CN1587453A - Photocatalytic and antiseptic far infrared fiber and its preparing method - Google Patents
Photocatalytic and antiseptic far infrared fiber and its preparing method Download PDFInfo
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- CN1587453A CN1587453A CN 200410062533 CN200410062533A CN1587453A CN 1587453 A CN1587453 A CN 1587453A CN 200410062533 CN200410062533 CN 200410062533 CN 200410062533 A CN200410062533 A CN 200410062533A CN 1587453 A CN1587453 A CN 1587453A
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- photocatalyst
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- antibiotic
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- infrared
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Abstract
The present invention discloses one kind of photocatalytic and antiseptic far infrared fiber and its preparation process. The fiber includes fiber forming polymer as well as photocatalytic material, antiseptic material and far infrared material, which have the weight ratio of 28-32 to 4-6 to 60-70, have particle size of 0.1-1 micron, and account for 3-36 % of fiber weight. The preparation process includes mixing photocatalytic material, antiseptic material and far infrared material to form mixture powder; mixing the mixture powder with fiber forming polymer in the ratio of 30-60 to 40-70 to form slice or agglomerate; mixing the slice or agglomerate with fiber forming polymer in the ratio of 10-60 to 40-90 and spinning in spinning machine to produce the fiber.
Description
Technical field:
The present invention relates to a kind of weaving face fabric and preparation method thereof, particularly a kind of photocatalyst, antibiotic, far IR fibre and preparation method thereof.
Background technology:
Along with science and technology development, various functional textile materials constantly occur, far IR fibre is confirmed to have health protection and therapeutic action to human body by physics and medical research except that the effect with conventional fibre, photocatalyst material has automatically cleaning and antibacterial action; But the textile material that does not also have now photocatalyst, antibiotic, far-infrared functional simultaneously.
Summary of the invention:
The objective of the invention is to overcome above-mentioned defective, provide a kind of satisfy take requirement, have the photocatalyst of health protection and therapeutic action and antibiotic self-cleaning effect, antibiotic, far IR fibre simultaneously, and this fiber preparation method be provided simultaneously.
For achieving the above object, the invention provides following technical scheme:
Photocatalyst of the present invention, antibiotic, far IR fibre, comprise fibre-forming polymer, also comprise a kind of in every group of following three groups of powder, weight ratio is a photocatalyst material: anti-biotic material: far-infrared material=28-32: 4-6: 60-70, the particle diameter of photocatalyst material, anti-biotic material, far-infrared material is 0.1 μ m-1 μ m, also include spinning-aid agent, the weight ratio 1.2-2 of spinning-aid agent and photocatalyst, antibiotic, three kinds of powder body material summations of far infrared: 28-34; Photocatalyst material, anti-biotic material, far-infrared material, spinning-aid agent account for the 3%-36% of total weight of fibers,
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO.
The preparation method of photocatalyst of the present invention, antibiotic, far IR fibre may further comprise the steps successively:
1. prepare photocatalyst, antibiotic, far infrared composite powder mixture:
With in every group of following three groups of powder wherein any with other arbitrary group wherein any mixes, wherein the weight ratio of Hun Heing is a photocatalyst material: anti-biotic material: far-infrared material=28-32: 4-6: 60-70; Every kind of powder body material particle diameter mixes spinning-aid agent simultaneously at 0.1 μ m-1 μ m, and spinning-aid agent and photocatalyst, weight ratio antibiotic, the far infrared powder mixture are 1.2-2: 28-34.
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO
2. prepare photocatalyst, far infrared composite powder mixture master batch or section
The photocatalyst that 1. above-mentioned steps is made, antibiotic, far infrared composite powder mixture are made with the fibre-forming polymer blend by weight 30-60: 70-40 and are cut into slices or master batch.
3. spinning
Section that 2. above-mentioned steps is made or master batch are made fiber through spinning machine after mixing by weight 10-60: 90-40 and fibre-forming polymer.
Because contain photocatalyst material, anti-biotic material, far-infrared material in photocatalyst of the present invention, antibiotic, the far IR fibre, and photocatalyst material: TiO
2Has automatic cleaning action, anti-biotic material: Ag
2O, ZnO, CuO have antibacterial action, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO has health protection and therapeutic action to human body; So photocatalyst of the present invention, antibiotic, far IR fibre have health protection and therapeutic action and antibiotic self-cleaning effect simultaneously.The present invention provides the preparation method of photocatalyst, antibiotic, far IR fibre simultaneously, to realize goal of the invention.
The specific embodiment:
Photocatalyst of the present invention, antibiotic, far IR fibre, comprise fibre-forming polymer, as: polypropylene, polyamide, polyester etc., also comprise a kind of in every group of following three groups of powder, weight ratio is a photocatalyst material: anti-biotic material: far-infrared material=28-32: 4-6: 60-70, the particle diameter of photocatalyst material, anti-biotic material, far-infrared material is 0.1 μ m-1 μ m
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO.
For making the fibre-forming polymer that is mixed with photocatalyst material, anti-biotic material, far-infrared material have better spinnability, also be added with spinning-aid agent among the present invention, the weight ratio 1.2-2 of spinning-aid agent and photocatalyst, antibiotic, three kinds of powder body material summations of far infrared: 28-34; Described spinning-aid agent is r-methacryl trimethyl silane and stearic acid, and r-methacryl trimethyl silane and stearic weight ratio are 4: 3.Photocatalyst material, anti-biotic material, far-infrared material, spinning-aid agent account for the 3%-36% of total weight of fibers,
The preparation method of photocatalyst of the present invention, antibiotic, far IR fibre may further comprise the steps successively:
1. prepare photocatalyst, antibiotic, far infrared composite powder mixture:
With in every group of following three groups of powder wherein any with other arbitrary group wherein any mixes, wherein the weight ratio of Hun Heing is a photocatalyst material: anti-biotic material: far-infrared material=28-32: 4-6: 60-70; Every kind of powder body material particle diameter is at 0.1 μ m-1 μ m,
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO
For making the fibre-forming polymer that is mixed with photocatalyst material, anti-biotic material, far-infrared material have better spinnability, when preparation photocatalyst, antibiotic, far infrared composite powder mixture, also be mixed with spinning-aid agent, the weight ratio 1.2-2 of spinning-aid agent and photocatalyst, antibiotic, far infrared powder mixture: 28-34.Described spinning-aid agent is r-methacryl trimethyl silane and stearic acid, and r-methacryl trimethyl silane and stearic weight ratio are 4: 3.
Photocatalyst, antibiotic, far infrared powder and spinning-aid agent can carry out 10 minutes time under the normal temperature in airtight high-speed mixer.
2. prepare photocatalyst, far infrared composite powder mixture master batch or section
The photocatalyst that 1. above-mentioned steps is made, antibiotic, far infrared composite powder mixture mix (in the high-speed mixer) afterwards in double screw extruder by weight 30-60: 70-40 with fibre-forming polymer, 240 ℃ of following blend are made and cut into slices or master batch.
3. spinning
Section that 2. above-mentioned steps is made or master batch are made fiber through spinning machine after mixing by weight 10-60: 90-40 and fibre-forming polymer.
Photocatalyst of the present invention, antibiotic, far IR fibre can be processed into administer product such as knitted underwear and socks with common process.Its infrared emittance is at 85-95%; Staphylococcus aureus antibiotic rate 〉=90%, Escherichia coli antibiotic rate 〉=90%, Candida albicans antibiotic rate 〉=80%.
Embodiment 1
1. prepare photocatalyst, antibiotic, far infrared composite powder mixture:
With in every group of following three groups of powder wherein any with other arbitrary group wherein any mixes, wherein the weight ratio of Hun Heing is a photocatalyst material: anti-biotic material: far-infrared material=28: 4: 60; Every kind of powder body material particle diameter is at 0.1 μ m-1 μ m,
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO
Mix spinning-aid agent simultaneously, the weight ratio of spinning-aid agent and photocatalyst, antibiotic, far infrared powder mixture 1.2: 28, spinning-aid agent is r-methacryl trimethyl silane and stearic acid, r-methacryl trimethyl silane and stearic weight ratio are 4: 3.
Photocatalyst, antibiotic, far infrared powder and spinning-aid agent can carry out 10 minutes time under the normal temperature in airtight high-speed mixer.
2. prepare photocatalyst, far infrared composite powder mixture master batch or section
The photocatalyst that 1. above-mentioned steps is made, antibiotic, far infrared composite powder mixture were made section or master batch with fibre-forming polymer blend (in the high-speed mixer) by weight 30: 70 in double screw extruder, under 240 ℃.
3. spinning
Section that 2. above-mentioned steps is made or master batch or section are made fiber through spinning machine after mixing with fibre-forming polymer by weight 10: 90.
Photocatalyst material, anti-biotic material, far-infrared material, spinning-aid agent account for 3% of total weight of fibers in the photocatalyst that present embodiment makes, antibiotic, the far IR fibre.
Embodiment 2
1. prepare photocatalyst, antibiotic, far infrared composite powder mixture:
With in every group of following three groups of powder wherein any with other arbitrary group wherein any mixes, wherein the weight ratio of Hun Heing is a photocatalyst material: anti-biotic material: far-infrared material=30: 5: 65; Every kind of powder body material particle diameter is at 0.1 μ m-1 μ m,
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO
Mix spinning-aid agent simultaneously, the weight ratio of spinning-aid agent and photocatalyst, antibiotic, far infrared powder mixture 1.5: 30, spinning-aid agent is r-methacryl trimethyl silane and stearic acid, r-methacryl trimethyl silane and stearic weight ratio are 4: 3.
Photocatalyst, antibiotic, far infrared powder and spinning-aid agent can carry out 10 minutes time under the normal temperature in airtight high-speed mixer.
2. prepare photocatalyst, far infrared composite powder mixture master batch or section
The photocatalyst that 1. above-mentioned steps is made, antibiotic, far infrared composite powder mixture were made section or master batch with fibre-forming polymer blend (in the high-speed mixer) by weight 45: 55 in double screw extruder, under 240 ℃.
3. spinning
Section that 2. above-mentioned steps is made or master batch are made fiber through spinning machine after mixing with fibre-forming polymer by weight 35: 65.
Photocatalyst material, anti-biotic material, far-infrared material, spinning-aid agent account for 15.75% of total weight of fibers in the photocatalyst that present embodiment makes, antibiotic, the far IR fibre.
Embodiment 3
1. prepare photocatalyst, antibiotic, far infrared composite powder mixture:
With in every group of following three groups of powder wherein any with other arbitrary group wherein any mixes, wherein the weight ratio of Hun Heing is a photocatalyst material: anti-biotic material: far-infrared material=32: 6: 70; Every kind of powder body material particle diameter is at 0.1 μ m-1 μ m,
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO
Mix spinning-aid agent simultaneously, the weight ratio of spinning-aid agent and photocatalyst, antibiotic, far infrared powder mixture 2: 34, spinning-aid agent is r-methacryl trimethyl silane and stearic acid, r-methacryl trimethyl silane and stearic weight ratio are 4: 3.
Photocatalyst, antibiotic, far infrared powder and spinning-aid agent can carry out 10 minutes time under the normal temperature in airtight high-speed mixer.
2. prepare photocatalyst, far infrared composite powder mixture master batch or section
The photocatalyst that 1. above-mentioned steps is made, antibiotic, far infrared composite powder mixture were made section or master batch with the fibre-forming polymer blend by weight 60: 40 in double screw extruder, under 240 ℃.
3. spinning
Section that 2. above-mentioned steps is made or master batch are made fiber through spinning machine after mixing with fibre-forming polymer by weight 60: 40.
Photocatalyst material, anti-biotic material, far-infrared material, spinning-aid agent account for 36% of total weight of fibers in the photocatalyst that present embodiment makes, antibiotic, the far IR fibre.
Claims (5)
1, a kind of photocatalyst, antibiotic, far IR fibre, comprise fibre-forming polymer, it is characterized in that: also comprise a kind of in every group of following three groups of powder, weight ratio is a photocatalyst material: anti-biotic material: far-infrared material=28-32: 4-6: 60-70, the particle diameter of photocatalyst material, anti-biotic material, far-infrared material is 0.1 μ m-1 μ m, also include spinning-aid agent, the weight ratio 1.2-2 of spinning-aid agent and photocatalyst, antibiotic, three kinds of powder body material summations of far infrared: 28-34; Photocatalyst material, anti-biotic material, far-infrared material, spinning-aid agent account for the 3%-36% of total weight of fibers,
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO.
2, photocatalyst according to claim 1, antibiotic, far IR fibre, it is characterized in that: photocatalyst material: anti-biotic material: the weight ratio of far-infrared material=30: 5: 65, the weight ratio of spinning-aid agent and photocatalyst, antibiotic, three kinds of powder body material summations of far infrared 1.5: 30.
3, according to claim 1,2 described photocatalysts, antibiotic, far IR fibre, it is characterized in that described spinning-aid agent is r-methacryl trimethyl silane and stearic acid, r-methacryl trimethyl silane and stearic weight ratio are 4: 3.
4, the preparation method of a kind of photocatalyst, antibiotic, far IR fibre may further comprise the steps successively:
1. prepare photocatalyst, antibiotic, far infrared composite powder mixture:
With in every group of following three groups of powder wherein any with other arbitrary group wherein any mixes, wherein the weight ratio of Hun Heing is a photocatalyst material: anti-biotic material: far-infrared material=28-32: 4-6: 60-70; Every kind of powder body material particle diameter mixes spinning-aid agent simultaneously at 0.1 μ m-1 μ m, and spinning-aid agent and photocatalyst, weight ratio antibiotic, the far infrared powder mixture are 1.2-2: 28-34;
A, photocatalyst material: TiO
2
B, anti-biotic material: Ag
2O, ZnO, CuO
C, far-infrared material: ZrO, Fa
2O
3, SiO
2, Al
2O
3, MgO
2. prepare photocatalyst, far infrared composite powder mixture master batch or section
The photocatalyst that 1. above-mentioned steps is made, antibiotic, far infrared composite powder mixture are made with the fibre-forming polymer blend by weight 30-60: 70-40 and are cut into slices or master batch;
3. spinning
Section that 2. above-mentioned steps is made or master batch are made fiber through spinning machine after mixing by weight 10-60: 90-40 and fibre-forming polymer.
5, the preparation method of photocatalyst according to claim 4, antibiotic, far IR fibre; it is characterized in that: described spinning-aid agent is r-methacryl trimethyl silane and stearic acid, and r-methacryl trimethyl silane and stearic weight ratio are 4: 3.
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|---|---|---|---|
| CN 200410062533 CN1587453A (en) | 2004-07-02 | 2004-07-02 | Photocatalytic and antiseptic far infrared fiber and its preparing method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200410062533 CN1587453A (en) | 2004-07-02 | 2004-07-02 | Photocatalytic and antiseptic far infrared fiber and its preparing method |
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|---|---|
| CN1587453A true CN1587453A (en) | 2005-03-02 |
Family
ID=34603721
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|---|---|---|---|
| CN 200410062533 Pending CN1587453A (en) | 2004-07-02 | 2004-07-02 | Photocatalytic and antiseptic far infrared fiber and its preparing method |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102560723A (en) * | 2010-12-31 | 2012-07-11 | 上海德福伦化纤有限公司 | Production method of inorganic nanometer quantum energy healthy functional polyester fiber |
| CN105483934A (en) * | 2013-11-08 | 2016-04-13 | 丹阳市超超服饰有限公司 | Preparation method capable of effectively improving far-infrared radiation function of non-glue cotton |
| CN106234413A (en) * | 2016-07-28 | 2016-12-21 | 东莞市雄林新材料科技股份有限公司 | A kind of nano antibacterial agent with infra red radiation function and preparation method thereof |
| CN108741266A (en) * | 2018-07-04 | 2018-11-06 | 佛山市南海区佳妍内衣有限公司 | Underwear and cup bra |
| CN108977925A (en) * | 2018-07-04 | 2018-12-11 | 佛山市南海区佳妍内衣有限公司 | A kind of far-infrared anti-biotic polyester fiber |
| CN109012018A (en) * | 2018-08-06 | 2018-12-18 | 广州市花林景观工程有限公司 | Filter screen based on purifying formaldehyde function |
| CN109049908A (en) * | 2018-07-04 | 2018-12-21 | 佛山市南海区佳妍内衣有限公司 | A kind of fitting fabric with transparent effect |
| CN109853079A (en) * | 2018-12-31 | 2019-06-07 | 盐城工学院 | A kind of photocatalytic self-cleaning fabric and preparation method thereof |
| CN111235669A (en) * | 2020-04-07 | 2020-06-05 | 湖南翰坤实业有限公司 | Modified spinning material with self-cleaning function |
-
2004
- 2004-07-02 CN CN 200410062533 patent/CN1587453A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102560723A (en) * | 2010-12-31 | 2012-07-11 | 上海德福伦化纤有限公司 | Production method of inorganic nanometer quantum energy healthy functional polyester fiber |
| CN105483934A (en) * | 2013-11-08 | 2016-04-13 | 丹阳市超超服饰有限公司 | Preparation method capable of effectively improving far-infrared radiation function of non-glue cotton |
| CN106234413A (en) * | 2016-07-28 | 2016-12-21 | 东莞市雄林新材料科技股份有限公司 | A kind of nano antibacterial agent with infra red radiation function and preparation method thereof |
| CN108741266A (en) * | 2018-07-04 | 2018-11-06 | 佛山市南海区佳妍内衣有限公司 | Underwear and cup bra |
| CN108977925A (en) * | 2018-07-04 | 2018-12-11 | 佛山市南海区佳妍内衣有限公司 | A kind of far-infrared anti-biotic polyester fiber |
| CN109049908A (en) * | 2018-07-04 | 2018-12-21 | 佛山市南海区佳妍内衣有限公司 | A kind of fitting fabric with transparent effect |
| CN109012018A (en) * | 2018-08-06 | 2018-12-18 | 广州市花林景观工程有限公司 | Filter screen based on purifying formaldehyde function |
| CN109853079A (en) * | 2018-12-31 | 2019-06-07 | 盐城工学院 | A kind of photocatalytic self-cleaning fabric and preparation method thereof |
| CN111235669A (en) * | 2020-04-07 | 2020-06-05 | 湖南翰坤实业有限公司 | Modified spinning material with self-cleaning function |
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