CN1587496A - Sol-gel anti-ultraviolet finishing method for cotton fabric - Google Patents
Sol-gel anti-ultraviolet finishing method for cotton fabric Download PDFInfo
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- CN1587496A CN1587496A CN 200410053059 CN200410053059A CN1587496A CN 1587496 A CN1587496 A CN 1587496A CN 200410053059 CN200410053059 CN 200410053059 CN 200410053059 A CN200410053059 A CN 200410053059A CN 1587496 A CN1587496 A CN 1587496A
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Abstract
The present invention performs anti-ultraviolet finishing of cotton fabric by means of sol-gel technology, and in a rolling-stoving-roasting process with tetrabutyl titanate as precursor for preparing titanium-containing nanometer solution. At the same time, fluorescent whitening agent and synthetic latex are used to make the fabric possess excellent lasting anti-ultraviolet performance while producing few influence on the hand feeling and mechanical and physical performance of the fabric.
Description
Technical field:
The invention belongs to chemical technology field, be specifically related to a kind of colloidal sol-gel uvioresistant method of COTTON FABRIC.
Background technology:
The basic principle of colloidal sol-gel technique is metal alkoxide or inorganic salts hydrolysis are directly formed or to form colloidal sol with fixed attention through separating, and makes the solute gelation then, again with gel drying, bake, remove organic principle, obtain inorganic material at last.Be mainly used in preparing on glass, superfine powder and the film at present, adopt 300～800 ℃ high-temperature roasting, when the system film, adopt smooth surfaces such as glass, metal, plastics to carry out coating as matrix, form continuous film in stromal surface, combine by Van der Waals force between film and the carrier, do not have chemical bond.It is unpractical that such technology is used on the textiles, because textiles can't bear high-temperature roasting.
It is a special kind of skill that new development is got up that the utilization nanometer technology improves the fabric uvioresistant performance, also is in the exploratory stage at present, as add nano-TiO in spinning process
2, SiO
2, the ZnO particle textile fabric, perhaps with nano-TiO
2, ZnO, SiO
2Microparticulate is carried out coating etc. to textiles in coating agent, but also exist some that problem to be solved is arranged, dispersion problem as nanoparticle, nanoparticle is in the associativity of fabric with in conjunction with the fastness problem, and the interpolation of nanoparticle is to the problems such as influence of the physicochemical properties of fiber and fabric itself.
So people expect to occur a kind of novel nano uvioresistant method that overcomes direct employing nano material dispersion and emulsion post processing fabric, give the uvioresistant performance of cotton textiles excellence, washability is good and the fabric Physical Mechanical loss of energy is little.
Summary of the invention:
The sol-gel uvioresistant method that the objective of the invention is a kind of COTTON FABRIC.
The present invention adopts butyl titanate to prepare stable, the transparent Nano sol that contains titanium elements under certain condition as presoma, under certain condition fabric is put in order, directly form the nanogel particle at fabric face, strong absorption and uv reflectance, give the uvioresistant performance of fabric excellence, overcome the shortcoming of nano particle a little less than easy gathering and adhesion on the fabric, given play to the nano particle special performances simultaneously.
The present invention uses synthetic latex not only to strengthen the uvioresistant durability of fabric, and improves the uvioresistant ability of fabric greatly, use fluorescent whitening agent strengthened fabric at the UVA wave band to ultraviolet absorbability, improved the whiteness of fabric simultaneously.
A kind of gel-sol uvioresistant method of the present invention comprises the following steps:
(1) preparation dressing liquid
Form by following percentage by weight material:
Butyl titanate: 0.1%～15%
Organic solvent: 0%～80%
Hydrochloric acid: 0.03%～0.1%
Acetic acid: 2%～25%
Described organic solvent is the organic solvent that dissolves each other with water, as ethanol, isopropyl alcohol, ethylene glycol, acetone, acetonitrile etc., with alcohols solvent for well.
The preparation method:
Butyl titanate is dissolved in the acetic acid, and the acetum with butyl titanate under mechanical agitation is added drop-wise in the aqueous solution that contains hydrochloric acid and organic solvent, stir certain hour under the room temperature after ageing obtained transparent titaniferous colloidal sol in 24 hours.
(2) titanium colloidal sol arrangement
COTTON FABRIC two is soaked two and rolled pressure 2～3kg/cm in above-mentioned dressing liquid
2, liquid carrying rate 60～70% is dried in convection oven, washes then or with alkali neutralization (remove excessive acid on the fabric, avoid high temperature to bake and cause the fabric strength loss), bakes 3～5 minutes at 100～180 ℃ at last.
(3) brighten processing
Cotton have stronger absorbability with fluorescent whitening agent to the ultraviolet ray of 320～400nm (UVA) wave band, and fabric obviously improves in the uvioresistant ability of UVA wave band through after brightening processing, and whiteness also is improved simultaneously.
As the VBL fluorescent whitening agent, concrete grammar is as follows: use VBL fluorescent whitening agent 0.1～0.5% (heavy to fabric), inorganic base with the monovalence metal is regulated pH to 8～9, as NaOH or potassium, sodium carbonate or potassium, sodium bicarbonate or potassium etc., but with carbonate or bicarbonate for well; bath raio 50: 1,50 ℃ will be immersed in the container 10～30 minutes down through the COTTON FABRIC of titanium colloidal sol arrangement.
(4) synthetic latex post processing
In order to improve the uvioresistant durability of nanogel particle, fabric needs to handle with synthetic latex behind (3) anti UV finishing.As use the polyacrylate synthetic latex, concrete grammar is as follows:
COTTON FABRIC two is soaked two and rolled pressure 2～3kg/cm in the dressing liquid of synthetic latex
2, liquid carrying rate 60～70% is with the oven dry below 100 ℃ in convection oven of the fabric after the arrangement.
Described synthetic latex is the polyacrylate synthetic latex.Described COTTON FABRIC and synthetic latex percentage by weight are: 0.1～8%.
The present invention selects for use butyl titanate to prepare the Nano sol of titaniferous as precursor, the method for sorting of this suitable textiles is padded in employing, only need textiles is carried out 100～180 ℃ heat treatment, can form the nano titania gel particles on the inside and outside surface of fiber, it has strong reflection and absorption to ultraviolet ray, the combined with fluorescent brightening agent is handled fabric simultaneously, greatly reduces the ultraviolet transmittance of fabric, reaches anti-ultraviolet purpose.The use of arrangement back synthetic latex has improved uvioresistant ability of fabric and durability greatly.
This uvioresistant method is different with existing nano material uvioresistant method, and it is that utilization colloidal sol-gel process forms the nano titania gel particles on fabric, thereby plays uvioresistant effect.Overcome the shortcoming of conventional nano particle a little less than easily gathering on the fabric, easy migration and adhesion, given play to the nano particle special performances simultaneously.
Advantage of the present invention
Compare with the anti-ultraviolet method of nano material with traditional sol-gel processing technology, the present invention has the following advantages:
1. baking temperature is low, only need bake at 100～180 ℃, than low 200～600 ℃ of the baking temperature of traditional colloidal sol-gel process;
2. when having overcome the nano particle finish fabric difficult disperse with and the problem of poor stability; Overcome nano particle on fabric, easily assemble, easily migration, disperse uneven shortcoming; Overcome a little less than nano particle and the fabric adhesion weakness of washability difference.
3. the use of fluorescent whitening agent has strengthened the absorbability of fabric to 320～400nm (UVA) band ultraviolet, has improved the whiteness of fabric simultaneously.
4. the use of synthetic latex improves the uvioresistant durability of fabric, but also has significantly strengthened the uvioresistant ability of fabric.
Description of drawings:
Fig. 1 is the ultraviolet transmission rate curve figure of COTTON FABRIC before and after the inventive method is handled.
The specific embodiment:
Example can further be understood the present invention by experiment.But can not limit content of the present invention.Preparation process described in the embodiment and fabric performance test are as follows:
(1) preparation of dressing liquid
Butyl titanate is dissolved in the acetic acid, in the aqueous solution of the organic solvent that under mechanical agitation, the acetum of butyl titanate is added drop-wise to hydrochloric acid and dissolves each other with water, the percentage by weight of above-mentioned substance is followed successively by: 0.1%～15%, 2%～25%, 0.03%～0.1% and 0%～80% they are mixed, 300～600 rev/mins of mixing speeds, at room temperature stirred ageing 24 hours 2 hours.
(2) titanium colloidal sol arrangement
COTTON FABRIC two is soaked two and rolled pressure 2～3kg/cm in above-mentioned dressing liquid
2, liquid carrying rate 60～70% is dried in convection oven, washes or with alkali neutralization (remove excessive acid on the fabric, avoid high temperature to bake and cause the fabric strength loss), bakes 3～5 minutes at 100～180 ℃ then.
(3) brighten processing
Cotton have stronger absorbability with fluorescent whitening agent to the ultraviolet ray of 320～400nm (UVA) wave band, and fabric obviously improves in the uvioresistant ability of UVA wave band through after brightening processing, and whiteness also is improved simultaneously.
As the VBL fluorescent whitening agent, concrete grammar is as follows: use VBL fluorescent whitening agent 0.1～0.5% (heavy to fabric), regulate pH to 8～9 with sodium carbonate, bath raio 50: 1 is immersed in cloth under 50 ℃ in the container 10～30 minutes.
(4) synthetic latex post processing
In order to improve the uvioresistant durability of Nano sol particle, need behind the fabric anti UV finishing to handle with synthetic latex.As use the polyacrylate synthetic latex, concrete grammar is as follows:
COTTON FABRIC two is soaked two and rolled pressure 2～3kg/cm in the dressing liquid of polyacrylate synthetic latex (0.1～8%)
2, liquid carrying rate 60～70% is dried the cloth after the arrangement in convection oven, and temperature is generally below 60～100 ℃.
(5) finish fabric is carried out every index test, specific as follows:
1. ultraviolet transmission rate and ultraviolet protection coefficient (Ultraviolet Protection Factor) test
UPF uses U.S. Labsphere company to produce UV-1000F ultraviolet transmission rate analyzer and records according to AS/NZS 4399-96 standard.
2. water-wash resistance is tested according to AATCC Test Method 135-2000.
3. tearing brute force is according to ASTM D1424-96 standard testing
4. tensile strength is according to ASTM D5034-95 standard testing
5. the fabric bending stiffness is according to the ZBW04003-87 standard testing
Embodiment (1)
Plain woven cotton (140g/m
2) the anti UV finishing step as follows:
Cotton (140g/m
2) in the colloidal sol dressing liquid, two soak two and roll pressure 3kg/cm
2, liquid carrying rate 60～70%, 70 ℃ of oven dry in convection oven, washing baked 5 minutes at 130～150 ℃ at last then.
Embodiment (2)
Plain woven cotton (140g/m
2) the anti UV finishing step as follows:
1. cotton (140g/m
2) two soak two and roll pressure 3kg/cm in people's colloidal sol dressing liquid
2, liquid carrying rate 60～70%, 70 ℃ of oven dry in convection oven, washing baked 5 minutes at 150 ℃ at last then.
2. with fabric 25 minutes (pH=8～9, bath raio 50: 1,50 ℃ of temperature) of dipping in the aqueous solution that contains 0.4% (heavy) VBL fluorescent whitening agent to fabric
Embodiment (3)
Plain woven cotton (140g/m
2) the anti UV finishing step as follows:
1. cotton (140g/m
2) in the colloidal sol dressing liquid, two soak two and roll pressure 3kg/cm
2, liquid carrying rate 60～70%, 70 ℃ of oven dry in convection oven, washing baked 5 minutes at 150 ℃ at last then.
2. with fabric 25 minutes (pH=8～9, bath raio 50: 1,50 ℃ of temperature) of dipping in the aqueous solution that contains 0.4% (heavy) VBL fluorescent whitening agent to fabric
3. fabric two is soaked two and rolls pressure 3kg/cm in the dressing liquid that contains polyacrylate low temperature synthetic latex (4%)
2, liquid carrying rate 60～70% is dried the cloth after the arrangement down at 100 ℃ in convection oven.
UPF estimates before and after table 1 fabric treating
| Sample | ????UPF | ????T(UVA) | ????T(UVB) | UPF progression |
| Former state | ????6.51 | ????22.60％ | ????12.05％ | ????5 |
| Embodiment (1) | ????79.18 | ????10.19％ | ????0.45％ | ????50+ |
| Embodiment (2) | ????221.02 | ????1.08％ | ????0.34％ | ????50+ |
Annotate: the ultraviolet transmission rate in T (UVA) expression UVA district, the ultraviolet transmission rate in T (UVB) expression UVB district.
Table 2 ultraviolet protection coefficient UPF classification schemes
| The UPF scope | Classification | The ultraviolet transmission rate |
| ????15～24 | Good protection | ????6.7～4.2％ |
| ????25～39 | Fine protection | ????4.1～2.6％ |
| ????40～50，50 | Fabulous protection | ????≤2.5％ |
The UPF that table 3 washing is 50 times estimates
| Sample | ??UPF | ????T(UVA) | ????T(UVB) | UPF progression |
| Embodiment (2) | ??221.02 | ????1.08％ | ????0.34％ | ????50+ |
| 50 washings of embodiment (2) fabric | ??177.72 | ????2.29％ | ????0.34％ | ????50+ |
| Embodiment (3) | ??240.49 | ????1.01％ | ????0.32％ | ????50+ |
| 50 washings of embodiment (3) fabric | ??291.36 | ????1.50％ | ????0.23％ | ????50+ |
By Fig. 1, table 1 as can be known, fabric significantly descends through titanium colloidal sol arrangement back ultraviolet transmission rate, especially in UVB (280～320nm) zones, the UPF of fabric significantly improves, bring up to 79.18 from original 6.51, the UPF grade reaches highest 50+, and fabric is again after fluorescent whitening agent is handled, (350～400nm) descend the ultraviolet transmission rate curve significantly in the UVA zone, UPF is significantly improved again, rise to 221.02 from 79.18,, make fabric good uvioresistant performance all be arranged at UVA and UVB zone so the auxiliary fluorescence that uses increases agent.
As shown in Table 3 after fabric that synthetic latex was handled is being washed for 50 times, the ultraviolet transmission rate decreases on the contrary, UPF is up to 291.36, and the UPF of the fabric of handling through synthetic latex drops to 177.72 from 221.02, hence one can see that, and synthetic latex not only improves the uvioresistant durability of fabric, and improved the UPF of fabric, and having improved the uvioresistant performance of fabric greatly, effect is significantly.
Table 4,5 has reflected the situation of change of fabric physical and mechanical properties before and after colloidal sol, fluorescent whitening agent, synthetic latex are handled.
Fabric is torn powerful the variation before and after table 4 arrangement
| Sample | Warp-wise (gram) | Broadwise (gram) |
| Before the processing | ????824.8 | ????581.6 |
| After the processing | ????810.1(-1.7％) | ????570.4(-1.9％) |
Fabric ultimate strength and fracture elongation change before and after table 5 arrangement
| Sample | Warp-wise | Broadwise | ||
| Ultimate strength (N) | Breaking ductility (%) | Fracture strength (N) | Fracture elongation (%) | |
| Before the processing | ????662.7 | ????8.64 | ????291.7 | ????14.76 |
| After the processing | ????650.1(-1.9％) | ????8.43 | ????287.3(-1.5％) | ????14.43 |
After passing through a series of arrangements as can be known by table 4, table 5, the tearing brute force of COTTON FABRIC, ultimate strength and fracture elongation change very little, and physical and mechanical properties is uninfluenced.
Table 6 has reflected the situation of change of textile finishing front and back bending stiffnesses.
The fabric bending stiffness changed before and after table 6 was handled
| Sample | Warp-wise (cm) | Broadwise (cm) |
| Before the processing | ????4.51 | ????3.98 |
| After the processing | ????4.45 | ????3.73 |
The rigidity of handling the back fabric as shown in Table 6 descends on the contrary to some extent, and the variation of the feel of a series of finishing of cotton textiles of process is little.
Claims (3)
1, a kind of sol-gel uvioresistant method of COTTON FABRIC is characterized in that making by following method:
(1) COTTON FABRIC two is soaked two and rolled in titaniferous colloidal sol dressing liquid, pressure 2～3kg/cm2, liquid carrying rate 60～70%, the oven dry of arrangement back, washing or with the alkali neutralization then baked 3～5 minutes at 100～180 ℃ at last;
(2) 0.1～0.5% heavy cotton fluorescent whitening agent of using of relative fabric is regulated pH to 8～9 with the inorganic base of monovalence metal, bath raio 50: 1, and 50 ℃ flood the COTTON FABRIC of described (1) 10～30 minutes down;
(3) (2) described COTTON FABRIC is weighed in 0.1～8% the synthetic latex dressing liquid two at relative fabric and soak two and roll, pressure 2～3kg/cm2, liquid carrying rate 60～70% dries then;
Described titaniferous colloidal sol dressing liquid is made up of the following substances percentage by weight: butyl titanate: the organic solvent that dissolves each other with water 0.1%～15%: hydrochloric acid 0%～80%: acetic acid 0.03%～0.1%: 2%～25% and water 20%～96%.
2, the sol-gel uvioresistant method of a kind of COTTON FABRIC according to claim 1 is characterized in that described organic solvent is ethanol, isopropyl alcohol.
3, the sol-gel uvioresistant method of a kind of COTTON FABRIC according to claim 1 is characterized in that described synthetic latex is the polyacrylate synthetic latex.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410053059 CN1282792C (en) | 2004-07-22 | 2004-07-22 | Sol-gel anti-ultraviolet finishing method for cotton fabric |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410053059 CN1282792C (en) | 2004-07-22 | 2004-07-22 | Sol-gel anti-ultraviolet finishing method for cotton fabric |
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| Publication Number | Publication Date |
|---|---|
| CN1587496A true CN1587496A (en) | 2005-03-02 |
| CN1282792C CN1282792C (en) | 2006-11-01 |
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|---|---|---|---|
| CN 200410053059 Expired - Fee Related CN1282792C (en) | 2004-07-22 | 2004-07-22 | Sol-gel anti-ultraviolet finishing method for cotton fabric |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101864666A (en) * | 2010-06-08 | 2010-10-20 | 东华大学 | Sol-gel flame-retardant finishing method for fabrics |
| CN102174744A (en) * | 2011-01-28 | 2011-09-07 | 东华大学 | Organic/inorganic compound photooxidation resistance protecting agent and application thereof in fiber product |
| CN103485167A (en) * | 2013-09-11 | 2014-01-01 | 昆山市万丰制衣有限责任公司 | Finishing process capable of enhancing anti-ultraviolet property of fabric |
| CN103485183A (en) * | 2013-09-11 | 2014-01-01 | 昆山市万丰制衣有限责任公司 | Method for fixing cyclodextrin on fabric by using colloidal sol |
| CN104179012A (en) * | 2014-08-26 | 2014-12-03 | 无锡市奇盛针织手套厂 | Mould inhibitor for woolen fabric |
| CN104294582A (en) * | 2014-09-25 | 2015-01-21 | 苏州印丝特纺织数码科技有限公司 | Preparation method of anti-ultraviolet finishing agent for silk fabric |
| CN105155256A (en) * | 2015-09-08 | 2015-12-16 | 湖州新创丝织品有限公司 | Natural anti-ultraviolet ramie cotton fabric finishing agent |
| CN107142738A (en) * | 2017-04-28 | 2017-09-08 | 浙江金三发粘合衬有限公司 | A kind of preparation technology of anti-ultraviolet function type apparel binding fibre |
| CN108951165A (en) * | 2018-07-20 | 2018-12-07 | 华南理工大学 | A kind of preparation method of super-hydrophobic/anti-ultraviolet functional fabric |
-
2004
- 2004-07-22 CN CN 200410053059 patent/CN1282792C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101864666A (en) * | 2010-06-08 | 2010-10-20 | 东华大学 | Sol-gel flame-retardant finishing method for fabrics |
| CN102174744A (en) * | 2011-01-28 | 2011-09-07 | 东华大学 | Organic/inorganic compound photooxidation resistance protecting agent and application thereof in fiber product |
| CN102174744B (en) * | 2011-01-28 | 2012-11-07 | 东华大学 | Organic/inorganic compound photooxidation resistance protecting agent and application thereof in fiber product |
| CN103485167A (en) * | 2013-09-11 | 2014-01-01 | 昆山市万丰制衣有限责任公司 | Finishing process capable of enhancing anti-ultraviolet property of fabric |
| CN103485183A (en) * | 2013-09-11 | 2014-01-01 | 昆山市万丰制衣有限责任公司 | Method for fixing cyclodextrin on fabric by using colloidal sol |
| CN104179012A (en) * | 2014-08-26 | 2014-12-03 | 无锡市奇盛针织手套厂 | Mould inhibitor for woolen fabric |
| CN104294582A (en) * | 2014-09-25 | 2015-01-21 | 苏州印丝特纺织数码科技有限公司 | Preparation method of anti-ultraviolet finishing agent for silk fabric |
| CN105155256A (en) * | 2015-09-08 | 2015-12-16 | 湖州新创丝织品有限公司 | Natural anti-ultraviolet ramie cotton fabric finishing agent |
| CN107142738A (en) * | 2017-04-28 | 2017-09-08 | 浙江金三发粘合衬有限公司 | A kind of preparation technology of anti-ultraviolet function type apparel binding fibre |
| CN108951165A (en) * | 2018-07-20 | 2018-12-07 | 华南理工大学 | A kind of preparation method of super-hydrophobic/anti-ultraviolet functional fabric |
| CN108951165B (en) * | 2018-07-20 | 2020-09-22 | 华南理工大学 | Preparation method of super-hydrophobic/anti-ultraviolet functional fabric |
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