CN1580205A - Alcohol diesel and its preparing method - Google Patents
Alcohol diesel and its preparing method Download PDFInfo
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- CN1580205A CN1580205A CN 03153101 CN03153101A CN1580205A CN 1580205 A CN1580205 A CN 1580205A CN 03153101 CN03153101 CN 03153101 CN 03153101 A CN03153101 A CN 03153101A CN 1580205 A CN1580205 A CN 1580205A
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Abstract
The invention relates to a kind of clear fuel, alcohol diesel oil, for diesel motor and the preparation method. alcohol for burning, base diesel oil and cosolvent are used as the raw material. 2-20 share alcohol for burning, 75-98 share base diesel oil and 0.1-10 share cosolvent, in normal temperature and atomospheric pressure, they are mixed and accordance to get output. The cosolvent is one dimensional aliphatic alcohol containing 3-12 carbon. It consists of all kinds of isomer, nonyl phenol polyethenoxy ether which molecular formula is C6H19C6H4O(CH2CH2O)nH, here, n=1-50, all kinds of mahogany acid ester is composed by aliphatic and nonyl phenol polyethenoxy ether, their volume percent is 70%-99% and 1%-30% and composed by 80-99% aliphatic alcohol-1-20% mahogany acid ester in volume percent. Using this new product, diesel motor need not any change and the capability of motor changes less, besides, carbon monoxide, hydrocarbon and smoke dust from end gas can be reduced very much.
Description
Technical field
The present invention relates to a kind of alcohol fuel, basic diesel oil, solubility promoter of utilizing and be clean fuel ethanol diesel fuel of the diesel motor of raw material and preparation method thereof.
Background technology
Along with the development of Chinese national economy, the oil shortage problem becomes increasingly conspicuous, and owing to a large amount of uses of fossil fuel, the air environmental pollution problem is on the rise simultaneously.China has been the net importer of oil at present, and crude oil import amount every year, the amplitude with 1,000 ten thousand tons increased.The crude oil problem of shortage has become one of factor of restriction China Economic development, and the Chinese government has proposed petroleum supplements such as exploitation alcohol fuel in " national economy and social development 10th Five-Year Plan outline " for this reason, to save the scheme of petroleum resources.The alcohol fuel main raw material is a grain, that is to say that it is a kind of reproducible energy, alcohol fuel is again a kind of clean fuel simultaneously, gasoline, diesel motor are being mixed the concentration that can reduce carbon monoxide, hydrocarbon polymer and the smokeshade in the tail gas of discharging after burning the fuel that contains alcohol fuel greatly, and minimizing is to atmospheric pollution.
The diesel oil demand is far longer than gasoline in China, though the oil refining industry of China at the production diesel oil of trying one's best because China's oil belongs to mink cell focus, the restriction of Technology makes diesel oil still can not satisfy the demand in market in addition, still wants a large amount of imports every year.The exploitation of ethanol diesel fuel and application not only meet the strategy of national development renewable energy source, can also alleviate the situation of China's diesel oil relative shortage.The topsoil of well-known diesel motor is much more serious than petrol engine, and the popularization of ethanol diesel fuel and application can improve environmental aspect to a greater degree, and therefore developing the ethanol diesel fuel product has more far reaching significance.But the difficulty that ethanol and diesel oil are mixed is big, and the solubility promoter that needs to add some amount just can make ethanol and diesel oil dissolve each other, and forms the ethanol diesel fuel product of stable not phase-splitting.Through experiment, ethanol diesel fuel is not done under the situation of change at diesel motor, engine power performance is constant substantially, and the concentration of carbon monoxide, hydrocarbon polymer and the flue dust that also greatly reduces in the tail gas simultaneously to be discharged also has good effect to environment purification.
Summary of the invention
The objective of the invention is in basic diesel oil, to mix a kind of reproducible, do not do under the situation of change at diesel motor, engine power performance is constant substantially, the concentration of carbon monoxide, hydrocarbon polymer and the flue dust that also greatly reduces in the tail gas simultaneously to be discharged, environment purification there is the alcohol fuel of good effect and is equipped with ethanol diesel fuel of solubility promoter and preparation method thereof, a kind of clean fuel of diesel motor is provided, the strategy that not only meets the national development renewable energy source can also be alleviated the situation of China's diesel oil relative shortage.
Ethanol diesel fuel of the present invention is made by following component, and consumption is a parts by volume.
Solubility promoter 0.1～10
Basis diesel oil 75～98
The formula optimization volume proportion scope of preparation ethanol diesel fuel of the present invention is:
Basis diesel oil 80～93
The optimal volume proportioning of ethanol diesel fuel of the present invention is:
Solubility promoter 1.3～3.8
Basis diesel oil 87.5～90.7
The method of making ethanol diesel fuel of the present invention by above-mentioned each set of dispense is:
With alcohol fuel, solubility promoter and basic diesel oil at normal temperatures and pressures in given ratio be in harmonious proportion, the mediation mode generally adopts jar and to be in harmonious proportion or pipeline is in harmonious proportion.After mediation is finished product.
Solubility promoter in the component is two kinds of compound preparations of compound, and employed compound mainly is divided three classes, and they are: contain the unitary fatty alcohol of ten carbon of three carbon to two, comprise its various isomer; Polyoxyethylene nonylphenol ether, its molecular formula are C
6H
19C
6H
4O (CH
2CH
2O)
nH, n=1～50 here; Various petroleum sulfonate classes.Solubility promoter of the present invention is respectively by Fatty Alcohol(C12-C14 and C12-C18)-polyoxyethylene nonylphenol ether, and two kinds of compound volume per-cents are respectively 70～99%, 1～30%; The mixture of Fatty Alcohol(C12-C14 and C12-C18)-petroleum sulfonate, the volume percent of two kinds of compounds is respectively 80～99%, 1～20% in the mixture.Basic diesel oil of the present invention is the diesel product that meets national standard of refinery production, the product that alcohol fuel makes for the grain zymotechnique.The existing proven technique of starting material that the present invention is all can have been bought on market.
Solubility promoter of the present invention is a kind ofly to be present in the individual system with lower concentration, can be adsorbed on the interface, and significantly reduce its interfacial free energy, finally makes system form the homogeneous material.Since exist on the chemical constitution than big-difference, the intermiscibility between basic diesel oil and alcohol fuel is not fine, just needs to add solubility promoter and improves intermiscibility between them.The solubility promoter that is added includes the amphiphile, amphiphilic molecule of hydrophilic group and oleophilic group (hydrophobic group), can between basic diesel oil and alcohol fuel, play a kind of tie effect, make the emulsion that in product, both can form basic diesel oil bag alcohol fuel, also can form the emulsion of alcohol fuel package base diesel oil, make product have good intermiscibility, and can be not stratified over a long time.
The basic diesel oil of its fundamental property of ethanol diesel fuel of the present invention and market sale is suitable, and most of performance parameter variations are little, and it can reduce the cloud point of basic diesel oil, and the zero pour of blend also has reduction in various degree.Because the alcoholic acid cetane value is lower, makes the cetane value of ethanol diesel fuel compare and decrease with basic diesel oil.Ethanol diesel fuel belongs to a kind of special mixture, and its cetane value can calculate by traditional formula in theory, but the calculated value of ethanol diesel fuel and measured value have than large deviation, need revise again.Cetane value is just weighed the index of oil product ignitability, though the cetane value of ethanol diesel fuel will be lower than basic diesel oil, but the platform experiment through diesel motor shows, ethanol diesel fuel can satisfy the requirement of the basic ignition quality of Diesel fuel of the equal trade mark, the adding of this explanation ethanol solubility promoter to the diesel-fuel ignition performance without any influence.Because it is first with the diesel oil compression ignite, ethanol again ignites.
The dynamic performance of the ethanol diesel fuel of the present invention also basic diesel oil with market sale is suitable, and the platform experiment of process diesel motor is confirmed, also can reduce the discharging of carbon monoxide in the discharge, hydrocarbon polymer and flue dust simultaneously.
Description of drawings
The graphic representation of Fig. 1 solubility promoter addition and phase separation temperature
Fig. 2 diesel oil difference is mixed burning than part throttle characteristics comparison diagram
Fig. 3 diesel oil difference is mixed burning than external characteristics dynamic property comparison diagram
Fig. 4 diesel oil difference is mixed burning than part throttle characteristics carbon monoxide emission comparison diagram
Fig. 5 diesel oil difference is mixed burning than part throttle characteristics hydrogen compound discharging comparison diagram
Fig. 6 diesel oil difference is mixed burning than external characteristics smoke emission comparison diagram
Embodiment
Get
43077 liters of-No. 20 basic diesel oil (market is bought)
4990 liters of alcohol fuels
1933 liters of solubility promoters
This kind solubility promoter is 11 carbon fatty alcohols-polyoxyethylene nonylphenol ether mixture by a certain percentage, and the volumetric ratio of 11 carbon fatty alcohols is 75%; Polyoxyethylene nonylphenol ether is 25%.The molecular formula of polyoxyethylene nonylphenol ether is C
6H
19C
6H
4O (CH
2CH
2O)
nH, n=8～10 here.
Production method is as follows:
Get above-mentioned three kinds of raw materials respectively, at first in basic diesel oil, add solubility promoter, and then add alcohol fuel, carry out mechanical stirring after reinforced the finishing at normal temperatures and pressures or adopt pipeline round-robin mode to stir, promptly get product after several minutes.
The fundamental property that-No. 20 basic diesel oil are buied in ethanol diesel fuel of the present invention and market is compared as follows:
| Cetane value | Flash-point ℃ | Cold filter clogging temperature ℃ | Condensation point ℃ | |
| The standard value of-No. 20 basic diesel oil | ????≥45 | ????≥55 | ????≤-14 | ????≤-20 |
| The measured value of-No. 20 basic diesel oil | ????48.0 | ????63 | ????-24 | ????-17 |
| Ethanol diesel fuel | ????45.1 | ????16 | ????-25 | ????-18 |
Through using-No. 20 basic diesel oil to show with the platform experiment of preparing according to the above ratio that ethanol diesel fuel carried out, when using ethanol diesel fuel, when high engine speeds turns round, power and moment of torsion do not reduce, when low-speed running, power descends also less than 1%, peak torque descends 0.4%, this mainly is because the calorific value of ethanol diesel fuel is 96.4% of a former basic diesel oil, under the situation that does not improve fuel delivery per cycle, but less than the calorific value slippage of propellant combination, this is because behind the engine for combusting propellant combination, ethanol is oxygenated fuel to the power drop-out value of engine, and combustionvelocity is very fast, and the comprehensive action of the effect of micro-explosion of emulsion fuel, engine active combustion thermo-efficiency is increased, thereby compensated the power loss of a part of engine.
The engine pedestal experiment also shows, in the ethanol diesel fuel along with the increase of proportion of ethanol, the discharging of carbon monoxide and hydrocarbon polymer obviously improves in the tail gas of engine, the ethanol diesel fuel that uses preparation according to the above ratio than the carbon monoxide emission of former basic diesel oil descended 35%, hydrocarbon emission descended 10%, soot emissions have descended 14%.
Get
43792 liters of-No. 35 basic diesel oil (market is bought)
5000 liters of alcohol fuels
1208 liters of solubility promoters
This kind solubility promoter is eight carbon fatty alcohols-petroleum sulfonate mixture by a certain percentage, and their volumetric ratio is that eight carbon alcohol account for 80%, and petroleum sulfonate accounts for 20%.Eight carbon alcohol is n-Octanol, and petroleum sulfonate is polyoxyethylene octylphenol ether (a 10) sulphonate, and molecular formula is C
8H
17C
6H
6O (CH
2CH
2O)
nCOOSO
3, n=10 here.Concrete production method is with embodiment 1.
The fundamental property that-No. 35 basic diesel oil are buied in ethanol diesel fuel of the present invention and market is compared as follows:
| Cetane value | Flash-point ℃ | Cold filter clogging temperature ℃ | Condensation point ℃ | |
| The standard value of-No. 35 basic diesel oil | ????≥45 | ????≥45 | ????≤-29 | ????≤-35 |
| The measured value of-No. 35 basic diesel oil | ????46.0 | ????58 | ????-30 | ????-36 |
| Ethanol diesel fuel | ????41.3 | ????15 | ????-30 | ????-35 |
The platform experiment that ethanol diesel fuel carried out through-No. 35 basic diesel oil of use and present embodiment preparation shows, power and moment of torsion are all less than reducing, simultaneously carbon monoxide emission has descended 36%, hydrocarbon emission descended 9.7%, and soot emissions have descended 14.1%.
Get
44826 liters of No. 0 basic diesel oil (market is bought)
4450 liters of alcohol fuels
724 liters of solubility promoters
This kind solubility promoter is ten carbon fatty alcohols-polyoxyethylene nonylphenol ether mixture by a certain percentage, and the volumetric ratio of ten carbon fatty alcohols is 80%; Polyoxyethylene nonylphenol ether is 20%.The molecular formula of polyoxyethylene nonylphenol ether is C
6H
19C
6H
4O (CH
2CH
2O)
nH, n=12 here.Concrete production method is with embodiment 1.
The fundamental property of No. 0 basic diesel oil that ethanol diesel fuel of the present invention and market are buied is compared as follows:
| Cetane value | Flash-point ℃ | Cold filter clogging temperature ℃ | Condensation point ℃ | |
| The standard value of-No. 0 basic diesel oil | ????≥45 | ????≥55 | ????≤4 | ????≤0 |
| The measured value of-No. 0 basic diesel oil | ????51.5 | ????80 | ????-3 | ????-6 |
| Ethanol diesel fuel | ????46.8 | ????15 | ????-3 | ????-7 |
The platform experiment that ethanol diesel fuel carried out through using the preparation of No. 0 basic diesel oil and present embodiment shows that power and moment of torsion all do not reduce, and the while carbon monoxide emission has descended 30%, hydrocarbon emission has descended 8.2%, and soot emissions have descended 13.8%.
Embodiment 4
Get
40038 liters of-No. 35 basic diesel oil (market is bought)
9000 liters of alcohol fuels
962 liters of solubility promoters
This kind solubility promoter is 11 carbon fatty alcohols-polyoxyethylene nonylphenol ether mixture by a certain percentage, and the volumetric ratio of 11 carbon fatty alcohols is 75%; Polyoxyethylene nonylphenol ether is 25%.The molecular formula of polyoxyethylene nonylphenol ether is C
6H
19C
6H
4O (CH
2CH
2O)
nH, n=12～14 here.Concrete production method is with embodiment 1.
Through using-No. 35 basic diesel oil and the platform experiment that ethanol diesel fuel carried out of present embodiment preparation to show that power is not reduction when time of engine low speed, descend to some extent during high speed but not obvious.Carbon monoxide emission has descended 50%, hydrocarbon emission slightly increases, and the discharging of flue dust has descended 40%.
Get
38366 liters of-No. 20 basic diesel oil (market is bought)
9950 liters of alcohol fuels
1684 liters of solubility promoters
This kind solubility promoter is ten carbon fatty alcohols-petroleum sulfonate mixture by a certain percentage, and their volumetric ratio is that ten carbon alcohol account for 83%, and petroleum sulfonate accounts for 17%.Petroleum sulfonate is polyoxyethylene octylphenol ether (a 14) sulphonate, and molecular formula is C
8H
17C
6H
6O (CH
2CH
2O)
nCOOSO
3, n=14 here.Concrete production method is with embodiment 1.
The platform experiment that ethanol diesel fuel carried out through-No. 20 basic diesel oil of use and present embodiment preparation shows, power and moment of torsion are all less than reducing, simultaneously carbon monoxide emission has descended 51%, hydrocarbon emission increased by 5%, and the discharging of flue dust has descended 42.1%.
According to the cloud point method for measuring ethanol diesel fuel of embodiment 1 is measured, to determine phase separation temperature.With embodiment unique different be that ethanol diesel fuel water content in the present embodiment is different, be respectively 0.0～0.5%, the result of gained such as Fig. 1.
Adopt electric eddy current dynamometer, the ethanol diesel fuel among embodiment 1, the embodiment 4 and-No. 20 basic diesel oil have been carried out under certain rotating speed of engine, the contrast experiment of moment of torsion and fuel oil consumption mensuration, what record the results are shown in Fig. 2.The contrast experiment who has carried out the external characteristics dynamic property of motor speed and power measures, and what record the results are shown in Fig. 3.
Adopt emission analyzer, to the ethanol diesel fuel among embodiment 1, the embodiment 4 and-No. 20 basic diesel oil has also carried out the carbon monoxide emission of engine load characteristic respectively and the contrast experiment of hydrocarbon emission measures, the result who records lists in Fig. 4, Fig. 5 respectively.The contrast experiment who has carried out the engine test bench characteristic smoke emission measures, and what record the results are shown in Fig. 6.
Claims (7)
1, a kind of preparation method of ethanol diesel fuel is characterized in that he adopts jar mediation or pipeline to be in harmonious proportion by alcohol fuel, solubility promoter and basic diesel oil to form at normal temperatures and pressures,
Raw material volume proportion (part):
Alcohol fuel 2～20
Solubility promoter 0.1～10
Basis diesel oil 75～98
2, the preparation method of a kind of ethanol diesel fuel according to claim 1 is characterized in that wherein the volume proportion of each raw material (part) is:
Alcohol fuel 6～15
Solubility promoter 1～5
Basis diesel oil 80～93
3, the preparation method of a kind of ethanol diesel fuel according to claim 1 is characterized in that: wherein the volume proportion of each raw material (part) is:
Alcohol fuel 8～10
Solubility promoter 1.3～3.8
Basis diesel oil 87.5～90.7
4, the preparation method of a kind of ethanol diesel fuel according to claim 1 is characterized in that: solubility promoter is the unitary fatty alcohol that contains ten carbon of three carbon to two, comprises its various isomer, or polyoxyethylene nonylphenol ether, and its molecular formula is C
6H
19C
6H
4O (CH
2CH
2O)
nH, n=1～50, or various petroleum sulfonate class here.
5, the preparation method of a kind of ethanol diesel fuel according to claim 4, it is characterized in that: solubility promoter is two kinds of compound preparations of compound, they are by the compound preparation of Fatty Alcohol(C12-C14 and C12-C18)-polyoxyethylene nonylphenol ether, and two kinds of compound volume per-cents are respectively 70～99%, 1～30%.
6, the preparation method of a kind of ethanol diesel fuel according to claim 4, it is characterized in that: solubility promoter is two kinds of compound preparations of compound, they are mixtures of Fatty Alcohol(C12-C14 and C12-C18)-petroleum sulfonate, and the volume percent of two kinds of compounds is respectively 80～99%, 1～20% in the mixture.
7, the ethanol diesel fuel of the preparation method of a kind of ethanol diesel fuel according to claim 1 preparation is characterized in that: he adopts jar mediation or pipeline to be in harmonious proportion by alcohol fuel, solubility promoter and basic diesel oil to form at normal temperatures and pressures.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03153101 CN1247750C (en) | 2003-08-07 | 2003-08-07 | Alcohol diesel and its preparing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03153101 CN1247750C (en) | 2003-08-07 | 2003-08-07 | Alcohol diesel and its preparing method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1580205A true CN1580205A (en) | 2005-02-16 |
| CN1247750C CN1247750C (en) | 2006-03-29 |
Family
ID=34579917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03153101 Expired - Fee Related CN1247750C (en) | 2003-08-07 | 2003-08-07 | Alcohol diesel and its preparing method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1247750C (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101982530A (en) * | 2010-11-02 | 2011-03-02 | 中国农业大学 | Biological ethanol/diesel blended fuel and preparation method thereof |
| CN101705117B (en) * | 2009-11-18 | 2012-07-04 | 济南开发区星火科学技术研究院 | Ethanol diesel fuel |
| CN103540366A (en) * | 2013-10-21 | 2014-01-29 | 中国石油化工股份有限公司 | Cosolvent for improving storage stability of ethanol diesel and ethanol diesel containing same |
-
2003
- 2003-08-07 CN CN 03153101 patent/CN1247750C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101705117B (en) * | 2009-11-18 | 2012-07-04 | 济南开发区星火科学技术研究院 | Ethanol diesel fuel |
| CN101982530A (en) * | 2010-11-02 | 2011-03-02 | 中国农业大学 | Biological ethanol/diesel blended fuel and preparation method thereof |
| CN101982530B (en) * | 2010-11-02 | 2014-02-19 | 中国农业大学 | Biological ethanol/diesel blended fuel and preparation method thereof |
| CN103540366A (en) * | 2013-10-21 | 2014-01-29 | 中国石油化工股份有限公司 | Cosolvent for improving storage stability of ethanol diesel and ethanol diesel containing same |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1247750C (en) | 2006-03-29 |
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Granted publication date: 20060329 Termination date: 20210807 |