CN1513929A - Nano-fluoro carbon aircraft paint and its preparation method - Google Patents
Nano-fluoro carbon aircraft paint and its preparation method Download PDFInfo
- Publication number
- CN1513929A CN1513929A CNA031114881A CN03111488A CN1513929A CN 1513929 A CN1513929 A CN 1513929A CN A031114881 A CNA031114881 A CN A031114881A CN 03111488 A CN03111488 A CN 03111488A CN 1513929 A CN1513929 A CN 1513929A
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- CN
- China
- Prior art keywords
- nano
- fluorine carbon
- synthetic resin
- aeroplane dope
- solvent
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- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 14
- 239000003973 paint Substances 0.000 title abstract description 10
- 239000000057 synthetic resin Substances 0.000 claims abstract description 39
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 39
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 21
- 239000002002 slurry Substances 0.000 claims abstract description 20
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000000049 pigment Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 238000000576 coating method Methods 0.000 claims description 37
- 239000011248 coating agent Substances 0.000 claims description 35
- 239000011737 fluorine Substances 0.000 claims description 32
- 229910052731 fluorine Inorganic materials 0.000 claims description 32
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 31
- 229910052799 carbon Inorganic materials 0.000 claims description 29
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 21
- 239000011347 resin Substances 0.000 claims description 20
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 15
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 13
- 239000003921 oil Substances 0.000 claims description 11
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 claims description 9
- -1 octane-iso Substances 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000000178 monomer Substances 0.000 claims description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 7
- 229920002554 vinyl polymer Polymers 0.000 claims description 7
- GXDHCNNESPLIKD-UHFFFAOYSA-N 2-methylhexane Natural products CCCCC(C)C GXDHCNNESPLIKD-UHFFFAOYSA-N 0.000 claims description 6
- 239000005995 Aluminium silicate Substances 0.000 claims description 6
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical group O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 claims description 6
- HJOVHMDZYOCNQW-UHFFFAOYSA-N isophorone Chemical compound CC1=CC(=O)CC(C)(C)C1 HJOVHMDZYOCNQW-UHFFFAOYSA-N 0.000 claims description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 6
- 235000010215 titanium dioxide Nutrition 0.000 claims description 6
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims description 6
- 229910000165 zinc phosphate Inorganic materials 0.000 claims description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 5
- UOCLXMDMGBRAIB-UHFFFAOYSA-N 1,1,1-trichloroethane Chemical compound CC(Cl)(Cl)Cl UOCLXMDMGBRAIB-UHFFFAOYSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 claims description 4
- ZCZSIDMEHXZRLG-UHFFFAOYSA-N Heptyl acetate Chemical compound CCCCCCCOC(C)=O ZCZSIDMEHXZRLG-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- RWGFKTVRMDUZSP-UHFFFAOYSA-N cumene Chemical compound CC(C)C1=CC=CC=C1 RWGFKTVRMDUZSP-UHFFFAOYSA-N 0.000 claims description 4
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 claims description 4
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 3
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- GJRQTCIYDGXPES-UHFFFAOYSA-N iso-butyl acetate Natural products CC(C)COC(C)=O GJRQTCIYDGXPES-UHFFFAOYSA-N 0.000 claims description 3
- FGKJLKRYENPLQH-UHFFFAOYSA-M isocaproate Chemical compound CC(C)CCC([O-])=O FGKJLKRYENPLQH-UHFFFAOYSA-M 0.000 claims description 3
- OQAGVSWESNCJJT-UHFFFAOYSA-N isovaleric acid methyl ester Natural products COC(=O)CC(C)C OQAGVSWESNCJJT-UHFFFAOYSA-N 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000011133 lead Substances 0.000 claims description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 3
- FIABMSNMLZUWQH-UHFFFAOYSA-N propyl 2-methoxyacetate Chemical compound CCCOC(=O)COC FIABMSNMLZUWQH-UHFFFAOYSA-N 0.000 claims description 3
- 150000003505 terpenes Chemical class 0.000 claims description 3
- 235000007586 terpenes Nutrition 0.000 claims description 3
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 claims description 2
- WUPHOULIZUERAE-UHFFFAOYSA-N 3-(oxolan-2-yl)propanoic acid Chemical compound OC(=O)CCC1CCCO1 WUPHOULIZUERAE-UHFFFAOYSA-N 0.000 claims description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 2
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 2
- 239000004411 aluminium Substances 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- IRERQBUNZFJFGC-UHFFFAOYSA-L azure blue Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[S-]S[S-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] IRERQBUNZFJFGC-UHFFFAOYSA-L 0.000 claims description 2
- QBLDFAIABQKINO-UHFFFAOYSA-N barium borate Chemical compound [Ba+2].[O-]B=O.[O-]B=O QBLDFAIABQKINO-UHFFFAOYSA-N 0.000 claims description 2
- QFFVPLLCYGOFPU-UHFFFAOYSA-N barium chromate Chemical compound [Ba+2].[O-][Cr]([O-])(=O)=O QFFVPLLCYGOFPU-UHFFFAOYSA-N 0.000 claims description 2
- 239000001273 butane Substances 0.000 claims description 2
- 229910052793 cadmium Inorganic materials 0.000 claims description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052980 cadmium sulfide Inorganic materials 0.000 claims description 2
- RFAFBXGYHBOUMV-UHFFFAOYSA-N calcium chromate Chemical compound [Ca+2].[O-][Cr]([O-])(=O)=O RFAFBXGYHBOUMV-UHFFFAOYSA-N 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- ZLFVRXUOSPRRKQ-UHFFFAOYSA-N chembl2138372 Chemical compound [O-][N+](=O)C1=CC(C)=CC=C1N=NC1=C(O)C=CC2=CC=CC=C12 ZLFVRXUOSPRRKQ-UHFFFAOYSA-N 0.000 claims description 2
- XCJYREBRNVKWGJ-UHFFFAOYSA-N copper(II) phthalocyanine Chemical compound [Cu+2].C12=CC=CC=C2C(N=C2[N-]C(C3=CC=CC=C32)=N2)=NC1=NC([C]1C=CC=CC1=1)=NC=1N=C1[C]3C=CC=CC3=C2[N-]1 XCJYREBRNVKWGJ-UHFFFAOYSA-N 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 150000002168 ethanoic acid esters Chemical class 0.000 claims description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims description 2
- 239000010439 graphite Substances 0.000 claims description 2
- 229910002804 graphite Inorganic materials 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 2
- 239000012948 isocyanate Substances 0.000 claims description 2
- 150000002513 isocyanates Chemical class 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 claims description 2
- 229940017144 n-butyl lactate Drugs 0.000 claims description 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 claims description 2
- ZTFZSHLWORMEHO-UHFFFAOYSA-A pentaaluminum;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O.[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O ZTFZSHLWORMEHO-UHFFFAOYSA-A 0.000 claims description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 claims description 2
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 claims description 2
- 239000011297 pine tar Substances 0.000 claims description 2
- 229940068124 pine tar Drugs 0.000 claims description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims description 2
- NVKTUNLPFJHLCG-UHFFFAOYSA-N strontium chromate Chemical compound [Sr+2].[O-][Cr]([O-])(=O)=O NVKTUNLPFJHLCG-UHFFFAOYSA-N 0.000 claims description 2
- 239000010456 wollastonite Substances 0.000 claims description 2
- 229910052882 wollastonite Inorganic materials 0.000 claims description 2
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- 238000000227 grinding Methods 0.000 abstract description 3
- 238000001914 filtration Methods 0.000 abstract 1
- 241000549556 Nanos Species 0.000 description 7
- 229910000838 Al alloy Inorganic materials 0.000 description 4
- 238000007605 air drying Methods 0.000 description 4
- 239000008199 coating composition Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 230000018109 developmental process Effects 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000004446 fluoropolymer coating Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- OVSKIKFHRZPJSS-UHFFFAOYSA-N 2,4-D Chemical compound OC(=O)COC1=CC=C(Cl)C=C1Cl OVSKIKFHRZPJSS-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- VWWMOACCGFHMEV-UHFFFAOYSA-N dicarbide(2-) Chemical compound [C-]#[C-] VWWMOACCGFHMEV-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000011858 nanopowder Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007750 plasma spraying Methods 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- MWWATHDPGQKSAR-UHFFFAOYSA-N propyne Chemical compound CC#C MWWATHDPGQKSAR-UHFFFAOYSA-N 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
A nano-class fluorocarbon paint for airplane is composed of the modified synthetic resin and the solidifying agent. Said modifyed synthetic resin is prepared through adding nano slurry to synthetic resin solution, mixing with solvent and pigment, grinding and filtering. Its advantages are high storage stability and high weatherability.
Description
Technical field
The present invention relates to coating technology, be specially a kind of fluorocarbon resin coating and preparation method thereof with super weather-proof function.
Background technology
The raising of aircraft speed and the variation of complex environment of living in make people have higher requirement to aeroplane dope.Phthalic resin coating, epoxypaint, acrylic resin paint, silicone resin coating, poly-propylhomoserin coating successively use on aircraft.Fluorine resin coating has obtained extensively should having in industrial aspect owing to good weathering resistance, chemical proofing, mechanical property.Fluorine resin paints can be dissolved in common solvent and be made at a lower temperature especially in recent years, but even drying and forming-film just at room temperature, and protect light and tint retention good.This fluorine resin coating have weathering resistance and pollution resistance well outside, application property is also very good, is a kind of filmogen that is fit to do aeroplane dope.United States Patent (USP) 4,347,376 have reported that the coating by the preparation of perfluor propine acetylide can be used for the protection of aircraft windscreen.United States Patent (USP) 4,595,718 have reported and are making and can use a kind of normal temperature solidifying fluorine-carbon polymer coating during the maintenance aircraft, the elastomer coating that its forms has anti-fuel functional.The disclosed two kinds of fluorocarbon resin coatings of above-mentioned United States Patent (USP) are all normal temperature solidified, made things convenient for construction.
The fast development of nanosecond science and technology is for the development of coating provides opportunity.The research that utilizes nano material to improve coating property has also obtained remarkable progress.Reported with nanometer slurry preparation nano-photo catalytic fluorocarbon resin coating method as Chinese patent (application number 02109488.8), but this coating has photo-catalysis function, the cost height only is applicable to the special occasions that needs environmental purification.Chinese patent CN1412258A discloses a kind of nano UV resistant acrylate paint, though the ultraviolet light performance of this coating improves a lot, weathering resistance also has certain gap from fluorocarbon resin coating.
In addition, U.S. Pat P6,432,486 have reported that recently the coating that aircraft surfaces plasma spraying fluoropolymer coating forms has the freezing function, and this fluoropolymer coating needs the specific equipment spraying, and construction adaptability has been subjected to considerable restraint.
Summary of the invention
The purpose of this invention is to provide a kind of nano-fluorine carbon aeroplane dope and preparation method thereof with super-weathering resistance.
Technical scheme of the present invention is: a kind of nano-fluorine carbon aeroplane dope is made of matching used synthetic resins and solidifying agent two-pack, synthetic resins is one or more of fluorocarbon resin of hydroxyl, solidifying agent is the isocyanates solidifying agent, described synthetic resins is modified synthetic resin, by weight percentage, modified synthetic resin is by the solvent composition of 1-75% nanometer slurry, 10-65% synthetic resins, 0-40% pigment, surplus; The proportioning of solidifying agent and modified synthetic resin is pressed NCO: OH=0.8-1.5: 1 mol ratio;
Described nanometer slurry refers to the Nanos type nanometer slurry with uvioresistant function of Metal Inst., Chinese Academy of Sciences's development, and nanometer slurry content in modified synthetic resin is preferably 10-55%;
Described synthetic resins content is preferably 10-40%;
Described pigment content is preferably 5～35%;
Described solvent is that one or more of aliphatic hydrocarbon, aromatic hydrocarbon, ester class, ketone, terpene, replacement hydro carbons are composite.Wherein aliphatic solvents refer to sherwood oil, No. 200 solvent oils, raffinate oil, butane, Skellysolve A, iso-pentane, isohexane, normal hexane, normal heptane, isoheptane, octane, octane-iso; Aromatic hydrocarbon solvent refers to benzene,toluene,xylene, Three methyl Benzene, Solvesso100, Solvesso150, Solvesso200, solvent naphtha, ethylbenzene, isopropyl benzene; Ketones solvent refers to acetone, methylethylketone, mibk, pimelinketone, isophorone, diacetone alcohol, metacetone, methyl propyl ketone; Esters solvent refers to vinyl acetic monomer, n-butyl acetate, isobutyl acetate, capryl acetate, acetic acid heptyl ester, acetic acid ester in the last of the ten Heavenly stems, n-Butyl lactate, methoxyacetic acid propyl ester; Terpene type solvent refers to turps, pine tar, kautschin; Replace varsol and refer to trichloroethane, 2-nitropropane; Solvent is No. 200 solvent oils, Skellysolve A, iso-pentane, isohexane, normal hexane, normal heptane, isoheptane, toluene, dimethylbenzene, Three methyl Benzene, Solvesso100, Solvesso150, Solvesso200, solvent naphtha, methylethylketone, mibk, pimelinketone, isophorone, vinyl acetic monomer, n-butyl acetate, isobutyl acetate, methoxyacetic acid propyl ester, trichloroethane preferably;
Described pigment is selected from titanium white, ground barium sulfate, GL ground limestone, precipitated calcium carbonate, talcum powder, quartzy, zinc phosphate, aluminium triphosphate, yellow ultramarine, strontium yellow, baryta yellow, zinc-chrome yellow, wollastonite, kaolin, mica powder, phthalocyanine green, cadmium red, toluidine red, red iron oxide, iron oxide yellow, iron oxide black, graphite, phthalocyanine blue, ultramarine, Chinese blue, red lead, yellow lead, carbon black, zinc powder, aluminium powder, lithopone, zinc sulphide, Cadmium Sulfide, one of barium metaborate or two or more composite.
In the nano-fluorine carbon aeroplane dope of the present invention, employed synthetic resins, can be selected from the fluorocarbon resin of Japan AGC Zhu Shi commercial firm commodity Lumiflon by name, as Lumiflon LF-100, Lumiflon LF-200, Lumiflon LF-400 etc., the ザ Off ロ Application trade mark fluorocarbon resin of Japan East Asia synthetic chemistry company, the Ford of the new chemical industry of Xi'an Le Jia company limited
Fluorocarbon resin, the FEVE type fluorocarbon resin of Mingzhan fluorin coating stock Co., Ltd., Dalian city; Can be selected from the Desmodur of Bayer (Bayer) company as the curing agent component of nano-fluorine carbon aeroplane dope
N75, Desmodur
N100, Desmodur
N3390, Desmodur
N3300, Desmodur
VPLS 2010/1, Desmodur
VPLS 2103, Desmodur
Z4470; The Tolonate of France inferior (Rhodia) company in sieve ground
TMHDB-75MX, Tolonate
TMHDT-90; CORONATE 2604, CORONATE HX-T, CORONATE 2384, the CORONATE HK of Japan fluorocarbon resin Co., Ltd..The proportioning of curing agent component and modified synthetic resin component is NCO: OH=0.8-1.5: 1 (mol ratio).
The present invention also provides the preparation method of above-mentioned nano-fluorine carbon aeroplane dope, and its process is as follows:
1) preparation modified synthetic resin: by weight percentage, at first 1-75% nanometer slurry is added in the 10-65% synthetic resin solution, the solvent that adds 0-40% pigment, surplus again mixes, high speed dispersion also is ground to fineness less than 30 μ m, makes the modified synthetic resin component of nano-fluorine carbon aeroplane dope;
2) preparation coating: the proportioning of solidifying agent and modified synthetic resin is pressed NCO: OH=0.8-1.5: 1 mol ratio uniform mixing, promptly form the nano-fluorine carbon aeroplane dope.
Nano-fluorine carbon aeroplane dope mixing of the present invention and grinding dispersing apparatus are the common equipments in the paint manufacturing process, comprise high speed dispersor, sand mill, ball mill, ball mill and triple-roller mill.
Advantage of the present invention is as follows:
1. the present invention proposes and adopt the method for nanometer slurry to prepare the nano-fluorine carbon aeroplane dope, employed nanometer slurry is mainly to be made up of the nano powder of stable dispersion, and this method has improved nano-fluorine carbon aeroplane dope package stability.
2. finely disseminated nanoparticle can reduce the porosity of coating, improves the permeability resistance of coating, has improved the weathering resistance and the solidity to corrosion of coating.
3. coating application adaptability of the present invention is strong, and cost is low.
4. nano-fluorine carbon coating of the present invention has super-weathering resistance.
Embodiment
Unless outside specializing among the present invention, related ratio all is weight percentage.
The evaluation method of nano-fluorine carbon coat-thickness: coating dry film thickness is measured with the 6000FN1 type thickness tester of U.S. DeFelsko company.
The evaluation method of nano-fluorine carbon coating adhesion: GB9286-88 tests by GB.
The nano-fluorine carbon coating is pressed GB/T 1865-1997 3500 hours artificial weathering of continuous illumination experiment on the Ci3000 ageing device of U.S. Atlas Electric Devices company, and weathering resistance is carried out the Comprehensive Assessment grade according to GB1766-1995 and estimated.
The used nanometer slurry of preparation nano-fluorine carbon aeroplane dope is starched for the Nanos type nanometer of Metal Inst., Chinese Academy of Sciences's development, its preparation method is as follows: take by weighing methylethylketone 80g, trichloroethane 10g in the 500ml beaker, add 10g macromolecule dispersing agent Dispers610 (Di Gao chemical company), add nano-titanium oxide 30g, nano zircite 30g and nano zine oxide 40g again, with ball mill grinding 11 hours, make nano material content and be 50% Nanos type nanometer slurry.
Embodiment 1
In the beaker of 300ml, claim 25g Lumiflon LF-400 fluorocarbon resin, add Nanos type nanometer slurry 32g, add titanium white 6g, kaolin 5g, zinc phosphate 5g then, add 25g dimethylbenzene, 1g methylethylketone, 1g vinyl acetic monomer again, more than mixed paint vehicle 1600rpm high speed dispersion 50 minutes, and be ground to fineness less than 30 μ m, be prepared into the modified synthetic resin component; Curing agent component is Desmudur
N75; Solidifying agent and modified synthetic resin component two components are pressed NCO: OH=0.9: 1 (mol ratio) proportioning, stirring the back uses spreader to be coated with this nano-fluorine carbon aeroplane dope on through oil removing, except that the LY12 aluminium alloy plate of the 150mm * 75mm * 2mm after the water treatment, behind the sample Air drying of coating composition, making build is the coating sample of 23 ± 2 μ m.
Embodiment 2
In the beaker of 300ml, claim 25g Lumiflon LF-400 fluorocarbon resin, add Nanos type nanometer slurry 8g, add titanium white 6g, kaolin 5g, zinc phosphate 5g then, add 49g dimethylbenzene, 1g methylethylketone, 1g vinyl acetic monomer again, more than mixed paint vehicle 2000rpm high speed dispersion 40 minutes, and be ground to fineness less than 30 μ m, be prepared into the modified synthetic resin component; Curing agent component is Tolonate
TMHDT-90; Solidifying agent and modified synthetic resin component two components are pressed NCO: OH=0.9: 1 (mol ratio) proportioning, stirring the back uses spreader to be coated with this nano-fluorine carbon aeroplane dope on through oil removing, except that the LY12 aluminium alloy plate of the 150mm * 75mm * 2mm after the water treatment, behind the sample Air drying of coating composition, making build is the coating sample of 23 ± 2 μ m.
Embodiment 3
In the beaker of 300ml, claim 25g Lumiflon LF-400 fluorocarbon resin, add Nanos type nanometer slurry 52g, add titanium white 6g, kaolin 5g, zinc phosphate 5g then, add 5g dimethylbenzene, 1g methylethylketone, 1g vinyl acetic monomer again, more than mixed paint vehicle 2400rpm high speed dispersion 30 minutes, and be ground to fineness less than 30 μ m, be prepared into the modified synthetic resin component; Curing agent component is CORONATE HX-T; Solidifying agent and modified synthetic resin component two components are pressed NCO: OH=0.9: 1 (mol ratio) proportioning, the stirring back uses line rod spreader to be coated with this nano-fluorine carbon aeroplane dope on through oil removing, except that the LY12 aluminium alloy plate of the 150mm * 75mm * 2mm after the water treatment, behind the sample Air drying of coating composition, making build is the coating sample of 23 ± 2 μ m.
Comparative example 1
In the beaker of 300ml, claim 25g Lumiflon LF-400 fluorocarbon resin, add titanium white 6g, kaolin 5g, zinc phosphate 5g, add 57g dimethylbenzene, 1g methylethylketone, 1g vinyl acetic monomer again, more than mixed paint vehicle 2000rpm high speed dispersion 40 minutes, and be ground to fineness less than 30 μ m, be prepared into the modified synthetic resin component; Curing agent component is Desmudur
N75; Solidifying agent and synthetic resins component are pressed NCO: OH=0.9: 1 (mol ratio) proportioning, stirring the back uses spreader to be coated with this fluorocarbon resin coating on through oil removing, except that the LY12 aluminium alloy plate of the 150mm * 75mm * 2mm after the water treatment, behind the sample Air drying of coating composition, making build is the contrast coating sample of 23 ± 2 μ m.
Table 1
| Nanometer slurry (%) in the modified synthetic resin | Sticking power (level) | Weathering resistance (level) | |
| Embodiment 1 | ????32 | ????0 | ????0 |
| Embodiment 2 | ????8 | ????0 | ????1 |
| Embodiment 3 | ????52 | ????0 | ????1 |
| Comparative example 1 | ????0 | ????0 | ????4 |
Table 1 is the super weather resistance fluorocarbon resin coating of nanometer of different N anos type nanometer slurry content.As shown in Table 1, the Nanos type nanometer of embodiment 1～3 slurry content is in the 10-55% scope, and durability of coating and coating adhesion are very good.
Claims (8)
1, a kind of nano-fluorine carbon aeroplane dope, constitute by matching used synthetic resins and solidifying agent two-pack, synthetic resins is the fluorocarbon resin of hydroxyl, solidifying agent is the isocyanates solidifying agent, it is characterized in that: described synthetic resins is modified synthetic resin, by weight percentage, modified synthetic resin is by the solvent composition of 1-75% nanometer slurry, 10-65% synthetic resins, 0-40% pigment, surplus; The proportioning of solidifying agent and modified synthetic resin is pressed NCO: OH=0.8-1.5: 1 mol ratio.
2, according to the described nano-fluorine carbon aeroplane dope of claim 1, it is characterized in that: described nanometer slurry content is 10-55%.
3, according to the described nano-fluorine carbon aeroplane dope of claim 1, it is characterized in that: described synthetic resins content is 10-40%.
4, according to the described nano-fluorine carbon aeroplane dope of claim 1, it is characterized in that: described pigment content is 5～35%.
5, according to the described nano-fluorine carbon aeroplane dope of claim 1, it is characterized in that: described solvent is that one or more of aliphatic hydrocarbon, aromatic hydrocarbon, ester class, ketone, terpene, replacement hydro carbons are composite.
6, according to the described nano-fluorine carbon aeroplane dope of claim 5, it is characterized in that: described solvent is a sherwood oil, No. 200 solvent oils, raffinate oil, butane, Skellysolve A, iso-pentane, isohexane, normal hexane, normal heptane, isoheptane, octane, octane-iso, benzene, toluene, dimethylbenzene, Three methyl Benzene, Solvesso100, Solvesso150, Solvesso200, solvent naphtha, ethylbenzene, isopropyl benzene, acetone, methylethylketone, mibk, pimelinketone, isophorone, diacetone alcohol, metacetone, methyl propyl ketone, vinyl acetic monomer, n-butyl acetate, isobutyl acetate, capryl acetate, the acetic acid heptyl ester, acetic acid ester in the last of the ten Heavenly stems, n-Butyl lactate, the methoxyacetic acid propyl ester, turps, pine tar, kautschin, trichloroethane, one of 2-nitropropane or two or more composite.
7, according to the described nano-fluorine carbon aeroplane dope of claim 1, it is characterized in that: described pigment is titanium white, ground barium sulfate, GL ground limestone, precipitated calcium carbonate, talcum powder, quartzy, zinc phosphate, aluminium triphosphate, yellow ultramarine, strontium yellow, baryta yellow, zinc-chrome yellow, wollastonite, kaolin, mica powder, phthalocyanine green, cadmium red, toluidine red, red iron oxide, iron oxide yellow, iron oxide black, graphite, phthalocyanine blue, ultramarine, Chinese blue, red lead, yellow lead, carbon black, zinc powder, aluminium powder, lithopone, zinc sulphide, Cadmium Sulfide, one of barium metaborate or two or more composite.
8, a kind of preparation method according to the described nano-fluorine carbon aeroplane dope of one of claim 1-7 is characterized in that process is as follows:
1) preparation modified synthetic resin: by weight percentage, at first 1-75% nanometer slurry is added in the 10-65% synthetic resin solution, the solvent that adds 0-40% pigment, surplus again mixes, high speed dispersion also is ground to fineness less than 30 μ m, makes the modified synthetic resin component of nano-fluorine carbon aeroplane dope;
2) preparation coating: the proportioning of solidifying agent and modified synthetic resin is pressed NCO: OH=0.8-1.5: 1 mol ratio uniform mixing, promptly form the nano-fluorine carbon aeroplane dope.
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| CN 03111488 CN1207357C (en) | 2003-04-18 | 2003-04-18 | Nano-fluoro carbon aircraft paint and its preparation method |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702876A (en) * | 2012-03-20 | 2012-10-03 | 广东电网公司电力科学研究院 | Nanometer composite fluoro-carbon heavy anticorrosive coating for electric power rod tower and preparation method of coating |
| CN102732107A (en) * | 2012-07-13 | 2012-10-17 | 上海电缆研究所 | Coating and method for improving weathering resistance of resin matrix composite mandril |
| CN103131273A (en) * | 2012-11-07 | 2013-06-05 | 惠州圣帕新材料有限公司 | High weather resistance fluorocarbon material prescription and manufacturing process |
| CN108641574A (en) * | 2018-05-09 | 2018-10-12 | 欧利生东邦涂料（东莞）有限公司 | A kind of recoverability acrylic acid high-gloss paint |
| CN110396331A (en) * | 2019-08-28 | 2019-11-01 | 中铁二院工程集团有限责任公司 | One kind can recoat flexible fluorocarbon coating |
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2003
- 2003-04-18 CN CN 03111488 patent/CN1207357C/en not_active Expired - Fee Related
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102702876A (en) * | 2012-03-20 | 2012-10-03 | 广东电网公司电力科学研究院 | Nanometer composite fluoro-carbon heavy anticorrosive coating for electric power rod tower and preparation method of coating |
| CN102732107A (en) * | 2012-07-13 | 2012-10-17 | 上海电缆研究所 | Coating and method for improving weathering resistance of resin matrix composite mandril |
| CN102732107B (en) * | 2012-07-13 | 2014-08-13 | 上海电缆研究所 | Coating and method for improving weathering resistance of resin matrix composite mandril |
| CN103131273A (en) * | 2012-11-07 | 2013-06-05 | 惠州圣帕新材料有限公司 | High weather resistance fluorocarbon material prescription and manufacturing process |
| CN103131273B (en) * | 2012-11-07 | 2015-12-02 | 惠州圣帕新材料有限公司 | High weather resistance fluorocarbon material prescription and manufacturing process |
| CN108641574A (en) * | 2018-05-09 | 2018-10-12 | 欧利生东邦涂料（东莞）有限公司 | A kind of recoverability acrylic acid high-gloss paint |
| CN108641574B (en) * | 2018-05-09 | 2020-08-21 | 欧利生东邦涂料（东莞）有限公司 | Repairable acrylic acid highlight coating |
| CN110396331A (en) * | 2019-08-28 | 2019-11-01 | 中铁二院工程集团有限责任公司 | One kind can recoat flexible fluorocarbon coating |
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| CN1207357C (en) | 2005-06-22 |
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