CN1526854A - Process for producing non-orientation electromagnetic steel plate and used insulation film forming agent - Google Patents
Process for producing non-orientation electromagnetic steel plate and used insulation film forming agent Download PDFInfo
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- CN1526854A CN1526854A CNA2003101242599A CN200310124259A CN1526854A CN 1526854 A CN1526854 A CN 1526854A CN A2003101242599 A CNA2003101242599 A CN A2003101242599A CN 200310124259 A CN200310124259 A CN 200310124259A CN 1526854 A CN1526854 A CN 1526854A
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Abstract
The present invention provides one kind of insulating film forming agent for coating non-oriented electromagnetic steel plate, which, after annealing to eliminate stress, has high gap coefficient, excellent punching and cutting process, good film adhering performance and sliding performance, and the preparation process of the non-oriented electromagnetic steel plate. The said insulating film forming agent has metal phosphate and organic resin as main components, as well as processing liquid of water soluble organic compound with boiling point or sublimation temperature over 100 deg.c, with the added quantity of the organic compound being 5-50 weight portions to 100 weight portions of the metal phosphate.
Description
(the present invention be submitted on December 17th, 1998, application number is 98125578.7, denomination of invention is divided an application for the application of " non-orientation type electromagnetic steel board, its manufacture method and used isolation film form agent ".)
Technical field
The present invention relates to a kind of insulating film that is used to have the non-orientation type electromagnetic steel board of high percent break and form agent, it has good insulating film adhesive property and die-cutting performance, and after stress relief annealing, have good sliding capability, insulating film cohesiveness and erosion resistance, also relate to the method that forms agent coated steel plates substrate preparation non-orientation type electromagnetic steel board with described insulating film.
Background technology
When being used for the laminated core employing non-orientation type electromagnetic steel board manufacturing of motor, transformer etc., unit core usually with non-orientation type electromagnetic steel board through shear or die-cut after stacked preparation, the unit core of lamination is fixed through bolt, riveted joint, welding, bonding or similar operation.The laminated core coils that obtains is thus twined combination or is similarly handled, and finally is assembled into motor or transformer.
The general insulating film that forms on non-orientation type electromagnetic steel board.Because therefore many performances of steel plate such as the performance that weldability, die-cut property and erosion resistance etc. depend on insulating film to a great extent importantly not only should have insulating property for insulating film but also should have excellent film properties.
Hitherto known non-orientation type electromagnetic steel board insulating film has inorganic, organic and inorganic-organic mixed insulation.Yet, to compare with the steel plate that applies organic insulating film or inorganic-organic mixed insulating film, the steel plate die-cutting performance of coating inorganic insulating film is very poor.Compare with the steel plate of coating inorganic insulating film or inorganic-organic mix mode insulating film, the steel plate that applies organic insulating film is very poor in stress relief annealing caudacoria cohesiveness and erosion resistance.Therefore, the insulation of inorganic insulating membrane and organic mix mode is difficult to use.
To inorganic-organic mixed insulating film, people have carried out deep research to solve inorganic and problem organic insulating film.Japanese Patent (bulletin) No.50-15013 proposes a kind of method for preparing insulating film on non-orientation type electromagnetic steel board, make final steel plate have film properties such as high percent break, good film cohesiveness and die-cut property, this method comprises with the treatment solution that contains dichromate with as vinyl-acetic resin, butadiene-styrene copolymer or acrylic resin and prepares insulating film as the organic resin emulsion of main ingredient.
Yet, when using dichromate see that chromium cpd is as the composition of film in the inorganic-organic mixed insulating film of traditional non-orientation type electromagnetic steel board.Therefore, all be faced with serious environmental problem, thereby need a kind of technology that does not contain the processing insulating film of chromium cpd of exploitation the user of this non-orientation type electromagnetic steel board production technique or this non-orientation type electromagnetic steel board.
Therefore, Japanese patent laid-open No.6-330338 discloses following treatment process, this treatment process comprise will have the phosphoric acid salt of specific composition mixed with the organic resin emulsion that contains the specified particle diameter ratio, with resulting treatment solution coated steel plates and toast steel plate.This method is used a kind of treatment solution that does not contain chromium cpd, and the film properties that the steel plate that adopts this method to make shows can be compared with the tradition insulation that contains chromium cpd, and can keep excellent sliding capability after stress relief annealing.
Yet the disclosed this technology of Japanese patent laid-open No.6-330338 has found to exist following problems.Organic resin emulsion often condenses in treatment solution or in coating and the roasting procedure.Consequently, the part that does not contain organic resin in the insulating film and the partial confounding that contains organic resin reduce the die-cutting performance of steel plate together.
In the time will on non-orientation type electromagnetic steel board, forming insulating film, on steel plate, apply insulating film treatment solution and baking, continuous annealing afterwards usually.Therefore, can form the insulating film of film properties excellence long-term and stably and the cohesion of organic resin not take place, this industrial be crucial.
In addition, because many motors and transformer are complex-shaped, some die-cut condition partly departs from optimum value sometimes as cleaning.Have been found that and use the die-cut in this case property of the disclosed technology of Japanese patent laid-open No.6-330338 to reduce.
As result to these problem further investigations, the inventor has been found that, even still have the best method of the non-orientation type electromagnetic steel board of excellent die-cut property with phosphoric acid salt and organic resin during not so good and complicated die-cut shapes in die-cut condition as main ingredient as the preparation insulating film, be to be distributed with organic compounds by disperse in traditional organic resin that adds the film composition and inorganic components phosphoric acid salt, make the organic carbon content on insulating film surface increase, thereby improved die-cut property.
Summary of the invention
The present invention just is being based on above-mentioned discovery.Main points of the present invention are as described below.
First purpose of the present invention is to provide a kind of non-orientation type electromagnetic steel board with the good insulating film of film properties, as main ingredient, the 1S peak intensity of its C (carbon) was 4～20 times of 2S peak intensity of P to described insulating film when this insulating film was tested with the light electron spectroscopy analysis with metal phosphate and organic resin.
Second purpose of the present invention is to provide a kind of preparation to have the method for the non-orientation type electromagnetic steel board of the good insulating film of film properties, comprise that forming agent with insulating film applies the non-orientation type electromagnetic steel board matrix, it is as main ingredient with metal phosphate and organic resin that this insulating film forms agent, further comprise the treatment solution that boiling point or sublimation point are at least 100 ℃ water-soluble organic compounds, the addition of this water-soluble organic compounds is the organic compound of the metal phosphate of 100 weight parts than 5～50 weight parts, and the steel plate that coating is finished is 200 to 400 ℃ of bakings.
The 3rd purpose of the present invention is to provide a kind of insulating film that is used to prepare the non-orientation type electromagnetic steel board with the good insulating film of film properties to form agent, described formation agent be with metal phosphate and organic resin as main ingredient, further comprise the treatment solution that boiling point or sublimation point temperature are at least 100 ℃ water-soluble organic compounds.
Embodiment
Below will be described in detail the present invention.
As everyone knows, the die-cut property of non-orientation type electromagnetic steel board is subjected to the very big influence that insulating film is formed.Non-orientation type electromagnetic steel board with organic insulating film demonstrates good die-cut property, and the non-orientation type electromagnetic steel board with the mixed organic and inorganic mixed type insulating film of chromic salt and organic resin also has good die-cut property.Therefore, conjecture thinks that the die-cut property of non-orientation type electromagnetic steel board is that slip effect owing to organic resin improves.Yet, have the die-cut property that the non-orientation type electromagnetic steel board of the insulating film that consists of phosphoric acid salt and organic resin miscellany shows, do not bring up to and the identical degree of the die-cut property of the non-orientation type electromagnetic steel board with the insulating film that consists of chromic salt and organic resin.
On the other hand, containing phosphoric acid salt and organic resin measures as the C content available light electron spectroscopy analysis on the insulating film surface of main ingredient.The present invention finds, uses this assay, and when the 1S of carbon peak intensity was 4 to 20 times of phosphorus 2S peak intensity, the die-cutting performance of non-orientation type electromagnetic steel board was improved.And, the inventor finds, use phosphoric acid salt and organic resin to form agent as insulating film as the treatment solution of main ingredient and the miscellany of water-soluble organic compounds, the ratio of carbon 1S peak intensity and phosphorus 2S peak intensity is increased, and the die-cut property of this non-orientation type electromagnetic steel board is improved significantly.
Although it be unclear that the details that this water-soluble organic compounds works, but infer and think that this compound has improved the stability of organic resin molecule in treatment solution, and after baking, be retained in the slip effect that has strengthened film in the film.
Used mineral compound among explained later the present invention.Used metal phosphate comprises aluminum phosphate, calcium phosphate, zinc phosphate and trimagnesium phosphate among the present invention.Metal phosphate plays a part joint compound.Metal phosphate generally is the reaction product of metal oxide and phosphoric acid.The performance of the film of Xing Chenging changes with the molecular ratio of metal oxide and phosphoric acid thus.In the present invention when with Al during as metal, the Al that is adopted
2O
3/ H
3PO
4Molecular ratio is 0.13 to 0.20.When molecular ratio was lower than 0.13, free phosphoric acid increased, and the water-absorbent of insulating film increases inevitably.On the other hand, when molecular ratio surpassed 0.20, the stability of aluminum phosphate itself reduced, and aluminum phosphate unavoidably can precipitate in the solution.Similarly, when using calcium phosphate, zinc phosphate or trimagnesium phosphate, the molecular ratio of its metal oxide/phosphoric acid is limited between 0.40 to 0.60.
In the present invention, be selected from silica gel, boric acid or boratory one or both materials if need then can use.When adding this class material, film properties improves, for example, the film densification, surface gloss increases, or the like.
Below organic resin used among the present invention is described.Used organic resin comprises acrylic resin, polystyrene, vinyl-acetic resin, Resins, epoxy, urethane, nylon, resol, trimeric cyanamide (melamine), silicone resin, polypropylene, polyethylene among the present invention.These resins a kind of or at least two kinds can be used for the present invention.Particle size to organic resin emulsion does not have special restriction.But grain diameter preferably reaches 1.0 μ m when considering treatment solution stable.
Organic resin is the phosphoric acid salt of the organic resin composition of 5 to 300 weight parts than 100 weight parts with phosphatic preferred mixed ratio.When organic resin composition was lower than 5 weight parts, film was white in color, and tarnishes.When organic resin composition was higher than 300 weight parts, film may peel off after stress relief annealing.
Used water-soluble organic compounds is a kind of water miscible organism such as ethanol, ester class, ketone, ethers, carboxylic acid or sugar among the present invention, and it is solvable in inorganics such as phosphatic solution.When non-orientation type electromagnetic steel board mixed the miscellany coating that obtains and drying with the treatment solution that comprises phosphoric acid salt and organic resin with water-soluble organic compounds, water-soluble organic compounds just was included in inorganic component such as the phosphoric acid salt.And water-soluble organic compounds is to be called unlimited soluble organic compound in the water in nature in the present invention, but the organic compound that has relative higher solubility in water also can be used as organic compound described herein.The concrete instance of spendable this water-soluble organic compounds comprises: alcohols such as butanols and propyl alcohol, polyvalent alcohol such as propylene glycol, glycerol, ethylene glycol and triethyl ethylene glycol, ketone such as methyl ethyl ketone and diethyl ketone, carboxylic acid such as acetic acid and propionic acid, material such as maleic acid sodium with metal carboxylate structure, carbohydrate such as sucrose, cellosolve such as methylcyclohexane and ethylene glycol butyl ether, Trivalin SF such as diethyl ethylene glycol monomethyl ether and diethyl ethylene glycol diethyl ether, ethers such as tetraethyleneglycol dimethyl ether and 1,4-dioxy hexane, ester class such as glycol monomethyl methyl ether carboxylic acid and sorbyl alcohol or pyrogallol.
Since among the present invention used water-soluble organic compounds apply and baking after must be retained in the film, the boiling point of this liquid water soluble organic compound or the sublimation point of solid compounds must be higher than 100 ℃ of the boiling points of water.Usually, its boiling point or sublimation point should be 200 ℃ at least.
Because as described later, the mixed volume of water-soluble organic compounds is limited in phosphate ratio 5～50 weight part organic compound of 100 weight parts.When content is lower than 5 weight parts, be difficult to obtain the effect of water-soluble organic compounds; When content 〉=50 weight parts, film becomes muddiness and is white in color, and is difficult to obtain glossiness film surface.
In the present invention, the 1S peak intensity of the carbon that the photoelectron spectrum analysis is recorded owing to following reason is defined as 4 to 20 times of phosphorus 2S peak intensity.This is because when the 1S peak intensity of the carbon that demonstrates when film was lower than 4 times of phosphorus 2S peak intensity, non-orientation type electromagnetic steel board was difficult to guarantee enough die-cutting performances; When the 1S peak intensity of the carbon that shows when film was higher than 20 times of phosphorus 2S peak intensity, the gloss of film was very poor.This technology of employing adopt the photoelectron spectrum analysis to be herein owing to can be measured the constituent content that exists in the insulating film surface.
Thickness is that the foil of the non-orientation type electromagnetic steel board of 0.5mm is used the treatment solution shown in the rubber rollers coating equipment coating table 1 after finishing the anneal of traditional technology, and in 300 ℃ (plate temperatures) baking down, coated weight is 1.2g/m
2Cut sample from foil, sample segment carries out 2 hours stress relief annealing of 750 ℃ of insulations in the nitrogen gas stream.Then film properties is tested and assessed, the gained result is as shown in table 2.
Table 1
| Treatment solution | Inorganic component (parts by weight) | Organic resin component (parts by weight) | Water soluble organic substance |
| Embodiment 1 | Aluminum phosphate (100) | Styrene-propene acid (50) | Glycerol (10) |
| Embodiment 2 | Aluminum phosphate (100) | Styrene-propene acid (30) | Sorbyl alcohol (6) |
| Embodiment 3 | Aluminum phosphate (100) | Vinylformic acid-Resins, epoxy (25) | Glycerol (40) |
| Embodiment 4 | Trimagnesium phosphate (100) | Vinylformic acid-phenol (30) | Ethylene glycol (20) |
| Embodiment 5 | Aluminum phosphate (100) | Vinylformic acid-Resins, epoxy (75) | 1,4-dioxane (15) |
| Embodiment 6 | Trimagnesium phosphate (100) | Vinylformic acid-vinyl acetate between to for plastic (30) | Ethylene glycol butyl ether (20) |
| Embodiment 7 | Trimagnesium phosphate (100) | Vinylformic acid-phenol (30) | Diethyl ethylene glycol monomethyl ether (40) |
| Comparative example 1 | Aluminum phosphate (100) | Styrene-propene acid (30) | Ethylene glycol (1) |
| Comparative example 2 | Aluminum phosphate (100) | Resins, epoxy (30) | Ethylene glycol (80) |
| Comparative example 3 | Trimagnesium phosphate (100) | Styrene-propene acid (30) | Ethyl hexanol (10) |
| Conventional case 1 | Aluminum phosphate (100) | Vinylbenzene (30) | Do not add |
| Conventional case 2 | Magnesium chromate (100) boric acid (20) | Vinylformic acid-vinylbenzene-vinyl acetate between to for plastic (20) | Ethylene glycol (2) |
Remarks: conventional case 2 is that its film is with the example of magnesium chromate as the common insulating film of the magnetic steel plate of main ingredient.
Table 2
| Treatment solution | Peak intensity ratio during photoelectron spectrum is analyzed | Percent break (%) | Adhesive property *a | Sliding capability (%) *b | Die-cutting performance (* 10 4Inferior) *c |
| Embodiment 1 | ????5.16 | ????99.6 | ???? | ????100 | ????＞100 |
| Embodiment 2 | ????6.57 | ????99.5 | ???? | ????100 | ????＞100 |
| Embodiment 3 | ????7.59 | ????99.6 | ???? | ????100 | ????＞100 |
| Embodiment 4 | ????7.20 | ????99.7 | ???? | ????100 | ????＞100 |
| Embodiment 5 | ????8.80 | ????99.6 | ???? | ????100 | ????＞100 |
| Embodiment 6 | ????11.00 | ????99.5 | ???? | ????100 | ????＞100 |
| Embodiment 7 | ????6.19 | ????99.6 | ???? | ????100 | ????＞100 |
| Comparative example 1 | ????2.13 | ????99.6 | ???? | ????100 | ??????12 |
| Comparative example 2 | ????21.63 | ????99.5 | ????△ | ????100 | ??????100 |
| Comparative example 3 | ????2.95 | ????99.4 | ???? | ????100 | ??????45 |
| Conventional case 1 | ????1.30 | ????99.4 | ???? | ????100 | ??????8 |
| Conventional case 2 | ????- ** | ????99.6 | ???? | ????20 | ????＞100 |
Remarks:
*A: with the antistrip performance of viscous glass paper tape evaluation; : inviscid; Zero:
Viscosity is to a certain degree arranged; △: viscosity is big; *: peel off
*B: the born ratio (acceptance ratio) in the test of sliding
*C: with the wide EI iron core of 66mm formula punching block, die-cut limit wing height reaches 6 μ m
The time die-cut numeration.
*: the phosphorated tradition does not contain the chromic acid film.
In addition, in the photoelectron spectrum analytical test, phosphorus is tested with ESCA-K1 (trade(brand)name is made by Tianjin, island company) near the 1S peak of 285eV near 2S peak and the carbon of 189eV.Testing sample cleans the back test with distilled water and acetone.
In addition, measure sliding capability with the sliding performance test apparatus of surface tears of industrial application.Test condition is: steel ball size 10mm, load 100gf, steel ball translational speed 20mm/s.When finishing 10 week friction circulation times, with following standard evaluation frictional behaviour: do not form on the sample defective or peel off qualified; What formation defective or ball were stuck on the sample is defective.
Can find out the sample that from table 2 non-orientation type electromagnetic steel board that forms insulating film demonstrates high percent break, good die-cut property, fabulous film cohesiveness and outstanding sliding capability.
According to the present invention, can obtain having with the insulating film that does not contain chromium and handle the insulating film non-orientation type electromagnetic steel board that forms, this steel plate has high percent break, good die-cutting performance, film adhesive property and sliding capability.
Claims (2)
1. method for preparing non-orientation type electromagnetic steel board, this electro-magnetic steel plate has the good insulating film of film properties, comprises the steps:
Form agent with insulating film and apply non-orientation type electromagnetic steel board, it is as main ingredient, also comprise the treatment solution of water-soluble organic compounds with metal phosphate and organic resin that this insulating film forms agent, the boiling point of this water-soluble organic compounds or sublimation point temperature are 100 ℃ at least, and its addition is that 100 weight part metal phosphates are than 5～50 weight part organic compound; And
Steel plate after 200～400 ℃ of bakings apply.
2. insulating film formation agent that is used to prepare non-orientation type electromagnetic steel board, this electro-magnetic steel plate has the good insulating film of film properties, wherein: it is as main ingredient, also comprise the treatment solution of water-soluble organic compounds with metal phosphate and organic resin that described insulating film forms agent, the boiling point of this organic compound or sublimation point temperature are 100 ℃ at least, and its addition is that the metal phosphate of 100 weight parts is than 5～50 weight part organic compound.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101242599A CN100465337C (en) | 1998-12-17 | 1998-12-17 | Process for producing non-orientation electromagnetic steel plate and used insulation film forming agent |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2003101242599A CN100465337C (en) | 1998-12-17 | 1998-12-17 | Process for producing non-orientation electromagnetic steel plate and used insulation film forming agent |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB981255787A Division CN1177951C (en) | 1998-11-23 | 1998-12-17 | Non-orientation type electromagnetic steel board, its preparation method used isolation film formation agent |
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| Publication Number | Publication Date |
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| CN1526854A true CN1526854A (en) | 2004-09-08 |
| CN100465337C CN100465337C (en) | 2009-03-04 |
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| CNB2003101242599A Expired - Lifetime CN100465337C (en) | 1998-12-17 | 1998-12-17 | Process for producing non-orientation electromagnetic steel plate and used insulation film forming agent |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI398351B (en) * | 2008-11-27 | 2013-06-11 | Nippon Steel & Sumitomo Metal Corp | Electromagnetic steel plate and manufacturing method thereof |
| CN114423885A (en) * | 2019-09-20 | 2022-04-29 | 日本制铁株式会社 | Non-oriented electrical steel sheet and surface treatment agent for non-oriented electrical steel sheet |
| CN115210828A (en) * | 2020-06-17 | 2022-10-18 | 日本制铁株式会社 | Electromagnetic steel sheet, laminated iron core, and method for manufacturing laminated iron core |
| CN117157426A (en) * | 2021-03-30 | 2023-12-01 | 日本制铁株式会社 | Non-oriented electromagnetic steel sheet and method for producing same |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| WO2011033943A1 (en) * | 2009-09-15 | 2011-03-24 | 新日本製鐵株式会社 | Electromagnetic steel sheet and method for producing same |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS578855A (en) * | 1980-06-18 | 1982-01-18 | Fujitsu Ltd | Interruption processing system |
| JP2728836B2 (en) * | 1993-02-08 | 1998-03-18 | 川崎製鉄株式会社 | Electrical steel sheet with electrical insulation coating with excellent weldability |
| KR0129687B1 (en) * | 1993-05-21 | 1998-04-16 | 다나까 미노루 | Treating agent for producing an insulating film on a non-oriented elecrical steel sheet |
| JP2944849B2 (en) * | 1993-05-21 | 1999-09-06 | 新日本製鐵株式会社 | Method for producing non-oriented electrical steel sheet with extremely good coating properties |
| JPH08260052A (en) * | 1995-03-27 | 1996-10-08 | Nippon Steel Corp | Production of high magnetic flux density nonoriented silicon steel sheet |
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1998
- 1998-12-17 CN CNB2003101242599A patent/CN100465337C/en not_active Expired - Lifetime
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI398351B (en) * | 2008-11-27 | 2013-06-11 | Nippon Steel & Sumitomo Metal Corp | Electromagnetic steel plate and manufacturing method thereof |
| CN114423885A (en) * | 2019-09-20 | 2022-04-29 | 日本制铁株式会社 | Non-oriented electrical steel sheet and surface treatment agent for non-oriented electrical steel sheet |
| CN115210828A (en) * | 2020-06-17 | 2022-10-18 | 日本制铁株式会社 | Electromagnetic steel sheet, laminated iron core, and method for manufacturing laminated iron core |
| US11749431B2 (en) | 2020-06-17 | 2023-09-05 | Nippon Steel Corporation | Electrical steel sheet, laminated core, and laminated core manufacturing method |
| CN117157426A (en) * | 2021-03-30 | 2023-12-01 | 日本制铁株式会社 | Non-oriented electromagnetic steel sheet and method for producing same |
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