CN1583935A - Multifunctional long-effect environmental protective glass antifogging defrosting agent - Google Patents
Multifunctional long-effect environmental protective glass antifogging defrosting agent Download PDFInfo
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- CN1583935A CN1583935A CN 03153629 CN03153629A CN1583935A CN 1583935 A CN1583935 A CN 1583935A CN 03153629 CN03153629 CN 03153629 CN 03153629 A CN03153629 A CN 03153629A CN 1583935 A CN1583935 A CN 1583935A
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- glass
- polyoxyethylene glycol
- polyvinylpyrrolidone
- environmental protection
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Abstract
'The multi-functional long result environmental protection glass defends the fog defrosting compound' it is a field of fine chemistry industry in this invention, it is the transparent neutral liquid, the smell is cool and pleasant, all raw materials, among them are nonpoisonous in environmental protection, nonpoisonous and harmless to the human body, have ordinary to defend the long-term dyle fog defends the frost function 30 days such as what pharmaceutical can not reach such as fog; Still defend the static, dustproof function; Can keep with the pure and fresh air, have calm and sober functions to people' But as the sanitizer of the ordinary glass, do not have corrosion, gentle both hands to the glass and metal, use for clean hand pharmaceutical. Include the following component parts mainly; The fatty alcohol gathers 0.1-2.6% of ethylene ether of oxygen, the fatty alcohol gathers oxygen ethylene ether sulphuric acid sodium 0.2-2.8, different propyl alcohol is 5-30%, medical use ethanol is 5-40%, menthol is 0.2-1.6%, gather 0.1-2% of ethylene glycol (2000), polyethylene pyrrole is 0-2% of alkane and ketone, the quantity of the deionized water the other left.
Description
What technical field multifunction long-acting environmental protection of the present invention glass antifogging anti defrosting compound related to is a kind of to various hard surfaces, especially glass surface has the inaccessible long lasting antifog defrosting effect of common antifogging agent, and also has the antifog defrosting compound of other many-sided functions.
The background technology glass surface easily produces mist or frost that one deck is formed by water having under humidity and the inside and outside condition uneven in temperature, and this causes very poor of the transparency of glass or reflectance.Tied one deck mist in winter as windshield, just this has caused very big trouble to the driver, constantly clean the windows under the situation of travelling, this has caused very big potential harm to traffic.The glass surface of the instrument in space shuttle, the workshop, eyes or the like is also all tied one deck mist easily in addition, and this allows the people feel very big trouble.
In the eighties patent of this respect is arranged all, but on market, also do not popularize so far, can be to find out that more original antifogging products also do not reach good effect on the market.That have even also be added with some other Harmful chemicalss such as methyl alcohol, di-alcohol, because antifogging agent is directly to contact human body, this has caused very big harm to operator and environment.
Summary of the invention
This prescription has fully taken into account the antifog long-lasting and feature of environmental protection and the multifunctionality of prescription.
Function of the present invention has:
1, cleaning function adopts the compound prescription of nonionic and anion surfactant that glass and other surperficial dirts cleaning are had good effect.Cleaning function has also improved the surface effects of glass.
2, antifog defrost function, antifog defrosting has long-lasting.This prescription adopts the organic macromolecule water-absorbent and at the adhesive ability of glass surface, form the firm film of layer of transparent at glass surface, product is had than the longer validity of the micromolecular antifogging agent of general employing, once can keep 30 validity period with this product wiping.
3, make with fresh airly, the people is had calm clear-headed function.This prescription all adopts nontoxic raw material, has the feature of environmental protection.In raw material, contain peppermint alcohols and organic polymer, but product is sprayed on the dirt that active adsorption is removed airborne bad smell and flown upward in the air, make the refrigerant fragrance of air.This helps the head driver time and sails car.
4, gentle both hands can effectively be removed heavy oil spot on hand, and this has very big effect to the driver master worker.The present invention adopts is adversary's gentleness but the strong prescription of spatter property, and a spray one is wiped, and just can remove greasy dirt on hand.If make paper handkerchief, can directly wipe the hand decontamination with paper handkerchief.
5, glass had defencive function.Organic polymer has very good lubricity at the film of formation on glass, can prevent in the process that cleans the windows, and the adhered dust friction scratches glass.After having wiped, but firm attachment makes the sticking in a long time dust of glass at polymeric membrane on glass anti-electrostatic also, makes glass exceptionally bright.So this product also can be used as the sanitising agent of general glass.
6, antifreeze function.Can regulate Virahol and the medical ethanol content in product and make it can reach subzero 35 ℃ low temperature at least, be convenient to preserve and use, can be fit to district in all parts of the country.
The various functions of the present invention realize that by following method " multifunction long-acting environmental protection glass antifogging anti defrosting compound " of the present invention mainly comprises following component:
Fatty alcohol-polyoxyethylene ether 0.1-2.6%
Polyoxyethylenated alcohol sodium sulfate 0.2-2.8%
Virahol 5-30%
Medical ethanol 5-40%
Menthol 0.2-1.6%
Polyoxyethylene glycol (600) 0.1-3%
Polyoxyethylene glycol (2000) 0.1-2%
Polyvinylpyrrolidone 0.1-2%
Deionized water all the other
" multifunction long-acting environmental protection glass antifogging anti defrosting compound " of the present invention prepared as follows:
At normal temperatures, earlier the Virahol and the ethanol of aequum are put into stainless steel vessel, add fatty alcohol-polyoxyethylene ether, polyoxyethylenated alcohol sodium sulfate, menthol, polyoxyethylene glycol (600), polyoxyethylene glycol (2000), polyvinylpyrrolidone again, stir then, stirring velocity is 50 rev/mins, all dissolve until raw material, and then add the deionized water mixing stirring of aequum, churning time is 30-60 minute.Through natural froth breaking, get final product packing after detected result is qualified.If make Antifogging towel, the spray solution that then needs to prepare is at senior textile slurry paper handkerchief, and hygenic towelette is that the 3-5 of dried paper handkerchief weight doubly is that easily cutting is enclosed in the plastics bag then, can adorn one or more pieces for one bag.
The present invention's's " multifunction long-acting environmental protection glass antifogging anti defrosting compound " compound method is easy, the raw material environment-protecting asepsis, to environment and human body without any murder by poisoning.
Concrete raw material in will filling a prescription below and concrete prescription are further described.In above-mentioned prescription:
Fatty alcohol-polyoxyethylene ether is nonionogenic tenside, and is soluble in water, has good decontamination, wetting and emulsion dispersion property, biological degradability is good, use softly, can do wetting, the emulsification and the static inhibitor of textile industry, also be commonly used for the washing composition of makeup.
Polyoxyethylenated alcohol sodium sulfate belongs to anion surfactant, and good water solubility still can keep transparent at low temperatures, and is little to the human body skin pungency, has good detersive power, wetting power and foaming power.Biological degradability is higher than 90%.Be widely used in shampoo and bubble bath and cream cream cosmetic etc.Also can do the static inhibitor in the BLENDED FABRIC course of processing.
Virahol is water white flammable liquid, can dissolve each other with water, alcohol, ether etc., is used as sanitas in makeup, has the sterilization and anticorrosion ability, and performance and ethanol are similar, also can be used as solvent and replaces ethanol to use antifog can be used as, antifreeze, defrosting compound.
Menthol has by bright, happy peppermint fragrance strong cold, clear, and refrigerant fragrance is given salubrious sensation.Be mainly used in medical toothpaste etc., play the effect of restoring consciouness disinfectant.
Polyoxyethylene glycol water soluble, ethanol and multiple organic solvent have good water absorbability, cohesiveness, oilness.Nontoxic, non-stimulated, harmless.Than the polyvinylpyrrolidone low price, adopt high molecular and lower molecular weight to mix and just can play best effect.
Polyvinylpyrrolidone has film-forming properties and water absorbability, and its film is colourless bright.Because intramolecularly contains amide structure, thus can with many polar group generation complexing actions, very strong cohesive action is arranged.This product is nontoxic to have good biocompatibility, non-stimulated to skin and eye, no anaphylaxis.The adding of this raw material can complexing polarity group on glass, plays very big effect to improving film in stability on glass.
It is as shown in the table for the optimum formula that uses in the North China winter of embodiment " multifunction long-acting environmental protection glass antifogging anti defrosting compound " of the present invention:
Amounts of components %
Fatty alcohol-polyoxyethylene ether 0.6%
Polyoxyethylenated alcohol sodium sulfate 0.8%
Virahol 10%
Medical ethanol 10%
Menthol 0.5%
Polyoxyethylene glycol (600) 0.8%
Polyoxyethylene glycol (2000) 0.2%
Polyvinylpyrrolidone 0.5%
Deionized water all the other
The concrete preparation method of " multifunction long-acting environmental protection glass antifogging anti defrosting compound " of the present invention is as follows:
At normal temperatures, earlier 10Kg Virahol and 10Kg ethanol are put into stainless steel vessel, add 0.6Kg fatty alcohol-polyoxyethylene ether, 0.8Kg polyoxyethylenated alcohol sodium sulfate, 0.5Kg menthol, 0.8Kg polyoxyethylene glycol (600), 0.2Kg polyoxyethylene glycol (2000), 0.5Kg polyvinylpyrrolidone again, stir then, stirring velocity is 50 rev/mins, all dissolve until raw material, and then add deionized water to 100Kg mixing stirring, churning time is 30-60 minute, promptly obtains the 100Kg final mean annual increment solution.Through natural froth breaking, get final product packing after detected result is qualified.If make Antifogging towel, the spray solution that then needs to prepare is at senior textile slurry paper handkerchief, and hygenic towelette is that the 3-5 of dried paper handkerchief weight doubly is that easily cutting is enclosed in the plastics bag then, can adorn one or more pieces for one bag.
The every index of final mean annual increment solution before packing of this product and the sprinkling is as follows,
| Index name | Index |
| Outward appearance | Water white transparency, sediment-free.Free from extraneous odour has the refrigerant fragrance of peppermint. |
| Stability | -25 ℃ of freezing backs, that 24h recovers the room temperature sample is normal.After 50 ℃ of heating, phenomenon such as the separation of 24h absence of liquid, precipitation, variable color. |
| PH value | 6-8 |
| Performance | Dip in a little with senior cotton and smear test plate to clear, dry back test piece should be clear bright, do not have obvious water smoke and mottling, do not answer frosting.Smear on hand with shoe polish, dip in and be less than solution and apply on greasy dirt, the wiping in a moment is promptly clean, and the adversary does not have any sensation.The freezing point of solution can be used in the winter of North China between-10--15 ℃. |
" multifunction long-acting environmental protection glass antifogging anti defrosting compound " of the present invention is transparent neutral liquid, and smell is refrigerant pleasant, and wherein each raw material environment-protecting asepsis is nontoxic to human body, has antifog, frost prevention, the dust reduction capability of 8-10 days long-acting phases; Can keep with fresh air, the people is had calm clear-headed function; Can be used as the sanitising agent of simple glass, the glass metal thing is not had corrosion; Also can clean the heavy oil spot on the both hands, gentle both hands are made the usefulness of hand detergent (towel).Being special-purpose antifog, frost prevention, cleaning, bright, the good product of dust-proof of the windshield glass of various automobiles, train, aircraft, steamer, common door and window, instrument and glasses and other glass-mirrors, is the indispensable articles for use of driver and household.
Claims (3)
1, the present invention's " multifunction long-acting environmental protection glass antifogging anti defrosting compound " prescription has fully taken into account the antifog long-lasting and feature of environmental protection and the multifunctionality of prescription.It is characterized in that filling a prescription required feed composition and ratio is:
Fatty alcohol-polyoxyethylene ether 0.1-2.6%
Polyoxyethylenated alcohol sodium sulfate 0.2-2.8%
Virahol 5-30%
Medical ethanol 5-40%
Menthol 0.2-1.6%
Polyoxyethylene glycol (600) 0.1-3%
Polyoxyethylene glycol (2000) 0.1-2%
Polyvinylpyrrolidone 0.1-2%
Deionized water all the other
2, polyethylene glycol polymer amount and low-molecular-weight compound, and match in film formed process with polyvinylpyrrolidone, macromolecular chain twines mutually, and polyvinylpyrrolidone has good complexing action with the polar group of the glass surface after cleaning, and has produced comparatively firm hydrophilic membrane like this.The proportion of composing that it is characterized in that them is: polyoxyethylene glycol (600) 0.1-3%, polyoxyethylene glycol (2000) 0.1-2%, polyvinylpyrrolidone 0.1-2%.
3, according to claim 1, it is as shown in the table to it is characterized in that best proportioning when freezing point of solution each raw material during for-10--15 ℃:
Amounts of components %
Fatty alcohol-polyoxyethylene ether 0.6%
Polyoxyethylenated alcohol sodium sulfate 0.8%
Virahol 10%
Medical ethanol 10%
Menthol 0.5%
Polyoxyethylene glycol (600) 0.8%
Polyoxyethylene glycol (2000) 0.2%
Polyvinylpyrrolidone 0.5%
Deionized water all the other
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031536298A CN100360632C (en) | 2003-08-18 | 2003-08-18 | Multifunctional long-effect environmental protective glass antifogging defrosting agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031536298A CN100360632C (en) | 2003-08-18 | 2003-08-18 | Multifunctional long-effect environmental protective glass antifogging defrosting agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1583935A true CN1583935A (en) | 2005-02-23 |
| CN100360632C CN100360632C (en) | 2008-01-09 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
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| CNB031536298A Expired - Fee Related CN100360632C (en) | 2003-08-18 | 2003-08-18 | Multifunctional long-effect environmental protective glass antifogging defrosting agent |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220257B (en) * | 2007-01-09 | 2010-09-01 | 青岛大学 | Process for producing vehicle glass antifogging agent |
| CN103600726A (en) * | 2013-10-31 | 2014-02-26 | 苏州宝丽洁日化有限公司 | Anti-fog wet tissue of automotive glass |
| CN103805139A (en) * | 2014-02-26 | 2014-05-21 | 海安县国力化工有限公司 | Deicing aerosol |
| WO2015017958A1 (en) * | 2013-08-08 | 2015-02-12 | 上海新阳半导体材料股份有限公司 | Additive c capable of changing microvia-filling method by tsv copper plating, and electroplating solution containing same |
| CN105219542A (en) * | 2015-10-22 | 2016-01-06 | 西安文理学院 | Non-setting adhesive cull scavenging agent of a kind of environment-protecting asepsis and preparation method thereof |
| CN107541190A (en) * | 2017-09-06 | 2018-01-05 | 苏州纽东精密制造科技有限公司 | A kind of anti-fog agent for wind-screen of automobile and preparation method thereof |
| CN108300580A (en) * | 2018-02-05 | 2018-07-20 | 安阳工学院 | A kind of low freezing point automatically cleaning vehicle glass water |
| CN108329856A (en) * | 2017-12-28 | 2018-07-27 | 广州华夏职业学院 | A kind of fog-proof adhesive film formula and its preparation process for vehicle glass |
| CN111087975A (en) * | 2019-12-06 | 2020-05-01 | 河北化工医药职业技术学院 | Antifogging and antifrosting agent for glass and its preparing method |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1023963C (en) * | 1990-09-10 | 1994-03-16 | 南智军 | Multifunciton mirror cleaning cloth |
| CN1056703A (en) * | 1991-03-30 | 1991-12-04 | 顾山圻 | glass surface antifogging agent and preparation method thereof |
| CN1107173A (en) * | 1994-02-21 | 1995-08-23 | 赵邦君 | Glass dirt removing and fogging-proof agent |
-
2003
- 2003-08-18 CN CNB031536298A patent/CN100360632C/en not_active Expired - Fee Related
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101220257B (en) * | 2007-01-09 | 2010-09-01 | 青岛大学 | Process for producing vehicle glass antifogging agent |
| WO2015017958A1 (en) * | 2013-08-08 | 2015-02-12 | 上海新阳半导体材料股份有限公司 | Additive c capable of changing microvia-filling method by tsv copper plating, and electroplating solution containing same |
| US9915005B2 (en) | 2013-08-08 | 2018-03-13 | Shanghai Sinyang Semiconductor Materials Co., Ltd. | Additive C capable of changing microvia-filling method by TSV copper plating, and electroplating solution containing same |
| CN103600726A (en) * | 2013-10-31 | 2014-02-26 | 苏州宝丽洁日化有限公司 | Anti-fog wet tissue of automotive glass |
| CN103805139A (en) * | 2014-02-26 | 2014-05-21 | 海安县国力化工有限公司 | Deicing aerosol |
| CN105219542A (en) * | 2015-10-22 | 2016-01-06 | 西安文理学院 | Non-setting adhesive cull scavenging agent of a kind of environment-protecting asepsis and preparation method thereof |
| CN107541190A (en) * | 2017-09-06 | 2018-01-05 | 苏州纽东精密制造科技有限公司 | A kind of anti-fog agent for wind-screen of automobile and preparation method thereof |
| CN108329856A (en) * | 2017-12-28 | 2018-07-27 | 广州华夏职业学院 | A kind of fog-proof adhesive film formula and its preparation process for vehicle glass |
| CN108300580A (en) * | 2018-02-05 | 2018-07-20 | 安阳工学院 | A kind of low freezing point automatically cleaning vehicle glass water |
| CN111087975A (en) * | 2019-12-06 | 2020-05-01 | 河北化工医药职业技术学院 | Antifogging and antifrosting agent for glass and its preparing method |
| CN111087975B (en) * | 2019-12-06 | 2023-04-07 | 河北化工医药职业技术学院 | Antifogging and antifrosting agent for glass and its preparing method |
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|---|---|
| CN100360632C (en) | 2008-01-09 |
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