CN1526804A - Crystalline jelly wax and its production process - Google Patents
Crystalline jelly wax and its production process Download PDFInfo
- Publication number
- CN1526804A CN1526804A CNA031600204A CN03160020A CN1526804A CN 1526804 A CN1526804 A CN 1526804A CN A031600204 A CNA031600204 A CN A031600204A CN 03160020 A CN03160020 A CN 03160020A CN 1526804 A CN1526804 A CN 1526804A
- Authority
- CN
- China
- Prior art keywords
- butadiene rubber
- add
- styrene butadiene
- thermoplastic styrene
- wax
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 235000015110 jellies Nutrition 0.000 title claims abstract description 23
- 239000008274 jelly Substances 0.000 title claims abstract description 23
- 238000004519 manufacturing process Methods 0.000 title claims description 12
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 15
- 229920001169 thermoplastic Polymers 0.000 claims abstract description 14
- 239000004416 thermosoftening plastic Substances 0.000 claims abstract description 14
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims abstract description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000002425 crystallisation Methods 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 13
- 230000008025 crystallization Effects 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 238000001816 cooling Methods 0.000 claims description 4
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000049 pigment Substances 0.000 claims description 3
- 241000533950 Leucojum Species 0.000 abstract description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 abstract 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 abstract 1
- 235000021360 Myristic acid Nutrition 0.000 abstract 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 12
- 238000002485 combustion reaction Methods 0.000 description 4
- 241000549173 Celastrus scandens Species 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The crystalline jelly candle is compounded with white oil and thermoplastic styrene-butadiene rubber mixed fully and added myristic acid, and the styrene-butadiene rubber is compounded with styrene in 70wt% and butadiene in 30wt%. The addition of proper amount of myristic acid makes the jelly candle generate crystalline matter possessing excellent artistic effect of representing snowflake and being beautiful.
Description
Affiliated technical field
The invention belongs to wax work; Be specifically related to manufacture method with novel crystallization jelly wax material and this wax work material.
Background technology
It is disclosed like that existing jelly wax is gone into Chinese patent ZL00111030.6, and the jelly wax of producing with proportioning is transparent in this way.There is following shortcoming in it:
1, because this jelly wax mainly is to make the artwork candle to use, the apparent variation of candle is less again for this transparent jelly wax, can not produce various crystallization effects such as flakes;
2, the Actual combustion poor effect of this jelly wax influences the practical effect of jelly wax.
So the not enough people of above-mentioned jelly wax aspect need to be resolved hurrily.
Summary of the invention
The objective of the invention is provides a kind of crystallization jelly wax that can produce the flakes crystallization effect for addressing the above problem; Another object of the present invention provides a kind of manufacture method of making above-mentioned macromolecule modified clear gel wax.
For achieving the above object, the present invention is a kind of crystallization jelly wax of realizing like this, and is formulated by following material, and every 88-85 gram white oil adds 6.7-6.4 gram thermoplastic styrene butadiene rubber, treats to add 5-8 gram TETRADECONIC ACID behind the thorough mixing; Described thermoplastic styrene butadiene rubber is to join divinyl by 70 parts of vinylbenzene to make for 30 parts.
A kind of manufacture method of making the crystallization jelly wax of claim 1 is characterized in that: carries out as follows,
A. an amount of white oil is poured in the container into heating;
B. add thermoplastic styrene butadiene rubber by the proportion relation of claim 1 then, temperature stirs between 105～120 ℃, wait thermoplastic styrene butadiene rubber and white oil thorough mixing after, stop stirring;
C. reduce the temperature between 100～110 ℃, the proportion relation adding TETRADECONIC ACID by claim 1 stirs, and allows it fully dissolve;
D. above-mentioned wax liquid is poured into loose tool 90～100 ℃ the time;
E. add wick;
F. crystallisation by cooling.
After finishing, above-mentioned steps C adds corresponding pigment or corresponding essence.
Advantage and effect
Add an amount of TETRADECONIC ACID in the material that the present invention produces after original white oil and thermoplastic styrene butadiene rubber hybrid reaction; Make to produce crystalline material in the jelly wax of final generation, be good at very much showing technological effects such as snowflake, and very attractive in appearance, will greatly enrich the kind and the manifestation mode of technology jelly wax like this; Simultaneously in jelly wax, add TETRADECONIC ACID, can improve sufficient combustion and the combustion efficacy of jelly wax in combustion processes.And can not change little, the softer characteristic of the original shrinkage rates of jelly wax; This method processing is easy simultaneously.
Specific embodiment
Embodiment 1:
Manufacture method is carried out as follows,
A. white oil is extracted in the reflection jar heating;
B. per then 85 gram white oils add 6.7 gram thermoplastic styrene butadiene rubbers, and its commercial code is the KratonG1650 type, relative density 0.91, hardness 72; Temperature stirs at 120 ℃, waits (2～4 hours) behind thermoplastic styrene butadiene rubber and the white oil thorough mixing, stops to stir;
C. reduce the temperature between 100 ℃, per then 88 gram white oils add 5 gram TETRADECONIC ACID, stir;
D. above-mentioned wax liquid is poured into loose tool 90 ℃ the time;
E. add wick;
F. crystallisation by cooling.
Embodiment 2:
Manufacture method is carried out as follows,
A. white oil is extracted in the reflection jar heating;
B. per then 88 gram white oils add 6.4 gram thermoplastic styrene butadiene rubbers, and its commercial code is the KratonG1650 type, relative density 0.91, hardness 72; Temperature stirs at 105 ℃, waits (2～4 hours) behind thermoplastic styrene butadiene rubber and the white oil thorough mixing, stops to stir;
C. reduce the temperature between 110 ℃, per then 88 gram white oils add 8 gram TETRADECONIC ACID, stir; And add an amount of spices and pigment and mix and stir;
D. above-mentioned wax liquid is poured into loose tool 100 ℃ the time;
E. add wick;
F. crystallisation by cooling.
Claims (3)
1. crystallization jelly wax is characterized in that: formulated by following material, every 88-85 gram white oil adds 6.7-6.4 gram thermoplastic styrene butadiene rubber, treats to add 5-8 gram TETRADECONIC ACID behind the thorough mixing; Described thermoplastic styrene butadiene rubber is to join divinyl by 70 parts of vinylbenzene to make for 30 parts.
2. manufacture method of making the crystallization jelly wax of claim 1 is characterized in that: carries out as follows,
A. white oil is extracted in the reflection jar heating;
B. add thermoplastic styrene butadiene rubber by the proportion relation of claim 1 then, temperature stirs between 105～120 ℃, wait thermoplastic styrene butadiene rubber and white oil thorough mixing after, stop stirring;
C. reduce the temperature between 100～110 ℃, the proportion relation adding TETRADECONIC ACID by claim 1 stirs;
D. above-mentioned wax liquid is poured into loose tool 90～100 ℃ the time;
E. add wick;
F. crystallisation by cooling.
3. the manufacture method of crystallization jelly wax according to claim 2 is characterized in that: add corresponding pigment or corresponding essence after above-mentioned steps C finishes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03160020 CN1238483C (en) | 2003-09-22 | 2003-09-22 | Crystalline jelly wax and its production process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03160020 CN1238483C (en) | 2003-09-22 | 2003-09-22 | Crystalline jelly wax and its production process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1526804A true CN1526804A (en) | 2004-09-08 |
| CN1238483C CN1238483C (en) | 2006-01-25 |
Family
ID=34287357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03160020 Expired - Fee Related CN1238483C (en) | 2003-09-22 | 2003-09-22 | Crystalline jelly wax and its production process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1238483C (en) |
-
2003
- 2003-09-22 CN CN 03160020 patent/CN1238483C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1238483C (en) | 2006-01-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20060125 Termination date: 20160922 |