CN1544575A - Boron-containing luminescent powder for LED, preparing method thereof and electric light source therefrom - Google Patents
Boron-containing luminescent powder for LED, preparing method thereof and electric light source therefrom Download PDFInfo
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- CN1544575A CN1544575A CNA2003101135065A CN200310113506A CN1544575A CN 1544575 A CN1544575 A CN 1544575A CN A2003101135065 A CNA2003101135065 A CN A2003101135065A CN 200310113506 A CN200310113506 A CN 200310113506A CN 1544575 A CN1544575 A CN 1544575A
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- powder
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B20/00—Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps
Abstract
The invention discloses a category of white light LED use fluorescent powder, process for preparation and electric light source made thereby, the chemical formula of the fluorescent powder is disclosed in the specification, wherein R is at least one of Y, Gd, Lu, La, and Sm, M is at least one of Zn, Ca, Sr, Ba, Mg, an is at least one of P, Si, Al, Ga, In, X is at least one of Ce, Tb, Pr, Eu, Mn, Li, where 0.9<=x<=5, 0<=y<=1, 1<=z1<=10, 0<=z2<=3, 0.01<=k<=0.5, 0.1<=b<=50. The invention also discloses its preparation process, an electric light source containing InGaN, GaN series ultraviolet light, or purple light, or blue light LED chip and white light LED use fluorescent powder according to the invention, and its manufacture process.
Description
Technical field
The present invention relates to phosphor for white light LED and the manufacture method and the made electric light source of a class boracic.
Background technology
LED is a kind of high-level efficiency, low-cost solid state light emitter, have little electric current, at room temperature can obtain enough intensity, luminescence response is fast, stable performance, life-span is long, and volume is little, and is durable in use, advantages such as shock resistance, therefore be widely used in fields such as pilot lamp, signal lamps, and be expected to replace incandescent light and enter the general lighting field, have a extensive future.
The manufacture method of current white light LEDs has three kinds: 1, coating efficiently can be by blue-light excited yellow fluorescent powder on blue-light LED chip, and blue light and yellow light mix form white light; 2, coating is by blue-light excited and fluorescent material transmitting green light and ruddiness on blue-light LED chip, and ruddiness, green glow, blue light form white light; 3, on purple light or ultraviolet LED chip, apply efficiently three primary colors fluorescent powder and make white light LEDs.From above implementation method as can be seen, fluorescent material is one of critical material of white light LEDs.But the current effective efficiency of conversion of fluorescent material that can be applicable to white light LEDs is lower, can't satisfy high performance device needs, especially red fluorescence powder kind seldom, efficient is lower.Therefore the white light LEDs of development of new becomes the focus of domestic and international research with the fluorescent material of transmitting green light and ruddiness.
United States Patent (USP) 6255670 and United States Patent (USP) 6294800 have been reported Ba respectively
2(Mg, Zn) Si
2O
7: Eu and Ca
8Mg (SiO
4)
4Cl
2: Eu, Mn fluorescent material and preparation method thereof, this class fluorescent material are the green emitting phosphors with ultraviolet excitation, chemical property is stable, but luminous intensity awaits further to improve.6252254 of United States Patent (USP)s have been reported several sulfide greens and red fluorescence powder, and its emissive porwer is better, but stability is very poor, produce the look drift in device uses, and are serious even directly damage device.
Summary of the invention
The purpose of this invention is to provide that a class chemical property is stable, the phosphor for white light LED of good luminous performance.
Another object of the present invention provides a kind of method of making such fluorescent material, this fluorescent material manufacture method is simple, easy handling, pollution-free, cost is low.
A further object of the present invention provides a kind of by the made electric light source of this phosphor for white light LED.
For achieving the above object, the present invention takes following technical scheme:
The chemical formula of a class phosphor for white light LED of the present invention is: R
xM
yB
Z1A
Z2O
b: X
kWherein, R is Y, Gd, and Lu, La, at least a among the Sm; M is Zn, Ca, and Sr, Ba, at least a among the Mg; A is P, Si, and Al, Ga, at least a among the In; X is Ce, Tb, and Pr, Eu, Mn, at least a among the Li; 0.9≤x≤5 wherein; 0≤y≤1; 1≤z1≤10,0≤z2≤3,0.01≤k≤0.5,0.1≤b≤50, and x, y, z1, z2, b, k can increase or reduce in proportion.
The present invention is the red, green, blue three-color phosphor of a class boracic, is fit to the optical excitation of 300-490nm, has higher luminous intensity, good stability.In LED, use the result to show that this powder is long prepared device lifetime, the luminous efficiency height, color developing is good, can be widely used in white light LEDs.
The method of making a described class phosphor for white light LED comprises the steps:
(1), respectively with Y, Gd, Lu, La, Sm, Zn, Ca, Sr, Ba, Mg, B, P, Si, Al, Ga, In, Ce, Tb, Pr, Eu, Mn, the simple substance of Li or oxygenatedchemicals are raw material, and form and stoichiometric ratio takes by weighing corresponding raw material by the chemical formula of above-mentioned materials;
(2), in above-mentioned raw materials, add a certain amount of reaction flux, and with raw material and the abundant mixing of reaction flux;
(3), with the roasting under given conditions of said mixture material.
(4), again through last handling process, promptly make phosphor for white light LED of the present invention.
In described step (2), fusing assistant is an alkali metal halide, alkaline earth metal halide, Na
2SO
4, the halogenide of ammonium, at least a in the halogenide of aluminium.
In described step (2), the consumption of fusing assistant is the 0.005%-0.5% of synthesis material weight ratio.
In described step (3), " mixture is roasting under given conditions ", its specified conditions are: maturing temperature is at 600-1800 ℃, and each roasting time is 1-30 hour, the roasting number of times is at least once, and calcination atmosphere is at least a in air, nitrogen, hydrogen, the CO gas.
In described step (4), last handling process is a conventional process, is about to product of roasting and washes 3～5 times, filters the process of oven dry.
In described step (4), bake out temperature is 90～160 ℃.
The fluorescent material of gained of the present invention can be used for making white light LEDs.This phosphor for white light LED can both well be used on following two kinds of methods.That is, coating is by blue-light excited and fluorescent material transmitting green light and ruddiness on blue-light LED chip, and ruddiness, blue light, green glow mix and form white light; Or on purple light or ultraviolet LED chip, apply efficiently three primary colors fluorescent powder and make white light LEDs.Therefore, adopt phosphor for white light LED of the present invention can make the electric light source of following white light LEDs.
Electric light source of the present invention contains UV-light or purple light or blue-light LED chip and phosphor for white light LED R of the present invention
xM
yB
Z1A
Z2O
b: X
kWherein, R is Y, Gd, and Lu, La, at least a among the Sm; M is Zn, Ca, and Sr, Ba, at least a among the Mg; A is P, Si, and Al, Ga, at least a among the In; X is Ce, Tb, and Pr, Eu, Mn, at least a among the Li; 0.9≤x≤5 wherein; 0≤y≤1; 1≤z1≤10,0≤z2≤3,0.01≤k≤0.5,0.1≤b≤50, and x, y, z1, z2, b, k can increase or reduce in proportion.
Electric light source of the present invention can be formed by following two kinds:
A kind of electric light source of the present invention, described phosphor for white light LED is red fluorescence powder, green emitting phosphor and blue colour fluorescent powder, be to be coated on the UV-light or purple LED chip of InGaN, GaN series, the ratio of the weight of red glimmering coloured light powder, green emitting phosphor and blue colour fluorescent powder is W
Rouge and powder: W
Green powder: W
Blue powder, wherein: 0.1≤W
Rouge and powder≤ 0.6,0.1≤W
Green powder≤ 0.6,0.1≤W
Blue powder≤ 0.5.
The manufacture method of this electric light source is: take by weighing gained red, green, blue fluorescent material of the present invention respectively by above-mentioned weight ratio, be coated on the UV-light or purple LED chip of InGaN, GaN series after sizing mixing with solvent, welded circuit, use the resin sealed knot, the gained solid light source is white light LED electric light source of the present invention.
Another kind of electric light source of the present invention, described phosphor for white light LED is green emitting phosphor and red fluorescence powder, is to be coated on the blue-light LED chip of InGaN, GaN series.The ratio of the weight of red glimmering coloured light powder, green emitting phosphor is W
Rouge and powder: W
Green powderWherein: 0.1≤W
Rouge and powder≤ 0.5,0.1≤W
Green powder≤ 0.7.The manufacture method of this electric light source is: take by weighing respectively by above-mentioned weight ratio that gained of the present invention is red, the green fluorescence powder, be coated on the blue-light LED chip of InGaN, GaN series after sizing mixing with solvent, welded circuit, used the resin sealed knot, the gained solid light source is white light LED electric light source of the present invention.
Characteristics of the present invention are:
1, Fa Ming matrix of materials is highly stable, and it is through bubble, and the intensity of processing fluorescent material such as heat does not change substantially.2, the excitation spectrum broad of material of the present invention is fit to the optical excitation of 300nm-460nm scope.(see figure 1) 3, simple, the easy handling of this fluorescent material manufacture method.
Description of drawings
Fig. 1 is excitation spectrum and the emmission spectrum figure of embodiment 1, excitation spectrum supervisory wavelength: 543nm, emmission spectrum excitation wavelength: 360nm.
Fig. 2 is excitation spectrum and the emmission spectrum figure of embodiment 2, excitation spectrum supervisory wavelength: 409nm, emmission spectrum excitation wavelength: 360nm.
Fig. 3 is excitation spectrum and the emmission spectrum figure of embodiment 3, excitation spectrum supervisory wavelength: 593nm, emmission spectrum excitation wavelength: 393nm.
Fig. 4 is for using embodiment 1,2 simultaneously, and the luminescent spectrum figure of the obtained white light LEDs of 3 three-color phosphor excites chip wavelength 380nm.
Embodiment
Embodiment 1
Y
0.4Gd
0.5Mg
0.95B
4.5P
0.5O
10: Ce
0.05, Tb
0.05, Mn
0.05The preparation embodiment of fluorescent material.Specific implementation process:
Stoichiometric ratio by above-mentioned chemical formula takes by weighing MgCO
3(AR), MnCO
3(AR), Y
2O
3(4N), Gd
2O
3(4N), CeO
2(4N), Tb
4O
7(4N), (NH
4)
2HPO
4(AR), 0.5% the MgCl that adds above-mentioned synthesis material weight
2As fusing assistant H
3BO
3(AR).Fully behind the mix grinding, roasting is 4 hours in 1200 ℃ of air atmospheres; Behind the abundant mix grinding of product of roasting, calcination is 2 hours under 600 ℃ of air atmospheres, 1200 ℃ of hydrogen 5% and 95% time roasting of nitrogen 4 hours, product of roasting is washed 3 times with deionized water again, filters, and dries under 90 ℃ of temperature.Obtain white powder of the present invention---the LED green emitting phosphor.The excitation spectrum of this embodiment 1 and emmission spectrum figure see Fig. 1, excitation spectrum supervisory wavelength: 543nm, emmission spectrum excitation wavelength: 360nm.
Embodiment 2
Y
0.45Gd
0.5Zn
0.95Mg
0.05B
4.5Al
0.5O
10: Ce
0.05, Mn
0.05Preparation embodiment.Specific implementation process:
Stoichiometric ratio by above-mentioned chemical formula takes by weighing MgCO
3(AR), MnCO
3(AR), H
3BO
3(AR), Y
2O
3(4N), Gd
2O
3(4N), CeO
2(4N), ZnO (AR), Al
2O
3(AR) 0.1%AlF of the above-mentioned synthesis material weight of adding
3(AR).Fully behind the mix grinding, roasting is 4 hours in 1200 ℃ of air atmospheres; Behind the abundant mix grinding of product of roasting, the crucible of packing into, shop, surface charcoal 1200 ℃ of following roastings 4 hours, is washed product of roasting 4 times with deionized water, filters, and dries under 120 ℃ of temperature.The white powder of the present invention that obtains---LED bluish voilet fluorescent material.The excitation spectrum of embodiment 2 and emmission spectrum figure see Fig. 2, excitation spectrum supervisory wavelength: 409nm, emmission spectrum excitation wavelength: 360nm.
Embodiment 3
Y
0.45Gd
0.49BO
3: Eu
0.04, Li
0.02Preparation embodiment.Specific implementation process:
Stoichiometric ratio by above-mentioned chemical formula takes by weighing H
3BO
3(AR), Y
2O
3(4N), Gd
2O
3(4N), Eu
2O
3(4N), Li
2CO
3(AR), 0.04% the Na that adds above-mentioned synthesis material weight
2SO
4As fusing assistant.Fully behind the mix grinding, roasting is 1 hour in 1600 ℃ of air atmospheres, and product of roasting is washed 5 times with deionized water, filters, and dries under 160 ℃ of temperature.The white powder of the present invention that obtains---LED red fluorescence powder.The excitation spectrum of embodiment 3 and emmission spectrum figure see Fig. 3, excitation spectrum supervisory wavelength: 593nm, emmission spectrum excitation wavelength: 393nm.
Embodiment 4
Use embodiment 1,2,3 three-color phosphor to make the embodiment of white light LED electric light source.
Implementation process: took by weighing embodiment 1,2 respectively in 0.4: 0.2: 0.4 by weight proportion, and after 3 gained fluorescent material are sized mixing, be coated on the ultraviolet InGaN chip, welded circuit, use the resin sealed knot, the gained solid light source is white light LED electric light source of the present invention.Use embodiment 1,2 simultaneously, the luminescent spectrum figure of the obtained white light LEDs of 3 three-color phosphor sees Fig. 4, excites chip wavelength 380nm.
Embodiment 5
Use embodiment 1,3 gained fluorescent material to make the embodiment of white light LED electric light source.
Implementation process: took by weighing respectively in 0.6: 0.4 by weight proportion after embodiment 1,3 gained fluorescent material sizes mixing, be coated on the blue light InGaN chip, welded circuit, use the resin sealed knot, the gained solid light source is white light LED electric light source of the present invention.
In sum, fluorescent material of the present invention has characteristics such as chemical stability is good, luminous intensity is high, excitation wavelength broad, and manufacture method is simple, pollution-free, cost is low.
Claims (12)
1, a class phosphor for white light LED is characterized in that: R
xM
yB
Z1A
Z2O
b: X
kWherein, R is Y, Gd, and Lu, La, at least a among the Sm; M is Zn, Ca, and Sr, Ba, at least a among the Mg; A is P, Si, and Al, Ga, at least a among the In; X is Ce, Tb, and Pr, Eu, Mn, at least a among the Li; 0.9≤x≤5 wherein; 0≤y≤1; 1≤z1≤10,0≤z2≤3,0.01≤k≤0.5,0.1≤b≤50.
2, the manufacture method of the described phosphor for white light LED of a kind of claim 1 comprises the steps:
(1), respectively with Y, Gd, Lu, La, Sm, Zn, Ca, Sr, Ba, Mg, B, P, Si, Al, Ga, In, Ce, Tb, Pr, Eu, Mn, the simple substance of Li or oxygenatedchemicals are raw material, and form and stoichiometric ratio takes by weighing corresponding raw material by the chemical formula of above-mentioned materials;
(2), in above-mentioned raw materials, add reaction flux, and with raw material and the abundant mixing of reaction flux;
(3), the said mixture material is carried out roasting;
(4), again through last handling process, promptly make phosphor for white light LED.
3, the manufacture method of phosphor for white light LED according to claim 2 is characterized in that: in described step (2), fusing assistant is an alkali metal halide, alkaline earth metal halide, H
3BO
3, Na
2SO
4, the halogenide of ammonium, at least a in the halogenide of aluminium.
4, according to the manufacture method of claim 2 or 3 described phosphor for white light LED, it is characterized in that: in described described step (2), the consumption of fusing assistant is the 0.005%-0.5% of synthesis material weight ratio.
5, according to the manufacture method of claim 2 or 3 described phosphor for white light LED, it is characterized in that: in described step (3), maturing temperature is at 600-1800 ℃, each roasting time is 1-30 hour, the roasting number of times is at least once, and calcination atmosphere is at least a in air, nitrogen, hydrogen, the CO gas.
6, according to the manufacture method of claim 2 or 3 described phosphor for white light LED, it is characterized in that: in described step (4), last handling process is that product of roasting is washed 3～5 times, filters the process of oven dry.
7, the manufacture method of phosphor for white light LED according to claim 6 is characterized in that: in described step (4), bake out temperature is 90～160 ℃.
8, a kind of electric light source is characterized in that: the UV-light or purple light or blue-light LED chip and the described phosphor for white light LED R of claim 1 that contain InGaN, GaN series
xM
yB
Z1A
Z2O
b: X
k, wherein, R is Y, Gd, and Lu, La, at least a among the Sm; M is Zn, Ca, and Sr, Ba, at least a among the Mg; A is P, Si, and Al, Ga, at least a among the In; X is Ce, Tb, and Pr, Eu, Mn, at least a among the Li; 0.9≤x≤5 wherein; 0≤y≤1; 1≤z1≤10,0≤z2≤3,0.01≤k≤0.5,0.1≤b≤50.
9, electric light source according to claim 8, it is characterized in that: described phosphor for white light LED is red fluorescence powder, green emitting phosphor and blue colour fluorescent powder, be to be coated on the UV-light or purple LED chip of InGaN, GaN series, the ratio of the weight of red fluorescence powder, green emitting phosphor and blue colour fluorescent powder is W
Rouge and powder: W
Green powder: W
Blue powder, wherein: 0.1≤W
Rouge and powder≤ 0.6,0.1≤W
Green powder≤ 0.6,0.1≤W
Blue powder≤ 0.5.
10, a kind of method of making the described electric light source of claim 9, it is characterized in that: take by weighing gained red, green, blue fluorescent material of the present invention respectively by the described weight ratio of claim 9, be coated on the UV-light or purple LED chip of InGaN, GaN series after sizing mixing with solvent, welded circuit, use the resin sealed knot, the gained solid light source is white light LED electric light source of the present invention.
11, electric light source according to claim 8, it is characterized in that: described phosphor for white light LED is green emitting phosphor and red fluorescence powder, be to be coated on the blue-light LED chip of InGaN, GaN series, the ratio of the weight of red glimmering coloured light powder, green emitting phosphor is W
Rouge and powder: W
Green powderWherein: 0.1≤W
Rouge and powder≤ 0.5,0.1≤W
Green powder≤ 0.7.
12, a kind of method of making the described electric light source of claim 11, it is characterized in that: take by weighing respectively by the described weight ratio of claim 11 that gained of the present invention is red, the green fluorescence powder, be coated on the blue-light LED chip of InGaN, GaN series after sizing mixing with solvent, welded circuit, use the resin sealed knot, the gained solid light source is white light LED electric light source of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101135065A CN1255506C (en) | 2003-11-13 | 2003-11-13 | Boron-containing luminescent powder for LED, preparing method thereof and electric light source therefrom |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101135065A CN1255506C (en) | 2003-11-13 | 2003-11-13 | Boron-containing luminescent powder for LED, preparing method thereof and electric light source therefrom |
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| Publication Number | Publication Date |
|---|---|
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| CN1255506C CN1255506C (en) | 2006-05-10 |
Family
ID=34336884
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|---|---|---|---|
| CNB2003101135065A Expired - Fee Related CN1255506C (en) | 2003-11-13 | 2003-11-13 | Boron-containing luminescent powder for LED, preparing method thereof and electric light source therefrom |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2410956A (en) * | 2004-01-21 | 2005-08-17 | Gen Electric | Phosphors containing boron and rare-earth metals, and light sources incorporating the same |
| CN100367523C (en) * | 2005-12-19 | 2008-02-06 | 中山大学 | White LED parts, mono-component dual-wavelength rare earth fluoresent powder for fluorescence conversion therefor and preparation method thereof |
| CN100554367C (en) * | 2007-04-11 | 2009-10-28 | 山东大学 | A kind of whole color fluorescent material and preparation method thereof |
| CN101649197A (en) * | 2009-09-01 | 2010-02-17 | 四川九洲光电科技有限公司 | Method for recovering fluorescent powders of light emitting diode |
| CN102121677A (en) * | 2009-12-16 | 2011-07-13 | 优志旺电机株式会社 | Fluorescent lamp |
| CN102604634A (en) * | 2012-02-10 | 2012-07-25 | 南通南京大学材料工程技术研究院 | Yellow fluorescent powder for white light emitting diode (LED) |
| US8262934B2 (en) * | 2007-11-21 | 2012-09-11 | Samsung Electro-Mechanics Co., Ltd. | Silicate phosphor and white light emitting device including the same |
| CN102660262A (en) * | 2012-05-04 | 2012-09-12 | 苏州大学 | Eu<2+> activated chloride calcium silicate fluorescent powder, preparation method and application |
| CN102660275A (en) * | 2012-05-04 | 2012-09-12 | 苏州大学 | Vanadate fluorescent powder, and preparation method and application thereof |
| CN103154196A (en) * | 2010-10-06 | 2013-06-12 | 默克专利有限公司 | Mn-activated phosphors |
| CN104004519A (en) * | 2014-06-06 | 2014-08-27 | 西北大学 | Near-infrared down-conversion luminescent material as well as preparation method and application thereof |
| CN109592978A (en) * | 2018-12-03 | 2019-04-09 | 江苏师范大学 | High-capacity LED/LD illumination refers to fluorescence ceramics and the preparation method and application thereof with warm white height is aobvious |
| CN110513605A (en) * | 2019-08-20 | 2019-11-29 | 西安鸿钧睿泽新材料科技有限公司 | A kind of garden landscape lamp and its manufacturing method with self light emission function |
-
2003
- 2003-11-13 CN CNB2003101135065A patent/CN1255506C/en not_active Expired - Fee Related
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2410956B (en) * | 2004-01-21 | 2009-03-04 | Gen Electric | Phosphors containing boron and rare-earth metals, and light sources incorporating the same |
| GB2410956A (en) * | 2004-01-21 | 2005-08-17 | Gen Electric | Phosphors containing boron and rare-earth metals, and light sources incorporating the same |
| CN100367523C (en) * | 2005-12-19 | 2008-02-06 | 中山大学 | White LED parts, mono-component dual-wavelength rare earth fluoresent powder for fluorescence conversion therefor and preparation method thereof |
| CN100554367C (en) * | 2007-04-11 | 2009-10-28 | 山东大学 | A kind of whole color fluorescent material and preparation method thereof |
| US8262934B2 (en) * | 2007-11-21 | 2012-09-11 | Samsung Electro-Mechanics Co., Ltd. | Silicate phosphor and white light emitting device including the same |
| CN101649197B (en) * | 2009-09-01 | 2013-12-11 | 四川九洲光电科技股份有限公司 | Method for recovering fluorescent powders of light emitting diode |
| CN101649197A (en) * | 2009-09-01 | 2010-02-17 | 四川九洲光电科技有限公司 | Method for recovering fluorescent powders of light emitting diode |
| CN102121677A (en) * | 2009-12-16 | 2011-07-13 | 优志旺电机株式会社 | Fluorescent lamp |
| CN102121677B (en) * | 2009-12-16 | 2014-11-12 | 优志旺电机株式会社 | Fluorescent lamp |
| CN103154196A (en) * | 2010-10-06 | 2013-06-12 | 默克专利有限公司 | Mn-activated phosphors |
| CN102604634A (en) * | 2012-02-10 | 2012-07-25 | 南通南京大学材料工程技术研究院 | Yellow fluorescent powder for white light emitting diode (LED) |
| CN102660262A (en) * | 2012-05-04 | 2012-09-12 | 苏州大学 | Eu<2+> activated chloride calcium silicate fluorescent powder, preparation method and application |
| CN102660275B (en) * | 2012-05-04 | 2014-02-26 | 苏州大学 | Vanadate fluorescent powder, and preparation method and application thereof |
| CN102660275A (en) * | 2012-05-04 | 2012-09-12 | 苏州大学 | Vanadate fluorescent powder, and preparation method and application thereof |
| CN104004519A (en) * | 2014-06-06 | 2014-08-27 | 西北大学 | Near-infrared down-conversion luminescent material as well as preparation method and application thereof |
| CN104004519B (en) * | 2014-06-06 | 2016-02-10 | 西北大学 | A kind of near infrared down-conversion luminescent material, preparation method and application thereof |
| CN109592978A (en) * | 2018-12-03 | 2019-04-09 | 江苏师范大学 | High-capacity LED/LD illumination refers to fluorescence ceramics and the preparation method and application thereof with warm white height is aobvious |
| CN109592978B (en) * | 2018-12-03 | 2021-07-23 | 江苏师范大学 | Warm white light high-color rendering index fluorescent ceramic for high-power LED/LD illumination and preparation method and application thereof |
| CN110513605A (en) * | 2019-08-20 | 2019-11-29 | 西安鸿钧睿泽新材料科技有限公司 | A kind of garden landscape lamp and its manufacturing method with self light emission function |
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