CN1563156A - Method for preparing antibiosis (coating) film - Google Patents
Method for preparing antibiosis (coating) film Download PDFInfo
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- CN1563156A CN1563156A CN 200410022142 CN200410022142A CN1563156A CN 1563156 A CN1563156 A CN 1563156A CN 200410022142 CN200410022142 CN 200410022142 CN 200410022142 A CN200410022142 A CN 200410022142A CN 1563156 A CN1563156 A CN 1563156A
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- film
- nano
- powder
- antiseptic
- antibiotic
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/34—Shaped forms, e.g. sheets, not provided for in any other sub-group of this main group
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Medicinal Preparation (AREA)
Abstract
In the preparing method, nanoantibiotic powder is prepared by connecting germicide covalency of quaternary ammoium salt or quaternary phosphorus salt polymer on nanopowder through covalent decoration method in utilizing nanopowder with functional perssad of antibiosis, prepared powder is disposed to be antibiotic solution containing 0.01-0.1% nanogermicide and then the colution is added into four sorts of film forming materials for making film with conventional process.
Description
Technical field:
The present invention relates to the preparation method of a kind of nano-antibacterial (being coated with) film.
Technical background:
The preparation method of existing antibiotic (being coated with) film adopts organic antibacterial agent such as organic acid, antibacterial peptide, biological enzyme etc. to combine with mould material such as polyose, protein, Mierocrystalline cellulose and derivatives class, synthetic macromolecule etc., utilizes the differing molecular interphase interaction to form antibiotic (being coated with) film with porous network structure.The problem of this class antibiotic (being coated with) film is, antiseptic-germicide is insecure with combining of mould material, break away from easily, and the easy inactivation of antiseptic-germicide, inefficacy and do not reach antibiotic purpose.
Summary of the invention:
The objective of the invention is: adopt nano-powder with antibacterial group, utilize the big specific surface area and the strong absorption property of nano-powder, the antibacterial group is adhered to and be embedded in the mould material, thereby make mould material have broad-spectrum antimicrobial, efficient, long-acting and stable antibacterial.
The present invention is achieved in that and utilizes the nano-powder with antibacterial group, with Chinese patent application 03117920.7 disclosed covalent modification method, quaternary ammonium salt or quaternary alkylphosphonium salt polymkeric substance antiseptic-germicide is covalently bound to nano-powder and the antiseptic nano powder that obtains, the nano-powder antiseptic-germicide is pressed different needs, be configured to contain the antimicrobial of nano antibacterial agent 0.01~0.1% concentration, joining then can film forming polyose, protein-based, Mierocrystalline cellulose and derivatives class thereof, in the synthetic polymeric kind film material, frequent regulation membrane process system film, or directly material surface routinely coating process film, form antibiotic (being coated with) film.
Described polyose mould material is meant can film forming polyose such as starch, glucomannan, alginates, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
Described protein-based mould material is meant can be film forming protein-based as gelatin, zein, whey-protein, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
Described Mierocrystalline cellulose and derivatives class mould material thereof are meant can film forming Mierocrystalline cellulose and derivatives class such as carboxymethyl cellulose, cellulose acetate, Natvosol, Microcrystalline Cellulose, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
Described synthetic polymeric kind film material is meant can film forming synthetic macromolecule class such as polyvinyl alcohol, sodium polyacrylate, polyvinylpyrrolidone, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
The present invention compared with prior art has following advantage:
1. adopt covalently bound quaternary ammonium salt or quaternary alkylphosphonium salt polymkeric substance antiseptic-germicide, have broad spectrum antibacterial.Utilizing nano-powder is antibiotic carrier, and antibiotic effect is lasting, efficient, stable.
The present invention prepare the method for antibiotic (being coated with) film be mould material and antimicrobial powder in varing proportions with the concentration uniform mixing, often regulation membrane process or coating process carry out the film forming processing, technology is simple, does not change original technology, and the performance of antibiotic (being coated with) film each side that forms all obviously improves.
Embodiment:
Embodiments of the invention:
1. the preparation of polyose antibacterial film: at first the nano-powder of antibacterial group is with in preparation, utilizes nano SiO 2 particle, generates covalently bound QAS polymer antiseptic-germicide nano-powder with Chinese patent application 03117920.7 disclosed method.Its method is: nano particle silica 10g, in the 100ml solvent chloroform, with 2ml 4-bromobutanoylchloride stirring reaction at room temperature, nano-material surface is activated by the 4-bromobutanoylchloride, the nano material after the activation is collected, wash with methanol solvate, place 100ml seasons four amylalcohol solvent then, add 10g polymine and an amount of potassium hydroxide, stirring reaction under 90 ℃ of temperature, obtain the covalently bound nano particle of polymine, collect after scouring for several times.Place 100ml seasons four amylalcohol again, add 10ml hexyl bromide 1 bromohexane and an amount of potassium hydroxide, reaction is stirred under 90 ℃ of temperature, collect after scouring for several times, obtain the polyethylene imine nanometer particle of hexylization, further be positioned in the seasons four amylalcohol solvent, add the 10ml methyl iodide, under 60 ℃ of temperature, react, can obtain having the nano particle of the quaternary ammonium salt antibacterial base of polymine.Above-mentioned antiseptic nano powder 1mg and konjak glucomannan 1g thorough mixing is even, add 100ml water, regulate the PH10-12 scope, add film coalescence aid, filming technology prepares the glucomannan antibacterial film with antiseptic nano powder routinely.
2. the preparation of protein antibiotic (being coated with) film: the gelatin solution of above-mentioned antimicrobial nano powder 100ppm and 5% is mixed, add conventional film coalescence aid, coating process is filmed routinely, and the gelatin that can obtain containing antiseptic nano powder is filmed, and can be used for the fresh-keeping, anticorrosion of food.
3. the preparation of Mierocrystalline cellulose and derivative antibacterial film thereof: with above-mentioned antiseptic nano powder 100ppm with mix with 5% cellulose acetate of dissolution with solvents, add conventional film coalescence aid, film-forming method prepares routinely, obtains having the cellulose acetate antibacterial film of antimicrobial nano material.
4. high molecular polymer class antibacterial film: with 5% polyvinyl alcohol solution of complete hydrolysis, mix with the above-mentioned antimicrobial nano powder of 100ppm, add conventional film coalescence aid, by polyvinyl alcohol filming technology system film, can obtain having the polyvinyl alcohol antibacterial film of transparent, tough and tensile, anti tear and shock-resistant characteristics.
Claims (5)
1, the preparation method of a kind of antibiotic (being coated with) film, it is characterized in that: utilize nano-powder with antibacterial group, with known covalent modification method, quaternary ammonium salt or quaternary alkylphosphonium salt polymkeric substance antiseptic-germicide is covalently bound to nano-powder and the antiseptic nano powder that obtains, the nano-powder antiseptic-germicide is pressed different needs, be configured to contain the antimicrobial of nano antibacterial agent 0.01~0.1% concentration, joining then can film forming polyose, protein-based, Mierocrystalline cellulose and derivatives class thereof, in the synthetic polymeric kind film material, frequent regulation membrane process system film, or directly material surface routinely coating process film, form antibiotic (being coated with) film.
2, the preparation method of antibiotic (being coated with) according to claim 1 film, it is characterized in that: described polyose mould material is meant can film forming polyose such as starch, glucomannan, alginates, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
3, the preparation method of antibiotic (being coated with) according to claim 1 film, it is characterized in that: described protein-based mould material is meant can be film forming protein-based as gelatin, zein, whey-protein, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
4, the preparation method of antibiotic (being coated with) according to claim 1 film, it is characterized in that: described Mierocrystalline cellulose and derivatives class mould material thereof are meant can film forming Mierocrystalline cellulose and derivatives class such as carboxymethyl cellulose, cellulose acetate, Natvosol, Microcrystalline Cellulose, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
5, the preparation method of antibiotic (being coated with) according to claim 1 film, it is characterized in that: described synthetic polymeric kind film material is meant can film forming synthetic macromolecule class such as polyvinyl alcohol, sodium polyacrylate, polyvinylpyrrolidone, and itself and antiseptic nano powder are mixed into and contain nano antibacterial agent 0.01~0.1% concentration in the film-forming soln.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200410022142 CN1266195C (en) | 2004-03-25 | 2004-03-25 | Method for preparing antibiosis (coating) film |
Applications Claiming Priority (1)
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CN 200410022142 CN1266195C (en) | 2004-03-25 | 2004-03-25 | Method for preparing antibiosis (coating) film |
Publications (2)
Publication Number | Publication Date |
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CN1563156A true CN1563156A (en) | 2005-01-12 |
CN1266195C CN1266195C (en) | 2006-07-26 |
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CN 200410022142 Expired - Fee Related CN1266195C (en) | 2004-03-25 | 2004-03-25 | Method for preparing antibiosis (coating) film |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102212209A (en) * | 2011-04-29 | 2011-10-12 | 钟春燕 | Packaging film for refrigerated foods and preparation method thereof |
CN102389716A (en) * | 2011-09-26 | 2012-03-28 | 温州市宝信科技有限公司 | Antibacterial and alga-control film for barreled drinking water |
CN102490985A (en) * | 2011-11-15 | 2012-06-13 | 温州市宝信科技有限公司 | Water barrel |
CN102643554A (en) * | 2012-05-08 | 2012-08-22 | 福州大学 | Edible fishskin collagen antibiosis membrane and preparing method thereof |
CN103114501A (en) * | 2013-01-21 | 2013-05-22 | 金红叶纸业集团有限公司 | Production process of antibacterial paper and antibacterial paper |
CN103772752A (en) * | 2014-01-20 | 2014-05-07 | 南通天合包装有限公司 | Fruit preservative film and preparation method thereof |
CN106819076A (en) * | 2016-12-27 | 2017-06-13 | 华中农业大学 | A kind of preparation method of the bacteriostasis, preservation plastics based on natural polysaccharide particle |
CN111440406A (en) * | 2020-04-09 | 2020-07-24 | 安徽松泰包装材料有限公司 | Antibacterial food packaging film and processing technology thereof |
CN115612354A (en) * | 2022-10-24 | 2023-01-17 | 聊城鸿元达降解材料有限公司 | Nano-scale biodegradable fruit and vegetable liquid packaging coating and production method thereof |
-
2004
- 2004-03-25 CN CN 200410022142 patent/CN1266195C/en not_active Expired - Fee Related
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102212209B (en) * | 2011-04-29 | 2013-03-20 | 钟春燕 | Packaging film for refrigerated foods and preparation method thereof |
CN102212209A (en) * | 2011-04-29 | 2011-10-12 | 钟春燕 | Packaging film for refrigerated foods and preparation method thereof |
CN102389716A (en) * | 2011-09-26 | 2012-03-28 | 温州市宝信科技有限公司 | Antibacterial and alga-control film for barreled drinking water |
CN102490985A (en) * | 2011-11-15 | 2012-06-13 | 温州市宝信科技有限公司 | Water barrel |
CN102643554B (en) * | 2012-05-08 | 2013-12-04 | 福州大学 | Edible fishskin collagen antibiosis membrane and preparing method thereof |
CN102643554A (en) * | 2012-05-08 | 2012-08-22 | 福州大学 | Edible fishskin collagen antibiosis membrane and preparing method thereof |
CN103114501A (en) * | 2013-01-21 | 2013-05-22 | 金红叶纸业集团有限公司 | Production process of antibacterial paper and antibacterial paper |
CN103114501B (en) * | 2013-01-21 | 2016-06-08 | 金红叶纸业集团有限公司 | Antibacterial paper production technique and antibacterial paper |
CN103772752A (en) * | 2014-01-20 | 2014-05-07 | 南通天合包装有限公司 | Fruit preservative film and preparation method thereof |
CN103772752B (en) * | 2014-01-20 | 2016-04-06 | 南通天合包装有限公司 | A kind of fruit freshness preserving film and preparation method thereof |
CN106819076A (en) * | 2016-12-27 | 2017-06-13 | 华中农业大学 | A kind of preparation method of the bacteriostasis, preservation plastics based on natural polysaccharide particle |
CN111440406A (en) * | 2020-04-09 | 2020-07-24 | 安徽松泰包装材料有限公司 | Antibacterial food packaging film and processing technology thereof |
CN111440406B (en) * | 2020-04-09 | 2023-01-17 | 安徽松泰包装材料有限公司 | Antibacterial food packaging film and processing technology thereof |
CN115612354A (en) * | 2022-10-24 | 2023-01-17 | 聊城鸿元达降解材料有限公司 | Nano-scale biodegradable fruit and vegetable liquid packaging coating and production method thereof |
Also Published As
Publication number | Publication date |
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CN1266195C (en) | 2006-07-26 |
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