CN1594455A - Method for manufacturing infrared radiation coating by using waste abrasive particles - Google Patents

Method for manufacturing infrared radiation coating by using waste abrasive particles Download PDF

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Publication number
CN1594455A
CN1594455A CN 200410041005 CN200410041005A CN1594455A CN 1594455 A CN1594455 A CN 1594455A CN 200410041005 CN200410041005 CN 200410041005 CN 200410041005 A CN200410041005 A CN 200410041005A CN 1594455 A CN1594455 A CN 1594455A
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Prior art keywords
infrared radiation
radiation coating
abrasive particle
high temperature
abrasive particles
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CN 200410041005
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CN1271151C (en
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周锦才
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Publication of CN1271151C publication Critical patent/CN1271151C/en
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Abstract

The invention discloses a method for manufacturing an infrared radiation coating by using waste abrasive particles, which comprises the following steps: recovering waste abrasive particles of the grinding wheel; removing impurities in the waste abrasive particles by using a screening tool; mixing the waste abrasive particles with high-temperature-resistant ingredients, and uniformly stirring and mixing to obtain a matrix raw material of the infrared radiation coating; preparing a carrier binder, adding the matrix raw material into the carrier binder, stirring into a thin paste fluid, and sealing and storing the infrared radiation coating. When preparing the matrix raw material, the high-temperature phase equilibrium relationship is adopted, the ingredient composition of the matrix is reasonably designed, so that the phase composition and the microstructure which are suitable for the use condition are obtained through high-temperature in-situ reaction in the use process, and the ceramic matrix has high bonding strength, ceramic property, high temperature resistance, abrasion resistance, wear resistance and high radiance. The invention can realize the recycling of the waste abrasive particles, has low production cost and lightens the environmental pollution.

Description

A kind of method of utilizing useless abrasive particle manufacturing infrared radiation coating
Technical field
The present invention relates to a kind of method of utilizing the useless abrasive particle that produces in the wheel grinding polishing process to make infrared radiation coating.
Background technology
The useless abrasive particle that at present emery wheel abrasive material, grinding tool is produced when the processing metal members generally is to process in the presence of industrial refuse, and both contaminated environment has been wasted again the host material of valuable preparation coatings capable of preventing from far infrared radiation.
Summary of the invention
The invention provides a kind of method of utilizing useless abrasive particle manufacturing infrared radiation coating, adopt this method to produce infrared radiation coating, production cost is low, realizes the regeneration of useless abrasive particle, can not cause environmental pollution again simultaneously.
Technical scheme of the present invention is as follows: utilize useless abrasive particle to make the method for infrared radiation coating, it comprises the steps:
1), reclaims the useless abrasive particle of emery wheel;
2), with the impurity in the useless abrasive particle of screening instrument removing;
3), will give up abrasive particle and high temperature resistant batching carry out proportioning, through mix the base starting material of infrared radiation coating;
4), the formulation vehicle binding agent, base starting material is added in the carrier adhesive, stir into the scattered paste shape fluid, remove the gas in the fluid after, get the infrared radiation coating sealing and preserve.
Described in the present invention high temperature resistant batching is according to the employed temperature difference of coatings capable of preventing from far infrared radiation, selects different materials for use.Described high temperature resistant batching can be the high alumina fine powder, and the mol ratio of it and useless abrasive particle is 1: 1.5--2; Described high temperature resistant batching can be schmigel, and the mol ratio of it and useless abrasive particle is 1: 1.5--2; Described high temperature resistant batching also can be Al 2O 3Super fine, the mol ratio of it and useless abrasive particle is 1: 1; Described high temperature resistant batching can also be SiO 2Super fine, the mol ratio of it and useless abrasive particle is 1: 1.
Described carrier adhesive is that concentration is about 40% phosphoric acid.
If the useless abrasive particle oxidation bunching caking that is reclaimed should become powder shaped with the abrasive particle grinding that gives up earlier before screening.
For reducing cost, the gas of removing in the fluid can adopt the ageing mixture method, and the ageing mixture time is 10-24 hour.
The emery wheel grinding tool in the grinding work piece process, emery wheel powder and alloy powder particle that mutually friction, wearing and tearing produce, its main chemical analysis is Al 2O 3, SiC, TiO 2, Na 2O, Fe 2O 3, Cr 2O 3, they are high-grade refractory materials, also are the base starting materials of excellent preparation ceramic infrared radiation coating.Above-mentioned useless abrasive particle is combined with carrier adhesive phosphoric acid and is namely consisted of the original position refractory material, use through on-the-spot, its composition is tended to balance or generating cenotype, no longer is original state and make the composition of refractory material for working layer and microstructure, consists of SiC--Al 2O 3Base, CrO 3--Al 2O 3Base, ZrO 2--Al 2O 3--SiO 2The high radiant refractory material of base.Utilize the emery wheel abrasive particle that gives up in the present invention, by the high temperature phase equilibrium relationship, the batching of appropriate design matrix is formed, make infrared radiation coating in use obtain to adapt to the phase composite and the microstructure of working conditions, its bonding strength height, potteryization, high temperature resistant, erosion resistant, wear-resistant and have than high radiant rate through high-temp in-situ reaction.Carrier adhesive phosphoric acid almost can be used for all refractory raw materials and be mixed with castable refractory, it can form strong combination and generate compound with oxide in addition, forms polymerization, bur surface, form Ceramic bond by high temperature, therefore select in the present invention phosphoric acid as carrier adhesive.Selecting different high temperature resistant batchings is in order to satisfy different service conditions, to be the high alumina fine powder such as batching, being applicable to about 1300 degree; Select schmigel, serviceability temperature is about 1600 degree; Select Al 2O 3Super fine, serviceability temperature is more than 1600 degree; Select SiO 2Super fine, serviceability temperature are also more than 1600 degree.Owing to only add a kind of batching, batching is simple, and does not add low-melting agglutinant, and the coatings formulated resistance to elevated temperatures is good.The paint brush of manufacturing of the present invention is applied to kiln metope formation fire-resistant coating, protection refractorily lined chemical resistance of concrete, high temperature resistant flue gas flow, grit wearing and tearing, the high radiative transfer in furnace wall, the work-ing life of prolongation furnace wall.
After adopting technical scheme of the present invention, can realize the regeneration of useless abrasive particle, production cost is low, has alleviated again environmental pollution.This application of paints in flame-proof kiln, can be saved energy and reduce the cost, increase the service life.
Embodiment
The present invention utilizes useless abrasive particle to make the method for infrared radiation coating, and it is achieved in that reclaims the useless abrasive particle of emery wheel, with good conditionsi can storing classifiedly by the powder that emery wheel material kind will be gathered recovery.The useless abrasive material of emery wheel is wet or accumulation overlong time because of torrent, powdered alloy oxidation bunching caking, and the use properties of powder is unaffected behind grinding.Make the screening instrument with Stainless Steel Cloth, remove the impurity in the powder.According to different serviceability temperatures, will give up abrasive particle and high temperature resistant batching are carried out proportioning, through mix the base starting material of infrared radiation coating.Useless abrasive particle of emery wheel in the base starting material and high alumina fine powder (granularity is 0.088mm) mol ratio are 1.5: 1 or 2: 1, and use temperature is about 1300 degree.Useless abrasive particle of emery wheel in the base starting material and lapis amiridis (granularity is 120 orders) mol ratio are 1.5: 1 or 2: 1, and use temperature is about 1600 degree.Carborundum and Al in the base starting material 2O 3The super fine mol ratio is 1: 1, and serviceability temperature is more than 1600 degree.The compound and the SiO of the useless abrasive particle of base starting material medium plain emery wheel 2The ultra-fine micropowder mol ratio is 1: 1, and use temperature is also more than 1600 degree.Powder body material in mass ratio weighing accurately mixes evenly by mixer.It is about 40% that the PHOSPHORIC ACID TECH.GRADE thin up is become concentration, and the mass ratio of strong phosphoric acid and water is 1: 1.Earlier weighing is needed with water pour in the container, the weighing SPA slowly is added to the water again, the limit edged stirs, until evenly.The base starting material adding has been diluted in the good phosphoric acid solution, because the irony in phosphoric acid acid group and the base starting material is swift in response, has produced a large amount of bubbles and cause that feed liquid overflows, accelerated mixing speed gas is outwards discharged, it is excessive to suppress coating mud.When stirring into sposh shape fluid, ageing mixture 16 hours is promptly finished the preparation infrared radiation coating.With the infrared radiation coating for preparing plastic tank sealed storage.Settling with wire brush or pressurized air cleaning refractory brick surface.Handwork with the charging of dustpan formula hawk, is evenly coated on the wall with hairbrush.Large tracts of land adopts spray gun spraying.Its thickness is few≤2mm, and 2.5 kilograms/square metre of materials amounts, natural air drying.
In the present invention, carrier adhesive also can be waterglass aqueous solvent or silicon-aluminum sol, but effect does not have phosphoric acid good.For making the air release in the coating fluid, also can add foam-reducing or foam inhibitor in addition, just do not needed ageing mixture, but the cost of ageing mixture be low.

Claims (9)

1, a kind of method of utilizing useless abrasive particle manufacturing infrared radiation coating, it comprises the steps:
1), reclaims the useless abrasive particle of emery wheel;
2), with the impurity in the useless abrasive particle of screening instrument removing;
3), will give up abrasive particle and high temperature resistant batching carry out proportioning, through mix the base starting material of infrared radiation coating;
4), the formulation vehicle binding agent, base starting material is added in the carrier adhesive, stir into the scattered paste shape fluid, remove the gas in the fluid after, get the infrared radiation coating sealing and preserve.
2, the method for manufacturing infrared radiation coating according to claim 1 is characterized in that described high temperature resistant batching is according to the employed temperature difference of infrared radiation coating, selects different materials for use.
3, the method for manufacturing infrared radiation coating according to claim 2 is characterized in that described high temperature resistant batching is the high alumina fine powder, and the mol ratio of it and useless abrasive particle is 1: 1.5---2.
4, the method for manufacturing infrared radiation coating according to claim 2 is characterized in that described high temperature resistant batching is a lapis amiridis, and the mol ratio of it and useless abrasive particle is 1: 1.5---2.
5, the method for manufacturing infrared radiation coating according to claim 2 is characterized in that described high temperature resistant batching is Al 2O 3Super fine, the mol ratio of it and useless abrasive particle is 1: 1.
6, the method for manufacturing infrared radiation coating according to claim 2 is characterized in that described high temperature resistant batching is SiO 2Ultra-fine micropowder, the mol ratio of it and useless abrasive particle is 1: 1.
7, the method for manufacturing infrared radiation coating according to claim 1 is characterized in that described carrier adhesive is that concentration is about 40% phosphoric acid.
8, the method for manufacturing infrared radiation coating according to claim 1 is characterized in that described useless abrasive particle carried out grinding earlier before screening, and the useless abrasive particle grinding that the oxidation bunching is lumpd becomes powder.
9, the method for manufacturing infrared radiation coating according to claim 1, the gas that it is characterized in that removing in the fluid can adopt ageing mixture 10-24 hour.
CN 200410041005 2004-06-18 2004-06-18 Method for manufacturing infrared radiation coating by using waste abrasive particles Expired - Fee Related CN1271151C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200410041005 CN1271151C (en) 2004-06-18 2004-06-18 Method for manufacturing infrared radiation coating by using waste abrasive particles

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Application Number Priority Date Filing Date Title
CN 200410041005 CN1271151C (en) 2004-06-18 2004-06-18 Method for manufacturing infrared radiation coating by using waste abrasive particles

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CN1594455A true CN1594455A (en) 2005-03-16
CN1271151C CN1271151C (en) 2006-08-23

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103072983A (en) * 2012-12-19 2013-05-01 广东奔朗新材料股份有限公司 Ceramic grinding wheel abrasive recovery method
CN106187273A (en) * 2016-07-25 2016-12-07 滁州市瑞景园林建设有限公司 A kind of little porous brick of deflection
CN106187096A (en) * 2016-07-25 2016-12-07 安徽圆梦建筑有限公司 A kind of emery wheel ash hollow brick and preparation method thereof
CN106187272A (en) * 2016-07-25 2016-12-07 滁州市瑞景园林建设有限公司 A kind of crack resistence porous brick
CN106220143A (en) * 2016-07-25 2016-12-14 滁州市瑞景园林建设有限公司 A kind of low cost wall brick

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103072983A (en) * 2012-12-19 2013-05-01 广东奔朗新材料股份有限公司 Ceramic grinding wheel abrasive recovery method
CN103072983B (en) * 2012-12-19 2014-09-17 广东奔朗新材料股份有限公司 Ceramic grinding wheel abrasive recovery method
CN106187273A (en) * 2016-07-25 2016-12-07 滁州市瑞景园林建设有限公司 A kind of little porous brick of deflection
CN106187096A (en) * 2016-07-25 2016-12-07 安徽圆梦建筑有限公司 A kind of emery wheel ash hollow brick and preparation method thereof
CN106187272A (en) * 2016-07-25 2016-12-07 滁州市瑞景园林建设有限公司 A kind of crack resistence porous brick
CN106220143A (en) * 2016-07-25 2016-12-14 滁州市瑞景园林建设有限公司 A kind of low cost wall brick

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