CN1597592A - Ceramic fiber back lining board - Google Patents

Ceramic fiber back lining board Download PDF

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Publication number
CN1597592A
CN1597592A CN 200410035686 CN200410035686A CN1597592A CN 1597592 A CN1597592 A CN 1597592A CN 200410035686 CN200410035686 CN 200410035686 CN 200410035686 A CN200410035686 A CN 200410035686A CN 1597592 A CN1597592 A CN 1597592A
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Prior art keywords
parts
starch
ceramic fiber
polyacrylamide
fiber
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CN 200410035686
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CN100439274C (en
Inventor
鹿成洪
刘超
李京友
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Luyang Energy Saving Materials Co Ltd
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Shandong Luyang Co Ltd
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Priority to CNB2004100356864A priority Critical patent/CN100439274C/en
Publication of CN1597592A publication Critical patent/CN1597592A/en
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Publication of CN100439274C publication Critical patent/CN100439274C/en
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Abstract

A backing ceramic-fibre board as refractory is prepared from aluminium silicate fibre, organic fibre, mineral wool, expanded pearlite, clay, starch, polyacrylamide, and polymerized aluminium chloride through proportional mixing, preparing paste, shaping, drying and post-processing.

Description

The ceramic fiber backing plate
Technical field
The invention belongs to the refractory ceramic fibre material type, specifically is a kind of ceramic fiber backing plate.
Background technology
Traditional heat insulating inorganic fiberboard mainly contains: block of glass wool, rock wool heat-preservation plate, slag wool warming plate, mineral wool insulation and decoration absorbing ceiling, asbestos plate, aluminosilicate fiberboard and the fiberboard etc. that is mixed.
Traditional heat insulating inorganic fiberboard use temperature or below 600 ℃, such as: block of glass wool, rock wool heat-preservation plate, slag wool warming plate, mineral wool insulation and decoration absorbing ceiling, asbestos plate; More than 1000 ℃, such as the aluminosilicate fiberboard and the fiberboard that is mixed; At present, the heat insulating fiberboard that does not still have 600 ℃~1000 ℃ of use temperatures.Although some fibre enhanced composite heat insulation board is arranged, use temperature is in 600 ℃~1000 ℃ scopes, but owing to be not to be base material with the fiber, make that these material fragilities are big, easy efflorescence during use, for example: calcium silicate board fragility in the transportation use is big, and is damaged easily, and cause the efflorescence of calcium silicate board when using owing to high temperature burning mistake effect, thereby the intensity of losing.
Summary of the invention
The objective of the invention is to overcome above-mentioned deficiency of the prior art, use temperature is in 600 ℃~1000 ℃ scopes, adopting ceramic fiber is that base material replaces fibrous magnesium silicate, and after adding one or more reinforcing fibres and adding part of auxiliary, and a kind of ceramic fiber backing plate that can increase substantially the thermal and insulating performance of thermal insulation thermal insulation board that makes.
The present invention is achieved by the following technical solutions:
It is a kind of ceramic fiber backing plate, with the pure aluminium silicate series fiber as base material, add one or more organic fibres or inorganic fibre and do fortifying fibre, and organic bond or inorganic bonding agent, filler and the additive of adding suitable proportion, make through operations such as batching slurrying, moulding, drying and following process, it is characterized in that it forms weight ratio is aluminum silicate fiber 50-85 part, organic fibre 0-3 part, 5~30 parts of ore deposit rock wools, 0~20 part of pearlstone, 5~20 parts of clays, 3~8 parts of starch, 0~1 part of polyacrylamide, 0.01~0.5 part of polymerize aluminum chloride.
It forms weight ratio further is aluminum silicate fiber 55-80 part, organic fibre 1.5-2.5 part, 7~25 parts of ore deposit rock wools, 2~17 parts of pearlstones, 5~16 parts of clays, 4~7 parts of starch, 0.2~0.8 part of polyacrylamide, 0.03~0.4 part of polymerize aluminum chloride.
It forms weight ratio further is aluminum silicate fiber 60-75 part, organic fibre 1.8-2.1 part, 9~19 parts of ore deposit rock wools, 5~15 parts of pearlstones, 7~13 parts of clays, 5~6.5 parts of starch, 0.4~0.7 part of polyacrylamide, 0.1~0.3 part of polymerize aluminum chloride.
The present invention adopts to such an extent that fortifying fibre is one or more organic fibres or inorganic fibre, improves the intensity of product of the present invention and reduces cost with this.Organic fibre is meant a kind of or compound use in the fiber kinds such as disregard message paper, ramie yarn, polyvinyl alcohol fiber, polyethylene fibre; Inorganic fibre is meant a kind of or compound use in the fiber kinds such as rock wool, slag wool, glass fibre.
Wedding agent of the present invention is a kind of or compound use in the starch, silicon sol, aluminium colloidal sol, two kinds.Starch can adopt a kind of or compound use in 9 kinds of the cationic starches, anionic starch, carboxymethyl starch, hydroxyalkyl starch, cross-linking starch, Sumstar 190, denaturated starch by acid, pre-gelatinized starch, phosphate ester starch, and the starch material can adopt a kind of or compound use in 5 kinds of the tapioca (flour)s, yam starch, W-Gum, sweet potato starch, wheat starch.
The present invention adopts filler to be light filler and clay class filler and to be used for further improving the intensity of backing plate by compound making.
The said light filler of the present invention is meant tap density 1000kg/m 3Following lightweight heat-proof material comprises: pearlstone, diatomite, expanded vermiculite, sepiolite, float pearl, ceramic fiber waste material etc.
The said clay class of the present invention filler is meant that having expansile using always in water is stained with filler, comprising: wilkinite, kaolin, soft clay, semisoft clay, ball clay and attapulgite etc.
The said batching slurrying of the present invention is meant carries out mechanically mixing with aluminum silicate fiber, fortifying fibre, wedding agent, filler and additive by the above-mentioned materials proportioning, and between 2-5mm, the slurry concentration of making is 2.5-5% to the staple length in the slurry usually.
Additive of the present invention comprises flocculation agent and condensing agent two portions, adopts polyacrylamide as flocculation agent, adopts polymerize aluminum chloride or Tai-Ace S 150 as condensing agent.
The said flocculation agent of the present invention is a polyacrylamide, and polyacrylamide can be cationic, anionic property or both sexes, and the polyacrylamide of different charge properties can use separately also and can and use.
The said condensing agent of the present invention is a kind of or compound use in polymerize aluminum chloride and the Tai-Ace S 150, and its effect is that the wedding agent and the filler that flocculate to fiber are fixed up, and avoids in the moulding process floc sedimentation destroyed.
The molding procedure that the present invention introduced is meant dewaters water-based slurry and forms wet base by molding device, the drying process that the present invention introduced is with the wet base after the moulding, sends into the process that kiln carries out thermal dehydration.
Beneficial effect of the present invention is as follows:
Because the present invention adopts ceramic fiber as base material, the mating part fortifying fibre, the light filler and the clay filler that add suitable proportion, can effectively improve resistance toheat, intensity and the elasticity of heat insulating inorganic fiberboard, and production cost reduces widely, thereby overcome the not neutral gear in 600 ℃~1000 ℃ scopes of traditional heat insulating inorganic fiberboard use temperature, and, can be used as the favorable substitutes of calcium silicate board owing to intensity height, good springiness.
Embodiment
Embodiment one
With 50 parts of aluminum silicate fibers, 4 parts of polyvinyl alcohol fibers, 6 parts of ore deposit rock wools, 3 parts of pearlstones, 5 parts of clays, 3 parts of starch, 0.2 part of polyacrylamide, 0.01 part of adding pulper of polymerize aluminum chloride carries out slurrying, and the staple length after slurrying is finished is 3mm, the water that adds suitable proportion then, make slurry concentration remain on 2.5%, adopt vacuum forming equipment to carry out moulding then, be of a size of 900 * 600 * 50, product was sent into the drying shed oven dry after moulding finished, by cutting, the final realization of polishing the present invention.Product chemical ingredients of the present invention is as follows: Al 2O 3: 25%; SiO 2: 59%; Organism: 12%; Fe 2O 3+ CaO+MgO+K 2O+Na 2O:4%, small product size density is 280Kg/m 3, heat permanent linear shrinkage ratio (800 ℃ * 24h) be 1.8%; The cold conditions compressive strength is 0.23MPa; Thermal conductivity (600 ℃ of hot-face temperatures) is 0.122W/m.k.
Embodiment two
With 60 parts of aluminum silicate fibers, 5 parts of ore deposit rock wools, 10 parts of pearlstones, 5 parts of clays, 5 parts of starch, 0.15 part of polyacrylamide, 0.05 part of adding pulper of polymerize aluminum chloride carries out slurrying, staple length after slurrying is finished is 2mm, adds the water of suitable proportion then, makes slurry concentration remain on 3%, adopt then and copy taking equipment and carry out moulding, be of a size of 900 * 600 * 50, product was sent into the drying shed oven dry after moulding finished, by cutting, the final realization of polishing the present invention.Product chemical ingredients of the present invention is as follows: Al 2O 3: 29%; SiO 2: 60%; Organism: 8%; Fe 2O 3+ CaO+MgO+K 2O+Na 2O:3%, small product size density is 280Kg/m 3, heat permanent linear shrinkage ratio (800 ℃ * 24h) be 1.6%; The cold conditions compressive strength is 0.24MPa; Thermal conductivity (600 ℃ of hot-face temperatures) is 0.121W/m.k.
Embodiment three
With 65 parts of aluminum silicate fibers, 4.5 parts of polyvinyl alcohol fibers, 20 parts of ore deposit rock wools, 5 parts of pearlstones, 5 parts of clays, 5 parts of starch, 0.6 part of polyacrylamide, 0.2 part of adding pulper of polymerize aluminum chloride carries out slurrying, and the staple length after slurrying is finished is 3mm, the water that adds suitable proportion then, make slurry concentration remain on 2.5%, adopt vacuum forming equipment to carry out moulding then, be of a size of 900 * 600 * 50, product was sent into the drying shed oven dry after moulding finished, by cutting, the final realization of polishing the present invention.Product chemical ingredients of the present invention is as follows: Al 2O 3: 38%; SiO 2: 54%; Organism: 3%; Fe 2O 3+ CaO+MgO+K 2O+Na 2O:5%, small product size density is 280Kg/m 3, heat permanent linear shrinkage ratio (800 ℃ * 24h) be 1.8%; The cold conditions compressive strength is 0.25MPa; Thermal conductivity (600 ℃ of hot-face temperatures) is 0.12W/m.k.
Embodiment four
With 70 parts of aluminum silicate fibers, 15 parts of ore deposit rock wools, 15 parts of pearlstones, 17 parts of clays, 7 parts of starch, 0.8 part of polyacrylamide, 0.7 part of adding pulper of polymerize aluminum chloride carries out slurrying, staple length after slurrying is finished is 2mm, adds the water of suitable proportion then, makes slurry concentration remain on 3%, adopt then and copy taking equipment and carry out moulding, be of a size of 900 * 600 * 50, product was sent into the drying shed oven dry after moulding finished, by cutting, the final realization of polishing the present invention.Product chemical ingredients of the present invention is as follows: Al 2O 3: 49%; SiO 2: 35%; Organism: 11%; Fe 2O 3+ CaO+MgO+K 2O+Na 2O:5%, small product size density is 280Kg/m 3, heat permanent linear shrinkage ratio (800 ℃ * 24h) be 1.6%; The cold conditions compressive strength is 0.23MPa; Thermal conductivity (600 ℃ of hot-face temperatures) is 0.122W/m.k.
Embodiment five
With 85 parts of aluminum silicate fibers, 30 parts of ore deposit rock wools, 20 parts of pearlstones, 20 parts of clays, 8 parts of starch, 1 part of polyacrylamide, 1 part of adding pulper of polymerize aluminum chloride carries out slurrying, staple length after slurrying is finished is 2mm, adds the water of suitable proportion then, makes slurry concentration remain on 3%, adopt then and copy taking equipment and carry out moulding, be of a size of 900 * 600 * 50, product was sent into the drying shed oven dry after moulding finished, by cutting, the final realization of polishing the present invention.Product chemical ingredients of the present invention is as follows: Al 2O 3: 50%; SiO 2: 40%; Organism: 6%; Fe 2O 3+ CaO+MgO+K 2O+Na 2O:4%, small product size density is 280Kg/m 3, heat permanent linear shrinkage ratio (800 ℃ * 24h) be 1.6%; The cold conditions compressive strength is 0.25MPa; Thermal conductivity (600 ℃ of hot-face temperatures) is 0.12W/m.k.
Because the present invention adopts ceramic fiber as base material, the mating part fortifying fibre, the light filler and the clay filler that add suitable proportion, can effectively improve resistance toheat, intensity and the elasticity of heat insulating inorganic fiberboard, and production cost reduces widely, thereby overcome the not neutral gear in 600 ℃~1000 ℃ scopes of traditional heat insulating inorganic fiberboard use temperature, and, can be used as the favorable substitutes of calcium silicate board owing to intensity height, good springiness.

Claims (4)

1, a kind of ceramic fiber backing plate, with the pure aluminium silicate series fiber as base material, add one or more fortifying fibres, and organic bond or inorganic bonding agent, filler and the additive of adding suitable proportion, make through operations such as batching slurrying, moulding, drying and following process, it is characterized in that it forms weight ratio is aluminum silicate fiber 50-85 part, organic fibre 0-3 part, 5~30 parts of ore deposit rock wools, 0~20 part of pearlstone, 5~20 parts of clays, 3~8 parts of starch, 0~1 part of polyacrylamide, 0.01~0.5 part of polymerize aluminum chloride.
2, ceramic fiber backing plate according to claim 1, it is characterized in that it forms weight ratio is aluminum silicate fiber 55-80 part, organic fibre 1.5-2.5 part, 7~25 parts of ore deposit rock wools, 2~17 parts of pearlstones, 5~16 parts of clays, 4~7 parts of starch, 0.2~0.8 part of polyacrylamide, 0.03~0.4 part of polymerize aluminum chloride.
3, ceramic fiber backing plate according to claim 1, it is characterized in that it forms weight ratio is aluminum silicate fiber 60-75 part, organic fibre 1.8-2.1 part, 9~19 parts of ore deposit rock wools, 5~15 parts of pearlstones, 7~13 parts of clays, 5~6.5 parts of starch, 0.4~0.7 part of polyacrylamide, 0.1~0.3 part of polymerize aluminum chloride.
4, ceramic fiber backing plate according to claim 1 is characterized in that in its chemical constitution: Al 2O 3: 25~50%, SiO 2: 35~60%, Fe 2O 3+ CaO+MgO+K 2O+Na 2O:3~5%, organism: 3-12%.
CNB2004100356864A 2004-09-14 2004-09-14 Ceramic fiber back lining board Expired - Lifetime CN100439274C (en)

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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300062C (en) * 2005-10-14 2007-02-14 宜兴天霸非金属材料有限公司 Setting accelerated fibre fire-proof plastic and production thereof
CN100385072C (en) * 2006-06-16 2008-04-30 中国建筑材料科学研究总院 High temp. resisting low thermoconducting flexible ceramics fibre composite paper and its making method
CN102351470A (en) * 2011-07-18 2012-02-15 刘全友 Fireproof vacuum warming plate core material and production technology
CN101497513B (en) * 2008-01-31 2012-02-22 北新集团建材股份有限公司 Light mineral wool slab
CN101486543B (en) * 2009-01-07 2012-05-23 浙江红鹰集团股份有限公司 Environment friendly type heat-insulating plate formula
CN102476942A (en) * 2010-11-23 2012-05-30 山东鲁阳股份有限公司 Inorganic combined ceramic fiberboard
CN102515661A (en) * 2011-12-02 2012-06-27 山东鲁阳股份有限公司 Inorganically combined ceramic fiber board
CN102910860A (en) * 2012-10-19 2013-02-06 山东鲁阳股份有限公司 Preparation method of environment-friendly and ageing-resistant calcium silicate ceramic fiber building insulation board
CN105271960A (en) * 2014-07-14 2016-01-27 北新集团建材股份有限公司 Electromagnetic radiation resistant heat insulation sheet and making method thereof
CN105859310A (en) * 2016-04-01 2016-08-17 常州朗锐铸造有限公司 Material formula and preparation method of metal bag insulation cover
CN106187254A (en) * 2016-07-06 2016-12-07 南京理工宇龙新材料科技股份有限公司 A kind of high strength fiberboard and preparation method thereof
CN108439869A (en) * 2018-04-28 2018-08-24 山东鲁阳节能材料股份有限公司 A kind of heat preserving and insulating material
CN111848105A (en) * 2020-07-30 2020-10-30 福建省中能泰丰节能环保科技有限公司 Composite heat-insulating material containing ceramic fiber and preparation method thereof
CN112374818A (en) * 2020-11-27 2021-02-19 山东鲁阳节能材料股份有限公司 High-density ceramic fiber board with use temperature of more than 1100 ℃ and preparation method thereof
CN112624721A (en) * 2020-12-16 2021-04-09 山东鲁阳节能材料股份有限公司 High-density ceramic fiber board with built-in embedded part and integrated forming method thereof
CN112624722A (en) * 2020-12-18 2021-04-09 山东鲁阳节能材料股份有限公司 High-density board with expanded vermiculite as base material and preparation method thereof
CN112661527A (en) * 2020-12-18 2021-04-16 山东鲁阳浩特高技术纤维有限公司 Expandable alumina-based fiber module and preparation method thereof
CN112723897A (en) * 2020-12-18 2021-04-30 山东鲁阳节能材料股份有限公司 High-density ceramic fiber board not prone to secondary cracking and preparation method thereof

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CN1124261A (en) * 1994-12-10 1996-06-12 王兴 Asbestos-free compound dry powder insulation paint and producing method
CN1159468A (en) * 1996-03-11 1997-09-17 刘作君 Green composite thermal-insulating paint for wall and production technology
CN1137234C (en) * 2001-04-20 2004-02-04 宋英辉 Insulating silicate grout for external wall and its preparing process

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1300062C (en) * 2005-10-14 2007-02-14 宜兴天霸非金属材料有限公司 Setting accelerated fibre fire-proof plastic and production thereof
CN100385072C (en) * 2006-06-16 2008-04-30 中国建筑材料科学研究总院 High temp. resisting low thermoconducting flexible ceramics fibre composite paper and its making method
CN101497513B (en) * 2008-01-31 2012-02-22 北新集团建材股份有限公司 Light mineral wool slab
CN101486543B (en) * 2009-01-07 2012-05-23 浙江红鹰集团股份有限公司 Environment friendly type heat-insulating plate formula
CN102476942B (en) * 2010-11-23 2013-07-03 山东鲁阳股份有限公司 Inorganic combined ceramic fiberboard
CN102476942A (en) * 2010-11-23 2012-05-30 山东鲁阳股份有限公司 Inorganic combined ceramic fiberboard
CN102351470A (en) * 2011-07-18 2012-02-15 刘全友 Fireproof vacuum warming plate core material and production technology
CN102351470B (en) * 2011-07-18 2013-01-09 刘全友 Fireproof vacuum warming plate core material and production technology
CN102515661B (en) * 2011-12-02 2013-07-03 山东鲁阳股份有限公司 Inorganically combined ceramic fiber board
CN102515661A (en) * 2011-12-02 2012-06-27 山东鲁阳股份有限公司 Inorganically combined ceramic fiber board
CN102910860A (en) * 2012-10-19 2013-02-06 山东鲁阳股份有限公司 Preparation method of environment-friendly and ageing-resistant calcium silicate ceramic fiber building insulation board
CN102910860B (en) * 2012-10-19 2013-12-04 山东鲁阳股份有限公司 Preparation method of environment-friendly and ageing-resistant calcium silicate ceramic fiber building insulation board
CN105271960A (en) * 2014-07-14 2016-01-27 北新集团建材股份有限公司 Electromagnetic radiation resistant heat insulation sheet and making method thereof
CN105859310A (en) * 2016-04-01 2016-08-17 常州朗锐铸造有限公司 Material formula and preparation method of metal bag insulation cover
CN106187254A (en) * 2016-07-06 2016-12-07 南京理工宇龙新材料科技股份有限公司 A kind of high strength fiberboard and preparation method thereof
CN108439869A (en) * 2018-04-28 2018-08-24 山东鲁阳节能材料股份有限公司 A kind of heat preserving and insulating material
CN111848105A (en) * 2020-07-30 2020-10-30 福建省中能泰丰节能环保科技有限公司 Composite heat-insulating material containing ceramic fiber and preparation method thereof
CN112374818A (en) * 2020-11-27 2021-02-19 山东鲁阳节能材料股份有限公司 High-density ceramic fiber board with use temperature of more than 1100 ℃ and preparation method thereof
CN112624721A (en) * 2020-12-16 2021-04-09 山东鲁阳节能材料股份有限公司 High-density ceramic fiber board with built-in embedded part and integrated forming method thereof
CN112624722A (en) * 2020-12-18 2021-04-09 山东鲁阳节能材料股份有限公司 High-density board with expanded vermiculite as base material and preparation method thereof
CN112661527A (en) * 2020-12-18 2021-04-16 山东鲁阳浩特高技术纤维有限公司 Expandable alumina-based fiber module and preparation method thereof
CN112723897A (en) * 2020-12-18 2021-04-30 山东鲁阳节能材料股份有限公司 High-density ceramic fiber board not prone to secondary cracking and preparation method thereof
CN112661527B (en) * 2020-12-18 2022-09-30 山东鲁阳浩特高技术纤维有限公司 Expandable alumina-based fiber module and preparation method thereof

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Address after: 256120 Shandong city of Zibo province Yiyuan County Yi River Road No. 11

Patentee after: LUYANG ENERGY-SAVING MATERIALS Co.,Ltd.

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Granted publication date: 20081203