CN1535579A - Monosultap granules and its preparation method - Google Patents
Monosultap granules and its preparation method Download PDFInfo
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- CN1535579A CN1535579A CNA031131107A CN03113110A CN1535579A CN 1535579 A CN1535579 A CN 1535579A CN A031131107 A CNA031131107 A CN A031131107A CN 03113110 A CN03113110 A CN 03113110A CN 1535579 A CN1535579 A CN 1535579A
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- China
- Prior art keywords
- preparation
- disintegrant
- granular insecticide
- filler
- powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000002360 preparation method Methods 0.000 title claims abstract description 26
- 239000008187 granular material Substances 0.000 title abstract description 8
- MBNMHBAJUNHZRE-UHFFFAOYSA-M thiosultap monosodium Chemical compound [Na+].OS(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O MBNMHBAJUNHZRE-UHFFFAOYSA-M 0.000 title abstract 4
- 239000000843 powder Substances 0.000 claims abstract description 18
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000004094 surface-active agent Substances 0.000 claims abstract description 9
- 239000002917 insecticide Substances 0.000 claims description 34
- 239000000945 filler Substances 0.000 claims description 21
- 239000007884 disintegrant Substances 0.000 claims description 17
- 238000005469 granulation Methods 0.000 claims description 13
- 230000003179 granulation Effects 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 230000000149 penetrating effect Effects 0.000 claims description 8
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 7
- 235000011152 sodium sulphate Nutrition 0.000 claims description 7
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 6
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 6
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 5
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 5
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 5
- 239000000440 bentonite Substances 0.000 claims description 5
- 229910000278 bentonite Inorganic materials 0.000 claims description 5
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 5
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 5
- 229960000892 attapulgite Drugs 0.000 claims description 4
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052625 palygorskite Inorganic materials 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 3
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 239000004202 carbamide Substances 0.000 claims description 3
- 230000000295 complement effect Effects 0.000 claims description 3
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 claims description 3
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 3
- 229920001223 polyethylene glycol Polymers 0.000 claims description 3
- -1 polyoxyethylene Polymers 0.000 claims description 3
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 claims description 3
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 claims description 3
- 229940113124 polysorbate 60 Drugs 0.000 claims description 3
- 239000011780 sodium chloride Substances 0.000 claims description 3
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 238000009792 diffusion process Methods 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 2
- 238000012216 screening Methods 0.000 claims description 2
- 239000001488 sodium phosphate Substances 0.000 claims description 2
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 2
- 239000013638 trimer Substances 0.000 claims description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical group [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- 239000000463 material Substances 0.000 abstract description 4
- 239000000853 adhesive Substances 0.000 abstract description 3
- 230000001070 adhesive effect Effects 0.000 abstract description 3
- 238000001035 drying Methods 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 2
- 230000018044 dehydration Effects 0.000 abstract 1
- 238000006297 dehydration reaction Methods 0.000 abstract 1
- 238000000034 method Methods 0.000 description 16
- 239000000047 product Substances 0.000 description 9
- 238000009736 wetting Methods 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 238000007906 compression Methods 0.000 description 4
- 230000006835 compression Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 239000012752 auxiliary agent Substances 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000005453 pelletization Methods 0.000 description 3
- 241000255789 Bombyx mori Species 0.000 description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000011507 gypsum plaster Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- QSOHVSNIQHGFJU-UHFFFAOYSA-L thiosultap disodium Chemical compound [Na+].[Na+].[O-]S(=O)(=O)SCC(N(C)C)CSS([O-])(=O)=O QSOHVSNIQHGFJU-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003337 fertilizer Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 235000011868 grain product Nutrition 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000009490 roller compaction Methods 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 235000019832 sodium triphosphate Nutrition 0.000 description 1
- 239000001226 triphosphate Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 235000020985 whole grains Nutrition 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a monosultap granules preparation. It is made up by using monosultap raw pesticide (raw powder) directly or mixing it with surfactant, disintegrating agent and filling material through a certain preparation process. Its effective component monosultap content can be up to 99%. In the course of production it does not add water or other adhesive, said powder material is placed into the mould hole, and instantaneously forcedly compressed into the granules, so that it has no need of drying and making dehydration. The physical form of said preparation is white or light yellow granule, and its concentration is high, disintegration speed is quick and environment compatibility is good.
Description
One, technical field
The present invention relates to a kind of agricultural insecticidal agent formulation and processing method thereof, exactly is a kind of granular insecticide and preparation method thereof.
Two, background technology
The preparation of desinsection list mainly contains soluble powder, low concentrations of particulates agent at present." agriculture chemical registration bulletin compilation " disclosed desinsection list soluble powder specifications in 2002 that the China Agricultyre University Press publishes have: 36%, 50%, 80%, 90%, 95%; The granular insecticide kind has only a kind of i.e. 3.6% granular insecticide.Because soluble powder easily lumps in storage process, easily produce the dust drift in production and the use, contaminated environment, especially in the silkworm area, desinsection Dan Yi works the mischief to silkworm during the spraying use, seriously restricts this product promotion and use.And the low concentration granular insecticide as 3.6% granular insecticide, though solved the problem that desinsection list soluble powder exists, because concentration is low, thereby increases packing and cost of transportation.The disclosed process for preparing granular insecticide of CN1094567A: at first former medicine of dimehypo and watery hydrochloric acid are stirred, be mixed with the 22%-26% desinsection list aqueous solution, adding 2.5～3.5 times of plaster of paris to the 22%-26% desinsection list aqueous solution again mixes thoroughly, solidify, carry out the method that granulation forms product at last.The shortcoming that the method exists: the one, dimehypo is changed into the desinsection list by adding hydrochloric acid, technology is loaded down with trivial details; The 2nd, must add the binding agent such as the plaster of paris, could form particle; The 3rd, contain a large amount of water in the product, so final products must be dried, equipment investment is big; Four-way is crossed this prilling process, causes the product effective component content to hang down between 5%-10%.
The method of the disclosed production particle of " formulations of pesticide process technology " second edition of chemical industry publication in 1998 has: coating pelletizing method, spray granulation, rotation comminution granulation, extruder grain method, absorption comminution granulation, fluidized bed prilling method etc., these prilling process exist needs to add binding agent and water in the production process, the product of producing need be dried, energy consumption height, shaping rate be low, yield poorly, production cost height, process conditions harshness, operation easier is big, investment is big, concentration product is low, intensity is low, easily come off, and produces dust, is difficult for storing shortcoming such as transportation.
Three, summary of the invention
Task of the present invention is the granule of processing high concentration.When effective composition desinsection list content improved, other additives such as filler, auxiliary agent equal size must reduce.In the present invention, the content of desinsection list can be brought up to 99% (same under the proportion by subtraction of weight), and other content of additive can be reduced to zero, and the content of desinsection list is 11-99% in this granule in other words, and surplus is filler and auxiliary agent.
The alternative kind of filler (also claiming carrier, adsorbent) has: white carbon, potter's clay, attapulgite, precipitated calcium carbonate, sodium sulphate, talcum powder can be used alone, but also also mix together.
Auxiliary agent comprises surfactant and disintegrant.Surfactant plays dispersion, wetting osmosis, alternative kind has: sodium phosphate trimer, lignosulfonates, NNO, polyoxyethylene propylene ether block copolymers, rope uncle SOPA, diffusion agent N O, dispersing agent MF, neopelex, draw back powder, penetrant t, penetrating agent JFC, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, polysorbate60, the basic phenol polyethenoxy base of suffering (ninth of the ten Heavenly Stems) ether, can be used alone, but also also mix together.
The alternative kind of disintegrant has: ammonium sulfate, sodium chloride, magnesium chloride, aluminium chloride, urea, bentonite can be used alone, but also also mix together.
The each component percentage by weight is as follows in this granule:
Desinsection list 11-99%
Surfactant 0-15%
Disintegrant 0-10%
Filler 0 and/or complement to 100%.
Preferred each constituent content:
Desinsection list 80-95%
Surfactant 0-12%
Disintegrant 0-8%
Filler 0 and/or complement to 100%.
In this granule, its essence is exactly directly with the former medicine granulation of desinsection list when other additive levels are zero.The desinsection list is water miscible, if in process, add water or moisture adhesive by conventional method, and technologic loaded down with trivial details discussing for the present, the water that is added finally will remove by drying, and this is just not economic rationally.If can in process, not add water, not only simplify literary writing by leaving out superfluous words on the technology, and will cut down the consumption of energy significantly.
Found through experiments, the mixed powder of former powder of desinsection list or desinsection list and other additives (the dried powder of general designation down) can obtain closely knit and particle that certain intensity is arranged by physical compression in die cavity.This shows that non-slurry pelletizing is feasible.
In the prior art, realize that mold pressing has multiple mode and device.But the optimum device of realizing the application's non-slurry pelletizing is a double roller compaction granulator; its granulation mechanism is the roll that two levels are put; the Surface Machining of roll has the half module cave of mutual correspondence; the half module cave of two correspondences is in roll constant speed reverse rotation process; beginning is drawn close mutually, separates immediately after moment constitutes a complete die cavity (being cavity), whenever rotates a circle; form one time cavity, go round and begin again.The powder of doing is exactly in the half module cave of correspondence, is squeezed into particle in the moment that forms a complete die cavity.Concrete granulation process is as follows: at first the powder of doing is added in the material bin, the precompressed conveyor screw of hopper bottom is evenly delivered to the powder of doing in the half module cave on the deep-slotted chip breaker surface that constitutes between the roll of two levels storings.Under the effect of transmission mechanism, the reverse rotation of two roll constant speed, corresponding half module cave forms particle at the moment enforce compression powder that forms complete die cavity.Served as region of maximum compression, the two halves die cavity is separated from each other, the elastic recovery of material self in addition, and the particle automatic demoulding falls down, and obtains desired grain products through screening, and it is recycling that the powder under the sieve returns hopper.
The pair roller granulation utilizes your power of intermolecular Van der Waals to make particle firm, therefore need not to add water or other adhesives, and can process the granular insecticide of arbitrary content and size specification as required.
The present invention kills the technical indicator of individual particle agent:
Desinsection list content, % (m/m) 11-99
Granularity, mm (0.1-10), % 〉=90
Moisture, % (m/m)≤1.0
PH value scope: 4.5-7.5
Disintegration time, min≤3.0
Expulsion rate, %≤3.0
Heat storage stability (54 ± 2 ℃, 14d), resolution ratio %≤5.0.
Product appearance is white or faint yellow particle, room temperature storage 2 years, resolution ratio≤5%.Product content height in addition, epigranular, intensity is big, disintegration is fast, no dust drift, Environmental compatibility be good, easy to use, to water spray or directly spraying spread fertilizer over the fields, store and transport safe etc.
This manufacturing approach craft is simple, if use former powder, directly granulation if need to add other components, gets final product granulation after mixing.Equipment volume is little, can produce continuously in confined conditions, can realize cleaner production, does not need drying especially, greatly reduces energy resource consumption.
Four, embodiment
Non-limiting examples is described below:
1, gets 90% desinsection list 11.2Kg, pentasodium triphosphate of dispersing agent 5Kg, lauryl sodium sulfate 1Kg, disintegrant ammonium sulfate 5Kg, bentonite 5Kg, filler precipitated calcium carbonate 72.8Kg, through mixing, being added in the hopper by elevator, again through preloaded helical compression, pair roller granulation, broken whole grain, sieve granular insecticide.
2, get 95% desinsection list 21.1Kg, dispersant sodium lignin sulfonate 15Kg, wetting and penetrating agent draws back powder 10Kg, OPEO 2Kg,, disintegrant urea 5 filler attapulgite 46.9Kg,, press example 1 preparation method and granular insecticide.
3, get 95% desinsection list 31.6Kg, dispersant calcium lignosulfonate 10Kg, dispersing agent MF 5Kg, disintegrant sodium chloride 3Kg, filler talcum powder 20Kg, sodium sulphate 30.4Kg, press example 1 preparation method and granular insecticide.
4, get the extremely single 44.5Kg of 90%% worm, wetting agent penetrating agent JFC 5Kg, disintegrant bentonite 10Kg, the white carbon black 40.5Kg of filler press example 1 preparation method and must granular insecticide.
5, get the extremely single 56.3Kg of 80% worm, disintegrant ammonium sulfate 7Kg, filler potter's clay 36.7Kg press example 1 preparation method and must granular insecticide.
6, get the extremely single 52.1Kg of 96% worm, dispersant NO15Kg, wetting and penetrating agent lauryl alcohol polyethylene glycol oxide base ether sodium sulfate 3Kg, filler potter's clay 10Kg, precipitated calcium carbonate 19.9Kg press example 1 preparation method and must granular insecticide.
7, get 95% desinsection list 57.9Kg, dispersant rope uncle SOPA3Kg, disintegrant magnesium chloride 5Kg, filler sodium sulphate 20Kg, white carbon black 11.4Kg press example 1 preparation method and must granular insecticide.
8, get 90% desinsection list 66.7Kg, disintegrant aluminium chloride 5Kg, filler attapulgite 28.3Kg, press example 1 preparation method and granular insecticide.
9, get 95% desinsection list 68.5Kg, dispersant polyoxyethylene poly-oxygen propylene aether block copolymer 4Kg, wetting and penetrating agent T5Kg, the white carbon black 22.5Kg of filler, press example 1 preparation method and granular insecticide.
10, get 97% desinsection list 72.2Kg, wetting and penetrating agent polysorbate60 6Kg, disintegrant bentonite 8Kg, filler talcum powder 13.8Kg, press example 1 preparation method and granular insecticide.
11, get 95% desinsection list 79Kg, dispersant NNO2Kg, disintegrant ammonium sulfate 4Kg, filler potter's clay 15Kg, press example 1 preparation method and granular insecticide.
12, get 80% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
13, get 95% desinsection list 89.5Kg, wetting and penetrating agent lauryl sodium sulfate 2Kg, filler precipitated calcium carbonate 8.5Kg, press example 1 preparation method and granular insecticide.
14, get 90% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
15, get 92% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
16, get 95% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
17, get 97% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
18, get 98% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
19, get 99% desinsection list 100Kg, press example 1 preparation method and granular insecticide.
Claims (6)
1, a kind of granular insecticide, its component and content (percentage by weight):
Desinsection list: 11-99%
Surfactant: 0-15%
Disintegrant: 0-10%
Filler: 0 and/or complement to 100%.
2, according to the described granular insecticide of claim, it is characterized in that: each constituent content is:
Desinsection list: 80～95%
Surfactant: 0～12%
Disintegrant: 0～8%
Filler: 0 and/or supply as for 100%.
3, granular insecticide according to claim 1 and 2 is characterized in that: described surfactant is sodium phosphate trimer, lignosulfonates, NNO, polyoxyethylene poly-oxygen propylene aether block copolymer, rope uncle SOPA, diffusion agent N O, dispersing agent MF, neopelex, draws back one or more mixed surfactants in powder, penetrant t, penetrating agent JFC, lauryl alcohol polyethylene glycol oxide base ether sodium sulfate, polysorbate60, the basic phenol polyethenoxy base of suffering (ninth of the ten Heavenly Stems) ether.
4, granular insecticide according to claim 1 and 2 is characterized in that: described disintegrant is: one or more in ammonium sulfate, sodium chloride, magnesium chloride, aluminium chloride, urea, the bentonite mix disintegrant.
5, want 1 or 2 described granular insecticides according to right, it is characterized in that: described filler be white carbon, potter's clay, attapulgite, precipitated calcium carbonate sodium sulphate, talcum powder, in one or more mixed fillers.
6, by the preparation method of the described granular insecticide of claim 1, comprise and mix precompressed, the granulation demoulding and screening, it is characterized in that: described granulation is that the powder done is on the roll that two levels are put in the corresponding half module cave, when two roll constant speed reverse rotations, the moment that corresponding two halves die cavity forms a complete die cavity is squeezed into particle.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03113110 CN1285265C (en) | 2003-04-04 | 2003-04-04 | Monosultap granules and its preparation method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03113110 CN1285265C (en) | 2003-04-04 | 2003-04-04 | Monosultap granules and its preparation method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1535579A true CN1535579A (en) | 2004-10-13 |
| CN1285265C CN1285265C (en) | 2006-11-22 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03113110 Expired - Fee Related CN1285265C (en) | 2003-04-04 | 2003-04-04 | Monosultap granules and its preparation method |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1285265C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102215678A (en) * | 2008-12-01 | 2011-10-12 | 组合化学工业株式会社 | Process for producing water-dispersible particulate agricultural-chemical composition |
| CN104642316A (en) * | 2013-11-19 | 2015-05-27 | 南京华洲药业有限公司 | Composite insecticidal composition containing monosultap and spinetoram and application thereof |
-
2003
- 2003-04-04 CN CN 03113110 patent/CN1285265C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102215678A (en) * | 2008-12-01 | 2011-10-12 | 组合化学工业株式会社 | Process for producing water-dispersible particulate agricultural-chemical composition |
| US8632709B2 (en) | 2008-12-01 | 2014-01-21 | Kumiai Chemical Industry Co., Ltd. | Process for producing water-dispersible particulate agricultural-chemical composition |
| CN104642316A (en) * | 2013-11-19 | 2015-05-27 | 南京华洲药业有限公司 | Composite insecticidal composition containing monosultap and spinetoram and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1285265C (en) | 2006-11-22 |
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