Background technology: well-known, after the eighties in last century, there is numerous companies to produce the water treating apparatus product both at home and abroad.The water outlet of continous way water treating apparatus continuous electrolysis, computer control is easy to use, but shortcoming is can not remove various salts, heavy metal, the fluorine that is dissolved in the tap water and can not make water softening.ZL93225177.3 is the interval type water treating apparatus, though overcome the above-mentioned shortcoming of continous way water treating apparatus, inconvenience is used in manual operations.
It also is with the tap water electrolysis that high oxidation electric potential sterilized water generates machine, but earlier will be in the tap water before the electrolysis with salt (Nacl or Kcl), and need one to overlap complicated operating device, control electrolytic parameter, make the anode water outlet reach the technical indicator of high oxidation electric potential sterilized water, ORP>+1000mv, PH<2.7, so the equipment price costliness.The for example Japanese Sheng Tai SUNTECH-1000 of section acidified water generating apparatus per minute generates 1.1 liters of sterilized waters, 19.8 ten thousand yuan of price Renminbi.ZL01210497.3 is the fully automatic high oxidation electric potential sterilized water generator of interval type.Its anode generates high oxidation electric potential sterilized water, and the water that negative electrode generates is because with no longer drinking after the salt.
Though more than two kinds of products all be with the tap water electrolysis, water treating apparatus can not generate high oxidation electric potential sterilized water, the high oxidation electric potential sterilized water machine then can not generate health-care drinking-water simultaneously.
The purpose of invention: the interval type water treating apparatus is become does not need the full-automatic product of labor management, this interval type water treating apparatus is held concurrently simultaneously produce high oxidation electric potential sterilized water.
Summary of the invention: the structure diagram of interval type water treating apparatus as shown in Figure 1.It is made up of electrolyzer, direct supply and controller, water inlet system and outlet system.Wherein the formation of electrolyzer comprises that anode electrode metal plate (4) is equipped with in electrolyzer casing (1), barrier film (3) (be separated into about two partly), left side, cathode electrode metal plate (5) is equipped with on the right side to box house; Water inlet system is by water inlet pipe (8), magnetic valve V
1And liquidometer (2) is formed; Outlet system is by water shoot (9), water tap (6) and (7) and magnetic valve V
2And V
3Form; Direct supply and controller (10) are rectified into 100~190V dc electrolysis voltage by alternating current 220V, and it is the time variable control of coordinate that controller adopts with the clock; Have one with salt aperture (11) in electrolyzer casing top left side.
The electrolyzer casing is by the injection moulding of food grade engineering plastics; Barrier film micropore ceramics material; Electrode metal plate not corrodible titanium alloy Ban Jia Tu inert metal ruthenium or platinum manufacturing; Magnetic valve is a normally closed type; Controller any in programmable controller, micro-chip or the mimic channel.
Fig. 2 is for being the time variable control skeleton diagram of coordinate with the clock.From the time T of setting
0Start, program I is the surplus water of row; Program II is flushing; Program III is a water-filling; Program IV is electrolysis; Program V is natural sedimentation.During steering routine I, open V
2And V
3, with the surplus water emptying in electrolyzer both sides.Through setting-up time t
1Steering routine II flushing, V are continued in the back
1Open V
2Close V
3Open, water inlet is full of the left side and overflows into the right side by barrier film, because V
3Still open water inlet just with right side bottom settlings thing from V
3Discharge.Through setting-up time t
2Back steering routine III water-filling, V
3Close right side water level rising and locate V until liquidometer (2)
1Close.Steering routine IV electrolysis more immediately, the direct current input is through setting-up time t
3Back electrolysis finishes.That continue is natural sedimentation program V, and direct supply closes, because direct supply and magnetic valve have all been closed so controller does not need to control again, enters dormant state.Steering routine I-V needs more than 1 hour, T
oBe set in the length of one's sleep in the late into the night, when use daytime in the electrolyzer suspension floss that reaction generated of negative electrode one side all be deposited to the bottom, so what take all is clear water.The electrolysis time of interval type electrolyzer is long, generally need 30-60 minute, a series of electrochemical reaction and chemical reaction can take place in electrolytic process, ion can pass the exchange of barrier film micropore, and positive ion is enriched to negative electrode, and negative ion is enriched to anode, a part of heavy metal ion can deposit to negative electrode metal plate surface reduction and become metal, electrode make cathode surface contaminated, so after after a while, must clean to recover its conducting function.Calcium ions and magnesium ions and other metal ion meeting except that potassium sodium and the hydroxide ion in the negative electrode water are combined to undissolved oxyhydroxide separates out; microorganisms such as bacterium all can be killed; the protein of its corpse also can be charged; the colloidal solid that is not removed in the tap water also can take off surely; all these these particulates can produce the electrocoagulation reaction; produce a large amount of white flosss; be suspended in the water; because their proportion overweights water slightly; so need a natural sedimentation process; generally all can be deposited to the bottom, obtain very clear water through five or six hours.The physical characteristic change of negative electrode water outlet is very big after the electrolysis, and tap water is the macromolecular mass water (13 left and right sides water moleculess are formed) of loss of activity, becomes active small-micelle water (6 left and right sides water moleculess are formed) after the electrolysis, and its solubleness is big and osmotic pressure is little; Nearly neutral tap water becomes the slight alkalinity water that is about PH9-10.5; The oxidisability tap water (be about ORP+200~+ 500mv) change into reductibility water (be about ORP-750~-850mv).Small-micelle water can promote nutrition to absorb as the food and drink water and metabolism rubbish is drained, low negative reduction potential can be removed active oxygen (oxyradical) superfluous in the body, so what interval type water treating apparatus cathode side generated is fabulous health-care drinking-water, is the water that perfectly sterile can directly be drunk.The water that its anode generates is clear water, does not have any precipitate, also is the subset active water, is about PH3-5, ORP+700-+900mv.Certain disinfection is arranged but can not use, have convergency as sterilizing agent; Certain skin or hair care function is arranged.
The purging method of electrode is easy to finish, if in electrolysis negative electrode and anode reversal connection, the settling of cathode surface dissolving rapidly as anode time during electrolysis so only need just can be removed by once electrolytic fully.So cleaning electrode also can be automatically performed by controller, method is to establish the switch counter of an electrolysis direct current power supply in controller, and set a number N, when being the multiple of N, the electrolysis number of times prepares to clean the positive and negative electrode reverse graft of direct current output with regard to the program VI in the execution graph 2.During this day To, performed program I-V is the electrolysis of falling the utmost point, and is subsequent with regard to steering routine VII end cleaning, and direct current output positive and negative electrode is resetted, and carries out normal electrolysis program I-V more immediately.As can be seen from Figure 2 the water that is generated in the process of cleaning electrode is waste discharge immediately.
High oxidation electric potential sterilized water is the green disinfectant of the high-efficiency broad spectrum of new generation sterilization of substituted chemistry sterilizing agent, can 100% kill all bacteriophagees and harmless fully to environment in the several minutes at several seconds.Past can not be popularized use because machine is too expensive.So its machine price is expensive is because need the complicated Controlling System of a cover.Only needing in the present invention increases by one with salt aperture (11) at the anode side top of above-mentioned interval type water treating apparatus, when electrolysis begins, add a small amount of salt, just can when water treating apparatus makes health-care drinking-water, obtain qualified high oxidation electric potential sterilized water in anode one side.The water treating apparatus electrolytic process can not add any control in addition.Salt adding amount also can change in a big way.Generally be 0.01~0.05%, the long salt adding amount of electrolysis time is less, and the short salt adding amount of electrolysis time is some more.When holding concurrently the manufacturing high oxidation electric potential sterilized water, the negative electrode water outlet still can be drunk as usual, and its difference only is that the Na ion concentration in the water increases slightly.When need mending potassium ion, human body can use the Kcl instead of table salt.The present invention is confirmed in experiment, can obtain also on the principle explaining that regular high oxidation electric potential sterilized water machine is pursued is high yield under the stabilised quality prerequisite, continous way electrolysis time only several seconds, the interval type electrolysis is a several minutes, so reliable operating device must be arranged.Electrolysis time can reach 30~60 minutes among the present invention, though salt adding amount is less like this, electrolysis power is also much smaller, because of long reaction time, can reach the index of high oxidation electric potential sterilized water equally.The high oxidation electric potential sterilized water that the inventor once will produce with this method, its PH are 2.5, ORP is 1100mv, and Jining Medical College microorganism teaching and research room makes sterile test through Shandong, the result be 30 minutes after 37 ℃ cultivated 18 hours, make 5 * 10
7Individual/c.c intestinal bacteria 100% kill 5 * 10
7Individual/c.c staphylococcus aureus has only 1 colony growth, also is near 100%.Prove that it has fabulous sterilisation effect.
Fig. 1 explanation: (1) electrolyzer casing (2) liquidometer (3) barrier film (4) anode electrode metal plate (5) cathode electrode metal plate (6) water tap (7) water tap (8) water inlet pipe (9) water shoot (10) direct supply and controller (11) are with salt aperture V
1, V
2, V
3Be normally closed solenoid valve
Fig. 2 explanation: Fig. 2 is for being the time variable control skeleton diagram of coordinate with the clock, and the lastrow literal is a program name in the square frame, middle behavior DC power supply switch state, following behavior electromagnetic valve switch state.Direct supply and magnetic valve complete shut-down promptly no longer need be controlled after wherein program V carried out.To is start time every day of setting, t among the figure
1, t
2, t
3Be the controlled variable of in software, setting with N.
Embodiment: the water storage of electrolyzer casing is applicable to 4 mouthfuls family according to the user number design in this example, and gross reservoir capacity is 15 liters, and wherein cathode side is 9 liters, and anode side is 6 liters.The input of direct supply alternating current 220V is output as direct current 100~190V.Controller panel is provided with electrolysis voltage 100V/150V/190V and 2 system selector switches of 30/45/60 minute of electrolysis time.Software control parameter To is 23:00, t
1, t
2Be 10 ', t
3Select 45 for use ', N is 10.Electrolysis direct current voltage is selected 190V for use.Pilot lamp when panel is provided with the electrolysis energising.
In the present embodiment, midnight, the 23:00 controller started, steering routine I, V
2And V
3Energising is opened, is drained this sky and do not use up surplus water; 23:10 ' V
1And V
3Open, tap water enters from the anode bottom and overflows into right side flushing cathode side bottom settlings thing by barrier film; 23:20 ' V
3Close, when water level rises to liquidometer (2) from the beginning, V
1Close and export the 190V direct current simultaneously and begin electrolysis; 0:05 ' electrolysis finishes power supply and magnetic valve complete shut-down, and controller is in dormant state.If had 6 hours natural sedimentation process morning when 6 users use, the tap water of taking is limpid fully, and pH value is about 10~10.5.ORP is about-800~-850mv, directly drink and have extraordinary nourishing function.Make high oxidation electric potential sterilized water if desired, then when 23:20 ' back power light is glittering, add 1-2 gram salt from aperture (11), after 0:05 ' pilot lamp extinguishes can from water tap (6) put PH<2.7, ORP>+sterilized water of 1000mv.The point of attention is that electrolysis finishes the back and just sterilized water should be poured in airtight glass or the plastic containers standbyly, should not store in electrolyzer, can decay and influences sterilisation effect because ORP value.
That present embodiment uses is the FX-IS type PLC (programmable controller) of MIT.