CN1611670A - Nitrilon fiber oil solution - Google Patents
Nitrilon fiber oil solution Download PDFInfo
- Publication number
- CN1611670A CN1611670A CN 200310108335 CN200310108335A CN1611670A CN 1611670 A CN1611670 A CN 1611670A CN 200310108335 CN200310108335 CN 200310108335 CN 200310108335 A CN200310108335 A CN 200310108335A CN 1611670 A CN1611670 A CN 1611670A
- Authority
- CN
- China
- Prior art keywords
- polyoxyethylene
- component
- weight meter
- ch2ch2o
- general formula
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
This invention is a Nitrilon cotton fiber oil solution that is an emulsion liquid allocated by the effective components and the water. The components are as followings: alkyl polyoxyethylene with the general formula [RIO(CH2CH2O)n]aPO(OH.M)b, M is triethanolamine salt; polyoxyethylene alkanol with the general formula R2O(CH2CH2O)nH; the polyoxyethylene fatty acid esters mixture with the general formulas R3CO2(CH2CH2O)nH and R3CO2(CH2CH2O)nO2CR3 the mixture of Span-80 and Tween-80; the mineral oil. The weight proportions of each component are: A: 1.6-2.4 shares, B: 0.2-1 share; C: 0.4-1.5 shares; E: 1 share. This oil solution is suitable for the two-step sodium acid sulfate wet spinning that is complicated. It will not only grant the fiber with excellent smoothness and antistatic quality, but also the relatively good binding capacity.
Description
Technical field
The present invention relates to a kind of acrylic cotton type fiber finish that contains antistatic additive and smooth agent, particularly antistatic additive is the acrylic staple fibre type short fiber oil of the triethanolamine salt of alkyl polyoxyethylene phosphate.
Background technology
The hygroscopicity of acrylic fibers is little, poorly conductive, coefficient of friction are big, so must be in spinning process by the effect of finish, elimination is because of fricative static, adjust coefficient of friction, make acrylic fibers have suitable convergence, flatness and fiber separation, thereby reach better spinnability is arranged, guarantee carrying out smoothly of acrylic fiber production process and back processing.
In addition, acrylic fibers are because of difference, the kind difference of production process route, requirement to finish is also different, continuous development along with acrylic fiber production process, the variation of finish raw material, the development of the industrialization of high-speed spinning, spinning technology and high added value fibre in differentiation, the prescription of polyacrylic fibre oil is developed to specialized direction by the universal of past, more emphasized the adaptability of finish, be beneficial to the raising of product quality various fiber species and production Technology.
In existing industrialization acrylic fiber production process, sodium sulfocyanate two step method wet method spinning process is adopted morely, compares the control that more is easy to get of its product quality with one-step method wet method spinning process.But sodium sulfocyanate two step method wet method spinning process is comparatively complicated, and it is higher to spin speed, therefore requires finish to possess better flatness and convergence, simultaneously antistatic behaviour is also had higher requirement.Especially for acrylic cotton type fiber, because fiber is thin, relative surface area is big, adherence is bigger, adds man-hour in weaving, and shredding is difficulty, easily twines cylinder in the comb and parallel cotton fibers prior to spinning process and around phenomenons such as rollers.
Existing all acrylic fibre finishings are used for sodium sulfocyanate two step method wet method and spin when producing cotton acrylic technology, and its effect is always not ideal enough.
Summary of the invention
The invention provides a kind of acrylic cotton type fiber finish, the technical problem that it will solve is that the requirement finish is more suitable for sodium sulfocyanate two step method wet method spinning process.
Below be the technical scheme that the present invention solves the problems of the technologies described above:
A kind of acrylic cotton type fiber finish, its emulsion for being mixed with by active ingredient and water, contain following component in the described effective ingredient:
Component A: triethanolamine salt with alkyl polyoxyethylene phosphate of following general formula
[R1O(CH
2CH
2O)
n]
aPO(OH·M)
b
Wherein: R1 is C
12～C
18Straight chained alkyl, M is a triethanolamine, the integer of n=0～6, a=1,2 or 3, b=0,1 or 2, a+b=3;
B component: fatty alcohol-polyoxyethylene ether with following general formula
R2O(CH
2CH
2O)
nH
Wherein: R2 is C
12～C
18Straight chained alkyl, the integer of n=3～12;
Component C: have following general formula (I) and polyoxyethylene fatty acid ester mixture (II):
R3CO
2(CH
2CH
2O)
nH (I)
R3CO
2(CH
2CH
2O)
nO
2CR3 (II)
Wherein: R3 is C
12～C
18Straight chained alkyl, the integer of n=6～20;
Component D: the mixture of this Pan 80 and Tween 80, this Pan 80: Tween 80=1: (1～9);
Component E: mineral oil;
The weight proportion of each component is: A:1.6～2.4 part, B:0.2～1 part, C:0.4～1.5 part, D:0.4～1 part, E:1 part.
Above-mentioned R1, R2 are preferably C
16～C
18Straight chained alkyl; R3 is preferably C
12～C
16Straight chained alkyl.
The component C polyoxyethylene fatty acid ester is polyoxyethylene fatty acid list/diester mixture, and they obtain by esterification usually, because esterification is reversible reaction, and the actual list/diester mixture that is of the esterification products that obtains
Content of effective and prior art are identical in the finish product emulsion; the suggestion of the active ingredient concentration of finishing bathtray emulsion is 1.5～3.0wt% during use; adding the suggestion of liquid emulsion active ingredient concentration is 8～10wt%; as long as therefore content of effective is higher than 10wt% in the finish product emulsion; but can be mixed with higher concentration usually, otherwise will increase the expense of packing and transportation.
Acrylic cotton type fiber finish provided by the invention be suitable for technical process comparatively complicated, spin the higher sodium sulfocyanate two step method wet method spinning process of speed, it not only can give good flatness of fiber and antistatic behaviour, can give convergence preferably simultaneously.
Below will the invention will be further described by specific embodiment.
The specific embodiment
[embodiment 1]
A:C
12-162 parts of alkyl polyoxyethylene phosphate triethanolamine salt weight meters
B:C
12-161 part of alkyl polyoxyethylene (12) ether weight meter
C: polyoxyethylene (20) C
12-180.4 part of fatty acid ester weight meter
D: 1 part of this Pan 80 and Tween 80 (1: 9) weight meter
E: 1 part of mineral oil weight meter
[embodiment 2]
A:C
16-181.6 parts of alkyl polyoxyethylene (1) phosphate triethanolamine salt weight meters
B:C
16-180.2 part of alkyl polyoxyethylene (3) ether weight meter
C: polyoxyethylene (10) C
12-181.5 parts of fatty acid ester weight meters
D: 0.4 part of this Pan 80 and Tween 80 (1: 1) weight meter
E: 1 part of mineral oil weight meter
[embodiment 3]
A:C
16-182.4 parts of alkyl polyoxyethylene (1) phosphate triethanolamine salt weight meters
B:C
16-180.3 part of alkyl polyoxyethylene (3) ether weight meter
C: polyoxyethylene (10) C
12-181.2 parts of fatty acid ester weight meters
D: 0.6 part of this Pan 80 and Tween 80 (1: 3) weight meter
E: 1 part of mineral oil weight meter
[embodiment 4]
A:C
16-181.8 parts of alkyl polyoxyethylene (1) phosphate triethanolamine salt weight meters
B:C
16-180.3 part of alkyl polyoxyethylene (3) ether weight meter
C: polyoxyethylene (9) C
12-181.2 parts of fatty acid ester weight meters
D: 0.8 part of this Pan 80 and Tween 80 (1: 5) weight meter
E: 1 part of mineral oil weight meter
[embodiment 5]
A:C
16-182 parts of alkyl polyoxyethylene (2) phosphate triethanolamine salt weight meters
B:C
16-180.6 part of alkyl polyoxyethylene (6) ether weight meter
C: polyoxyethylene (9) C
12-181 part of fatty acid ester weight meter
D: 0.6 part of this Pan 80 and Tween 80 (1: 3) weight meter
E: 1 part of mineral oil weight meter
[embodiment 6]
A:C
16-181.6 parts of alkyl polyoxyethylene (2) phosphate triethanolamine salt weight meters
B:C
16-180.5 part of alkyl polyoxyethylene (6) ether weight meter
C: polyoxyethylene (9) C
12-181 part of fatty acid ester weight meter
D: 1 part of this Pan 80 and Tween 80 (1: 3) weight meter
E: 1 part of mineral oil weight meter
[embodiment 7]
A:C
16-182.2 parts of alkyl polyoxyethylene (2) phosphate triethanolamine salt weight meters
B:C
16-180.7 part of alkyl polyoxyethylene (6) ether weight meter
C: polyoxyethylene (9) C
12-180.8 part of fatty acid ester weight meter
D: 0.7 part of this Pan 80 and Tween 80 (1: 6) weight meter
E: 1 part of mineral oil weight meter
[embodiment 8]
A:C
16-182.4 parts of alkyl polyoxyethylene (2) phosphate triethanolamine salt weight meters
B:C
16-180.8 part of alkyl polyoxyethylene (6) ether weight meter
C: polyoxyethylene (9) C
12-181.2 parts of fatty acid ester weight meters
D: 0.6 part of this Pan 80 and Tween 80 (1: 6) weight meter
E: 1 part of mineral oil weight meter
[embodiment 9]
A:C
16-182.4 parts of alkyl polyoxyethylene (3) phosphate triethanolamine salt weight meters
B:C
16-181 part of alkyl polyoxyethylene (12) ether weight meter
C: polyoxyethylene (6) C
12-180.6 part of fatty acid ester weight meter
D: 0.6 part of this Pan 80 and Tween 80 (1: 2) weight meter
E: 1 part of mineral oil weight meter
[embodiment 10]
A:C
16-181.8 parts of alkyl polyoxyethylene (3) phosphate triethanolamine salt weight meters
B:C
16-180.8 part of alkyl polyoxyethylene (12) ether weight meter
C: polyoxyethylene (6) C
12-180.5 part of fatty acid ester weight meter
D: 1 part of this Pan 80 and Tween 80 (1: 1) weight meter
E: 1 part of mineral oil weight meter
The finish of the foregoing description 1～10 preparation is prepared the finishing bathtray emulsion with 60 ℃ warm water, and concentration is controlled at 2 ± 0.5%.Be used for sodium sulfocyanate two step method wet method and spin the spin finishing of producing 1.65dtex * 38mm acrylic cotton type fiber, the fiber rate of oiling is controlled at 0.3 ± 0.1%.Fiber has all showed better spinnability and processing characteristics in spinning process and back process, and the fiber softening that makes is smooth, and feel is good.
Claims (3)
1, a kind of acrylic cotton type fiber finish, its emulsion for being mixed with by active ingredient and water, contain following component in the described effective ingredient:
Component A: triethanolamine salt with alkyl polyoxyethylene phosphate of following general formula
[R1O(CH
2CH
2O)
n]
aPO(OH·M)
b
Wherein: R1 is C
12～C
18Straight chained alkyl, M is a triethanolamine, the integer of n=0～6, a=1,2 or 3, b=0,1 or 2, a+b=3;
B component: fatty alcohol-polyoxyethylene ether with following general formula
R2O(CH
2CH
2O)
nH
Wherein: R2 is C
12～C
18Straight chained alkyl, the integer of n=3～12;
Component C: have following general formula (I) and polyoxyethylene fatty acid ester mixture (II):
R3CO
2(CH
2CH
2O)
nH (I)
R3CO
2(CH
2CH
2O)
nO
2CR3 (II)
Wherein: R3 is C
12～C
18Straight chained alkyl, the integer of n=6～20;
Component D: the mixture of this Pan 80 and Tween 80, this Pan 80: Tween 80=1: (1～9);
Component E: mineral oil;
The weight proportion of each component is: A:1.6～2.4 part, B:0.2～1 part, C:0.4～1.5 part, D:0.4～1 part, E:1 part.
2, acrylic cotton type fiber finish according to claim 1 is characterized in that described R1, R2 are C
16～C
18Straight chained alkyl.
3, acrylic cotton type fiber finish according to claim 1 is characterized in that described R3 is C
12～C
16Straight chained alkyl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310108335 CN1611670A (en) | 2003-10-31 | 2003-10-31 | Nitrilon fiber oil solution |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200310108335 CN1611670A (en) | 2003-10-31 | 2003-10-31 | Nitrilon fiber oil solution |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1611670A true CN1611670A (en) | 2005-05-04 |
Family
ID=34758562
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200310108335 Pending CN1611670A (en) | 2003-10-31 | 2003-10-31 | Nitrilon fiber oil solution |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1611670A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051813B (en) * | 2009-11-05 | 2012-09-26 | 上海多纶化工有限公司 | Cotton type acrylic fibers spinning oil |
| CN103174021A (en) * | 2013-03-20 | 2013-06-26 | 常州市灵达化学品有限公司 | Environment-friendly acrylic fiber oiling agent |
| CN104060468A (en) * | 2014-06-27 | 2014-09-24 | 安庆一枝梅化工有限责任公司 | Wet-process polyacrylonitrile fiber oil and preparation method thereof |
| CN104278517A (en) * | 2014-10-16 | 2015-01-14 | 河南瑞贝卡发制品股份有限公司 | After-finishing smoothing addition agent for artificially synthetic fibers and preparation and impregnation methods of after-finishing smoothing addition agent |
| CN104911915A (en) * | 2015-06-29 | 2015-09-16 | 宁波懋盛纺织助剂科技有限公司 | Polyester pre-orient yarn oiling agent |
-
2003
- 2003-10-31 CN CN 200310108335 patent/CN1611670A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102051813B (en) * | 2009-11-05 | 2012-09-26 | 上海多纶化工有限公司 | Cotton type acrylic fibers spinning oil |
| CN103174021A (en) * | 2013-03-20 | 2013-06-26 | 常州市灵达化学品有限公司 | Environment-friendly acrylic fiber oiling agent |
| CN103174021B (en) * | 2013-03-20 | 2014-11-19 | 常州市灵达化学品有限公司 | Environment-friendly acrylic fiber oiling agent |
| CN104060468A (en) * | 2014-06-27 | 2014-09-24 | 安庆一枝梅化工有限责任公司 | Wet-process polyacrylonitrile fiber oil and preparation method thereof |
| CN104060468B (en) * | 2014-06-27 | 2016-07-13 | 安庆一枝梅化工有限责任公司 | A kind of wet spinning acrylic fiber oil preparation and preparation method thereof |
| CN104278517A (en) * | 2014-10-16 | 2015-01-14 | 河南瑞贝卡发制品股份有限公司 | After-finishing smoothing addition agent for artificially synthetic fibers and preparation and impregnation methods of after-finishing smoothing addition agent |
| CN104278517B (en) * | 2014-10-16 | 2016-04-13 | 河南瑞贝卡发制品股份有限公司 | Artificial synthetic fiber Final finishing slip aids and preparation thereof, dipping method |
| CN104911915A (en) * | 2015-06-29 | 2015-09-16 | 宁波懋盛纺织助剂科技有限公司 | Polyester pre-orient yarn oiling agent |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101440574B (en) | Oil solution for spandex spinning by dry method, and preparation and use thereof | |
| CN86106153A (en) | Half transparent oil-covered water emulsion | |
| CN1086740A (en) | Composition based on absorbable precipitate SiO 2 | |
| CN1865454A (en) | Composite phosphate grease-adding agent for leather and its preparation method | |
| CN1287130A (en) | Polyorganosiloxane containing nitrogen atom its production and fibre and fabric finishing agent composition | |
| CN101050339A (en) | Diamond polishing paste in high purity, and preparation method | |
| CN101054773A (en) | Fortifying fiber auxiliary agent and manufacturing method thereof | |
| CN1611670A (en) | Nitrilon fiber oil solution | |
| CN1148481C (en) | Polypropylene fine denier short fiber oiling agent | |
| CN1611668A (en) | Nitrilon fiber oil solution | |
| CN1923354A (en) | Method for preparing nano hollow inorganic microsphere | |
| CN1896347A (en) | Anti-ultraviolet superfine terylene and its preparation | |
| EP1803777B1 (en) | Crosslinkable compositions based on organosilicon compounds | |
| CN1611669A (en) | Nitrilon fiber oil solution | |
| CN1923355A (en) | Method for preparing nano hollow inorganic microsphere | |
| CN1238081C (en) | High-temperature and strong alkali organic silicon antifoamer emulsion composition and preparing method thereof | |
| CN1844382A (en) | Method for preparing immobilized lipase attapulgite clay | |
| CN104060468B (en) | A kind of wet spinning acrylic fiber oil preparation and preparation method thereof | |
| CN1265409A (en) | Formulation and production process of multipurpose shoe cream | |
| CN1136353C (en) | Short-staple dacron oil solution suitable for great-capacity high-speed spinning | |
| CN1247518C (en) | Condensation products of hydroxycarboxylic acids and glycols or glycerol | |
| CN1150364C (en) | Oiling agent for acrylic staple fiber | |
| CN1282772A (en) | Dual-component structural adhesive of silicone for biuldings | |
| CN1306120A (en) | Dipping oil for increasing strength of raw silk | |
| CN113308765B (en) | Spinning oil for polyester staple fibers and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |