CN1594509A - Process for hydrocracking of Fischer-Tropsch synthesized heavy hydrocarbon and/or kettle bottom wax - Google Patents
Process for hydrocracking of Fischer-Tropsch synthesized heavy hydrocarbon and/or kettle bottom wax Download PDFInfo
- Publication number
- CN1594509A CN1594509A CN 200410012378 CN200410012378A CN1594509A CN 1594509 A CN1594509 A CN 1594509A CN 200410012378 CN200410012378 CN 200410012378 CN 200410012378 A CN200410012378 A CN 200410012378A CN 1594509 A CN1594509 A CN 1594509A
- Authority
- CN
- China
- Prior art keywords
- fischer
- hydrocracking
- catalyst
- heavy hydrocarbon
- iron
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 46
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 46
- 239000004215 Carbon black (E152) Substances 0.000 title claims abstract description 44
- 238000000034 method Methods 0.000 title claims abstract description 38
- 238000004517 catalytic hydrocracking Methods 0.000 title claims abstract description 34
- 230000008569 process Effects 0.000 title claims abstract description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 73
- 239000003054 catalyst Substances 0.000 claims abstract description 47
- 238000006243 chemical reaction Methods 0.000 claims abstract description 32
- 239000002994 raw material Substances 0.000 claims abstract description 19
- 239000001257 hydrogen Substances 0.000 claims abstract description 18
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 18
- 239000003921 oil Substances 0.000 claims description 54
- 230000015572 biosynthetic process Effects 0.000 claims description 23
- 238000003786 synthesis reaction Methods 0.000 claims description 23
- 229910052742 iron Inorganic materials 0.000 claims description 20
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 7
- 239000006188 syrup Substances 0.000 claims description 7
- 235000020357 syrup Nutrition 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- 230000006837 decompression Effects 0.000 claims description 5
- 238000005194 fractionation Methods 0.000 claims description 5
- 239000007788 liquid Substances 0.000 claims description 5
- 239000011572 manganese Substances 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 239000010949 copper Substances 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000012808 vapor phase Substances 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QVYYOKWPCQYKEY-UHFFFAOYSA-N [Fe].[Co] Chemical compound [Fe].[Co] QVYYOKWPCQYKEY-UHFFFAOYSA-N 0.000 claims description 2
- CQSYFUDHMLBBOI-UHFFFAOYSA-N [Fe].[Mn].[Mo].[Ni] Chemical compound [Fe].[Mn].[Mo].[Ni] CQSYFUDHMLBBOI-UHFFFAOYSA-N 0.000 claims description 2
- AUDVLOZPHVZFCE-UHFFFAOYSA-N [K][Cu][Mn][Fe] Chemical compound [K][Cu][Mn][Fe] AUDVLOZPHVZFCE-UHFFFAOYSA-N 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 239000002131 composite material Substances 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical group [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 claims description 2
- 229910052746 lanthanum Inorganic materials 0.000 claims description 2
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 150000002739 metals Chemical class 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 2
- 229910052721 tungsten Inorganic materials 0.000 claims description 2
- 239000010937 tungsten Substances 0.000 claims description 2
- DWZGUUCIHUNHJZ-UHFFFAOYSA-N [K][Cu][Fe] Chemical compound [K][Cu][Fe] DWZGUUCIHUNHJZ-UHFFFAOYSA-N 0.000 claims 1
- VIJYFGMFEVJQHU-UHFFFAOYSA-N aluminum oxosilicon(2+) oxygen(2-) Chemical compound [O-2].[Al+3].[Si+2]=O VIJYFGMFEVJQHU-UHFFFAOYSA-N 0.000 claims 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract description 12
- 238000002156 mixing Methods 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000002699 waste material Substances 0.000 abstract 1
- 239000001993 wax Substances 0.000 description 39
- 239000002283 diesel fuel Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 10
- 239000003208 petroleum Substances 0.000 description 10
- 239000000725 suspension Substances 0.000 description 10
- 238000009835 boiling Methods 0.000 description 8
- 238000004939 coking Methods 0.000 description 8
- 238000005336 cracking Methods 0.000 description 7
- 150000001336 alkenes Chemical class 0.000 description 5
- 238000007667 floating Methods 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 239000004480 active ingredient Substances 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- -1 cerebrol 13 Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000007327 hydrogenolysis reaction Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 238000011020 pilot scale process Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410012378 CN1247747C (en) | 2004-07-02 | 2004-07-02 | Process for hydrocracking of Fischer-Tropsch synthesized heavy hydrocarbon and/or kettle bottom wax |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410012378 CN1247747C (en) | 2004-07-02 | 2004-07-02 | Process for hydrocracking of Fischer-Tropsch synthesized heavy hydrocarbon and/or kettle bottom wax |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1594509A true CN1594509A (en) | 2005-03-16 |
CN1247747C CN1247747C (en) | 2006-03-29 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 200410012378 Expired - Lifetime CN1247747C (en) | 2004-07-02 | 2004-07-02 | Process for hydrocracking of Fischer-Tropsch synthesized heavy hydrocarbon and/or kettle bottom wax |
Country Status (1)
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CN (1) | CN1247747C (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102260527A (en) * | 2011-06-29 | 2011-11-30 | 中国石油大学(华东) | New catalytic hydroprocessing thermal cracking-hydrotreating process of high-sulfur high-acid inferior heavy oil |
US10563130B2 (en) | 2014-07-17 | 2020-02-18 | Sabic Global Technologies B.V. | Upgrading hydrogen deficient streams using hydrogen donor streams in a hydropyrolysis process |
CN116410788A (en) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | Poor-quality heavy oil slurry bed hydrocracking treatment equipment and treatment method |
-
2004
- 2004-07-02 CN CN 200410012378 patent/CN1247747C/en not_active Expired - Lifetime
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102260527A (en) * | 2011-06-29 | 2011-11-30 | 中国石油大学(华东) | New catalytic hydroprocessing thermal cracking-hydrotreating process of high-sulfur high-acid inferior heavy oil |
CN102260527B (en) * | 2011-06-29 | 2014-05-28 | 中国石油大学(华东) | New catalytic hydroprocessing thermal cracking-hydrotreating process of high-sulfur high-acid inferior heavy oil |
US10563130B2 (en) | 2014-07-17 | 2020-02-18 | Sabic Global Technologies B.V. | Upgrading hydrogen deficient streams using hydrogen donor streams in a hydropyrolysis process |
CN116410788A (en) * | 2021-12-31 | 2023-07-11 | 中国石油天然气股份有限公司 | Poor-quality heavy oil slurry bed hydrocracking treatment equipment and treatment method |
Also Published As
Publication number | Publication date |
---|---|
CN1247747C (en) | 2006-03-29 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: ZHONGKE SYNTHETIC OIL TECHNOLOGY CO., LTD., DISTR Free format text: FORMER OWNER: SHANXI INST. OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES Effective date: 20070119 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20070119 Address after: 030006, Taiyuan hi tech Zone, Shanxi, South Central Cyberport, port 4, 2, A and B Patentee after: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. Address before: 165 mailbox 030001, Shanxi City, Taiyuan Province Patentee before: INSTITUTE OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES |
|
C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. Address before: 030006, Taiyuan hi tech Zone, Shanxi, South Central Cyberport, port 4, 2, A and B Patentee before: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. |
|
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: 101407 No. 1, south 2nd Street, paradise, Zone C, Yanqi Economic Development Zone, Huairou District, Beijing Patentee after: Zhongke synthetic oil Technology Co.,Ltd. Address before: 101407 No. 1, south 2nd Street, paradise, Zone C, Yanqi Economic Development Zone, Huairou District, Beijing Patentee before: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. |
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CX01 | Expiry of patent term | ||
CX01 | Expiry of patent term |
Granted publication date: 20060329 |