyl, alkenyl and the acyl group of carbonatoms 8～14, EO representative ring oxidative ethane, and BO represents butylene oxide ring, x, y and z represent average addition mole number respectively, wherein, 0≤x≤3,1≤y≤3,0≤z≤3,0≤x+z≤3.
2. the thickener for surface active agent shown in the following general formula (2),
R 1O(BO) yH??????????????????????(2)
In the formula, R 1Expression is selected from the group of alkyl, alkenyl and the acyl group of carbonatoms 8～14, and BO represents butylene oxide ring, and y represents average addition mole number, wherein, and 1≤y≤3.
3. cleanser compositions, it is characterized in that, contain the claim 1 of 0.5～10 weight % or the tensio-active agent of 2 described thickener for surface active agent and 2～40 weight %, described thickener for surface active agent and described tensio-active agent contain ratio in weight ratio, be 1/30～1/2.
4. cleanser compositions as claimed in claim 3; it is characterized in that described tensio-active agent is selected from least a in sulfate type anion surfactant, sulfonate type anion surfactant, acyl amino acid type anion surfactant and the alkyl imino dicarboxylic ester type amphoterics.
CNB2004101012159A 2003-12-15 2004-12-15 Thickener for surface active agent and cleanser compositions Active CN100558870C (en)

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Publication number Priority date Publication date Assignee Title
CN102438446A (en) * 2009-04-23 2012-05-02 先正达有限公司 Alcohol alkoxylates as adjuvants for agrochemical formulations

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JP2001334139A (en) 2000-05-30 2001-12-04 Nof Corp Surfactant and detergent composition containing the same
JP2003013099A (en) 2001-06-29 2003-01-15 Lion Corp Method for stabilizing high-concentrated aqueous liquid detergent composition and high-concentrated aqueous liquid detergent composition
JP2003226900A (en) * 2002-02-04 2003-08-15 Nof Corp Liquid detergent composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102438446A (en) * 2009-04-23 2012-05-02 先正达有限公司 Alcohol alkoxylates as adjuvants for agrochemical formulations

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