CN1546753A - Electrostatic spinning apparatus with multi-spraying heads for preparing coaxial composite continuous nanometer/micron fibre - Google Patents
Electrostatic spinning apparatus with multi-spraying heads for preparing coaxial composite continuous nanometer/micron fibre Download PDFInfo
- Publication number
- CN1546753A CN1546753A CNA2003101092229A CN200310109222A CN1546753A CN 1546753 A CN1546753 A CN 1546753A CN A2003101092229 A CNA2003101092229 A CN A2003101092229A CN 200310109222 A CN200310109222 A CN 200310109222A CN 1546753 A CN1546753 A CN 1546753A
- Authority
- CN
- China
- Prior art keywords
- flow container
- liquid
- nozzle
- coaxial
- low head
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/0007—Electro-spinning
- D01D5/0061—Electro-spinning characterised by the electro-spinning apparatus
- D01D5/0069—Electro-spinning characterised by the electro-spinning apparatus characterised by the spinning section, e.g. capillary tube, protrusion or pin
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
- D01D5/34—Core-skin structure; Spinnerette packs therefor
Abstract
The invention is a kind of multi-snoot electrostatic spinning device for producing coaxial compound continuous nano and micron meter fiber, it is made up of an inner liquid pot, an outer liquid pot, a sealing head, a several coaxial spraying pipe, liquid supplying system, flow guiding pipe, electricity guiding bar, electrostatic generator. Each snoot contains an inner and outer hollow thin spraying pipes, the inner one and the outer one are coaxial, the inner spraying pipes are all set on the subjacent sealing head of the inner liquid pot, which is the ejection outlet of inner liquid; the outer spraying pipes are all set on the subjacent sealing head of the outer pot, which is the ejection outlet of the outer liquid. The conducting bar in the inner and outer liquid pots are connected with the electrostatic generator, adds high pressure direct current electric field in the inner and outer liquid material, drives the liquid to be ejected form the spraying pipes, forms several radiate flows with the same centre. The fixed pressure liquid supplying system sprays out the radiate flow which is even and continuous, then the product can be got through high frequency extension and bending deformation.
Description
Technical field
The present invention relates to a kind of nano micron fibre material preparation device, specifically is a kind of many ejecting devices of electrostatic spinning that prepare coaxial compound continuous nano/micron fiber.
Background technology
Two kinds of materials is coaxial compound rather than mix and be combined into a kind of bar or filamentary material, can satisfy numerous demands of industrial cut stock or daily life aspect.Most typical is pencil, top layer and core matter be two kinds of different materials coaxial compound be a bar.When the diameter of this coaxial coupled pole line reached several microns or the following magnitude of micron, its Application Areas was then very extensive.Although existing many maturation process and device aspect the preparation of the coaxial coupled pole line (such as pencil) of large scale, yet this class device also is not suitable for the preparation of ultra-fine (the following magnitude of several microns to micron) coaxial composite fibre.By the spinning means in the conventional textile industry such as dry method or the resulting fibre diameter of wet spinning device generally also all more than 7 microns, and fiber generally all is that the mixing of single or multiple material is compound.In the application of considering such as the coated cloth of burned body, the fiber of more tiny diameter will help the rapid degraded and absorbed of organism and the controlled release of antibiotic medicine.This is because the surface fibre that contact with wound face, and it is degraded fully and finish within the time of relatively lacking.This just requires the filametntary diameter must be very tiny, reaches the following or nanometer scale of micron.
The single nozzle electrospinning device imagination that has proposed the continuous coaxial composite fibre of preparation nanometer scale is arranged at present.But the device for spinning efficient of single shower nozzle is not high.Up at present, also do not find many ejecting devices of the continuous coaxial composite superfine of preparation (diameter is that micron is following to several micron orders) fiber.
Summary of the invention
The object of the present invention is to provide a kind of multi-nozzle electrospinning device for preparing coaxial compound continuous nano/micron fiber.
The multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation that the present invention proposes is made up of main parts size such as interior flow container, outer flow container, interior flow container end socket, outer flow container end socket, bull combined sprinkler, liquid-supplying system, mozzle, contact rod, electrostatic generators.Each shower nozzle all contains inside and outside two hollow thin jet pipes, and wherein inner nozzle and outer nozzle are coaxial.In being arranged in, all inner nozzles on the low head of flow container, are the jet exit of interior liquid; All outer nozzles are arranged on the low head of outer flow container, are the jet exit of outer liquid.Contact rod in the inside and outside flow container and electrostatic generator are connected, and the DC electric field that adds high pressure in inside and outside fluent material respectively drives two liquid from spraying the jet pipe separately, forms many concentric layering jets, solidifies and changes composite ultrafine fiber into.
The present invention is special in Chinese patent application " coaxial compound continuous nano/micron fiber and preparation method thereof " (application number: 200310108130.9) She Ji " the multi-nozzle electrospinning device for preparing coaxial compound continuous nano/micron fiber "; Make continuously a large amount of production become possibility.
Description of drawings
Fig. 1 is a structural representation of the present invention.
Fig. 2 is a flow container low head sectional view in Figure 1A-A.
Fig. 3 is the outer flow container low head sectional view of Figure 1B-B.
Label declaration in the accompanying drawing
Flow container in the 1-; The outer flow container of 2-;
Flow container upper cover in the 3-; Flow container low head in the 4-;
The outer flow container low head of 5-; The 6-seal;
The outer flow container upper cover of 7-; 8-spacing adjusting nut;
The coaxial bull jet pipe of 9-; Liquid in the 10-;
The outer liquid of 11-; The 12-electrostatic generator;
The 13-fluid reservoir; The 14-return duct;
The 15-infusion pump; The 16-woven hose;
17-infuses jar; The quick formula pipe joint of 18-;
The quick formula union elbow of 19-20-contact rod;
The 21-set bolt; 22-gap step;
23-water conservancy diversion hole slot; 24-rectangle guide groove;
The 25-pulsometer; The 26-pressure regulator valve;
The 27-Pressure gauge; 28-air pressure liquid-supplying system;
29-hydraulic pressure liquid-supplying system.
The specific embodiment
The present invention places outer flow container 2 by an interior flow container 1 is coaxial, interior flow container upper cover 3 and low head 4, outer flow container upper cover 7 and low head 5, coaxial bull jet pipe 9, inside and outside jet pipe spacing adjusting nut 8, contact rod 20, set bolt 21, seal 6, woven hose 16, pipe joint 18 and 19, electrostatic generator 12I, 12II, and air pressure liquid-supplying system 28 or hydraulic pressure liquid-supplying system 29 compositions.
Be described further below in conjunction with accompanying drawing:
Outside on the flow container low head 5, have rectangle guide groove 24, pod apertures or groove 23, leave gap step 22, and in the rectangular channel plane, be drilled with some pores (being 5 holes among Fig. 3), so that fixing outer nozzle, the extension of outer nozzle (pass low head thickness after length) is generally 1~50mm, internal diameter is generally 0.3mm~2.0mm, the diameter of pore is the outer warp of outer nozzle, be generally 0.5mm~2.5mm, the number of pore and center must be consistent with the number and the center of the pore that bored on the interior flow container low head 3.The function of rectangle guide groove 24 internal clearance steps 22 is: isolate the gap between the low head of interior flow container and all outer nozzle inlet, so that outer fluid can successfully flow into outer nozzle.
Outer flow container is provided with upper cover 7, have centre bore coaxial with interior flow container, that also internal flow container plays the guide-localization effect on it, gap between centre bore and the interior flow container outer wall is the smaller the better, but make between the two and can produce relative slip, generally, this gap remains within 0.001mm~0.2mm.In addition, can also have some seal grooves as required on the upper cover 7, so as to install, fixing seals 6.Metal conductive bar 20 also is to pass from upper cover 7, enter outer liquid, certainly, contact rod 20 also can pass the sidewall of outer flow container, enter outer liquid, no matter pass upper cover or sidewall, metal conductive bar or line 20 generally should have insulating coating parcel and sealing fully when passing through, and liquid must not ooze out from pass through the hole.
Flow container upper cover end face outside, be provided with interior flow container outer wall on the adjusting nut 8 of threads engaged, in making flow container mutually externally flow container can produce and relatively move, thereby regulate the exit separation of inside and outside jet pipe, reach the purpose of adjusting spinning parameter.
Interior flow container then can be provided with upper cover 3 as required, if stored interior liquid 10 enough spinning are used and need not injection pressure in liquid (only depending on electric field force to drive liquid from interior spray jar ejaculation) in the interior flow container, then need not to be provided with upper cover 3, otherwise will be provided with.At this moment, need to have seal groove in the upper cover 3, outer top is provided with pipe joint 18, so that connect with the constant pressure liquid stream of liquid-supplying system output.Metal conductive bar or line 20 pass from upper cover 3, enter interior liquid, and when passing through, contact rod or line 20 generally have insulating coating parcel and sealing fully, and liquid must not ooze out from pass through the hole.
Outer flow container is provided with pipe joint 19 as required, if liquid 11 enough spinning stored in the outer flow container are used, and need not injection pressure in liquid (only depending on electric field force to drive liquid) from outer spray jar ejaculation, then need not to be provided with, otherwise, pipe joint 19 will be set, so that connect with the constant pressure liquid stream of liquid-supplying system output, each free liquid-supplying system of liquid provides in interior flow container 1 and the outer flow container 2.
Liquid-supplying system can be a hydraulic pressure liquid-supplying system 29, also can be air pressure liquid-supplying system 28.Hydraulic pressure liquid-supplying system 29 is made of transfusion jar 17, fluid reservoir 13, infusion pump 15 and return duct 14.Wherein, infusion pump 15 is squeezed into transfusion jars 17 endlessly with the liquid in the fluid reservoir 13, and 14 of return ducts will infuses, and liquid more than needed draws back fluid reservoir 13 in jars 17, thereby makes the fluid pressure of exporting from transfusion jar 17 constant.This hydraulic pressure liquid-supplying system mainly be by gravity, just transfusion jar 17 residing positions supply with constant pressure liquid to interior flow container 1 or outer flow container 2, the length of woven hose 16 can be determined as required.
Air pressure liquid-supplying system 28 is made of transfusion jar 17, pulsometer 25, pressure regulator valve 26 and Pressure gauge 27.Wherein, pulsometer 25 will be squeezed into transfusion jars 17 through the constant pressure of pressure regulator valve 26 and Pressure gauge 27 controls, make that the fluid pressure of output is constant from transfusion jars 17.This air pressure liquid-supplying system is not limited by gravity, the liquid of flow container 1 or outer flow container 2 elevated pressures stream in generally can offering.
Two kinds of liquid-supplying systems all are provided with in order to make successive, even constant the carrying out of spinning energy.
The ultra-fine coaxial composite fibre that apparatus of the present invention are prepared because its diameter is tiny, specific area is high, functionalization is easy, is very suitable for the application of aspects such as medicine, fine filtering, biochemical protection.As the medicinal polymer of making core material, absorbable and degradable of antibiotic is used as skin-material, be prepared into nonwoven fabric, paste at burn and wait the extensive wound position, can remove from and change dressings, take off the huge misery that gauze brings for this class patient; For another example with this fibre bundle that includes the antibiotic medicine as operation suture thread, can realize the controlled release of medicine, thereby mechanical stitch and biochemical treatment are combined together, patient's wound healing is brought optimum efficiency; And for example antiviral material is used as the core material, nontoxic, harmless, the scentless general polymer of human body is used as skin-material, be prepared into nonwoven fabric, make mouth mask, protective clothing etc., not only can isolate harmful virus to the infringement of human body, but also can not bring any discomfort to human body because of the defective of isolated material itself.Other application comprises being that the inorganic ceramic of carrier or metal are got and made skin-material with the polymer, handles through high temperature cabonization again, prepares the pottery or the ultra-fine pipe of metal of big L/D ratio.The present invention has that preparation technology is simple, equipment cost is cheap, wide advantage is used in market, has very big economic benefit and social benefit.
Claims (10)
1, a kind of multi-nozzle electrospinning device for preparing coaxial compound continuous nano/micron fiber is made up of interior flow container, outer flow container, flow container end socket, bull combination spray pipe, liquid-supplying system, mozzle, contact rod, electrostatic generator etc., it is characterized in that:
Each combined sprinkler all contains inside and outside two hollow jet pipes, wherein inner nozzle is coaxial with outer nozzle, on the low head of flow container, outer nozzle all placed on the low head of outer flow container in inner nozzle all placed, and the liquid in the inside and outside flow container is connected in the jet pipe of flow container separately.
2, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 1 is characterized in that:
The low head base profile of interior flow container is a rectangle, outer flow container low head then has a rectangle guide groove, form minim gap between the low head of rectangle guide groove and interior flow container, make the bull inner nozzle can effectively insert in each self-corresponding outer nozzle and make inside and outside jet pipe coaxial positioning.
3, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 1 and 2 is characterized in that:
Respectively on interior flow container rectangle low head or outside offer several pod apertures or groove on the rectangle trough rim of flow container low head, make outer liquid can from these pod apertures or groove, flow to the outer nozzle mouth.
4, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 1 and 2 is characterized in that:
Leave the gap step in the rectangle guide groove in the flow container low head outside, between the plane of the rectangle low head bottom surface of flow container and guide groove a minimum clearance distance is arranged in making, so that the liquid in the outer flow container can flow to the outer nozzle mouth.
5, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 1 is characterized in that:
The flow container upper cover offers the centre bore coaxial with interior flow container outside, so that and form minim gap between the interior flow container outer wall, make the bull combined sprinkler play coaxial guide effect.
6, prepare the multi-nozzle electrospinning device of coaxial compound continuous nano/micron fiber according to claim 1 or 5, it is characterized in that:
Flow container upper cover end face is provided with the adjusting nut that cooperates with interior flow container outer wall thread outside, by regulating distance between the inside and outside nozzle exit, reaches the purpose of adjusting spinning parameter.
7, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 1 is characterized in that:
Be mounted with contact rod respectively in the inside and outside flow container liquid or/and conductive coil, connect with dc static generator I and II separately, or parallel connection is switched to same electrostatic generator, the DC voltage that electrostatic generator provides is between 2kV~100kV.
8, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 1 is characterized in that:
Each free liquid-supplying system of liquid in interior flow container and the outer flow container provides.
9, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 8 is characterized in that:
The hydraulic pressure liquid-supplying system, be made of transfusion jar, fluid reservoir, infusion pump and return duct, wherein, infusion pump is squeezed into the transfusion jar endlessly with the liquid in the fluid reservoir, liquid more than needed during return duct then will be infused jar draws back fluid reservoir, thereby makes the fluid pressure of exporting in the transfusion jar constant.
10, the multi-nozzle electrospinning device of the coaxial compound continuous nano/micron fiber of preparation according to claim 8 is characterized in that:
The air pressure liquid-supplying system, by transfusion jar, pulsometer, pressure regulator valve, constitute with Pressure gauge, wherein, pulsometer will be squeezed into transfusion jar through pressure regulator valve and the list-directed constant pressure of pressure, make that the fluid pressure of exporting from the transfusion jar is constant.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2003101092229A CN100410429C (en) | 2003-12-10 | 2003-12-10 | Electrostatic spinning apparatus with multi-spraying heads for preparing coaxial composite continuous nanometer/micron fibre |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB2003101092229A CN100410429C (en) | 2003-12-10 | 2003-12-10 | Electrostatic spinning apparatus with multi-spraying heads for preparing coaxial composite continuous nanometer/micron fibre |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1546753A true CN1546753A (en) | 2004-11-17 |
CN100410429C CN100410429C (en) | 2008-08-13 |
Family
ID=34335094
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB2003101092229A Expired - Fee Related CN100410429C (en) | 2003-12-10 | 2003-12-10 | Electrostatic spinning apparatus with multi-spraying heads for preparing coaxial composite continuous nanometer/micron fibre |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN100410429C (en) |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100457985C (en) * | 2006-08-21 | 2009-02-04 | 福建师范大学 | Electrostatic spinning machine |
CN100513300C (en) * | 2006-11-28 | 2009-07-15 | 厦门大学 | Micro nano structure direct-writing device |
CN100577897C (en) * | 2007-01-15 | 2010-01-06 | 中国科学院化学研究所 | Multi-fluid composite electrostatic spinning device |
CN101845673A (en) * | 2010-06-13 | 2010-09-29 | 东华大学 | Electric fan blade type electrostatic spinning nozzle and using method thereof |
CN101967687A (en) * | 2010-09-20 | 2011-02-09 | 北京化工大学 | Multi-row electrostatic spinning spray head |
CN102191574A (en) * | 2011-05-19 | 2011-09-21 | 厦门大学 | Nano fiber batch manufacturing device |
CN101220524B (en) * | 2007-01-11 | 2011-09-28 | 云南炎尚科技有限公司 | Device for producing nano-fibre film with macromolecular solution electrostatic filature |
CN102275386A (en) * | 2011-06-17 | 2011-12-14 | 华中科技大学 | Coaxial jet head for electro-hydrodynamic jet printing and application thereof |
CN103451750A (en) * | 2012-05-30 | 2013-12-18 | 湖南博弈飞装备新材料研究所 | Electrostatic spinning device and method for manufacturing hollow nanometer fiber |
CN103572386A (en) * | 2013-10-12 | 2014-02-12 | 东华大学 | Flat plate pinhole coaxial electrostatic spinning fiber composite spinning jet and spinning method thereof |
CN107366028A (en) * | 2017-07-28 | 2017-11-21 | 浙江工业大学之江学院 | A kind of batch prepares the electrospinning process of core-sheath composite structure nanofiber |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010043002A1 (en) * | 2008-10-17 | 2010-04-22 | Deakin University | Electrostatic spinning assembly |
CN101871130B (en) * | 2010-07-06 | 2011-08-10 | 北京化工大学 | Novel straight-strut electrostatic spinning spray nozzle |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2620399C3 (en) * | 1976-05-08 | 1980-11-13 | Fa. Carl Freudenberg, 6940 Weinheim | Device for electrostatic spraying |
JP3782902B2 (en) * | 1999-06-24 | 2006-06-07 | 帝人ファイバー株式会社 | Method for producing high-strength monofilament with improved surface properties |
DE10023456A1 (en) * | 1999-07-29 | 2001-02-01 | Creavis Tech & Innovation Gmbh | Mesotubes and nanotubes |
US6776858B2 (en) * | 2000-08-04 | 2004-08-17 | E.I. Du Pont De Nemours And Company | Process and apparatus for making multicomponent meltblown web fibers and webs |
CN1216188C (en) * | 2002-10-25 | 2005-08-24 | 东华大学 | Double wave length fluorescent composite fibre, its production method and application |
-
2003
- 2003-12-10 CN CNB2003101092229A patent/CN100410429C/en not_active Expired - Fee Related
Cited By (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN100457985C (en) * | 2006-08-21 | 2009-02-04 | 福建师范大学 | Electrostatic spinning machine |
CN100513300C (en) * | 2006-11-28 | 2009-07-15 | 厦门大学 | Micro nano structure direct-writing device |
CN101220524B (en) * | 2007-01-11 | 2011-09-28 | 云南炎尚科技有限公司 | Device for producing nano-fibre film with macromolecular solution electrostatic filature |
CN100577897C (en) * | 2007-01-15 | 2010-01-06 | 中国科学院化学研究所 | Multi-fluid composite electrostatic spinning device |
CN101845673A (en) * | 2010-06-13 | 2010-09-29 | 东华大学 | Electric fan blade type electrostatic spinning nozzle and using method thereof |
CN101845673B (en) * | 2010-06-13 | 2012-07-04 | 东华大学 | Electric fan blade type electrostatic spinning nozzle and using method thereof |
CN101967687A (en) * | 2010-09-20 | 2011-02-09 | 北京化工大学 | Multi-row electrostatic spinning spray head |
CN101967687B (en) * | 2010-09-20 | 2012-08-29 | 北京化工大学 | Multi-row electrostatic spinning spray head |
CN102191574A (en) * | 2011-05-19 | 2011-09-21 | 厦门大学 | Nano fiber batch manufacturing device |
CN102191574B (en) * | 2011-05-19 | 2012-09-05 | 厦门大学 | Nano fiber batch manufacturing device |
CN102275386A (en) * | 2011-06-17 | 2011-12-14 | 华中科技大学 | Coaxial jet head for electro-hydrodynamic jet printing and application thereof |
CN102275386B (en) * | 2011-06-17 | 2013-05-22 | 华中科技大学 | Coaxial jet head for electro-hydrodynamic jet printing and application thereof |
CN103451750A (en) * | 2012-05-30 | 2013-12-18 | 湖南博弈飞装备新材料研究所 | Electrostatic spinning device and method for manufacturing hollow nanometer fiber |
CN103572386A (en) * | 2013-10-12 | 2014-02-12 | 东华大学 | Flat plate pinhole coaxial electrostatic spinning fiber composite spinning jet and spinning method thereof |
CN103572386B (en) * | 2013-10-12 | 2016-06-15 | 东华大学 | A kind of flat board pin hole coaxial electrostatic spinning fiber composite spinning head and spinning process thereof |
CN107366028A (en) * | 2017-07-28 | 2017-11-21 | 浙江工业大学之江学院 | A kind of batch prepares the electrospinning process of core-sheath composite structure nanofiber |
Also Published As
Publication number | Publication date |
---|---|
CN100410429C (en) | 2008-08-13 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN1546753A (en) | Electrostatic spinning apparatus with multi-spraying heads for preparing coaxial composite continuous nanometer/micron fibre | |
CN109371479B (en) | Solution melt co-spinning multi-nozzle electrostatic spinning integrated device | |
CN101565878B (en) | Ultrathin nanometer cobweb/nanometer fiber composite protective material manufacturing device | |
CN100577897C (en) | Multi-fluid composite electrostatic spinning device | |
CN104032383B (en) | A kind of bidirectional screw electrostatic spinning apparatus | |
CN103625089B (en) | The preparation method of nano fibrous membrane modified cellulose forming paper and application thereof | |
CN202809020U (en) | Continuous electrostatic spinning system | |
CN101210352A (en) | Taylor awl multiple spray head static spinning machine | |
CN105970314B (en) | A kind of air-flow aided linear tooth electrode electrostatic spinning apparatus | |
CN108034995A (en) | A kind of solid syringe needle electrospinning device | |
CN207362375U (en) | A kind of hand-held electrostatic spinning equipment | |
CN205347635U (en) | Supplementary reciprocating type electrostatic spinning device of induction type screw thread guide arm | |
CN103451750A (en) | Electrostatic spinning device and method for manufacturing hollow nanometer fiber | |
CN104611774B (en) | Electrostatic spinning device | |
CN107201559B (en) | Bead head spray head electrostatic spinning device | |
CN103451749A (en) | Continuous electrostatic spinning system and method for preparing fine fibers | |
CN205874597U (en) | Linear tooth electrode electrostatic spinning device is assisted to air current | |
CN2682089Y (en) | Multiple injector electrostatic spinning device | |
CN105970313B (en) | A kind of extensive electrostatic spinning apparatus for preparing micro nanometer fiber | |
CN110607566B (en) | Second-order differential melt electrostatic spinning device | |
CN107447267A (en) | For the shower nozzle for the high-voltage electrostatic spinning apparatus for mass producing nanofiber | |
CN110295399A (en) | A kind of brush electrostatic spinning apparatus and its application method | |
CN105568408B (en) | A kind of guide tracked electrospinning process of reciprocating linear | |
WO2022187383A1 (en) | Handheld/portable apparatus for the production of fine fibers | |
CN105088366A (en) | Electrospinning device, method and system for manufacturing nanofibers in batch |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C17 | Cessation of patent right | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20080813 Termination date: 20101210 |