CN1510186A - Heater for heating filament - Google Patents

Heater for heating filament Download PDF

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Publication number
CN1510186A
CN1510186A CNA2003101180056A CN200310118005A CN1510186A CN 1510186 A CN1510186 A CN 1510186A CN A2003101180056 A CNA2003101180056 A CN A2003101180056A CN 200310118005 A CN200310118005 A CN 200310118005A CN 1510186 A CN1510186 A CN 1510186A
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CN
China
Prior art keywords
long filament
heater
heat tunnel
heating
heat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CNA2003101180056A
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Chinese (zh)
Inventor
马丁・菲舍尔
马丁·菲舍尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Oerlikon Textile GmbH and Co KG
Original Assignee
Saurer GmbH and Co KG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saurer GmbH and Co KG filed Critical Saurer GmbH and Co KG
Publication of CN1510186A publication Critical patent/CN1510186A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J13/00Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
    • D02J13/003Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass by contact with at least one stationary surface, e.g. a plate
    • DTEXTILES; PAPER
    • D02YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
    • D02JFINISHING OR DRESSING OF FILAMENTS, YARNS, THREADS, CORDS, ROPES OR THE LIKE
    • D02J13/00Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass
    • D02J13/001Heating or cooling the yarn, thread, cord, rope, or the like, not specific to any one of the processes provided for in this subclass in a tube or vessel

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)

Abstract

A man-made thread (6) passes through an elongated externally heated passage (1) with an inlet (7) and an outlet (8). The passage has a series of hot air jet inlets (16) driving a flow of hot air (2) from a compressed source (13). The hot air inlets form part of a thread guide that is an insert (5) within the air passage (15). The heated insert is a profiled rail (9) with a series of jet outlets (16) linked via tubes (15) to a heated supply of compressed air. The tube jet outlets are located at intervals along the profile and are inclined against the direction of the oncoming thread.

Description

The heater that is used for heated yarn
Technical field
The present invention relates to a kind of heater that is used for heated yarn by claim 1 preamble.
Background technology
For example by the heater of known this type of DE 29 33 087A1.
Known long filament heats by means of heater in coiling deformation devices in order to make synthetic thread Texturized, so that Texturized and stretch and carry out shrink process.Here develop different heaters according to the difference of treatment step, they heat long filament in various processes best.For example, require long filament to pass heater in the de-stress effect that obtains during the shrink process on the high long filament as far as possible unstressedly.For this treatment step, a kind of like this heater has obtained special checking, and the long filament and the area of heating surface are advanced in contact in this heater, for example by known to the DE 2933087A1.Here long filament passes a heat tunnel from external heat.Adopt heat-carrying agent as heating agent, it produces the heat that requires on the heat tunnel outer wall owing to condensation.In such heater such problem can appear in principle.That is, owing to form stack effect within the heat tunnel between the upright position of the heater that the circulation of heat carrier forms exports common long filament below and top long filament enters the mouth.In order to obtain as far as possible little stack effect in heat tunnel, the flow cross of heat tunnel is selected greatly as far as possible.The oil agent steam that brings thus, give out from long filament directly enters heater and causes the shortcoming of deposition to solve by such method known heater,, produces a flushing air-flow in heat tunnel that is.Purge gas stream produces by an input unit, and introduces heat tunnel by many nozzle bores on the heat tunnel lid.But can not deal with problems thus, make the guiding of the long filament that in the wide flow cross of heat tunnel, guides particularly when noncontact is led, become problem unstressedly, need a lot of heat energy for the purpose heat tunnel that heats on the other hand.
When crimped filament distortion and stretching, preferably adopt for example by the heater known to the EP 0994206A1.Texturized and when stretching during heating the long filament band very big thread-tension and advance.At this moment long filament has the intrinsic power by Texturized generation, therefore the long filament guiding is proposed high requirement.This heater is preferably made so-called high temperature heater (HTH), and here long filament guides by fiber guiding element with a certain distance from the area of heating surface.Preferably by the resistive element heating, the area of heating surface has the temperature above the filamentary material fusion temperature to the area of heating surface here.Therefore require long filament to keep with a certain distance from the area of heating surface.This known heater has an insurance system for the situation of filament breakage, wherein produces an air-flow when filament breakage in heat tunnel, and it prevents the long filament that ruptures and the contact between the area of heating surface.This system has very big shortcoming, that is, the triggering of air input realizes according to filament breakage.Because the measured response time, pulling of long filament short time taken place before air-flow enters heat tunnel unavoidably, therefore be difficult to prevent with heat is surperficial contact.
Summary of the invention
The objective of the invention is now, improve such heater in this wise, that is, do not rely on the position and the type of heater, in heat tunnel, possesses an environment that is complementary with long filament respectively, to reach long filament rapidly and the guiding of uniform heating and/or long filament the best.
Another object of the present invention is, a kind of heater of this type is provided, and can change the long filament guiding and long filament heats by the device that can control easily during with this heater.
This purpose solves by such method, promptly, in heat tunnel, establish a heating insert that is used for guiding long filament, this heating insert comprises an air duct system, it is connected with the pressure source of air input unit by a pipeline, and on heating insert the formation jet hole and with the air duct system connectivity.
The present invention is based upon on the basis of such understanding, that is, the air-flow that produces in heat tunnel has the important effect that helps long filament heating and/or long filament guiding.Therefore the present invention produces an artificial airflow in heat tunnel, stops possible heat loss.For example can directly control the environment of long filament by the jet hole of heating insert.Particularly in heat tunnel, can produce the artificial airflow of for example offsetting undesirable big chimney draft.Another advantage by heater of the present invention is by the artificial air-flow that produces in heat tunnel, to reduce and dissolve rapidly the air that comes from the outside of bringing heat tunnel by long filament into.Reach the preheating of the artificial airflow that enters heat tunnel by the air duct system that is integrated in the heating insert in addition, thereby improve all even rapid heating of long filament in heat tunnel.Change by the artificial airflow in heat tunnel can make the condition in the heat tunnel mate individually with filament types arbitrarily.For example, can in heat tunnel, adjust to a correspondingly little artificial airflow, obtaining the positive effect of air-flow, and not form big heat loss for the long filament of little number.By the jet hole of processing on heating insert, more weak artificial airflow just can have been controlled the surrounding environment of the long filament of directly advancing on heating insert.
The good improvement structure of the present invention is determined by the feature and the feature combination of dependent claims.
Be made of moulding orbit according to a kind of good improvement structure heating insert of the present invention, wherein jet hole is made in the zone of the spigot surface that the long filament of moulding orbit advances on it, and with air duct system connectivity in moulding orbit.Thereby can irrespectively adjust the long filament route of the safety in the heat tunnel with the type of heater.
According to the difference for long filament desirable environment requirement in heater, the jet hole on the heating insert can be provided with dispersedly along the long filament stroke that leads, and perhaps is positioned in long filament inlet region or the long filament outlet area.Dividing timing not only to change the long filament guiding but also change the continuous direct influence that long filament heats to the long filament generation along long filament guiding stroke.The ambient air stream that can control chimney draft especially or bring in the time of in the jet hole part is arranged on the long filament inlet region or in the long filament outlet area.
According to a kind of particularly preferred improvement structure of the present invention, jet hole be arranged on the contacted spigot surface of long filament zone in.Can particularly reduce thus by the long filament friction that causes that contacts between long filament and the spigot surface.Can between long filament and spigot surface, produce one by the adjustment artificial airflow like this and help the air cushion that long filament leads.Therefore long filament can rub and heat tinily.
But in order to reach special effect, according to the another kind of good improvement structure of the present invention, jet hole can be done to such an extent that have one against the inclination angle of long filament route or have a tendency along the long filament route on spigot surface.So for example can on long filament, produce the conveying effect by a jet hole that tilts along the long filament route.Particularly before beginning, process when the long filament repiece, can advantageously utilize this effect.Therefore the pressure source that is connected in the air duct system by adjustment can produce the special big artificial airflow that is used for the long filament repiece.When operation long filament pressure source can be with the pressure operation of correspondingly adjusting smallerly between the period of heating in heat tunnel, make the less artificial airflow of generation in heat tunnel.
For make long filament directly by with the spigot surface Contact Heating, moulding orbit is preferably done with a seal wire groove that extends on heat tunnel, wherein spigot surface is made of the bottom land of seal wire groove.
But such do have a seal wire groove moulding orbit also can be used for the non-contacting basically heating of long filament.Here spigot surface is made of the groove section of the weak point of the many projections in the seal wire groove.The groove section is distributed on the length of seal wire groove.
In order to clean spigot surface, heating insert preferably is fixed in the heat tunnel replaceably.Here can on diverse location, load onto for example additional director element on the heating insert selectively, the silk thread guiding is carried out with the flexible way method.
Description of drawings
With reference to accompanying drawing other advantages of the present invention are done more detailed explanation by means of some embodiment below by device of the present invention.
Accompanying drawing is represented:
Fig. 1 schematically illustrates by the vertical profile of first kind of embodiment of heater of the present invention and looks,
Fig. 2 schematically illustrates the cross section of embodiment among Fig. 1,
Fig. 3 schematically illustrates by the vertical profile of the another kind of embodiment of heater of the present invention and looks,
Fig. 4 schematically illustrates the cross section of the embodiment among Fig. 3.
The specific embodiment
Schematically illustrate first kind of embodiment by heater of the present invention among Fig. 1, it for example can be used in the coiling deformation devices, so that heat Texturized long filament in the shrinking zone, handles to carry out stress.Expression is looked by the cross-sectional of embodiment of heater of the present invention among Fig. 2, and following explanation if specifically do not indicate at some figures, so just all is suitable for two figures.
The heat tunnel 1 that has the length of a band wall 3 by the embodiment of heater of the present invention.Heat tunnel 1 with wall 3 is made of the light-wall pipe with rectangular cross section in the present embodiment.Heat tunnel 1 opens to end face.The heating insert 5 of a moulding orbit 9 forms of in heat tunnel 1, packing into.Shaping track 9 has a cannelure 10, and it extends along the whole distance of heat tunnel 1.Heating insert 5 is placed directly on the wall 3 of heat tunnel 1 with the longitudinal side on cannelure 10 opposites.Here the contact between the wall 3 of moulding orbit 9 and heat tunnel 1 is designed to like this, and heat can be transmitted on the moulding orbit 9 from wall 3.Cannelure 10 in the moulding orbit 9 has a spigot surface 11 on bottom land, long filament 6 is advanced on it in contact.The spigot surface 11 that is made of the bottom land of cannelure 10 is done along the long filament direct of travel to be crooked, to pass heat tunnel 1 with making long filament circular arc, the long filaments outlet 8 from the long filament inlet 7 of an end to the other end.In the moulding orbit 9 inner air duct systems 15 that form.Air duct system 15 is communicated with the jet hole 16 of many feeding spigot surfaces 11.Jet hole 16 is arranged on the spigot surface 11 along heating distance space certain distance with forming a line.Here jet hole 16 has an inclination angle against long filament direct of travel layout.The air duct system 15 of moulding orbit 9 inside is connected with the pressure source 13 of air input unit 12 by a pipeline 14 on an end face of moulding orbit 9.
Heat tunnel 1 is heated hull shape ground encirclement outside the unit 2 on circumference.Heating unit 2 is made of the heat-carrying agent 4 that a heating cabinet 22 and dress are filled in the heating cabinet 22 in the present embodiment.Heating cabinet 22 outer hull shapes surround heat tunnel 1.Heating cabinet 22 connects into a heat carrier closed circuit by an input pipe 19 and an efferent duct 20 and an evaporimeter 21.Efferent duct 20 is preferably disposed on the lower end of heating cabinet 22, and input pipe is arranged on the upper end.Therefore heating cabinet 22 and be arranged on the interior preferably vertical or tiltably-mounted of heat tunnel 1 of heating cabinet 22.Here the condensate of heat-carrying agent 4 is discharged from heating cabinet 22 by efferent duct 20, and guides to evaporimeter 21.Heat-carrying agent 4 evaporates and imports heating cabinet 22 by input pipe in evaporimeter 21.The heating unit 2 that is made of the heat-carrying agent 4 and the heating cabinet 22 of steam shape heats heat tunnel 1 equably on periphery on the whole length of wall 3.
But heating unit also can be made of electric device, with heating heat tunnel 1.
For the Temperature Treatment of long filament 6, it passes heat tunnel 1 through long filament inlet 7 and long filament outlet 8.Long filament inlet 7 sets an inlet thread guide 18 for this reason, and long filament outlet 8 sets an outlet thread guide 17.Here the thread guide 18 that enters the mouth is provided with like this with outlet thread guide 17, makes long filament 6 pass heat tunnel 1 in contact in the cannelure 10 of moulding orbit 9 basically.Wherein directly flow to heat tunnel 1 from the wall 3 of heating unit 2 by heat tunnel 1 for heated yarn 6 energy needed.The wall 3 of heat tunnel 1 is preferably made by the material that very high capacity of heat transmission is arranged for this reason.Thereby the energy that passes on the wall 3 from heating unit 2 can not have directly input heat tunnel 1 of big loss ground.For unallowed contact between the wall 3 of avoiding long filament 6 and heat tunnel 1 when the contact ground guiding long filament 6, moulding orbit 9 one ends are fixed in the heat tunnel 1.Long filament 6 is advanced on the cannelure 10 inner faces 11 of moulding orbit 9.Moulding orbit 9 has wearing face at least on the spigot surface 11 of cannelure 12.Import moulding orbit 9 by heat into from wall 3 and reach the additional Contact Heating of long filament 6 in cannelure 10.
Advance for long filament 6 is not had frictionally as far as possible by spigot surface 11, in the air duct system 15 of moulding orbit 9, produce an air-flow by air input unit 12.Preferably compressed air is introduced air duct system 15 through piping 14 by pressure source 13 for this reason.Compressed air leads to jet hole 16 in air duct system 15, jet hole leads to spigot surface 11, and produces an artificial airflow in heat tunnel 1.Because the inclination angle of jet hole 16 forms an air-flow against the long filament direct of travel in heat tunnel 1.Jet hole 16 directly feeds in spigot surface 11 zones, and it contacts with long filament 6.Thereby form an air cushion below long filament 6, this air cushion can make long filament 6 not have frictionally guiding in seal wire groove 10.Here another advantage of the contrary long filament direct of travel airflow flowing in heat tunnel 1 is, dissolves soon at the long filament outside air that 7 places bring into by long filament 6 that enters the mouth, or avoids entering of outside air fully.Thereby reach the rapid and rapid heating of long filament 6.
In the embodiment of the heater shown in Fig. 1 and 2, moulding orbit 9 preferably can be fixed in the heat tunnel 1 with changing easily.Thereby can be easily carry out the cleaning of moulding orbit 9 for example and particularly because the cleaning of the contaminated cannelure 10 of deposition of long filament by such method, promptly before cleaning, moulding orbit 9 is taken out from heat tunnel 1, and after cleaning, reload heat tunnel 1.
Also can adopt other moulding orbits 9 in addition, on this moulding orbit for example nozzle bore 16 be not to form a line but be arranged on the spigot surface 11 with staggering mutually so that by artificial airflow only influence long filament around.Long filament intrinsic track on spigot surface 11 keeps opening wide like this, makes that the contact zone between long filament 6 and the spigot surface 11 does not produce additional air.A special advantage of the heater shown in Fig. 1 and 2 is, imported preheating of air in the heat tunnel 1 by the air duct systems 15 in the moulding orbit 9.
Express another embodiment by heater of the present invention in Fig. 3 and 4, it can for example be used for heating the false twisting long filament in a coiling deformation devices, so that it is Texturized in false twist zone.Here in Fig. 3, look, in Fig. 4, schematically illustrate heater with cross section with vertical profile.All be not suitable for for two figures if specifically indicate at some figures, so following explanation.
In this embodiment, heat tunnel 1 is processed in a cuboid calandria 23 with the form of cannelure.In heat tunnel 1, imbed the heating insert of vertical track 27 forms, have many director elements 26 that certain distance is provided with that leave mutually on the vertical free longitudinal side of track 27 in heat tunnel 1.Layout on the heating insert 5 of director element 26 in heat tunnel 1 can be arranged to row or zigzag or circular arc according to desirable long filament guiding.Here the director element 26 on the heating insert 5 is preferably done to such an extent that can change and can be fixed on the diverse location, thereby in the flexibility that gives height aspect long filament guiding and the long filament heating.Director element 26 preferably is made of ceramic material, or with the contact-making surface of long filament 6 on use ceramic coated.
Form an air duct system 15 in long rails 27, it is connected on the air input unit 12 in end face one side.Air input unit 12 has a pressure source 13 and a pipeline 14 for this reason, and this pipeline directly is connected in the air duct system 15.Air duct system 15 has a plurality of jet holes 16, and they feed heat tunnel 1 on the free longitudinal side of long rails 27.
Process to flute profile within it on the longitudinal side of calandria 23 of heat tunnel 1, have a lid 24 directly to be fitted on the calandria 23.Therefore 1 of heat tunnel is to end face one side opening.
In calandria 23, directly imbed many resistive elements 25 in order to heat heat tunnel 1 as heating unit 2.Resistive element 25 causes calandria 23 electrical heating, thereby heat tunnel 1 is heated.
Heat tunnel 1 opens towards end face, makes long filament 6 be directed to long filament outlet 8 through long filament inlet 7.Long filament 6 guides in this wise by the director element 26 on the long rails 27 in heat tunnel 1, that is, long filament 6 is not contacted with the wall of heat tunnel 1, does not also contact with long rails 27.Long filament inlet 7 sets an inlet thread guide 18, and long filament outlet 8 sets an outlet thread guide 17.
Embodiment at the heater shown in Fig. 3 and 4 is particularly suitable for, and the area of heating surface of heat tunnel is heated to temperature above the filamentary material fusion temperature.This so-called high temperature heater (HTH) has such advantage, that is, can reach for long filament on short heating distance and handle needed temperature.For the heat transmission between each the bar monofilament that improves surrounding environment and multifilament thread in heat tunnel, in heat tunnel 1, produce a slight artificial airflow through air duct systems 15 and jet hole 16 by air input unit 12.Artificial airflow in the heat tunnel 1 helps entering heat exchange fast between the long filament of heat tunnel 1 and the surrounding environment in the heat tunnel 1.Thereby reaching better heat by convection current transmits.
At the embodiment by heater of the present invention shown in Fig. 1 to 4 is being several examples aspect its structure and the moulding.The heat insulation layer that surrounds heating unit is not shown here.For the purpose of seal wire, can adopt here be designed to the arbitrary structures form, in heat tunnel with or without the heating insert of fiber guiding element.
The pictorial symbolization table
1 heat tunnel, 2 heating units
3 walls, 4 heat-carrying agents
5 heating inserts, 6 long filaments
The enter the mouth 8 long filaments outlet of 7 long filaments
9 moulding orbits, 10 cannelures
11 spigot surfaces, 12 air input units
13 pressure sources, 14 pipelines
15 channel systems, 16 jet holes
17 outlet thread guides, 18 inlet thread guides
19 input pipes, 20 efferent ducts
21 evaporimeters, 22 heating cabinets
23 calandrias, 24 lids
25 resistive elements, 26 director elements
27 long rails

Claims (9)

1. the heater that is used for heated yarn (6), comprise a long heat tunnel (1), described heat tunnel has a long filament inlet (7) and an opposed long filament outlet (8) in the end, comprise that also one is used for heating the heating unit (2) and an air input unit (12) of heat tunnel (1), can in heat tunnel (1), produce an air-flow by this air input unit through many jet holes (16)
It is characterized by:
In heat tunnel (1), be provided with a heating insert (5) that is used for guiding long filament (6); And described heating insert (5) comprises an air duct system (15), and it is connected with the pressure source (13) of air input unit (12) by a pipeline (14); And jet hole (16) is made in heating insert (5) and upward and with air duct system (15) is communicated with.
2. press the heater of claim 1,
It is characterized by:
Heating insert (5) is made of a moulding orbit (9); And jet hole (16) is made in spigot surface (11) zone of described moulding orbit (9), and with moulding orbit (9) in air duct system (15) be communicated with.
3. press the heater of claim 1 or 2,
It is characterized by:
Jet hole (16) on the heating insert (5) is provided with dispersedly along the seal wire distance.
4. press the heater of claim 1 or 2,
It is characterized by:
Jet hole (16) on the heating insert (5) is arranged in long filament inlet (7) zone or long filament outlet (8) zone.
5. by each heater of claim 2 to 4,
It is characterized by:
Jet hole (16) is arranged in spigot surface (11) zone that long filament contacts.
6. by each heater of claim 2 to 5,
It is characterized by:
Jet hole (16) has one against the inclination angle of long filament direct of travel or an inclination angle along the long filament direct of travel is arranged on spigot surface (11).
7. by each heater of claim 2 to 6,
It is characterized by:
Moulding orbit (9) has one at the last seal wire groove (10) that extends of heat tunnel (1), and wherein spigot surface (11) is made of the bottom land of seal wire groove (10).
8. by each heater of claim 2 to 7,
It is characterized by:
Moulding orbit (9) has one at the last seal wire groove (10) that extends of heat tunnel (1), and wherein spigot surface (11) is made of the groove section of the weak point of many projections, and these groove sections are distributed on the whole length of seal wire groove.
9. by each heater of claim 1 to 8,
It is characterized by:
Heating insert (5) is fixed in the heat tunnel (1) replaceably.
CNA2003101180056A 2002-12-21 2003-11-20 Heater for heating filament Pending CN1510186A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE10260564.5 2002-12-21
DE10260564 2002-12-21

Publications (1)

Publication Number Publication Date
CN1510186A true CN1510186A (en) 2004-07-07

Family

ID=32477920

Family Applications (1)

Application Number Title Priority Date Filing Date
CNA2003101180056A Pending CN1510186A (en) 2002-12-21 2003-11-20 Heater for heating filament

Country Status (2)

Country Link
CN (1) CN1510186A (en)
DE (1) DE10355196A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103154342A (en) * 2010-10-13 2013-06-12 欧瑞康纺织有限及两合公司 Device for thermally treating multiple threads
CN104342801A (en) * 2013-08-05 2015-02-11 T-马克有限公司 Closed-type contact heater assembly used for thermal-treatment of yarn
CN110318106A (en) * 2019-06-24 2019-10-11 郑州中远氨纶工程技术有限公司 Thick denier spandex of a kind of high rebound and preparation method thereof

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104233541A (en) * 2013-06-08 2014-12-24 苏州联优织造有限公司 Composite type doubling thread cooling device
CN108301089A (en) * 2018-04-07 2018-07-20 郭柏权 Elasticizer electric heating unit and elasticizer heater box

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103154342A (en) * 2010-10-13 2013-06-12 欧瑞康纺织有限及两合公司 Device for thermally treating multiple threads
CN103154342B (en) * 2010-10-13 2016-01-06 欧瑞康纺织有限及两合公司 The device of heat treatment multi-filament line
CN104342801A (en) * 2013-08-05 2015-02-11 T-马克有限公司 Closed-type contact heater assembly used for thermal-treatment of yarn
CN110318106A (en) * 2019-06-24 2019-10-11 郑州中远氨纶工程技术有限公司 Thick denier spandex of a kind of high rebound and preparation method thereof

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