Allow the liquid lithium ionic cell of high current charge-discharge
The conduction that technical field the present invention relates to secondary cell connects and the electrode manufacturing, relate in particular to lithium ion battery just/negative plate THICKNESS CONTROL and pole piece on lug quantity and distribution mode thereof.
Background technology is along with portable high-performance electric tool and intelligent toy is universal day by day, owing to the requirement of portable dam to weight and continuous working period improves day by day, the lithium ion battery that possesses high-energy-density and high working voltage just has stronger competitiveness simultaneously.But the prior art lithium ion battery just/negative plate is general only with single lug projected current, and pole piece thickness δ is often much in 150 μ m and less than 300 μ m.Because nonaqueous electrolyte is than the restriction of low conductivity, its high rate charge-discharge performance is not good, majority can only be so that (C is the rated capacity of battery less than 3C, as C=800mAh, it promptly is that discharging current is taken as 2.4A that 3C leads discharge) electric current continuous operation discharge, spark with electric current, can't satisfy the continuous operation discharge of application needs 7C to 10C such as electric tool, the transient large current discharge requirement of 20C less than 10C.Therefore, field of power tools is captured by big reasonable Ni-MH of multiplying power discharging property (ni-mh) and Ni-Cd (NI-G) battery always, and the battery of other kinds is difficult to enter this field.
The summary of the invention the technical problem to be solved in the present invention is to avoid above-mentioned the deficiencies in the prior art part and proposes a kind of liquid lithium ionic cell manufacture method and battery structure that allows high current charge-discharge, can significantly improve described battery high rate charge-discharge performance, adopt the lithium ion battery of non-aqueous solution electrolysis plastidome electrolyte also can be applied to field of power tools thereby allow.
The present invention solve the technical problem the technical scheme that adopts to be, proposes a kind of liquid lithium ionic cell manufacture method that allows high current charge-discharge, comprises the steps:
A. by just/the lug number that increase to connect respectively on the negative plate, making it respectively is 2 to 5, just is being connected to/bear block then respectively, to reduce the electric current that each single lug flows through, the charging and discharging currents of raising battery permission;
B. by just reducing/negative plate on the active material coating thickness, be (70~150) μ m to control described each pole piece gross thickness δ, thus the internal resistance of cell during the reduction high current charge-discharge;
C. just described/negative plate is respectively with after separately lug is connected, and is separated by and, is wound into one and forms electric core up and down behind the align center around the volume pin by barrier film, stops by stopping adhesive tape.
The present invention solve the technical problem the technical scheme that adopts also further to comprise, designs and produces a kind of liquid lithium ionic cell that allows high current charge-discharge, and being separated by by barrier film based on positive plate and negative plate is wound as one, stops by stopping adhesive tape.Especially, having 2 to 5 anode ears evenly to distribute is connected on the length of run L of positive plate, also have 2 to 5 negative electrode lugs evenly to distribute and be connected on the length of run L of negative plate, and just described/negative electrode lug is connected with separately block, and just described/negative plate thickness δ is (70~150) μ m.
Compare with prior art, the advantage of the inventive method and battery is: by adopting multipole ear structure and significantly reduce positive/negative plate thickness on each pole piece of battery, thereby can allow described battery with high current charge-discharge, make it to be widely used in fields such as electric tool.
Description of drawings Fig. 1 is that the present invention allows the master of the liquid lithium ionic cell electricity core of high current charge-discharge to look schematic diagram;
Fig. 2 is the upward view of Fig. 1 battery battery core;
Fig. 3 is the vertical view of Fig. 1 battery battery core;
Fig. 4 is the schematic diagram that each lug of lithium ion battery of the present invention connects with block;
Fig. 5 is that each negative electrode lug of lithium ion battery of the present invention connects and is distributed in schematic diagram on the negative plate;
Fig. 6 is that each anode ear of described battery connects and is distributed in schematic diagram on the positive plate;
Fig. 7 is the voltage-time curve family of lithium ion battery of the present invention under the different multiplying discharge scenario.
Embodiment is described in further detail below in conjunction with the most preferred embodiment shown in each accompanying drawing: a kind of liquid lithium ionic cell manufacture method that allows high current charge-discharge that the present invention proposes referring to Fig. 1 to Fig. 6, comprises the steps:
A. by just/the lug number that increase to connect respectively on the negative plate, making it respectively is 2 to 5, just is being connected to/bear block then respectively, to reduce the electric current that single lug flows through, the charging and discharging currents of raising battery permission;
B. by just reducing/negative plate on the active material thickness of lithium be (70~150) μ m to control described each pole piece gross thickness δ, thereby the internal resistance of cell during the reduction high current charge-discharge;
C. just described/negative plate is respectively with after separately lug is connected, and is separated by and, is wound into one and forms electric core up and down behind the align center around the volume pin by barrier film, stops by stopping adhesive tape.
Described 2 to 5 lugs are seen Fig. 5, Fig. 6, evenly distribute on the length of run L of just described/negative plate.And these 2 to 5 lugs with separately just/negative plate is connected by the method for weldering, riveting or conductive adhesion.
The present invention allows the liquid lithium ionic cell of high current charge-discharge, and its structure is seen Fig. 1 to Fig. 4, is based on positive plate 2 and is separated by by barrier film 3 with negative plate 1 and is wound as one, stops by stopping adhesive tape 4.Especially, having 2 to 5 anode ears 5 evenly to distribute is connected on the length of run L of positive plate 2, also having 2 to 5 negative electrode lugs 6 evenly to distribute is connected on the length of run L of negative plate 1, and just described/negative electrode lug 5/6 is connected with separately block 7/8, and just described/negative plate 2/1 thickness δ is (70~150) μ m.
The present invention is for improving the high current charge-discharge ability of battery, except that just increasing/quantity of negative electrode lug, also order just/negative plate thickness δ attenuate, the length L lengthening has increased the contact area with electrolyte.
Evidence, the product that adopts the inventive method and battery structure to make can increase substantially the high-rate charge-discharge capability of liquid lithium ionic cell.As follows with the discharge performance of battery under the different multiplying discharge scenario that this kind structural group is dressed up:
Discharge-rate | Discharge time (S) | The capacity release rate |
????3.5C | ????1080.0 | ????97.10% |
????5C | ????750.0 | ????97.20% |
????7C | ????520.0 | ????92.40% |
????20C | ????120.0 | ????66.70% |
Fig. 7 is the voltage-time curve family of drawing according to above-mentioned result of the test, proves that liquid lithium ionic cell of the present invention has good capacity release rate under the high-multiplying power discharge situation, is fit to electric tool one class occasion and uses.