CN1618471A - Non-urens type liquid adhesive tape - Google Patents
Non-urens type liquid adhesive tape Download PDFInfo
- Publication number
- CN1618471A CN1618471A CN 200410066117 CN200410066117A CN1618471A CN 1618471 A CN1618471 A CN 1618471A CN 200410066117 CN200410066117 CN 200410066117 CN 200410066117 A CN200410066117 A CN 200410066117A CN 1618471 A CN1618471 A CN 1618471A
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- CN
- China
- Prior art keywords
- urens
- adhesive tape
- type liquid
- liquid adhesive
- acid
- Prior art date
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- Medicinal Preparation (AREA)
Abstract
A liquid-type adhesive belt without irritation pain is prepared from the high-molecular material to become elastic film, volatile mixed solvent prepared from alkane and polydialkyl siloxane, and assistant. It has bactericiding, staltic, antalgic, antipruritic and healing-promoting functions.
Description
Technical field:
This utility model relates to a kind of Liplaster of protecting skin and the small-sized skin trauma of treatment.
Background technology:
Existing Liplaster, owing to reasons such as its compositions, the thin film that exist to form during use is difficult to evenly, the easy embrittlement of thin flexible film difference or easily be stained with ash, easy defective such as come off.
Summary of the invention:
The thin film pliability and the good springiness that form when the object of the present invention is to provide a kind of the use, non-fragile non-urens type liquid adhesive tape.
Technical solution of the present invention is:
A kind of non-urens type liquid adhesive tape is characterized in that: contain following weight composition:
Become the macromolecular material 1～40% of elastic film
Effumability mixed solvent 1～99%
Adjuvant 0～20%;
Wherein the effumability mixed solvent is made up of the alkane of 1～99% weight portion and many dialkylsiloxanes of 1～99% weight portion.
Adjuvant is antioxidant, antibacterial, coloring agent, fumet, infrared and ultraviolet absorber and has medicine and the additive of biological function or the like that object lesson has; Camphor, hydrocortisone, manganese alcohol, lidocaine hydrochloride, 2,4 ', 4 '-trichloro-2 '-hydroxydiphenylether benzalkonium chloride, ferrum oxide, coloring agent or spice etc.
Alkane is C
5～C
12Straight chain, side chain or annular alkane; Many dialkylsiloxanes are the siloxanes that contain 2～6 element silicons.
Many dialkylsiloxanes are hexamethyl disiloxane, prestox Fourth Ring siloxanes or octamethyltrisiloxane.
The macromolecular material that becomes elastic film is copolymer, vinyl-based alcoxyl silane or the vinyl-based alcoxyl silane and the non-siliceous monomolecular copolymer of copolymer, modified methyl acrylic and olefines of copolymer, modification acrylate and olefines of copolymer, methacrylate and olefines of copolymer, acrylate and the olefines of polyisobutylene, polyisobutylene.
Become the macromolecular material of elastic film to be made up of macromolecular material and salt or acid, the amount of salt or acid is 0.2～20% of macromolecular material amount by weight.Salt or acid are methacrylic acid, acrylic acid, maleic acid monoesters, fumaric monoalkylester, Ethenylbenzene formic acid, vinyl benzenesulfonic acid or their salt.Salt that adds and acid can strengthen the caking ability of macromolecule membrane and human body surface skin and resist is stained with grey function.
Vinyl-based its chemical formula of alcoxyl silane is: CH
2=C (R
1) COOR
2SiR
3R
4R
5
R wherein
1=H, CH
3, CH
2COOR ', and R '=R
2SiR
3R
4R
5
R
2=alkyl;
R
3, R
4, R
5=alkyl or OSi (X)
3A, and X=alkyl or OSi (Y)
3, (wherein Y=alkyl).
Vinyl-based alcoxyl silane is 3-methacryl oxidation propyl group three (front three siloxanes) silane, 3-methacryl oxidation propyl group pentamethyl disiloxane, 3-acryloyl group oxidation propyl group methyl two even (trimethylsiloxy group) silane or 3-acryloyl group oxidation propyl group methyl three (trimethylsiloxy group) silane.
Non-siliceous unimolecule is one or more in methyl methacrylate, acrylic acid methyl ester., 2-Propenoic acid, 2-methyl-, octyl ester, 1-Octyl acrylate, 2-Propenoic acid, 2-methyl-, isooctyl ester, Isooctyl acrylate monomer, butyl acrylate, Isobutyl 2-propenoate, butyl methacrylate, isobutyl methacrylate, Hexyl 2-propenoate, Isohexyl acrylate., N-Hexyl methacrylate, 4-Methylpentyl methacrylate, alkene, styrene, the cinnamic derivant.
Non-siliceous unimolecule is by the polymerization unimolecule that hardness performance can be provided and can provide the combined polymerization unimolecule of softness to form.The methacrylate that can provide the polymerization unimolecule of hardness performance can adopt 1～4 carbon can provide the combined polymerization unimolecule of softness can adopt the acrylate of 6～12 carbon.
The thin film pliability and the good springiness that form when the present invention uses are difficult for embrittlement, and have no twinge, be not stained with ash, the suitable humidity of maintenance wound healing and have water proofing property, stop that antibacterial enters the characteristics of wound; The adjuvant that adds has and strengthens sterilization, hemostasis, pain relieving, antipruritic and promote the function of wound healing.
The invention will be further described below in conjunction with embodiment.
The specific embodiment:
Embodiment 1:
(1) makes into the macromolecular material of elastic film according to a conventional method; specifically can adopt following steps: on the high molecular weight reactive still of a 1000ml; add agitator; be heated to 100 at reactor; keep this temperature; and dash to change with nitrogen and stop heating after 20 minutes; after the temperature of reactor drops to room temperature; add 3-methacryl oxidation propyl group three (front three siloxanes) silane; methyl methacrylate (or methacrylate of other 1～4 carbon); Isooctyl acrylate monomer (or acrylate of other 6～12 carbon) and ethyl acetate solvent; reactant mixture is heated to 65 ℃ again; stir; add the fine radical initiator of azo isobutyl; keep stirring; after 24 hours; stop heating and reactant mixture is deposited in separation then in the methanol,, must become the macromolecular material of elastic film the material heat drying after separating.The amount of above-mentioned 3-methacryl oxidation propyl group three (front three siloxanes) silane, methyl methacrylate, Isooctyl acrylate monomer can prepare by amount ratio routinely; example: 3-methacryl oxidation propyl group three (front three siloxanes) silane, methyl methacrylate, Isooctyl acrylate monomer adopt 10%～80%, 10%～60%, 10%～60% (above-mentioned consumption is a weight, and three's sum is 100%) respectively.
(2) macromolecular material with the above-mentioned one-tenth elastic film that obtains joins alkane--isobutyltrimethylmethane. (or other C
5～C
12Straight chain, side chain, annular alkane) and many dialkylsiloxanes--in the mixed solvent of hexamethyl disiloxane (or prestox Fourth Ring siloxanes, octamethyltrisiloxane, other contain the siloxanes of 2～6 element silicons), stir, to dissolving, add adjuvant camphor (or hydrocortisone, manganese alcohol, lidocaine hydrochloride, 2 again, 4 ', 4 '-trichloro-2 '-hydroxydiphenylether benzalkonium chloride, ferrum oxide, coloring agent, spice), product.Probationary certificate, product have good durability and resist is stained with grey performance.The consumption of above-mentioned each component (by weight) is: become macromolecular material 1～40% (example 1%, 10%, 20%, 30%, 40%), alkane and many dialkylsiloxanes mixed solvent 1～99% (example 1%, 20%, 50%, 80%, 99%), the adjuvant 0.1～20% (example 0.1%, 5%, 10%, 15%, 20%) of elastic film, said components weight sum is 100%; Wherein alkane accounts for 1～99% (example 1%, 20%, 50%, 80%, 99%) of mixed solvent gross weight in alkane and the many dialkylsiloxanes mixed solvent, many dialkylsiloxanes account for 1～99% (example 1%, 20%, 50%, 80%, 99%) of mixed solvent gross weight, and both weight sums are 100%.
Embodiment 2:
Methyl methacrylate in embodiment 1 step (1) and Isooctyl acrylate monomer are replaced with acrylic acid methyl ester. (or 2-Propenoic acid, 2-methyl-, octyl ester, 1-Octyl acrylate, 2-Propenoic acid, 2-methyl-, isooctyl ester, butyl acrylate, Isobutyl 2-propenoate, butyl methacrylate, isobutyl methacrylate, Hexyl 2-propenoate, Isohexyl acrylate., N-Hexyl methacrylate, 4-Methylpentyl methacrylate, alkene, styrene, cinnamic derivant), and its consumption is methyl methacrylate and Isooctyl acrylate monomer consumption sum in embodiment 1 step (1), and all the other are all with embodiment 1.
Embodiment 3:
3-methacryl oxidation propyl group three (front three siloxanes) silane in embodiment 1 or 2 is connected (trimethylsiloxy group) silane or the replacement of 3-acryloyl group oxidation propyl group methyl three (trimethylsiloxy group) silane with 3-methacryl oxidation propyl group pentamethyl disiloxane or 3-acryloyl group oxidation propyl group methyl two; all the other form new embodiment again all with embodiment 1 or 2.
Embodiment 4:
The macromolecular material of the one-tenth elastic film among embodiment 1 or embodiment 2 or the embodiment 3 is directly used polyisobutylene (or copolymer of the copolymer of the copolymer of the copolymer of the copolymer of polyisobutylene, acrylate and olefines, methacrylate and olefines, modification acrylate and olefines, modified methyl acrylic and olefines), all the other form new embodiment again with embodiment 1,2,3.
Embodiment 5:
In the step (1) of embodiment 1; also add during polyreaction and be the methacrylic acid (or acrylic acid, maleic acid monoesters, fumaric monoalkylester, Ethenylbenzene formic acid, vinyl benzenesulfonic acid or their salt) of macromolecular material 3-methacryl oxidation propyl group three (front three siloxanes) silane amount 0.2～20% (example 0.2%, 5%, 10%, 15%, 20%) by weight; all the other form new embodiment again all with embodiment 1.
Claims (10)
1, a kind of non-urens type liquid adhesive tape is characterized in that: contain following weight composition:
Become the macromolecular material 1～40% of elastic film
Effumability mixed solvent 1～99%
Adjuvant 0～20%;
Wherein the effumability mixed solvent is made up of the alkane of 1～99% weight portion and many dialkylsiloxanes of 1～99% weight portion.
2, non-urens type liquid adhesive tape according to claim 1, it is characterized in that: adjuvant is camphor, hydrocortisone, manganese alcohol, lidocaine hydrochloride, 2,4 ', 4 '-trichloro-2 '-hydroxydiphenylether benzalkonium chloride, ferrum oxide, coloring agent or spice.
3, non-urens type liquid adhesive tape according to claim 1 and 2 is characterized in that: alkane is C
5～C
12Straight chain, side chain or annular alkane; Many dialkylsiloxanes are the siloxanes that contain 2～6 element silicons.
4, non-urens type liquid adhesive tape according to claim 3 is characterized in that: many dialkylsiloxanes are hexamethyl disiloxane, prestox Fourth Ring siloxanes or octamethyltrisiloxane.
5, non-urens type liquid adhesive tape according to claim 1 and 2 is characterized in that: the macromolecular material that becomes elastic film is copolymer, vinyl-based alcoxyl silane or the vinyl-based alcoxyl silane and the non-siliceous monomolecular copolymer of copolymer, modified methyl acrylic and olefines of copolymer, modification acrylate and olefines of copolymer, methacrylate and olefines of copolymer, acrylate and the olefines of polyisobutylene, polyisobutylene.
6, non-urens type liquid adhesive tape according to claim 5 is characterized in that: become the macromolecular material of elastic film to be made up of macromolecular material and salt or acid, the amount of salt or acid is 0.2～20% of macromolecular material amount by weight.
7, non-urens type liquid adhesive tape according to claim 5 is characterized in that: salt or acid are methacrylic acid, acrylic acid, maleic acid monoesters, fumaric monoalkylester, Ethenylbenzene formic acid, vinyl benzenesulfonic acid or their salt.
8, non-urens type liquid adhesive tape according to claim 5 is characterized in that: vinyl-based alcoxyl silane is 3-methacryl oxidation propyl group three (front three siloxanes) silane, 3-methacryl oxidation propyl group pentamethyl disiloxane, 3-acryloyl group oxidation propyl group methyl two even (trimethylsiloxy group) silane or 3-acryloyl group oxidation propyl group methyl three (trimethylsiloxy group) silane.
9, non-urens type liquid adhesive tape according to claim 5 is characterized in that: non-siliceous unimolecule is one or more in methyl methacrylate, acrylic acid methyl ester., 2-Propenoic acid, 2-methyl-, octyl ester, 1-Octyl acrylate, 2-Propenoic acid, 2-methyl-, isooctyl ester, Isooctyl acrylate monomer, butyl acrylate, Isobutyl 2-propenoate, butyl methacrylate, isobutyl methacrylate, Hexyl 2-propenoate, Isohexyl acrylate., N-Hexyl methacrylate, 4-Methylpentyl methacrylate, alkene, styrene, the cinnamic derivant.
10, non-urens type liquid adhesive tape according to claim 5 is characterized in that: non-siliceous unimolecule is by the polymerization unimolecule that hardness performance can be provided and can provide the combined polymerization unimolecule of softness to form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410066117 CN1289153C (en) | 2004-12-06 | 2004-12-06 | Non-urens type liquid adhesive tape |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410066117 CN1289153C (en) | 2004-12-06 | 2004-12-06 | Non-urens type liquid adhesive tape |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1618471A true CN1618471A (en) | 2005-05-25 |
| CN1289153C CN1289153C (en) | 2006-12-13 |
Family
ID=34764842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410066117 Expired - Fee Related CN1289153C (en) | 2004-12-06 | 2004-12-06 | Non-urens type liquid adhesive tape |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1289153C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108785739A (en) * | 2018-08-13 | 2018-11-13 | 中国人民解放军南京军区福州总医院 | A kind of full-service fluid adhesive bandage and preparation method thereof |
| CN111714692A (en) * | 2020-07-07 | 2020-09-29 | 华熙生物科技股份有限公司 | Skin wound surface protection composition and preparation method thereof |
-
2004
- 2004-12-06 CN CN 200410066117 patent/CN1289153C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108785739A (en) * | 2018-08-13 | 2018-11-13 | 中国人民解放军南京军区福州总医院 | A kind of full-service fluid adhesive bandage and preparation method thereof |
| CN111714692A (en) * | 2020-07-07 | 2020-09-29 | 华熙生物科技股份有限公司 | Skin wound surface protection composition and preparation method thereof |
| CN111714692B (en) * | 2020-07-07 | 2022-04-15 | 华熙生物科技股份有限公司 | Skin wound surface protection composition and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1289153C (en) | 2006-12-13 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
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Granted publication date: 20061213 Termination date: 20101206 |