CN1613806A - Microcrystallizing glass for construction and produced from metal flume and its production - Google Patents

Microcrystallizing glass for construction and produced from metal flume and its production Download PDF

Info

Publication number
CN1613806A
CN1613806A CN 200410087656 CN200410087656A CN1613806A CN 1613806 A CN1613806 A CN 1613806A CN 200410087656 CN200410087656 CN 200410087656 CN 200410087656 A CN200410087656 A CN 200410087656A CN 1613806 A CN1613806 A CN 1613806A
Authority
CN
China
Prior art keywords
glass
construction
minutes
microcrystallizing
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN 200410087656
Other languages
Chinese (zh)
Other versions
CN1241856C (en
Inventor
刘军
徐长伟
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenyang Jianzhu University
Original Assignee
Shenyang Jianzhu University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenyang Jianzhu University filed Critical Shenyang Jianzhu University
Priority to CN 200410087656 priority Critical patent/CN1241856C/en
Publication of CN1613806A publication Critical patent/CN1613806A/en
Application granted granted Critical
Publication of CN1241856C publication Critical patent/CN1241856C/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/083—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound
    • C03C3/085—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal
    • C03C3/087—Glass compositions containing silica with 40% to 90% silica, by weight containing aluminium oxide or an iron compound containing an oxide of a divalent metal containing calcium oxide, e.g. common sheet or container glass
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0036—Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and a divalent metal oxide as main constituents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

A metal flume building microcrystalline glass and its production are disclosed. The base glass consists of SiO2 50-60wt%, Al2O3 6-9wt%, CaO 11-13wt%, MgO 3-8wt%, K2O+Na2O 3-8wt%, FeO+Fe2O3 2-8wt%. With TiO2 as crystal nucleus agent, the content of TiO2 is 2-4%, the content of Cr2O3 is 1-2%. Its advantages include low cost, and high mechanical strength, wear-resisting performance and corrosion resistance.

Description

Microcrystallizing glass for construction and produced from metal flume and preparation method thereof
Technical field
The present invention relates to a kind of building microcrystalline glass, particularly relate to a kind of with the industrial residue metal tailings as high-performance building devitrified glass of main raw material preparation and preparation method thereof, both belonged to the key technology that metal tailings utilizes, also belong to simultaneously a kind of high-grade construction decoration material, being mainly used in ground, decorating inner and external walls, partition and building block etc. in the building, is the best substitute of lithotome.
Background technology
At present, scorification is mostly adopted in the preparation that generally is used for the devitrified glass of building materials field, raw material is substantially based on the pure raw material of glass, the nucleus agent is all outer mixes, the principal crystalline phase of separating out is β-wollastonite, and this preparation method can make glass smelting temperature drift (about 1600 ℃), difficult forming, product cost is higher, and this also is one of outstanding problem that still exists in devitrified glass research and the production field.For this reason, many investigators have carried out the research that other approach prepare building microcrystalline glass.From starting material, beginning is by adopting the pure raw material of glass to developing for the main raw material direction with the industrial residue; On technology, develop to sol-gel novel process direction by traditional scorification.Aspect the research for preparing building microcrystalline glass with industrial residue as main raw material, a large amount of research is to concentrate on several industrial residues such as mine tailing, flyash, coal gangue and slag, but no matter adopt which kind of industrial residue, from the principal crystalline phase of separating out, remain β-wollastonite, recrystallization temperature is higher, and product cost is higher.Sol-gel technology is the focus in current silicate and the glasswork, and its technical process is:
Compare with traditional scorification, the advantage that adopts sol-gel technology to prepare building microcrystalline glass is: can prepare high strength and highly purified material under lower temperature, and can enlarge compositing range.But the greatest problem that this method exists also is an open question still now, promptly prepares block gel difficulty by colloidal sol, and the problem that particularly ftractures is still unresolved.Therefore, sol-gel method prepares the technology prematurity still of building microcrystalline glass, and suitability for industrialized production still is unrealized.This shows, can replace the pure raw material of glass with industrial residue, traditional suitability for industrialized production scorification for many years of realizing is improved, particularly solve the glass melting temperature height, the problem of difficult forming with further reduction product cost, increases the market competitiveness, expanding the scale of production is the most real feasible approach, also is simultaneously to realize economic benefit, social benefit and the most significant effective way of environmental benefit.
Summary of the invention
The objective of the invention is to solve present scorification and prepare ubiquitous glass melting temperature height in the building microcrystalline glass, difficult forming, thereby cause energy consumption to increase, finally make key technical problems such as product cost raising, improve by research, provide a kind of novel high-performance building devitrified glass, this kind building microcrystalline glass is as main raw material with metal tailings, adopt compound nucleus agent (major ingredient is taken from the agent of part nucleus), the principal crystalline phase of separating out is a diopside, can make glass melting temperature reduce to 1400～1450 ℃ from about 1600 ℃, and the crystallization rate of goods improves, and product has high physical strength, good wear resistance, erosion resistance and fastness to efflorescence.
The technical solution that the present invention provides is: the main chemical compositions of metal tailings is SiO 2, Al 2O 3, CaO, MgO, satisfy the chemical ingredients requirement of preparation glass, can be used as the raw material of preparation devitrified glass, and, product cost is reduced significantly because of metal tailings is an industrial residue.By adopting the compound of nucleus agent that lattice parameter and diopside be complementary and nucleus agent, making traditional building materials field separate out β-wollastonite with devitrified glass is principal crystalline phase, change into and separate out a kind of principal crystalline phase-diopside lower than wollastonite recrystallization temperature, paracrystalline phase is a wollastonite, can reduce glass melting temperature on the one hand, because of diopside has good fastness to efflorescence and high physical strength, product performance are improved on the other hand.The main composition of Microcrystallizing glass for construction and produced from metal flume comprises metal tailings, adjusts oxide compound and nucleus agent, and its characteristics are to adopt compound nucleus agent, and the agent of part nucleus takes from major ingredient, and by massfraction, the chemical constitution of its parent glass is: SiO 250～60%; Al 2O 36～%; CaO 11～13%; MgO3～8%; K 2O+Na 2O 3～8%; FeO+Fe 2O 32～8%.With TiO 2And Cr 2O 3Do the nucleus agent, TiO 2Content is 2～4%, Cr 2O 3Content is 1～2%.
The preparation technology of the Microcrystallizing glass for construction and produced from metal flume that the present invention provides is:
The present invention at first makes compound with metal tailings, adjustment oxide compound, nucleus agent behind mixing, grinding (granularity 200-300 order), with the compound fusion, temperature is 1400～1450 ℃, and soaking time is 0.5～1 hour; Anneal then, temperature is 680～700 ℃, and soaking time is 15～30 minutes; Carry out coring again and handle, temperature is 750～770 ℃ (are raw material with torticollis mountain iron tailings) or 850～870 ℃ (is raw material with the Xincheng Gold Mine mine tailing), and soaking time is 60～75 minutes; Then carry out crystallization and handle, temperature is 810～830 ℃ (are raw material with torticollis mountain iron tailings) or 890～910 ℃ (is raw material with the Xincheng Gold Mine mine tailing), and soaking time is 75～90 minutes; After naturally cooling (air cooling), polish at last, cut finished product.
The raw material of this high-performance metal tailings construction nucleated glass is formed and to be pressed massfraction and can be torticollis mountain iron tailings 60～65%; Rhombspar 3～%; Wingdale 10～15%; Kaolin 5～8%; K 2SO 42～4%; K 2CrO 43～5%; ZnO 0.5～1.0%; CaF 20.5～1.0%; S+C 0.5～1.0%; Bone meal 0.5～1.0%; TiO 21.5～3.5%.
The raw material of this high-performance metal tailings construction nucleated glass is formed and to be pressed massfraction and can be Xincheng Gold Mine mine tailing 60～65%; Rhombspar 6～9%; Wingdale 10～14%; Feldspar 3～5%; K 2SO 42～4%; K 2CrO 43～5%; ZnO 0.5～1.0%; CaF 20.5～1.0%; S+C 0.5～1.0%; Bone meal 0.5～1.0%; Sodium tetraborate 0.8～1.2%; TiO 21.5～2%.
Compared with prior art, the beneficial effect of this Microcrystallizing glass for construction and produced from metal flume that the present invention provides is: the glass smelting temperature can be reduced to 1400～1450 ℃ from 1600 ℃, greatly reduce energy consumption, thereby reduced product cost significantly; Major ingredient is partly taken from the nucleus agent, has reduced the outer consumption of mixing the nucleus agent, can further reduce product cost; Separating out with the diopside is the devitrified glass of principal crystalline phase, and physical strength, wear resistance, erosion resistance, the fastness to efflorescence of devitrified glass are further improved; Utilize the industrial residue metal tailings in a large number, the metal tailings volume reaches more than 65% (massfraction) in the batching, and the exploitation secondary resource reduces environmental pollution, environmental benefit and obvious social benefit; Easy construction, the construction loss is little.
Embodiment
Below in conjunction with embodiment concrete technical scheme of the present invention is described further:
Embodiment 1
Present embodiment provides a kind of high-performance metal tailings construction nucleated glass, and its raw material consists of torticollis mountain iron tailings, adjusts oxide compound and TiO 2And Cr 2O 3Compound nucleus agent, wherein the add-on of each constitutive material is (massfraction): torticollis mountain iron tailings 65%; Rhombspar 3%; Wingdale 14%; Kaolin 7%; K 2SO 43%; K 2CrO 43.1%; ZnO 0.9%; CaF 20.7%; S+C 0.9%; Bone meal 0.6%; TiO 21.8%.Acting as of each component: torticollis mountain iron tailings is basic raw material of producing building microcrystalline glass, and SiO mainly is provided 2, Al 2O 3, chemical ingredientss such as CaO, MgO; Rhombspar mainly is the deficiency of MgO in the compensating bar mine tailing; Wingdale mainly is the deficiency of CaO in the compensating bar mine tailing; Kaolin mainly is Al in the compensating bar mine tailing 2O 3Deficiency; K 2SO 4Mainly provide K 2O is to promote the formation of microlitic structure; K 2CrO 4Mainly provide Cr 2O 3, as the nucleus agent; ZnO realizes micritization when the less nucleus agent volume in order to guarantee; CaF 2Mainly be in order to reduce crystallization activation energy, to promote crystallization; The effect of S and C is for FeO in the feed glass and Fe 2O 3Ratio, and keep certain sulfide content, promote micritization; Bone meal mainly provides P 2O 5, with the reinforcing glass stability of network.
The chemical ingredients of described torticollis mountain iron tailings is (massfraction): SiO 279.10%, Al 2O 32.98%, Fe 2O 35.30%, FeO 4.32%, and CaO 3.40%, and MgO 3.87%, Na 2O 0.43%, K 2O 0.60%.
The chemical ingredients of described rhombspar is (massfraction): CaO 30%, and MgO 22%, SiO 24.0%, Al 2O 33.0%, Fe 2O 30.15%, loss on ignition is 40.85%, i.e. CO 2Loss.
Described kaolinic chemical ingredients is (massfraction): SiO 246.51%, Al 2O 339.53%, H 2O13.96%.
Described bone meal main chemical compositions is (massfraction): CaO 53.42%, P 2O 544.60%, SiO 20.90%, Al 2O 30.34%, Fe 2O 30.12%, MgO 0.62%.
The optimised process process of torticollis mountain iron tailings building microcrystalline glass is: metal tailings, adjustment oxide compound, nucleus agent are made admixtion through combined grinding (granularity 200-300 order), the batch melting heat-up rate is 6 ℃/min, 1450 ℃ of temperature of fusion, be incubated 30 minutes, 680 ℃ of annealing temperatures, be incubated 30 minutes, 760 ℃ of nucleation temperatures, be incubated 75 minutes, 820 ℃ of crystallization temperatures, soaking time 75 minutes, the heat-up rate that is risen to crystallization temperature by nucleation temperature is 3 ℃/min, the devitrified glass of acquisition consist of (massfraction): SiO 258.2%, Al 2O 37.4%, Fe 2O 33.9%, FeO 3.1%, and CaO 12.5%, and MgO 4.0%, K 2O 3.9%, and ZnO 1.0%, CaF 20.8%, S+C 1.0%, Cr 2O 32.0%, TiO 22.0%, P 2O 50.2%.
The physical and chemical index of gained devitrified glass is as follows: density 2.65g/cm 3, water-intake rate 0%, Mohs' hardness 6.0, flexural strength 90～110MPa, acid resistance (1%H 2SO 4) 0.02, alkali resistance (1%NaOH) 0.01, glossiness 90～100.
Embodiment 2
Difference from Example 1 is:
Present embodiment provides a kind of high-performance metal tailings construction nucleated glass, and its raw material consists of the Xincheng Gold Mine mine tailing, adjusts oxide compound and TiO 2And Cr 2O 3Compound nucleus agent, wherein the add-on of each constitutive material is (massfraction): Xincheng Gold Mine mine tailing 65%; Rhombspar 8%; Wingdale 12%; Feldspar 3%; K 2SO 42.6%; K 2CrO 43.5%; ZnO 0.9%; CaF 20.7%; S+C 0.9%; Bone meal 0.6%; Sodium tetraborate 1.0%; TiO 21.8%.Wherein, the Xincheng Gold Mine mine tailing is basic raw material of producing building microcrystalline glass, and SiO mainly is provided 2, Al 2O 3, chemical ingredientss such as CaO, MgO; Feldspar mainly is the SiO that proofreaies and correct in the gold mine tailings 2And Al 2O 3The effect of sodium tetraborate provides Na on the one hand 2O to keep the glass principal crystalline phase constant, improves glasswork and crystallization characteristic, provides B on the other hand 2O 3, can reduce the fusion clarifying temp, reduce melt viscosity.
The chemical ingredients of described Xincheng Gold Mine mine tailing is (massfraction): SiO 278.23%, Al 2O 310.88%, Fe 2O 31.65%, FeO 0.32%, and CaO 1.37%, and MgO 1.14%, K 2O 4.31%, Na 2O 1.69%, and ZnO 0.18%, and PbO 0.23%.
Described feldspar is an albite, and its chemical ingredients is (massfraction): SiO 272.66%, Al 2O 315.79%, Fe 2O 30.48%, CaO 1.23%, K 2O 0.74%, Na 2O 8.70%, TiO 20.4%.
The optimised process process of Xincheng Gold Mine tailings construction nucleated glass is: metal tailings, adjustment oxide compound, nucleus agent are made admixtion through combined grinding (granularity 200-300 order), the batch melting heat-up rate is 6 ℃/min, 1400 ℃ of temperature of fusion, be incubated 60 minutes, 700 ℃ of annealing temperatures, be incubated 15 minutes, 857 ℃ of nucleation temperatures, be incubated 60 minutes, 900 ℃ of crystallization temperatures, soaking time 90 minutes, the heat-up rate that is risen to crystallization temperature by nucleation temperature is 5 ℃/min, the devitrified glass of acquisition consists of (massfraction): SiO 259.4%, Al 2O 38.8%, Fe 2O 32.2%, CaO 11.6%, and MgO 3.1%, K 2O 6.5%, Na 2O 1.0%, and ZnO 1.0%, CaF 20.8%, S+C 1.0%, Cr 2O 32.0%, TiO 22.0%, P 2O 50.3%, B 2O 30.3%.
The physical and chemical index of gained devitrified glass is as follows: density 2.7g/cm 3, water-intake rate 0%, Mohs' hardness 6.5, flexural strength 100～120MPa, acid resistance (1%H 2SO 4) 0.01, alkali resistance (1%NaOH) 0.01, glossiness 95～100.
Embodiment 3
Be with embodiment 1 and example 2 differences:
Present embodiment provides a kind of high-performance metal tailings construction nucleated glass, and its raw material consists of torticollis mountain iron tailings, adjusts oxide compound and TiO 2And Cr 2O 3Compound nucleus agent, wherein the add-on of each constitutive material is (massfraction): torticollis mountain iron tailings 61%; Rhombspar 5%; Wingdale 15%; Kaolin 8%; K 2SO 42.3%; K 2CrO 42.0%; ZnO 0.9%; CaF 20.9%; S+C 0.9%; Bone meal 0.5%; TiO 23.5%.
The optimised process process of the building microcrystalline glass of this compositing formula is: metal tailings, adjustment oxide compound, nucleus agent are made admixtion through combined grinding (granularity 200-300 order), the batch melting heat-up rate is 5 ℃/min, 1420 ℃ of temperature of fusion, be incubated 45 minutes, 700 ℃ of annealing temperatures, be incubated 25 minutes, 770 ℃ of nucleation temperatures, be incubated 75 minutes, 830 ℃ of crystallization temperatures, soaking time 75 minutes, the heat-up rate that is risen to crystallization temperature by nucleation temperature is 4 ℃/min, the devitrified glass of acquisition consist of (massfraction): SiO 256.5%, Al 2O 36.2%, Fe 2O 33.7%, FeO 3.0%, and CaO 12.9%, and MgO 4.4%, K 2O 3.9%, and ZnO 1.0%, CaF 21.0%, S+C 1.0%, Cr 2O 32.0%, TiO 24.0%, P 2O 50.4%.
The physical and chemical index of gained devitrified glass is as follows: density 2.66g/cm 3, water-intake rate 0%, Mohs' hardness 6.2, flexural strength 90～110MPa, acid resistance (1%H 2SO 4) 0.02, alkali resistance (1%NaOH) 0.01, glossiness 95～100.
In concrete production process, because the metal tailings chemical ingredients difference in the different places of production of different kinds of metals mine tailing and same class, therefore in order to satisfy the requirement of producing, need be at the chemical ingredients of used metal tailings, adopt suitable adjustment oxide compound to be adjusted, make the chemical constitution of parent glass satisfy SiO 250～50%; Al 2O 36～9%; CaO 11～13%; MgO 3～8%; K 2O+Na 2O 3～8%; FeO+Fe 2O 32～8% requirement.In addition also can be by the product specified property to separating out principal crystalline phase kind requirement, by adopting the compound purpose that reaches the predetermined prod performance between suitable nucleus agent and the nucleus agent.
The Microcrystallizing glass for construction and produced from metal flume that the present invention provides is in application, and is identical with granitic constructional method with the lithotome marble, and the application scenario is that construction part is also identical, no particular requirement.

Claims (5)

1. Microcrystallizing glass for construction and produced from metal flume is characterized in that the parent glass composition by massfraction, comprising: SiO 250～60%; Al 2O 36～9%; CaO 11～13%; MgO 3～8%; K 2O+Na 2O 3～8%; FeO+Fe 2O 32～8%, with TiO 2And Cr 2O 3Do the nucleus agent, TiO 2Content is 2～4%, Cr 2O 3Content is 1～2%.
2. Microcrystallizing glass for construction and produced from metal flume according to claim 1 is characterized in that the raw material composition of this high-performance metal tailings construction nucleated glass by massfraction is: torticollis mountain iron tailings 60～65%; Rhombspar 3～6%; Wingdale 10～15%; Kaolin 5～8%; K 2SO 42～4%; K 2CrO 43～5%; ZnO 0.5～1.0%; CaF 20.5～1.0%; S+C 0.5～1.0%; Bone meal 0.5～1.0%; TiO 21.5～3.5%.
3. Microcrystallizing glass for construction and produced from metal flume according to claim 1 is characterized in that the raw material composition of this high-performance metal tailings construction nucleated glass by massfraction is: Xincheng Gold Mine mine tailing 60～65%; Rhombspar 6～9%; Wingdale 10～14%; Feldspar 3～5%; K 2SO 42～4%; K 2CrO 43～5%; ZnO 0.5～1.0%; CaF 20.5～1.0%; S+C 0.5～1.0%; Bone meal 0.5～1.0%; Sodium tetraborate 0.8～1.2%; TiO 21.5～2%.
4. the preparation method of Microcrystallizing glass for construction and produced from metal flume according to claim 2 is characterized in that the technological process of torticollis mountain iron tailings building microcrystalline glass is:
The batch melting heat-up rate is 5～6 ℃/min, 1400～1450 ℃ of temperature of fusion, be incubated 30～60 minutes, 680～700 ℃ of annealing temperatures, soaking time are 15～30 minutes, 750～770 ℃ of nucleation temperatures, be incubated 60～75 minutes, 810～830 ℃ of crystallization temperatures, soaking time 75～90 minutes, the heat-up rate that is warming up to crystallization temperature by nucleation temperature is 3～5 ℃/min.
5, the preparation method of Microcrystallizing glass for construction and produced from metal flume according to claim 3 is characterized in that the technological process of Xincheng Gold Mine tailings construction nucleated glass is:
The batch melting heat-up rate is 5～6 ℃/min, 1400～1450 ℃ of temperature of fusion, be incubated 60～75 minutes, 680～700 ℃ of annealing temperatures, soaking time are 15～30 minutes, 850～870 ℃ of nucleation temperatures, be incubated 60～75 minutes, 890～910 ℃ of crystallization temperatures, soaking time 75～90 minutes, the heat-up rate that is warming up to crystallization temperature by nucleation temperature is 3～5 ℃/min.
CN 200410087656 2004-11-24 2004-11-24 Microcrystallizing glass for construction and produced from metal flume and its production Expired - Fee Related CN1241856C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410087656 CN1241856C (en) 2004-11-24 2004-11-24 Microcrystallizing glass for construction and produced from metal flume and its production

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200410087656 CN1241856C (en) 2004-11-24 2004-11-24 Microcrystallizing glass for construction and produced from metal flume and its production

Publications (2)

Publication Number Publication Date
CN1613806A true CN1613806A (en) 2005-05-11
CN1241856C CN1241856C (en) 2006-02-15

Family

ID=34766060

Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200410087656 Expired - Fee Related CN1241856C (en) 2004-11-24 2004-11-24 Microcrystallizing glass for construction and produced from metal flume and its production

Country Status (1)

Country Link
CN (1) CN1241856C (en)

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417303A (en) * 2011-08-06 2012-04-18 蚌埠玻璃工业设计研究院 Glass batch containing synthesized diopside
CN102807324A (en) * 2012-09-05 2012-12-05 北京大有盛和科技有限公司 Natural-hetian-jade-imitated glass ceramics and preparation method for same
CN103214192A (en) * 2013-04-17 2013-07-24 内蒙古科技大学 Industrial wearable anti-corrosion glass ceramic composite bent pipe and manufacturing method thereof
CN103396002A (en) * 2013-08-01 2013-11-20 魏健 Metal tailing glass fiber and preparation method thereof
CN103553342A (en) * 2013-10-09 2014-02-05 浙江大学 Glass ceramic board for industrial protection and preparation method thereof
CN103864309A (en) * 2014-01-25 2014-06-18 浙江大学 Method of preparing high-strength wear-resisting glass ceramics by utilizing iron tailings
CN105347684A (en) * 2015-11-26 2016-02-24 上海宝田新型建材有限公司 Blast-furnace-slag glass ceramics and preparation method therefor
CN105565671A (en) * 2016-01-22 2016-05-11 邢台市晶玉微晶板材有限公司 Method for preparing microcrystalline glass from iron tailings
CN106746681A (en) * 2017-01-12 2017-05-31 丰城铭雪智能环保装饰材料有限公司 Wear-resistant glass-ceramics prepared by a kind of use trade waste
CN108558217A (en) * 2018-07-03 2018-09-21 四川名微晶科技股份有限公司 A method of devitrified glass is prepared with titanium slag tailings collaboration granite tailing
CN112266172A (en) * 2020-10-30 2021-01-26 王庆乐 Process for producing microcrystalline glass by using metal ore tailings
CN114573227A (en) * 2022-03-22 2022-06-03 洛阳理工学院 Calendered photovoltaic glass clarifying agent and application thereof
CN117185663A (en) * 2023-09-27 2023-12-08 江苏载彤新材料股份有限公司 Method for preparing microcrystalline glass from pyroxene tailings

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101298366B (en) * 2008-07-04 2011-06-15 沈阳建筑大学 Metal tailings construction nucleated glass and one-step sintering preparation thereof

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417303A (en) * 2011-08-06 2012-04-18 蚌埠玻璃工业设计研究院 Glass batch containing synthesized diopside
CN102807324A (en) * 2012-09-05 2012-12-05 北京大有盛和科技有限公司 Natural-hetian-jade-imitated glass ceramics and preparation method for same
CN103214192A (en) * 2013-04-17 2013-07-24 内蒙古科技大学 Industrial wearable anti-corrosion glass ceramic composite bent pipe and manufacturing method thereof
CN103214192B (en) * 2013-04-17 2015-05-20 内蒙古科技大学 Industrial wearable anti-corrosion glass ceramic composite bent pipe and manufacturing method thereof
CN103396002A (en) * 2013-08-01 2013-11-20 魏健 Metal tailing glass fiber and preparation method thereof
CN103553342B (en) * 2013-10-09 2015-10-28 浙江大学 Industrial protection glass-ceramic sheet material and preparation method thereof
CN103553342A (en) * 2013-10-09 2014-02-05 浙江大学 Glass ceramic board for industrial protection and preparation method thereof
CN103864309B (en) * 2014-01-25 2016-01-20 浙江大学 Iron tailings is utilized to prepare the method for high-strength wearable devitrified glass
CN103864309A (en) * 2014-01-25 2014-06-18 浙江大学 Method of preparing high-strength wear-resisting glass ceramics by utilizing iron tailings
CN105347684A (en) * 2015-11-26 2016-02-24 上海宝田新型建材有限公司 Blast-furnace-slag glass ceramics and preparation method therefor
CN105347684B (en) * 2015-11-26 2018-07-27 上海宝田新型建材有限公司 A kind of blast furnace slag glass ceramics and preparation method thereof
CN105565671A (en) * 2016-01-22 2016-05-11 邢台市晶玉微晶板材有限公司 Method for preparing microcrystalline glass from iron tailings
CN106746681A (en) * 2017-01-12 2017-05-31 丰城铭雪智能环保装饰材料有限公司 Wear-resistant glass-ceramics prepared by a kind of use trade waste
CN108558217A (en) * 2018-07-03 2018-09-21 四川名微晶科技股份有限公司 A method of devitrified glass is prepared with titanium slag tailings collaboration granite tailing
CN112266172A (en) * 2020-10-30 2021-01-26 王庆乐 Process for producing microcrystalline glass by using metal ore tailings
CN114573227A (en) * 2022-03-22 2022-06-03 洛阳理工学院 Calendered photovoltaic glass clarifying agent and application thereof
CN114573227B (en) * 2022-03-22 2024-02-20 洛阳理工学院 Calendaring photovoltaic glass clarifying agent and application thereof
CN117185663A (en) * 2023-09-27 2023-12-08 江苏载彤新材料股份有限公司 Method for preparing microcrystalline glass from pyroxene tailings
CN117185663B (en) * 2023-09-27 2024-03-08 江苏载彤新材料股份有限公司 Method for preparing microcrystalline glass from pyroxene tailings

Also Published As

Publication number Publication date
CN1241856C (en) 2006-02-15

Similar Documents

Publication Publication Date Title
CN101298366B (en) Metal tailings construction nucleated glass and one-step sintering preparation thereof
CN1241856C (en) Microcrystallizing glass for construction and produced from metal flume and its production
CN101439932B (en) Low-expansion glass-ceramics with lithia ore tailings as principal raw material and manufacturing method thereof
CN102690059B (en) Aluminosilicate glass for chemical tempering and glass ceramics
CN101066837B (en) Environment friendly heat resistant opal crystalline glass and its preparation process
CN1060456C (en) Fast-microcrystallized devitrified agrellite glass and its production process
CN114671618A (en) Microcrystalline glass, tempered glass, and preparation method and application thereof
CN101591144B (en) Thin-type CaO-Al2O3-SiO2 system glass ceramics and preparation
CN101759368B (en) Green glass-ceramic plate made from lead-zinc smelting slag and manufacturing method thereof
CN101857367A (en) Black glass ceramic and production method thereof
CN1246454A (en) Process for preparing decorative devitrified glass tile and its products
CN106082679B (en) A kind of method that full waste material short route prepares devitrified glass
CN101851064A (en) Blue glass ceramics and preparation method thereof
CN115286251A (en) Tempered glass, microcrystalline glass and preparation method and application thereof
CN112456793A (en) Lithium-aluminum silicate glass for float production
CN104108882A (en) Float microcrystalline glass and preparation method thereof
CA2664990A1 (en) Composition and methods of producing glass and glass-ceramic materials from manganese tailings
CN101774762B (en) Black microlite manufactured by using lead and zinc smelting dreg and manufacturing method thereof
CN105271764A (en) Low-energy-consumption building glass-ceramics prepared from iron tailings and preparation method of building glass-ceramics
CN114368914B (en) High-alumina microcrystalline glass with large amount of gangue and preparation method thereof
CN1209306C (en) Method for making composite type nucleated glass from flyash used in building
CN113461325B (en) Aluminum-silicon glass and preparation method and application thereof
CN110451793A (en) A kind of chemical strengthening glass and its preparation method and application
CN1066834A (en) The manufacture method of white series microlith glass high grade building material
CN114890679A (en) Tempered glass, phase-splitting glass, and preparation method and application thereof

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20060215

Termination date: 20141124

EXPY Termination of patent right or utility model