CN1552625A - Mole cular sieve with composite structure and preparing method thereof - Google Patents

Mole cular sieve with composite structure and preparing method thereof Download PDF

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CN1552625A
CN1552625A CNA031335578A CN03133557A CN1552625A CN 1552625 A CN1552625 A CN 1552625A CN A031335578 A CNA031335578 A CN A031335578A CN 03133557 A CN03133557 A CN 03133557A CN 1552625 A CN1552625 A CN 1552625A
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molecular sieve
ton
gel
crystallization
mfi
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CN1242918C (en
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刘全杰
徐会青
孙万付
周勇
杨军
王伟
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China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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China Petroleum and Chemical Corp
Sinopec Fushun Research Institute of Petroleum and Petrochemicals
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  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

A composite molecular sieve with TON and MFI structures is prepared in static crystallizing condition. In the procedure of preparing gel, less crystal seeds and salt are added. The Si/Al ratio on its crystal lattice is greater than 50.

Description

A kind of composite structure molecular sieve and preparation method thereof
Technical field
The present invention relates to a kind of composite structure molecular sieve and preparation method thereof, more particularly, the invention provides a kind of composite structure molecular sieve that has TON and two kinds of molecular sieve structure features of MFI simultaneously.
Background technology
Molecular sieve is important member in the crystalline material, has the crystalline structure (can characterize with XRD) of regular pore structure.Crystalline duct and hole can characterize with diverse ways.A variety of molecular sieves have been had been found that at present, zeolite A for example, ZSM series, β, X, Y, mesoporous molecular sieve such as micro porous molecular sieve such as SAPO series and MCM-41.These natural or synthetic crystalline molecular sieves are widely used in catalysis and the adsorbing domain.The absorption of various molecular sieves is relevant with the hole size with its duct with catalytic performance, that is to say, the particular molecule sieve is applied to special purpose and depends in part on its crystalline structure at least.Because molecular sieve has unique screening and catalytic performance, thus the drying of gas with separate and the hydrocarbon conversion aspect have special effect.
After the eighties in 20th century, found the high silicon Si-Al zeolite molecular sieve that a class is new, its XRD result has the feature of table 1, for example THA-1, Nu-10, KZ-2, ISI-1 and ZSM-22 etc., and its general code name is a TON type molecular sieve.The XRD result of an other class high-silica zeolite has the feature of table 2, ZSM-5 etc. for example, and its general code name is the MFI molecular sieve.
The XRD result of table 1TON structure molecular screen
d hkl(nm) I/I o
1.090±0.02 M-W
0.870±0.016 VW
0.694±0.010 VW
0.458±0.007 VW
0.436±0.007 VS
0.368±0.005 VS
0.362±0.005 S
0.347±0.004 M
0.252±0.002 W-VW
The XRD result of table 2MFI structure molecular screen
d hkl(nm) I/I o
1.114±0.004 S
0.999±0.005 M
0.972±0.004 VW
0.599±0.006 VW
0.558±0.004 VW
0.437±0.006 VW
0.386±0.002 VS
0.382±0.004 VS
0.375±0.004 S-M
0.373±0.004 S
0.365±0.005 W
0.332±0.006 VW
0.305±0.007 VW
0.298±0.006 W-VW
The represented relative intensity of symbol is worth as follows in the form: VS, 80%-100%; S, 60%-80%; M, 40%-60%; W, 20%-40%; VW,＜20%.
Document with TON structure and MFI structure molecular screen preparation method is a lot.The preparation of the molecular sieve of relevant MFI structure: USP5338525 discloses and a kind ofly need not organicly touch an edition agent, prepares the method for MFI structure molecular screen under the fluorine ambient condition; USP5082641 discloses a kind of MFI structure molecular screen preparation method who contains the heteroatoms titanium, and this molecular sieve has good selection adsorptive power and catalytic capability; USP5246688 discloses a kind of silica-based MFI structure molecular screen, in the building-up process of this molecular sieve, adds suitable compound, can prepare and contain different heteroatomic molecular sieves; USP5741904 discloses a kind of under gas phase condition, and the preparation method of symmetrical hydroxyl MFI structure molecular screen is contained on preparation molecular sieve surface; USP5672331 discloses a kind of preparation method of evengranular MFI structure molecular screen, and this method is to finish in the effect that crystal seed and structure directing agent are arranged; USP5,951,963 disclose the preparation method of the MFI molecular sieve that contains the P atom on a kind of lattice; CN1169953A discloses a kind of preparation method of the MFI of having structure Ga containing zeolite, is to prepare under hydrothermal condition; CN1194181A discloses a kind of phosphorus containing molecular sieve of the MFI of having structure, and the introducing of phosphorus improves the stability of this molecular sieve in the hydrocarbon conversion greatly.
Having of relevant TON structure molecular screen: USP4481177 discloses the method that a kind of low whipping speed is synthetic ZSM-22 under the 400RPM condition; EP-A-65400 discloses a kind of synthetic method of called after NU-10 molecular sieve, needs to stir in crystallization process; EP-A-87017 discloses the molecular sieve of a kind of called after ISI-1, and crystallization process is to finish under agitation condition; EP-A77624 discloses a kind of synthetic method of called after NU-10 molecular sieve; EP-A-57049 discloses the molecular sieve preparation method of a kind of called after THETA-1, and this process is finished in the rotation voltage-resistant reactor.
From top situation, preparation method about MFI structure and TON structure molecular screen is a lot, molecular sieve for different structure, owing to have its unique pore passage structure and physico-chemical property, so be fit to different purposes, for example the MFI structure molecular screen has three-dimensional zigzag duct, the less (0.65nm * 0.51nm), be applied to micromolecular conversion and macromolecular selective splitting process in aperture more; The TON structure molecular screen has suitable aperture, and (structure in 0.56nm * 0.56nm) and one dimension straight hole road in the isomerization reaction of hydrocarbon molecules, should have unique effect.
Yet for some reactions, particularly for the reaction of some mixtures, petroleum fractions for example, owing to wherein contain very complicated component, not that identical molecule is participated in reaction, so some adaptability problems will appear for the molecular sieve with homogeneous structural, to a kind of molecule can fine coupling catalytic material, be not very desirable just for other component.
Summary of the invention
At the deficiencies in the prior art, the invention provides composite molecular screen of a kind of TON of having and two kinds of structure molecular screen features of MFI and preparation method thereof, this molecular sieve XRD result has table 1 and table 2 feature.
Composite molecular screen of the present invention has TON and two kinds of structures of MFI, the SiO on the molecular sieve lattice 2/ Al 2O 3Mol ratio is generally 50～200 greater than 50, and the weight ratio of TON structure and MFI structure is 0.1～10: 1, and preferred 1～10: 1.
The main preparation process of composite molecular screen provided by the invention is:
(a) preparation is a kind of is selected from IV in the periodic table of elements by at least a AElement compound, mineral alkali, organic even gel of touching an edition agent, crystal seed, salt and water composition.
(b) gel of heating steps (a) preparation under the condition of static crystallization, makes the gel crystallization complete, through aftertreatment, obtains the composite structure crystalline molecular sieve.
Compare with the correlation technique document, molecular sieve of the present invention has TON and two kinds of constitutional featuress of MFI, can satisfy of the requirement of differential responses thing to catalytic material, reactive activity and selectivity have been improved, for example for lubricating oil distillate, owing to wherein mainly contain the macromole long chain alkane, and difference is bigger, if a kind of material can make C 20Hydrocarbon react, but for C 36Hydrocarbon, just may be improper.The present invention just provides a kind of composite molecular screen, can satisfy the requirement of differential responses thing to material simultaneously, thereby reaches the ideal reaction result; The another one characteristics of molecular sieve provided by the invention are the SiO on the molecular sieve lattice 2/ Al 2O 3Greater than 50, acid sites is few and be evenly distributed on this high-silica zeolite, being fit to very much some larger molecular organicses reacts, some generations have been reduced as side reactions such as cracking, the catalyst deactivation that also reduced simultaneously because carbon deposit etc. causes all is favourable to selectivity and the life of catalyst that improves reaction.In the preparation process of molecular sieve, the crystallization process of molecular sieve is that static state has under crystal seed and the halogenide acting in conjunction and finishes, need not stir, can save a large amount of energy and cost of equipment, there are crystal seed and halogenide to exist, can promote the crystallization of molecular sieve, crystallization time is shortened greatly, general crystallization time can shorten 10～100 hours.So just can reduce production costs significantly, enhance productivity.
Description of drawings
Fig. 1. be the XRD figure of Comparative Examples 1 sample C-1a.
Fig. 2. be the XRD figure of Comparative Examples 1 sample C-1b.
Fig. 3. be the XRD figure of Comparative Examples 2 sample C-2.
Fig. 4. be the XRD figure of embodiment 1 sample E-1.
Fig. 5. be the XRD figure of Comparative Examples 3 sample C-3a.
Fig. 6. be the XRD figure of Comparative Examples 3 sample C-3b.
Fig. 7. be the XRD figure of Comparative Examples 3 sample C-3c.
Fig. 8. be the XRD figure of Comparative Examples 3 sample C-3d.
Fig. 9. be the XRD figure of embodiment 2 sample E-2.
Figure 10. be the XRD figure of embodiment 3 sample E-3.
Figure 11. be the XRD figure of embodiment 4 sample E-4.
Figure 12. be the XRD figure of embodiment 5 sample E-5.
Figure 13. be the XRD figure of embodiment 6 sample E-6.
Embodiment
Composite molecular screen of the present invention has TON and two kinds of molecular sieve structures of MFI, the principal feature of building-up process is to have in static state to finish under crystal seed and the salt acting in conjunction, need not stir, crystal seed and halogenide can promote the crystallization of molecular sieve, crystallization time is shortened greatly, and the selection and the prior art of other condition and various raw materials are similar.Wherein said salt can be selected from one or more of basic metal or alkaline-earth metal salt, is preferably alkali metal halide, more preferably KF or NaCl etc.Said crystal seed can be selected from one or more of molecular sieve with TON or MFI structure, is preferably to have the TON structure molecular screen, and content (with respect to gel weight) is 0.01%～1%, is preferably 0.1%～0.5%, and more preferably 0.3%～0.5%.
In the process of preparation molecular sieve provided by the invention, other raw material and operational condition can be determined by prior art, IV in the common said periodic table of elements of step (a) AElement compound, can be selected from the compound of silicon or germanium one or more, be preferably the compound of silicon, can be all silicon-containing compounds that can be used in other molecular sieve of preparation, for example, active silica, silicate, silicon sol and siliceous organism etc. are preferably silicate, silicon sol and siliceous organism, more preferably silicon sol.Said mineral alkali can be all alkaline matters, and the oxyhydroxide of for example alkali-metal oxyhydroxide, carbonate, alkaline-earth metal and ammoniacal liquor etc. are preferably alkali-metal oxyhydroxide, more preferably potassium hydroxide.Said aluminium source can be to be selected from activated alumina and precursor, aluminum soluble salt and the organic aluminum contained compound one or more, for example clay, hydrated aluminum oxide, aluminium colloidal sol, aluminate, aluminium salt and aluminiferous organism, be preferably aluminate and aluminium salt, more preferably aluminium salt.Said organic directed agents is ammonium salt or amine organism, is preferably the amine organism, and more preferably hexanediamine and octamethylenediamine most preferably are octamethylenediamine.
The preparation method of the said gel of step (a) carries out thorough mixing with required material, obtains the homogeneous phase colloidal mixture.The mol ratio of each material is generally in the gained gel:
0.8～2.0M 2O/1.0～5.0R/0.01～1.0Al 2O 3/10SiO 2/0.1～2.0NX/50～600H 2O+0.01w％～1w％S，
Be preferably:
1.0～1.5M 2O/2.0～4.0R/0.05～0.5Al 2O 3/10SiO 2/0.2～1.0NX/100～500H 2O+0.05w％～0.5w％S，
More preferably:
1.1～1.4M 2O/2.5～3.5R/0.1～0.2Al 2O 3/10SiO 2/0.2～0.5NX/300～400H 2O+0.1w％～0.3w％S，
Wherein R is a structure directing agent, and M is the monovalent base metal ion, and NX is a halogenide, and S is a crystal seed, and content is the weight with respect to gel.
Said crystallization is to carry out in the high-pressure reactor of autogenous pressure in the step (b), and crystallization temperature is 120～200 ℃, is preferably 150～180 ℃, more preferably 160～170 ℃; Crystallization time is 10～240 hours, is preferably 24～96 hours, more preferably 48～72 hours; The method of aftertreatment can be any conventional molecular sieve aftertreatment means, for example collects, washs and drying etc.The XRD result of the molecular sieve that obtains has table 1 and table 2 feature, its anhydrous consisting of: 0.1～0.6M 2O/0.01～1.0Al 2O 3/ 10SiO 2
Be preferably: 0.1～0.3M 2O/0.1～0.2Al 2O 3/ 10SiO 2
Here, M is a monovalent metallic ion.
Give further instruction below by embodiment to technology of the present invention.
Comparative Examples 1
Get the TON type molecular sieve that obtains according to U.S. Pat 4902406 embodiment 1 disclosed method, be numbered C-1a, its XRD sees Fig. 1.MFI type molecular sieve according to Chinese patent CN1187462A embodiment 1 disclosed method obtains is numbered C-1b, and its XRD sees Fig. 2.
XRD result adopts D/MAX-RA type x-ray diffractometer of science, and source of radiation is the copper target, the filtering of graphite monocrystalline, operation tube voltage 35KV, tube current 30～50mA, sweep velocity (2 θ) be 4 degree/minute, sweep limit is 4～35 degree.The SiO of molecular sieve 2/ Al 2O 3Adopt plasma emission spectrum (ICP) method to measure.
Comparative Examples 2
Do not add crystal seed in the gel, the preparation process of molecular sieve mainly comprises:
(a) preparation process of gel is: with the KOH of 17.75 grams 82%, and 37.8 grams 1,8-octamethylenediamine, 4 gram AlCl 3, 200 gram SiO 2Content is 30% silicon sol, and 2.9 gram KF and 577 gram water mix according to a definite sequence, through 20 minutes vigorous stirring, obtain homogeneous gel shape mixture, and the mole that obtains gel consists of:
1.3K 2O/3.00R/0.15Al 2O 3/10SiO 2/0.5KF/400H 2O
R=1, the 8-octamethylenediamine
(b) crystallization process: the gel that step (a) obtains is transferred in the stainless steel autogenous pressure reactor, made reactor be elevated to 165 ℃ from room temperature in two hours, static constant temperature stops heating, reactor naturally cooling after 48 hours.
(c) aftertreatment: open reactor, can see that upper solution clarification, crystallisate all accumulate in the still bottom, through suction filtration, deionized water wash 3 times, 110 ℃ of dryings 4 hours obtain the former powder of crystalline molecular sieve, are numbered C-2.
(d) characterize: the SiO of C-2 2/ Al 2O 3Be 62, the XRD result of sample C-2 has table 1 feature, sees Fig. 3.Find out that by Fig. 3 product is pure MFI structure molecular screen, do not have the TON structure molecular screen to exist.
Embodiment 1
The gel of employing and Comparative Examples 2 described same compositions, but wherein add 0.5 gram SiO 2/ Al 2O 3Be 44, crystal grain is that 0.8 micron TON structure molecular screen (0.06% with respect to gel weight) is done crystal seed, and through crystallization and the last handling process identical with Comparative Examples 2, obtaining sample number into spectrum is E-1.
Characterize: the SiO of sample E-1 2/ Al 2O 3Be 58, XRD result has table 1 and table 2 feature, sees Fig. 4.Found out that by Fig. 4 product has TON and two kinds of structure knots of MFI molecular sieve feature, wherein the ratio of the content of TON structure and MFI structure molecular screen is 2.0.
Comparative Examples 3
Adopt gel with embodiment 1 described same composition, but do not add KF and crystal seed, the gel that obtains is through constant temperature under the crystallization temperature identical with embodiment 1, be respectively 48,72,96 and 120 hours sampling analysis at crystallization time, the sample of obtaining is through behind the last handling process, and numbering is respectively C-3a, C-3b, C-3c and C-3d.
Characterize: the SiO of C-3d 2/ Al 2O 3Be 58, the XRD figure of sample C-3a, C-3b, C-3c and C-3d is seen Fig. 5,6,7 and 8 respectively.Find out by these figure, contain a large amount of unformed products and a spot of MFI structure molecular screen among the C-3a; C-3b and C-3c mainly are MFI molecular sieve and a spot of unformed product; C-3d contains some MFI structure molecular screen and TON structure molecular screen, the ratio 0.6 of its content.This explanation is not having under the situation of KF, and the crystallization rate of molecular sieve is very slow, and beginning forms the MFI structure molecular screen earlier, and some MFI structure molecular screen was converted into the TON structure molecular screen afterwards.
Embodiment 2
The preparation process of molecular sieve mainly comprises:
(a) preparation process of gel is: with embodiment 1, remove the KOH that adds 20.50 grams 82%, 25.3 grams 1,8-octamethylenediamine, 10 gram Al 2(SO 4) 3.18H 2O replaces 4 gram AlCl 3, 5.8 gram KF, 1.0 gram TON molecular sieves (0.15w% is with respect to gel weight) and 400 gram water mix according to a definite sequence, through 20 minutes vigorous stirring, obtain homogeneous gel shape mixture, and the mole that obtains gel consists of:
1.5K 2O/2.01R/0.08Al 2O 3/10SiO 2/1.0KF/300H 2O
R=1, the 8-octamethylenediamine
(b) crystallization process: with embodiment 1.
(c) last handling process: with embodiment 1, obtaining sample number into spectrum is E-2.
(d) characterize: the SiO of E-2 2/ Al 2O 3Be 104, the XRD result of sample has table 1 and table 2 feature, sees Fig. 9.Found out to have TON and two kinds of configuration molecular sieves of MFI feature in the product by Fig. 9, wherein the ratio of the content of TON structure and MFI structure molecular screen is 5.0.
Embodiment 3
With embodiment 2, remove the KOH that 17.4 gram NaOH replace 20.50 grams 82%, 5.8 gram NaCl replace 5.8 gram KF.The mole that obtains gel consists of:
1.5Na 2O/2.01R/0.08Al 2O 3/10SiO 2/1.0NaCl/300H 2O
R=1, the 8-octamethylenediamine
(b) crystallization process: reactor was warmed up to 175 ± 1 ℃ in 2 hours, constant temperature 24 hours, and obtaining sample number into spectrum through aftertreatment is E-3.
(c) characterize: the SiO of sample E-3 2/ Al 2O 3Be 96, the XRD result of E-3 has table 1 and table 2 feature, sees Figure 10.Found out that by Figure 10 product has TON and two kinds of configuration molecular sieves of MFI feature, wherein the ratio of the content of TON structure and MFI structure molecular screen is 3.3.
Embodiment 4
Gel is formed with embodiment 1, and reactor was warmed up to 155 ± 1 ℃ in 2 hours, constant temperature 96 hours, and obtaining sample number into spectrum through aftertreatment is E-4.The SiO of sample E-4 2/ Al 2O 3Be 52, the XRD result of E-4 has table 1 and table 2 feature, sees Figure 11.Found out that by Figure 11 product has TON and two kinds of configuration molecular sieves of MFI feature, wherein the ratio of the content of TON structure and MFI structure molecular screen is 10.
Embodiment 5
Adopt the gel with embodiment 1 described same composition, but wherein replace octamethylenediamine with hexanediamine, through crystallization and the last handling process identical with Comparative Examples 2, obtaining sample number into spectrum is E-5.
Characterize: the SiO of sample E-5 2/ Al 2O 3Be 55, XRD result has table 1 and table 2 feature, sees Figure 12.Found out that by Figure 12 product has TON and two kinds of structure knots of MFI molecular sieve feature, wherein the ratio of the content of TON structure and MFI structure molecular screen is 0.5.
Embodiment 6
Adopt the gel with embodiment 5 described same compositions, but be that 1: 1 hexanediamine and octamethylenediamine mixture replaces hexanediamine with weight ratio wherein, pass through crystallization and the last handling process identical with Comparative Examples 2, obtaining sample number into spectrum is E-6.
Characterize: the SiO of sample E-6 2/ Al 2O 3Be 59, XRD result has table 1 and table 2 feature, sees Figure 13.Found out that by Figure 13 product has TON and two kinds of structure knots of MFI molecular sieve feature, wherein the ratio of the content of TON structure and MFI structure molecular screen is 2.0.

Claims (10)

1, a kind of composite structure crystalline molecular sieve is characterized in that composite molecular screen has TON and two kinds of structures of MFI, the SiO on the molecular sieve lattice 2/ Al 2O 3Mol ratio is greater than 50, and the weight ratio of TON structure and MFI structure is 0.1～10: 1.
2, according to the described molecular sieve of claim 1, it is characterized in that the SiO on the molecular sieve lattice 2/ Al 2O 3Mol ratio is 50～200, and the weight ratio of TON structure and MFI structure is 1～10: 1.
3, the preparation method of the described composite molecular screen of a kind of claim 1 may further comprise the steps:
(a) preparation is a kind of is selected from IV in the periodic table of elements by at least a AElement compound, mineral alkali, organic even gel of touching an edition agent, crystal seed, salt and water composition, wherein salt is selected from one or more of basic metal or alkaline-earth metal salt, crystal seed is selected from one or more of molecular sieve with TON or MFI structure, and crystal seed is 0.01%～1% with respect to the gel weight content;
(b) gel of heating steps (a) preparation under the condition of static crystallization, makes the gel crystallization complete, through aftertreatment, obtains the composite structure crystalline molecular sieve, and wherein crystallization temperature is 120～200 ℃, and crystallization time is 10～240 hours.
4, in accordance with the method for claim 3, it is characterized in that the salt described in the step (a) is halogenide, crystal seed is for having the TON structure molecular screen, and crystal seed is 0.1%～0.5% with respect to the gel weight content.
5, in accordance with the method for claim 4, it is characterized in that described halogenide is KF or NaCl.
6, in accordance with the method for claim 3, it is characterized in that IV in the said periodic table of elements of step (a) AElement compound, be selected from the compound of silicon or germanium one or more, said mineral alkali is selected from the oxyhydroxide and the ammoniacal liquor of alkali-metal oxyhydroxide, carbonate, alkaline-earth metal, said aluminium source is selected from one or more in activated alumina and precursor, aluminum soluble salt and the organic aluminum contained compound, said organic directed agents be ammonium salt or amine organism one or more.
7, in accordance with the method for claim 6, it is characterized in that IV in the described periodic table of elements AElement compound is selected from active silica, silicate, silicon sol and siliceous organism, and said mineral alkali can be alkali-metal oxyhydroxide, and said aluminium source is aluminate or aluminium salt, and said organic directed agents is hexanediamine or octamethylenediamine.
8, in accordance with the method for claim 7, the mol ratio that it is characterized in that each material of the said gel of step (a) is: 0.8～2.0M 2O/1.0～5.0R/0.01～1.0Al 2O 3/ 10SiO 2/ 0.1～2.0NX/50～600H 2O+0.01w%～1w%S, wherein R is a structure directing agent, and M is an alkalimetal ion, and NX is a halogenide, and S is a crystal seed.
9, in accordance with the method for claim 3, it is characterized in that the described crystallization of step (b) is to carry out in the high-pressure reactor of autogenous pressure, crystallization temperature is 150～180 ℃, and crystallization time is 24～96 hours, and the method for aftertreatment comprises collection, washing and dry.
10, in accordance with the method for claim 9, it is characterized in that described crystallization temperature is 160～170 ℃, crystallization time is 48～72 hours.
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Cited By (7)

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CN100494060C (en) * 2005-04-25 2009-06-03 中国科学院大连化学物理研究所 ZSM-23/ZSM-22 composite molecular sieve and preparation method
CN100509627C (en) * 2005-09-22 2009-07-08 中国科学院大连化学物理研究所 ZSM-23/ZSM-22 composite molecular sieve and preparation method thereof
CN100542956C (en) * 2005-04-25 2009-09-23 中国科学院大连化学物理研究所 A kind of ZSM-22/ZSM-23 composite molecular screen and method for making
CN101376505B (en) * 2007-08-27 2010-09-15 中国石油化工股份有限公司 Preparation of composite double microporous material
CN101428233B (en) * 2007-11-07 2011-04-27 中国石油化工股份有限公司 Catalyst for catalytic pyrolysis
CN107570216A (en) * 2016-07-04 2018-01-12 中国石油天然气股份有限公司 Catalyst used for hydrogenation of distilled oil fraction carrier and preparation method thereof
CN108298553A (en) * 2017-01-11 2018-07-20 中国科学院上海高等研究院 A method of preparing molecular sieve

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100494060C (en) * 2005-04-25 2009-06-03 中国科学院大连化学物理研究所 ZSM-23/ZSM-22 composite molecular sieve and preparation method
CN100542956C (en) * 2005-04-25 2009-09-23 中国科学院大连化学物理研究所 A kind of ZSM-22/ZSM-23 composite molecular screen and method for making
CN100509627C (en) * 2005-09-22 2009-07-08 中国科学院大连化学物理研究所 ZSM-23/ZSM-22 composite molecular sieve and preparation method thereof
CN101376505B (en) * 2007-08-27 2010-09-15 中国石油化工股份有限公司 Preparation of composite double microporous material
CN101428233B (en) * 2007-11-07 2011-04-27 中国石油化工股份有限公司 Catalyst for catalytic pyrolysis
CN107570216A (en) * 2016-07-04 2018-01-12 中国石油天然气股份有限公司 Catalyst used for hydrogenation of distilled oil fraction carrier and preparation method thereof
CN108298553A (en) * 2017-01-11 2018-07-20 中国科学院上海高等研究院 A method of preparing molecular sieve
CN108298553B (en) * 2017-01-11 2021-07-23 中国科学院上海高等研究院 Method for preparing molecular sieve

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