CN1530398A - Low-temperature resistant high-strength universal polyurethane elastomer pouring material for ground laying and preparing method thereof - Google Patents
Low-temperature resistant high-strength universal polyurethane elastomer pouring material for ground laying and preparing method thereof Download PDFInfo
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Abstract
A low temp-resistant high-strength universal pouring material of polyurethane elastomer laid on the ground surface is disclosed. During its preparing process, the new monomers, polytetrahydrofuran diol and tetrafuran-epoxy propane copolymer diol, are used to react on diisocyanate, and the cross-linking agent, filler and catalyst are newly designed. Its advantages are high versatility, high strength and high resistance to low temp.
Description
Technical field
The present invention relates to macromolecular material, particularly mould material is laid in the polyurethane elastomer place.
Background technology
Along with China's economy develops rapidly, the laying that mould material has been widely used in electronic machine, household electrical appliances, IT product manufacturing shop and warehouse, outdoor sport place, space for activities, kindergarten etc. is laid in the polyurethane elastomer place, the use region is vast, the purposes variation, thereby, the place paver has been proposed new requirement.High-strength mechanical properties if can be still kept at low temperatures, the stronger paver of snappiness, high rigidity, mechanical mechanics property that the gravity forklift rolls can be stood in place, above-mentioned warehouse.Present widespread usage is the material polymerization system that CN1033639A adopted just like the Chinese invention patent application publication number, i.e. TDI (tolylene diisocyanate)-PPG (hydroxyl polyoxytrimethylene ether) system.The subject matter of this material be under the normal temperature condition main mechanical mechanics property, be 105% only as elongation at break, (GB/T14833-93) reluctantly is up to state standards.And at low temperatures, as at-20 ℃--more show as easy embrittlement in the time of 30 ℃, have through one or two severe winter, the place is with regard to many places embrittlement, disconnection and can't use, and lets alone can stand the gravity forklift and roll required mechanics of machinery intensity.
Summary of the invention
Purpose of the present invention just is to address the above problem, and has introduced polytetrahydrofuran diol (PTMG) and tetrahydrofuran (THF)-propylene oxide copolymerization glycol (PTPG) new monomer and vulcabond polyreaction.In new molecular designing, also draw as having gone into the stronger diisocyanate monomer MDI-50 of rigidity; Thereby obtain low temperature resistantly, promptly keep required mechanics of machinery intensity at low temperatures, and have macromolecular material higher, more excellent mechanical property than TDI-PPG system polymer at normal temperatures.
Have side group different with PPG, the urethane that polytetrahydrofuran diol (PTMG) forms does not have side group at soft chain segment.Because the steric hindrance of side group, a little less than the hydrogen bond, crystallinity is poor, and the mechanical mechanics property of the polyurethane elastomer of its formation has better mechanical mechanics property with regard to the polyurethane elastomer that forms not as PTMG, as: stronger, more pliable and tougher, more low temperature resistant, more wear-resisting, hydrolysis etc. more.
The low price of tetrahydrofuran (THF)-propylene oxide copolymerization glycol, and the approximate polytetrahydrofuran diol goods of its product properties, resisting cold to reach-200 ℃
In molecular designing of the present invention, fully take into account the snappiness that increases molecule, anti-fragility, in linking agent, added and made the more flexible Viscotrol C of molecule.Consider the ease for operation of floor file construction, enough reinforcement should be arranged, its viscosity is also wanted appropriateness simultaneously, for it is controlled at 10, below the 000mPas, and has used kaolin-talcum powder casting resin mixture.The catalyzer that uses has been considered the ease for operation of construction too, makes real-world effectiveness be arranged an inductive phase, prolong storage period (Pot-life).After the place laying was finished, the elastic polyurethane physical efficiency is curing molding soon, has adopted nontoxic composite catalyst system, i.e. isocaprylic acid zinc-isocaprylic acid or stannous octoate-isocaprylic acid system.
The place paver of the polyurethane elastomer of the present invention's first scheme is, form through chain extension-crosslinking reaction by giving aggressiveness (A component) and chain extension-crosslinking agent (B component) and catalyzer, wherein: give polyether glycol that aggressiveness (A component) uses and introduced polytetrahydrofuran diol or tetrahydrofuran (THF)-propylene oxide copolymerization glycol and vulcabond TDI (tolylene diisocyanate) or MDI-50 (4.4 '-two isocyanato ditanes and 2.4 '-two isocyanato ditane mixtures) and react and get; And the chainextender that chain extension-crosslinking agent (B component) is used has also added dihydroxyl polyethenoxy ether (N220 molecular weight 2000) except MOCA (3.3 '-two chloro-4.4 '-diaminodiphenylmethane), linking agent is except adding trihydroxy-polyoxytrimethylene ether (N330, molecular weight 3000) also added Viscotrol C outside, softening agent is phthalic acid two 2-ethylhexoates (DOP) or clorafin.
The place paver of the polyurethane elastomer of alternative plan of the present invention is, what use in the auxiliary material of above-mentioned B component is kaolin-talcum powder (1: 2) mixed reinforcing agent, and catalyzer is nontoxic isocaprylic acid zinc-isocaprylic acid (2: 1) or stannous octoate-isocaprylic acid (2: 1) mixed system.The mill base material that the B component adds is Fe
2O
3(redness), Cr
2O
3(green).Softening agent is a clorafin, has also added antioxidant 1010, anti ultraviolet agent uv-327, antiseptic-germicide copper 8-quinolinolate.
The place paver of the polyurethane elastomer of third party's case of the present invention is that in above-mentioned first, second scheme, it specifically consists of:
The A component is formed (weight percent)
Vulcabond 20-40%
Tetrahydrofuran (THF)-propylene oxide copolymerization glycol
Or polytetrahydrofuran diol 20-30%
Dihydroxyl polyoxytrimethylene ether 30-40%
Softening agent 8-15%
The B component is formed (weight percent)
3.3 '-two chloro-4.4 ' diaminodiphenylmethane 1.5-8%
Dihydroxyl polyoxytrimethylene ether 2-8%
Viscotrol C 2-6%
Trihydroxy-polyoxytrimethylene ether 8-12%
Pigment 3-5%
Strengthening agent 28-45%
Softening agent 25-40%
Antioxidant 0.1-0.5%
Anti ultraviolet agent 0.1-0.5%
Antiseptic-germicide 0.1-0.5%
Wherein the weight ratio of A component and B component is 1: 3-1: 5.
Catalyst levels is the 1-10 weight % of the total weight of A component and B component.
The place pavement of the polyurethane elastomer of the cubic case of the present invention is to add the black rubber grain (the track and field runway is used) of the 20-30% weight of this material system in above-mentioned third party's case.
The manufacture method of the place paver of the polyurethane elastomer of the present invention's the 5th scheme may further comprise the steps:
1) preparation A component: tetrahydrofuran (THF)-propylene oxide copolymerization glycol or polytetrahydrofuran diol, dihydroxyl polyoxytrimethylene ether and softening agent with metering join in the reactor.Evenly stir at 80-90 ℃, vacuum (0.002MPa) dehydration was cooled to 45-50 ℃ after 2 hours; normal pressure adds the vulcabond of metering down, is warming up to 85-90 ℃ gradually, under nitrogen protection; reacted 2 hours, and be cooled to 50 ℃, the sealing of metering dress metal bucket is stand-by under nitrogen protection.
2) preparation B component: the softening agent and the pigment of metering are joined in the reactor, stir and after colloidal mill is worn into mill base, the dihydroxyl polyoxytrimethylene ether that adds metering successively, Viscotrol C, trihydroxy-polyoxytrimethylene ether, at last with chainextender MOCA, strengthening agent kaolin-talcum powder and other solid additive continue to join and stir with mill base in the stirring tank and be ground to below the 50 μ m through colloidal mill, be driven into reactor with toothed gear pump, be heated with stirring to 80-90 ℃ and vacuumize (0.002Mpa) dehydration 2.5 hours, be cooled to 50 ℃, metering barrelling sealing is standby.
3) lay the on-the-spot polyurethane elastomer paver of laying: with standby A component, the B component of aforesaid barrelling sealing is 1: 3～1: 5 computation weigh by weight on the scenely, stir, the catalyzer (A, B composition weight and 1-10%) that adds calculated weight stirs rapidly, pave immediately in advance on the ready-made smooth basis, under 15-30 ℃ of condition, about 30-60 divides inner gel, solidify in 24 hours, can come into operation after the complete slaking on the 14th (can survey its various mechanical properties).In the above scheme, catalyzer can be used isocaprylic acid zinc---isocaprylic acid or stannous octoate---, and isocaprylic acid is let alone a kind of mixed system (solvent is No. 200 gasoline).
Embodiment
Below, the invention will be further described (below, abbreviate low temperature resistant, high strength place as " glue " with the polyurethane elastomer mould material) by embodiment.
Employed raw material specification is:
1. vulcabond:
Tolylene diisocyanate (TDI)
Specification: the M/O ratio is 80/20.
4.4 4.2 '-two isocyanato ditane mixtures (MDI-50)
Specification: 4.4 ' and 4.2 ' volume ratio about 60/40.
2. polytetrahydrofuran diol (PTMG)
Specification: PTG 2000 average molecular mass Mn 2000 ± 100, hydroxyl value 53-59mgKOH/g.
PTG 1000 average molecular mass Mn 1000 ± 50, hydroxyl value 107-118mgKOH/g.
3. tetrahydrofuran (THF)-propylene oxide copolymerization glycol (PTPG)
Specification: Ng215 averagemolecular wt amount Mn 1500 ± 100, hydroxyl value 70-80mgKOH/g.
4. dihydroxyl polyoxytrimethylene ether (PPG)
Specification: N220 average molecular mass Mn 2000 ± 100, hydroxyl value 54-58mgKOH/g.
N210 average molecular mass Mn 1000 ± 70, hydroxyl value 105-117mgKOH/g.
5. trihydroxy-polyoxytrimethylene ether (PPG)
Specification: N330 average molecular mass Mn 3000 ± 100, hydroxyl value 54.5-57.5mgKOH/g.
6.3.3 '-two chloro-4.4 '-aminodiphenylmethane (MOCA)
Specification: mp 〉=100 ℃
7. pigment:
Redness, red iron oxide Fe
2O
3
Green, chromoxide green Cr
2O
3
8. Viscotrol C: hydroxyl value 160mgKOH/g
9. clorafin: cl content 50-52%, viscosity≤4000Mpas
10. dioctyl phthalate (DOP) (DOP): b.p384 ℃
11. kaolin: Al
2O
32SiO
2Fe content≤1%
12. talcum powder: 3MgO4SiO
2
13. antioxidant 1010 four (4-hydroxyl-3,5-tert-butyl-phenyl propionic acid) pentaerythritol ester
14. anti ultraviolet agent UV327[2, (2 '-hydroxyl-3 ', 5 '-di-t-butyl) phenyl-5-chlorinated benzotriazole]
15. antiseptic-germicide: copper 8-quinolinolate
16. catalyzer:
Isocaprylic acid zinc (CH
3CH
2CH
2CH
2CH-C-O)
2Zn 4% gasoline solution
Stannous octoate (C
4H
9-CH-C-O)
2The Sn weak yellow liquid
The present invention except that brand-new consideration molecular designing make its more reasonable, introduced polytetrahydrofuran diol and tetrahydrofuran (THF)-propylene oxide copolymerization glycol emphatically, make the place can be under low temperature more, the mechanical mechanics property that maintenance needs, at normal temperatures, higher mechanical property such as tensile strength are arranged, and elongation rate of tensile failure greatly strengthens (seeing attached list).Improved the place quality greatly, longer service life.
Embodiment 1 soft place is laid and is used glue
1) A component preparation
Difference weighing PTG2000 130kg, PTG1000 97kg, N220 194kg; N210146kg, and DOP 121kg injection reactor, the stirring vacuum dehydration is 2 hours under 80-85 ℃ of temperature; fill nitrogen and recover normal pressure; be cooled to 45 ℃, under nitrogen protection, add MDI-50 312kg again; under 80-85 ℃ of temperature; reacted 2 hours, and be cooled to 50 ℃ then, pack into metal bucket sealing of computation weigh is stand-by.
2) B component preparation
In stirring tank with pigment red iron oxide 36kg and clorafin 380kg stirs and after colloidal mill is worn into mill base, add MOCA 22.5kg more successively, N220 40kg, N330 100kg, Viscotrol C 40kg and solid material MOCA 22.5kg, kaolin 124.5kg, talcum powder 250kg, antioxidant 1010 2kg, anti ultraviolet agent UV-327 2kg and antiseptic-germicide copper 8-quinolinolate 3kg stir to stirring tank in the lump, (to 50 μ m) squeeze into reactor with toothed gear pump behind the colloidal mill porphyrize, at 80-90 ℃, vacuum hydro-extraction was cooled to 50 ℃ of metal buckets of packing into and seals stand-by after 2.5 hour.
(3) glue is in the laying in place
A component and B component are heavy by metering weighing in 1: 4, as A component 20kg, B component 80kg, in agitation vat, stir rapidly, add 25kg black rubber grain (diameter d is 3mm) back and continuing to add isocaprylic acid zinc-isocaprylic acid (2: 1) gasoline solution (concentration 3%) 6kg of the 6 weight % that account for glue weight under the stirring, pave then to the basis in place, automatic levelling, gel is solidified into elastomerics.After normal temperature slaking on the 14th, just can use, and measure its performance (seeing attached list).
Next day, the above-mentioned pure glue that does not add the black rubber grain that paves thereon, the about 2mm of thickness, the even pure urethane micelle of spreading (diameter is about 4mm) subsequently, the next day can firm adhesion.
Embodiment 2 soft places are laid and are used glue
(1) A component preparation
Weighing Ng215 250kg, N220 214kg, N210 160kg and clorafin 133kg add in the reactor; stir under 80-90 ℃ of temperature, vacuum hydro-extraction was filled nitrogen and is recovered normal pressure after 2 hour; be cooled to 45 ℃; under nitrogen protection, add TDI 242kg again, at 80-85 ℃; nitrogen protection is reacted after 2 hours down; after being cooled to 50 ℃, under nitrogen protection, measuring the metal bucket of packing into and seal stand-by.
(2) B component preparation
In stirring tank with pigment chromoxide green 36kg and clorafin 380kg, stir, and after colloidal mill is worn into mill base, add MOCA 19kg more successively, N220 40kg, N330 100kg, Viscotrol C 40kg adds solid material MOCA 19kg, kaolin 126kg while stirring, talcum powder 252kg, antioxidant 1010 2kg, anti ultraviolet agent UV-327 2kg and antiseptic-germicide copper 8-quinolinolate 3kg are to stirring tank, after stirring, behind colloidal mill levigate (to 50 μ m), squeeze into reactor with toothed gear pump, at 80-90 ℃, vacuum hydro-extraction is after 2.5 hours, be cooled to 50 ℃, measure the metal bucket of packing into and seal stand-by.
(3) glue is in the laying in place
The A group is pressed 1: 5 weight ratio computation weigh with the B component, as A component 20kg, B component 100kg, after stirring, add 24 kilograms of black rubber grains (diameter d is 3mm) after, continuing under the stirring, add stannous octoate-isocaprylic acid gasoline solution (concentration 5%) 7.2kg that accounts for glue weight 6 weight %, pave then on the basis in place, automatically levelling, gel has been solidified into elastomerics.According to the pure urethane micelle of spreading described in the embodiment 1 (3), after normal temperature slaking on the 14th, can use, and measure performance (seeing attached list).
Embodiment 3. high rigidity places are laid and are used glue:
(1) A group and preparation: computation weigh PTG2000 137kg, PTG1000 103kg, N220 206kg; N210 155kg and clorafin 86kg add in the reactor, stir under 80-90 ℃ of temperature; vacuum hydro-extraction 2 hours; fill nitrogen and recover normal pressure, be cooled to 45 ℃ after, add TDI 313kg again; in reaction under nitrogen protection and the 80-85 ℃ of temperature after 2 hours; be cooled to 50 ℃, computation weigh under nitrogen protection, it is stand-by to be filled to the metal bucket sealing.
(2) B component preparation:
In stirring tank, add pigment red iron oxide 35kg, clorafin 380kg, stir, and after the colloidal mill porphyrize becomes mill base, add N220 40kg more successively, N330 100kg, Viscotrol C 40kg continues to add solid material MOCA 55kg, kaolin 110kg while stir, talcum powder 220kg and antioxidant 1010 2kg, anti ultraviolet agent uv-327 2kg, antiseptic-germicide 8 copper quinolinate 2kg are to stirring tank, after stirring, behind colloidal mill porphyrize (to 50 μ m), squeeze in the reactor with toothed gear pump, at 80-90 ℃, vacuum hydro-extraction is after 2.5 hours, be cooled to 50 ℃, measure the metal bucket of packing into and seal stand-by.
(3) glue is in the laying in place:
A component and B component were by 1: 4 computation weigh, as A component 20kg, B component 80kg stirs, and adds isocaprylic acid zinc-isocaprylic acid (2: 1) gasoline solution (concentration 3%) 6kg of total glue weight 5 weight % again, after stirring rapidly, pave on the basis in place, levelling, gel are solidified into elastomerics automatically, after room temperature cure on the 14th, just can use, and measure its performance (seeing attached list).
Embodiment 4, and the high rigidity place is laid and used glue:
(1) A component preparation: claim Ng215 222kg, N220 190kg, N210 143kg and clorafin 119kg, add in the reactor, under 80-90 ℃ of temperature, stir, vacuum hydro-extraction 2 hours, fill nitrogen and recover normal pressure, be cooled to 45 ℃ and add TDI 326kg again, clorafin 380kg, stir, and after the colloidal mill porphyrize becomes mill base, add N220 40kg more successively, N330 120kg, Viscotrol C 30kg, continue to add solid material MOCA 55kg, kaolin 111kg, talcum powder 222kg while stirring, antioxidant 1010 2kg, anti ultraviolet agent uv-3272kg, antiseptic-germicide copper 8-quinolinolate 2kg is to stirring tank, after stirring, behind colloidal mill porphyrize (to 50 μ m), squeeze into reactor with toothed gear pump, at 80-90 ℃, vacuum hydro-extraction is after 2.5 hours, be cooled to 50 ℃, measure the metal bucket of packing into and seal stand-by.
(2) B component preparation:
In stirring tank with pigment chromoxide green 36kg and clorafin 380kg, stir, and after the colloidal mill porphyrize becomes mill base, add N220 40kg more successively, N330 120kg, Viscotrol C 30kg adds solid material MOCA 55kg, kaolin 111kg while stirring, talcum powder 222kg, antioxidant 1010 2kg, anti ultraviolet agent UV-327 2kg and antiseptic-germicide copper 8-quinolinolate 2kg are to stirring tank, after stirring, behind colloidal mill porphyrize (to 50 μ m), squeeze into reactor with toothed gear pump, at 80-90 ℃, vacuum hydro-extraction is after 2.5 hours, be cooled to 50 ℃, measure the metal bucket of packing into and seal stand-by.
(3) glue is in the laying in place:
A component and B component were by 1: 5 computation weigh, as A component 20kg, B component 100kg adds stannous octoate-isocaprylic acid gasoline solution (concentration 5%) 6kg of total glue weight 5 weight %, after stirring rapidly again, pave on the basis, court, automatic levelling, gel is solidified into elastomerics, after normal temperature slaking on the 14th, just can use, and measure its performance (seeing attached list).
Embodiment 5, track and field runway top layer pellet glue:
(1) A component preparation: claim PTG2000 115kg; PTG1000 86kg; N220 172kg N210 129kg and DOP 109kg add in the reactor, stir vacuum hydro-extraction 2 hours under 80-90 ℃ of temperature; fill nitrogen and recover normal pressure; be cooled to 45 ℃ and add MDI-50 389kg again,, react after 2 hours in nitrogen protection and under 80-85 ℃ of temperature; be cooled to 50 ℃, it is close stand-by to measure the metal bucket of packing under nitrogen protection.
(2) B component preparation:
In stirring tank, add pigment red iron oxide 36kg, clorafin 380kg, stir, and after the colloidal mill porphyrize becomes mill base, add N220 40kg more successively, N330 100kg, Viscotrol C 40kg continues to add solid material MOCA 48kg, kaolin 120kg while stir, antioxidant 1010 2kg, anti ultraviolet agent uv-327 2kg, antiseptic-germicide copper 8-quinolinolate 2kg is to stirring tank, after stirring, behind colloidal mill porphyrize (to 50 μ m), squeeze in the reactor with toothed gear pump, under 80-90 ℃ of temperature, vacuum hydro-extraction is after 2.5 hours, be cooled to 50 ℃, measure the metal bucket of packing into and seal stand-by.
(3) make pellet:
A component and B component were in 1: 4 ratio computation weigh, as A component 20kg, B component 80kg, isocaprylic acid zinc-isocaprylic acid gasoline solution (concentration 3%) 8kg that adds total glue weight 8 weight % after stirring again, continue to stir rapidly, pave then on the ground former vinyl film of grass, shakeout (thickness 6-8mm), gel solidification becomes glue, the next day after can be placed on and can on the rubber disintegrating machine, break into particle (general diameter is about 4mm) in 80 ℃ of drying rooms after slaking 3-4 hour on request, and measure its performance (seeing attached list)
Embodiment 6, track and field runway top layer pellet glue:
The preparation of A component; claim Ng215 244kg; N220kg, N210 157kg and clorafin 87kg add in the reactor; under 80-90 ℃ of temperature, stir; after the vacuum hydro-extraction 2 hours, inflated with nitrogen is protected and is cooled to 50 ℃ in reaction under the 80-85 ℃ of temperature after 2 hours; under nitrogen protection, pack into metal bucket sealing of computation weigh is stand-by.
The preparation of B component
In stirring tank, add pigment chromoxide green 36kg, clorafin 380kg stirs, and after the colloidal mill porphyrize becomes mill base, add N220 40kg more successively, N330 100kg, Viscotrol C 40kg continues to add solid material MOCA 40kg while stir, kaolin 120kg, talcum powder 238kg, antioxidant 1010 2kg, anti ultraviolet agent uv327 2kg, antiseptic-germicide copper 8-quinolinolate 2kg is to stirring tank, after stirring, (to 50 μ m) squeeze in the reactor with toothed gear pump behind the colloidal mill porphyrize, under 80-90 ℃ of temperature, after the vacuum hydro-extraction 2.5 hours, be cooled to 50 ℃, measure the metal bucket of packing into and seal stand-by.
(3) make pellet
A component and B component be in 1: 5 ratio computation weigh, as A component 20kg, and B component 100kg.After stirring, stannous octoate-isocaprylic acid (2: 1) gasoline solution (concentration 5%) 6kg that adds total rubber 5 weight % again, pave after stirring rapidly on the polyethylene film on plane earth, shakeout (thickness 6-8mm), gel is solidified into glue, the next day after can be placed in 80 ℃ of drying rooms after slaking 3-4 hour, can break into particle (about general diameter 4mm) on the rubber crusher on request, and measure its performance (seeing attached list).
The mould material The performance test results is laid in the place of subordinate list polyurethane elastomer
| Title | Standard GB/T-14833-93 | Soft place glue | Soft place glue | High rigidity place glue | High rigidity place glue | Pellet glue | Pellet glue |
| The characteristic test project | Polyurethane plastic track and field runway | Embodiment 1 A: B=1: 4 | Embodiment 2 A: B=1: 5 | Embodiment 3 A: B=1: 4 | Embodiment 4 A: B=1: 5 | Embodiment 5 A: B=1: 4 | Embodiment 6 A: B=1: 5 |
| Tensile strength (Mpa) | ??0.7 | ??1.8 | ??1.6 | ??5.4 | ??4.1 | ??3.6 | ??3.2 |
| Elongation at break (%) | ??90 | ??195 | ??170 | ??380 | ??320 | ??320 | ??300 |
| Hardness (Shao Shi A) | ??45-60 | ??52 | ??53 | ??76 | ??75 | ??65 | ??66 |
| Flame retardant resistance (level) | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 | ??1 |
| Elasticity (%) | ??≥20 | ??34 | ??34 | ??35 | ??35 | ??33 | ??33 |
| Compression recovery rate (%) | ??≥95 | ??99 | ??99 | ??99 | ??99 | ??98 | ??98 |
Claims (6)
1, mould material is laid in a kind of place of polyurethane elastomer, it is characterized in that: form through chain extension-crosslinking reaction by giving aggressiveness (A component) and chain extension-crosslinking agent (B component) and catalyzer, wherein: give polyether glycol that aggressiveness (A component) uses and introduced polytetrahydrofuran diol or tetrahydrofuran (THF)-propylene oxide copolymerization glycol and vulcabond TDI (tolylene diisocyanate) or MDI-50 (4.4 '-two isocyanato ditanes and 2.4 '-two isocyanato ditane mixtures) and react and get; And the chainextender that chain extension-crosslinking agent (B component) is used has also added dihydroxyl polyethenoxy ether (N220 molecular weight 2000) except MOCA (3.3 '-two chloro-4.4 '-diaminodiphenylmethane), linking agent is except adding trihydroxy-polyoxytrimethylene ether (N330, molecular weight 3000) also added Viscotrol C outside, softening agent is phthalic acid two 2-ethylhexoates (DOP) or clorafin.
2, mould material is laid in the place of polyurethane elastomer according to claim 1, and it is characterized in that: above-mentioned B component also comprises mixed reinforcing agent kaolin-talcum powder (1: 2), mill base material Fe
2O
3(redness), Cr
2O
3(green), softening agent clorafin, antioxidant 1010, anti UV agent uv-327, antiseptic-germicide copper 8-quinolinolate; Above-mentioned catalyzer is nontoxic isocaprylic acid zinc-isocaprylic acid (2: 1) or any mixed system of stannous octoate-isocaprylic acid (2: 1).
3, mould material is laid in the place of polyurethane elastomer according to claim 1 and 2, it is characterized in that:
The A component is formed (weight percent):
Vulcabond 20-40%
Tetrahydrofuran (THF)-propylene oxide copolymerization glycol
Or polytetrahydrofuran diol 20-30%
Dihydroxyl polyoxytrimethylene ether 30-40%
Softening agent 8-15%
The B component is formed (weight percent):
3.3 '-two chloro-4.4 '-diaminodiphenylmethane 1.5-8%
Dihydroxyl polyoxytrimethylene ether 2-8%
Viscotrol C 2-6%
Trihydroxy-polyoxytrimethylene ether 8-12
Pigment reason 3-5%
Strengthening agent 28-45%
Softening agent 25-40%
Antioxidant 0.1-0.5%
Anti UV agent 0.1-0.5%
Antiseptic-germicide 0.1-0.5%
Wherein, the weight ratio of A component and B component is 1: 3-1: 5.
Catalyst levels is the 1-10 weight % that A component and B component add up to weight.
4, mould material is laid in the place of polyurethane elastomer according to claim 3, it is characterized in that: the black rubber grain that adds system gross weight 20-30 weight % in this material system.
5, the manufacture method of mould material is laid in a kind of place of polyurethane elastomer, it is characterized in that: may further comprise the steps:
1) preparation A component: with tetrahydrofuran (THF)-propylene oxide copolymerization glycol or polytetrahydrofuran diol, dihydroxyl polyoxytrimethylene ether and the softening agent of metering, join in the reactor, evenly stir at 80-90 ℃, vacuum (0.002MPa) dehydration was cooled to 45-50 ℃ after 2 hours, the vulcabond that under normal pressure, adds metering, be warming up to 85-90 ℃ gradually, under nitrogen protection, reacted 2 hours, be cooled to 50 ℃, the sealing of metering dress metal bucket is stand-by under nitrogen protection;
2) preparation B component: the softening agent and the pigment of metering are joined in the reactor, stir and after colloidal mill is worn into mill base, the dihydroxyl polyoxytrimethylene ether that adds metering successively, Viscotrol C, trihydroxy-polyoxytrimethylene ether, at last with chainextender MOCA, strengthening agent kaolin-talcum powder and other solid additive continue to join stirring tank, stir and be ground to below the 50 μ m with mill base through colloidal mill, be driven into reactor with toothed gear pump, be heated with stirring to 80-90 ℃ and vacuumize (0.002Mpa) dehydration 2.5 hours, be cooled to 50 ℃, metering barrelling sealing is standby.
3) the on-the-spot polyurethane elastomer paver of laying in the place: with standby A component, the B component of aforesaid barrelling sealing is 1 by weight: 3-1: 5 computation weighs, stir, the catalyzer (A, B component add up to the 1-10% of weight) that adds calculated weight stirs rapidly, pave immediately in advance on the ready-made smooth basis, under 15-30 ℃ condition, through about 30-60 minute gel, solidify in 24 hours, just can come into operation after the complete slaking on the 14th.
6, the manufacture method of mould material is laid in the place of polyurethane elastomer according to claim 5, it is characterized in that: above-mentioned catalyzer use isocaprylic acid zinc-isocaprylic acid or any mixed system of stannous octoate-isocaprylic acid are dissolved in the solution in the gasoline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03119172 CN1227295C (en) | 2003-03-17 | 2003-03-17 | Low-temperature resistant high-strength universal polyurethane elastomer pouring material for ground laying and preparing method thereof |
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| CN 03119172 CN1227295C (en) | 2003-03-17 | 2003-03-17 | Low-temperature resistant high-strength universal polyurethane elastomer pouring material for ground laying and preparing method thereof |
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| CN1530398A true CN1530398A (en) | 2004-09-22 |
| CN1227295C CN1227295C (en) | 2005-11-16 |
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Cited By (9)
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| CN104262565A (en) * | 2014-10-10 | 2015-01-07 | 湖南优冠运动场材料有限公司 | Material formula of polyurethane micro-porous elastic playground and preparation method of material formula |
| CN104262564A (en) * | 2014-09-05 | 2015-01-07 | 常熟市中腾塑胶有限公司 | Antimicrobial plastic floor board |
| CN105085855A (en) * | 2015-08-04 | 2015-11-25 | 航天材料及工艺研究所 | High-temperature-resistance high-rigidity high-tenacity polyurethane pouring material and application thereof |
| CN105461877A (en) * | 2015-12-21 | 2016-04-06 | 中国科学院山西煤炭化学研究所 | Synthetic method of thermocuring polyurethane elastomer composite material for sealing materials |
| CN106366284A (en) * | 2016-09-12 | 2017-02-01 | 万华化学集团股份有限公司 | Polyurethane elastomer composition, and preparation method and application thereof |
| CN108034398A (en) * | 2017-12-15 | 2018-05-15 | 阜阳市龙建包装材料有限公司 | A kind of antibacterial and mouldproof polyurethane bicomponent compound adhesive |
| CN108504081A (en) * | 2018-04-17 | 2018-09-07 | 三河市中益明晟科技有限公司 | A kind of noctilucence Elastic plastic-rubber runway, in vigorous strides road and preparation method thereof |
| CN108503790A (en) * | 2018-03-09 | 2018-09-07 | 旭川化学（昆山）有限公司 | A kind of dual-component polyurethane mold glue and preparation method thereof |
| CN109912777A (en) * | 2017-12-13 | 2019-06-21 | 上海优迈材料科技有限公司 | A kind of tear-proof floor-cleaning machine water suction adhesive tape and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104262564A (en) * | 2014-09-05 | 2015-01-07 | 常熟市中腾塑胶有限公司 | Antimicrobial plastic floor board |
| CN104262565A (en) * | 2014-10-10 | 2015-01-07 | 湖南优冠运动场材料有限公司 | Material formula of polyurethane micro-porous elastic playground and preparation method of material formula |
| CN104262565B (en) * | 2014-10-10 | 2016-10-12 | 湖南优冠运动场材料有限公司 | A kind of microporous polyurethane elastic movement field material prescription and preparation method thereof |
| CN105085855B (en) * | 2015-08-04 | 2018-12-21 | 航天材料及工艺研究所 | A kind of high temperature resistant high hardness high toughness polyurethane casting material and its application |
| CN105085855A (en) * | 2015-08-04 | 2015-11-25 | 航天材料及工艺研究所 | High-temperature-resistance high-rigidity high-tenacity polyurethane pouring material and application thereof |
| CN105461877A (en) * | 2015-12-21 | 2016-04-06 | 中国科学院山西煤炭化学研究所 | Synthetic method of thermocuring polyurethane elastomer composite material for sealing materials |
| CN106366284A (en) * | 2016-09-12 | 2017-02-01 | 万华化学集团股份有限公司 | Polyurethane elastomer composition, and preparation method and application thereof |
| CN106366284B (en) * | 2016-09-12 | 2020-03-03 | 万华化学集团股份有限公司 | Polyurethane elastomer composite material and preparation method thereof, and preparation and application of polyurethane elastomer |
| CN109912777A (en) * | 2017-12-13 | 2019-06-21 | 上海优迈材料科技有限公司 | A kind of tear-proof floor-cleaning machine water suction adhesive tape and preparation method thereof |
| CN108034398A (en) * | 2017-12-15 | 2018-05-15 | 阜阳市龙建包装材料有限公司 | A kind of antibacterial and mouldproof polyurethane bicomponent compound adhesive |
| CN108503790A (en) * | 2018-03-09 | 2018-09-07 | 旭川化学（昆山）有限公司 | A kind of dual-component polyurethane mold glue and preparation method thereof |
| CN108504081A (en) * | 2018-04-17 | 2018-09-07 | 三河市中益明晟科技有限公司 | A kind of noctilucence Elastic plastic-rubber runway, in vigorous strides road and preparation method thereof |
| CN108504081B (en) * | 2018-04-17 | 2020-09-01 | 三河市中益明晟科技有限公司 | Luminous elastic plastic track, walking path and preparation method thereof |
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| CN1227295C (en) | 2005-11-16 |
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