CN1594482A - Polypropylene tow forming adhesive for cigarette - Google Patents
Polypropylene tow forming adhesive for cigarette Download PDFInfo
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- CN1594482A CN1594482A CN 200410023332 CN200410023332A CN1594482A CN 1594482 A CN1594482 A CN 1594482A CN 200410023332 CN200410023332 CN 200410023332 CN 200410023332 A CN200410023332 A CN 200410023332A CN 1594482 A CN1594482 A CN 1594482A
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Abstract
The invention discloses a polypropylene tow forming adhesive for cigarette wherein the adhesive is charged by, auxiliary solvent comprising the mixture of one or more from 0.1-2% of ethanol, propanol, butanol, 0.5-3% of emulsifying agent, which is the mixture of one or more from propanetriol, propylene glycol, ethylene glycol, the mixture of one or more from trishydroxymethylaminomethane, 2-amido-2-hydroxyl-1, 3-propylene glycol, 5,5-dimethyl-hydantoin, dehydration sorbic alcohol fatty acid ester, polyoxyethylene dehydration sorbic alcohol fatty acid ester, octadecanamide ethyl dimethyl-beta-hydroxyl ethyl nitrate.
Description
Technical field
The present invention relates to a kind of cigarette polypropylene fiber tow forming adhesive.
Background technology
Existing cigarette polypropylene fiber tow forming adhesive, mainly form by elastic resin, tackifying resin, softening agent, fat hydrocarbon solvent oil, oxidation inhibitor, whitening agent, this class tackiness agent is non-polar adhesive, adsorptive power to tar is poor, cause the suction flavor of cigarette bad on the one hand, also increased the tar in the cigarette to health effects simultaneously.
Summary of the invention
The object of the present invention is to provide a kind of adsorptive power that can strengthen, can improve the suction flavor of cigarette, improve the grade of cigarette, and reduce a kind of cigarette polypropylene fiber tow forming adhesive of cigarette health effects to tar.
Technical scheme of the present invention is: add the emulsifying agent that solubility promoter that 0.1-2% (weight) is made of one or more the mixture in ethanol, propyl alcohol, the butanols and 0.5-3% are made up of following component and weight percent in the existing non-polar adhesive of being made up of elastic resin, tackifying resin, softening agent, fat hydrocarbon solvent oil, oxidation inhibitor, whitening agent:
A. by one or more the mixture 12-36 in glycerol, propylene glycol, ethylene glycol, a condensed ethandiol, tirethylene glycol, the deionized water;
B. Tutofusin tris, 2-amino-2-hydroxyl-1, ammediol, 5, the mixture 4-25 of one or more in the 5-T10;
C. by sorbitan fatty acid ester 25-55, polyoxyethylene sorbitan fatty acid ester 6-25, stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate 10-35 compounded surfactant.
Its production method may further comprise the steps:
1. press the non-polar adhesive that prior art for preparing is made up of elastic resin, tackifying resin, softening agent, fat hydrocarbon solvent oil, oxidation inhibitor, whitening agent;
2. the preparation of emulsifying agent: mix by following component and weight percent, be heated to 80 ℃～100 ℃, stir into emulsion;
A. by one or more the mixture 12-36 in glycerol, propylene glycol, ethylene glycol, a condensed ethandiol, tirethylene glycol, the deionized water;
B. Tutofusin tris, 2-amino-2-hydroxyl-1, ammediol, 5, the mixture 4-25 of one or more in the 5-T10;
C. by sorbitan fatty acid ester 25-55, polyoxyethylene sorbitan fatty acid ester 6-25, stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate 10-35 compounded surfactant.
3. in non-polar adhesive, add 0.1-2% (weight) by the solubility promoter that one or more the mixture in ethanol, propyl alcohol, the butanols constitutes, add the emulsifying agent of 0.5-3% (weight) after the stirring again, stir.
The cigarette polypropylene fiber tow forming adhesive that is made of above component is a kind of polarity tackiness agent, this tackiness agent strengthens the absorption property of tar, our experiments show that and generally in wire-beam forming, use every reduced tar content 0.3-2 of this tackiness agent milligram, can improve the suction flavor of cigarette, also reduce cigarette health effects.
Embodiment
Embodiment 1:
1. 243.6 gram aliphatic solvents oil are added in the there-necked flask of 500 milliliters of belt stirrers, add 1 gram styrene-butadiene-styrene block elastic resin (SBS) again, 2 gram vinylbenzene-, isoprene-styrene block elastic resin (SlS), 30 gram petroleum resin, 15 gram terpine resins, 2 gram rosin glycerides, 30 milligram 2,5-two (5-tertiary butyl benzo oxazole-2 '-) thiophene phenol, 0.3 gram 2,6 ditertiary butyl p cresol, 4 gram dibutyl phthalates, 2 gram dioctyl phthalate (DOP)s add in the there-necked flasks, heated and stirred, dissolving fully the back existing non-polar adhesive;
2. the preparation of emulsifying agent: with 70 gram anhydrous sorbitol fatty acid esters (class of department 80), 16 gram polyoxyethylene sorbitan fatty acid esters (tween 80), 50 gram stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate (static inhibitor SN), 60 gram glycerol, 12 gram Tutofusin triss, 6 grams 5, the 5-T10 mixes, and adds deionized water 10 grams, be heated to 95 ℃, stir into emulsifying agent;
3. get 300 gram non-polar adhesives, add emulsifying agent 4.5 grams, after mixing, add 2 gram solubility promoter ethanol, stir, leave standstill, be finished product.
Filter with above tackiness agent moulding is chewed, 2 milligrams of every reduced tar contents.
Embodiment 2:
1. the non-polar adhesive preparation is with embodiment 1;
2. the preparation of emulsifying agent: with 80 gram anhydrous sorbitol fatty acid esters (class of department 80), 40 gram anhydrous sorbitol fatty acid esters (class of department 85), 16 gram polyoxyethylene sorbitan fatty acid esters (tween 80), 50 gram stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate (static inhibitor SN), 40 gram glycerol, 6 grams 5, the 5-T10 mixes, and is heated to 80 ℃～100 ℃, stirs into emulsifying agent;
3. get 300 gram non-polar adhesives, add emulsifying agent 8.0 grams, after mixing, add 0.3 gram solubility promoter propyl alcohol, stir, leave standstill, be finished product.
Filter with above tackiness agent moulding is chewed, 1.5 milligrams of every reduced tar contents.
Embodiment 3:
1. the non-polar adhesive preparation is with embodiment 1;
2. the preparation of emulsifying agent: with 70 gram anhydrous sorbitol fatty acid esters (class of department 80), 16 gram polyoxyethylene sorbitan fatty acid esters (tween 80), 30 gram polyoxyethylene sorbitan fatty acid esters (polysorbate60), 20 gram stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate (static inhibitor SN), 20 gram glycerol, 10 gram ethylene glycol, 10 grams, one condensed ethandiol, 8 gram Tutofusin triss, 4 grams 5, the 5-T10 mixes, add deionized water 10 grams, be heated to 90 ℃, stir into emulsifying agent;
3. get 300 gram non-polar adhesives, add emulsifying agent 5 grams, after mixing, add 1 gram solubility promoter ethanol, stir, leave standstill, be finished product.
Filter with above tackiness agent moulding is chewed, 0.8 milligram of every reduced tar content.
Embodiment 4:
1. the non-polar adhesive preparation is with embodiment 1;
2. the preparation of emulsifying agent: with 70 gram anhydrous sorbitol fatty acid esters (class of department 80), 16 gram polyoxyethylene sorbitan fatty acid esters (tween 80), 50 gram stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate (static inhibitor SN), 10 gram glycerol, 10 gram ethylene glycol, 10 grams, one condensed ethandiol, 30 gram Tutofusin triss, 15 grams 5, the 5-T10 mixes, and adds deionized water 40 grams, be heated to 95 ℃, stir into emulsifying agent;
3. get 300 gram non-polar adhesives, add emulsifying agent 3.5 grams, after mixing, add 1.5 gram solubility promoter butanols, stir, leave standstill, be finished product.
Filter with above tackiness agent moulding is chewed, 0.7 milligram of every reduced tar content.
Embodiment 5:
1. the non-polar adhesive preparation is with embodiment 1;
2. the preparation of emulsifying agent: with 70 gram anhydrous sorbitol fatty acid esters (class of department 80), 16 gram polyoxyethylene sorbitan fatty acid esters (tween 80), 50 gram stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate (static inhibitor SN), 10 gram glycerol, 10 gram ethylene glycol, 4 gram Tutofusin triss, 4 grams 5, the 5-T10 mixes, and is heated to 85 ℃, stirs into emulsifying agent;
3. get 300 gram non-polar adhesives, add emulsifying agent 3 grams, after mixing, add solubility promoter ethanol 3 grams, propyl alcohol 2 grams, stir, leave standstill, be finished product.
Filter with above tackiness agent moulding is chewed, 0.4 milligram of every reduced tar content.
Embodiment 6:
1. the non-polar adhesive preparation is with embodiment 1;
2. the preparation of emulsifying agent: with 70 gram anhydrous sorbitol fatty acid esters (class of department 80), 16 gram polyoxyethylene sorbitan fatty acid esters (tween 80), 40 gram stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate (static inhibitor SN), 10 gram glycerol, 30 gram Tutofusin triss, 15 grams 5, the 5-T10 mixes, and adds deionized water 40 grams, be heated to 98 ℃, stir into emulsifying agent;
3. get 300 gram non-polar adhesives, add emulsifying agent 4.5 grams, after mixing, add 0.5 gram solubility promoter ethanol, stir, leave standstill, be finished product.
Filter with above tackiness agent moulding is chewed, 0.7 milligram of every reduced tar content.
Claims (2)
1. cigarette polypropylene fiber tow forming adhesive is characterized in that adding the emulsifying agent that solubility promoter that 0.1-2% (weight) is made of one or more the mixture in ethanol, propyl alcohol, the butanols and 0.5-3% are made up of following component and weight percent in the existing tackiness agent of being made of elastic resin, tackifying resin, softening agent, fat hydrocarbon solvent oil, oxidation inhibitor, whitening agent:
A. by one or more the mixture 12-36 in glycerol, propylene glycol, ethylene glycol, a condensed ethandiol, tirethylene glycol, the deionized water;
B. Tutofusin tris, 2-amino-2-hydroxyl-1, ammediol, 5, the mixture 4-25 of one or more in the 5-T10;
C. by sorbitan fatty acid ester 25-55, polyoxyethylene sorbitan fatty acid ester 6-25, stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate 10-35 compounded surfactant.
2. the production method of cigarette polypropylene fiber tow forming adhesive is characterized in that may further comprise the steps:
1.. press the tackiness agent that prior art for preparing is made up of elastic resin, tackifying resin, softening agent, fat hydrocarbon solvent oil, oxidation inhibitor, whitening agent;
2.. the preparation of emulsifying agent: mix by following component and weight percent, be heated to 80～100 ℃, stir into emulsion;
A. by one or more the mixture 12-36 in glycerol, propylene glycol, ethylene glycol, a condensed ethandiol, tirethylene glycol, the deionized water;
B. Tutofusin tris, 2-amino-2-hydroxyl-1, ammediol, 5, the mixture 4-25 of one or more in the 5-T10;
C. by sorbitan fatty acid ester 25-55, polyoxyethylene sorbitan fatty acid ester 6-25, stearylamide ethyl dimethyl-beta-hydroxyethyl ammonium nitrate 10-35 compounded surfactant.
3.. in non-polar adhesive, add the emulsifying agent of 0.5-3% (weight), stir, add 0.1-2% (weight) again, leave standstill after the stirring, filter and be finished product by the solubility promoter that one or more the mixture in ethanol, propyl alcohol, the butanols constitutes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410023332 CN1234797C (en) | 2004-06-21 | 2004-06-21 | Polypropylene tow forming adhesive for cigarette |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410023332 CN1234797C (en) | 2004-06-21 | 2004-06-21 | Polypropylene tow forming adhesive for cigarette |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1594482A true CN1594482A (en) | 2005-03-16 |
| CN1234797C CN1234797C (en) | 2006-01-04 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200410023332 Expired - Fee Related CN1234797C (en) | 2004-06-21 | 2004-06-21 | Polypropylene tow forming adhesive for cigarette |
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| Country | Link |
|---|---|
| CN (1) | CN1234797C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101793885A (en) * | 2010-03-02 | 2010-08-04 | 重庆烟草工业有限责任公司 | Method for measuring ammonium content of watersoluble glue used for forming cigarette polypropylene fiber tow filter rods |
| CN102771893A (en) * | 2011-05-09 | 2012-11-14 | 湖北中烟工业有限责任公司 | Tip rod adopting chitosan fiber beams as filter materials and preparation method of tip rod |
| WO2023092854A1 (en) * | 2021-11-29 | 2023-06-01 | 内蒙古昆明卷烟有限责任公司 | High-efficiency tar-reducing cigarette filter, and preparation method therefor and application thereof |
-
2004
- 2004-06-21 CN CN 200410023332 patent/CN1234797C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101793885A (en) * | 2010-03-02 | 2010-08-04 | 重庆烟草工业有限责任公司 | Method for measuring ammonium content of watersoluble glue used for forming cigarette polypropylene fiber tow filter rods |
| CN101793885B (en) * | 2010-03-02 | 2013-03-06 | 重庆烟草工业有限责任公司 | Method for measuring ammonium content of watersoluble glue used for forming cigarette polypropylene fiber tow filter rods |
| CN102771893A (en) * | 2011-05-09 | 2012-11-14 | 湖北中烟工业有限责任公司 | Tip rod adopting chitosan fiber beams as filter materials and preparation method of tip rod |
| CN102771893B (en) * | 2011-05-09 | 2014-05-07 | 湖北中烟工业有限责任公司 | Tip rod adopting chitosan fiber beams as filter materials and preparation method of tip rod |
| WO2023092854A1 (en) * | 2021-11-29 | 2023-06-01 | 内蒙古昆明卷烟有限责任公司 | High-efficiency tar-reducing cigarette filter, and preparation method therefor and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1234797C (en) | 2006-01-04 |
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