CN1508407A - Method for reducing harmful matter of exhaust for motorcycle engine unmounted with oxygen sensor - Google Patents
Method for reducing harmful matter of exhaust for motorcycle engine unmounted with oxygen sensor Download PDFInfo
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- CN1508407A CN1508407A CNA021566445A CN02156644A CN1508407A CN 1508407 A CN1508407 A CN 1508407A CN A021566445 A CNA021566445 A CN A021566445A CN 02156644 A CN02156644 A CN 02156644A CN 1508407 A CN1508407 A CN 1508407A
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- catalyst
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Abstract
The invention is a method to reduce harmful matters in the waste gas of the motorcycle engine without oxygen sensor, comprising a front segment catalyst and a back segment catalyst set in the exhaust pipe of the engine, the front segment catalyst is an oxidizing-type one, the back segment catalyst is reducing-type one, control the guiding flow of the secondary air to maintain better air-combustion ratio before guiding the secondary air in the front segment catalyst, so as to make the CO and hydrocarbon in the waste gas able to have been converted into carbon dioxide and water when the waster gas passes through the front segment catalyst, sustainedly purify the waster gas by the back segment catalyst to make nitrogen oxide hardly converted able to be reduced into harmless nitrogen and oxygen molecules, which heightens the discharge quality of waste gas of the motorcycle engine.
Description
Technical field
The invention provides the method that a kind of motor engine of not installing Lambda sensor reduces harmful matter in the waste gas, particularly import secondary air at the motor engine exhaust duct, with the control air fuel ratio, and the leading portion catalyst of oxidized form and the back segment catalyst of reduced form be set, impel contained carbon monoxide (CO) in the waste gas, hydrocarbon (HC) and nitrogen oxide harmful matters such as (NOX), all can be under desirable air fuel ratio, accept the oxidation and the reduction reaction of above-mentioned catalyst respectively, fill a part effect that purifies motorcycle emission waste gas to reach.
Background technique
Lambda sensor alleged in title of the present invention (is O
2Sensor), be a kind of utensil that detects institute's oxygen-containing molecules content in the combustion gas that mixes by air and fuel oil.It is used in the inlet end of car engine usually, detect the content that contains oxygen molecule in the oil gas of desiring to be supplied to each cylinder, and will detect signal and be conveyed to engine control unit (EngineControlUnit ECU) integrates control, to promote the efficient of engine running and purifying exhaust air.
As everyone knows, in the streets than major general's Lambda sensor (O
2Sensor) use in the operating environment of motor engine, because the air displacement of motor engine is less, and most fuel system that generally adopt Carburetor to distribute oil gas, this motor engine is not installed engine control unit (EngineControlUnit, ECU), so can't install and use Lambda sensor.Precursor comparatively in the streets, on motor engine, disposed the engine control unit (ECU) of simple type, and provide electrospray fuel feeding and electronic ignition etc. to exactly like the control mode of car engine, but because of motor engine mostly is the single-cylinder pattern, simple than car engine, therefore in the design of engine control unit (ECU), level off to conservatively, that is exempted such as Lambda sensor (O
2Sensor) control project is to reduce cost.
Owing to do not install Lambda sensor (O
2SenSor) motor engine, accurately control obtains the mixed proportion (being air fuel ratio A/F) of air (Air) and fuel oil (Fuel), to such an extent as to the motor engine running efficiency is inferior than automobile, the phenomenon that incomplete combustion generates harmful exhaust is comparatively serious.
As shown in Figure 1, as everyone knows, ideal air fuel ratio is 14.7 in the general engine environment of operation, air fuel ratio is if can be controlled in the set scope in 14.7 front and back, the running efficiency of expression engine is better, more be difficult for taking place the incomplete combustion phenomenon, the catalyst that impels the engine exhaust pipeline to be installed is healed easily and the harmful matter in the waste gas is carried out oxidation and reduction reaction.But, this standard of control air fuel ratio convergence that can be stable except the engine task environment that disposes above-mentioned Lambda sensor, in the streets there is no other more efficient methods in the technology.
Influence the reason of motor engine waste gas purifying efficiency, still comprise the installing technology of catalyst.According to the technology of present stage in the streets, the catalyst that is applied to the motor exhaust pipeline is to utilize one or a most carrier mostly, while coating platinum (Pt), palladium (Pd) or rhodium precious metals such as (Rh) in each carrier, and utilize the platinum (Pt) in the catalyst to come carbon monoxide (CO) and hydrocarbon (HC) harmful in the oxidation gaseous effluent with palladium (Pd), utilize rhodium (Rh) in the catalyst to reduce harmful nitrogen oxide (NOX) in the waste gas again, to reach the effect of purifying exhaust air.But, if air fuel ratio can't be stablized the set scope interior (hatched example areas as shown in Figure 1) that is controlled at about 14.7, just can't efficient oxidation CO, HC and while reductive NO X.
In addition, what deserves to be mentioned is, the practice that imports secondary air at the motor engine exhaust duct is in the streets arranged, this secondary air is the intermittent negative pressure that produces when turning round by motor engine, utilize this negative pressure power, and outside fresh air is imported in the outlet pipe, so as to replenishing the oxygen molecule (O in the waste gas
2), to promote the transformation efficiency of catalyst oxidizing carbon monoxide (CO) and hydrocarbon (HC).But the practice of importing secondary air will make oxygen molecule (O in the carrier
2) quantity increase, air fuel ratio certainly will be greater than 14.7, thus, there is no and benefit mixing rhodium (Rh) in platinum in carrier (Pt) and the palladium (Pd), force the transformation efficiency of rhodium (Rh) reductive NO X more low on the contrary.
Can find by above explanation, in the streets do not install in the motor engine environment of Lambda sensor, only have secondary air is imported the engine exhaust pipeline, technology with carbon monoxide (CO) and hydrocarbon harmful matters such as (HC) in the promotion catalytic control waste gas, but make the rhodium (Rh) can't efficient while nitrogen oxides reduction (NOX), to such an extent as to nitrogen oxide (NOX) content that is disposed in the atmosphere only increases, and is the main cause that causes acid rain, it is more serious to influence physical environment.
Summary of the invention
The purpose of this invention is to provide the method that a kind of motor engine of not installing Lambda sensor reduces harmful matter in the waste gas, by the leading portion catalyst of an oxidized form and the back segment catalyst of another reduced form are set at the engine exhaust pipeline, promote tradition to adopt Carburetor or idea to spray the motor engine of fuel feeding, can promote the transformation efficiency of harmful matter in catalyst oxidation and the reduction waste gas at its exhaust duct, reach the purpose of the toxic emission quality that promotes motor engine.
The object of the present invention is achieved like this: a kind of motor engine of not installing Lambda sensor reduces the method for harmful matter in the waste gas, and it is characterized in that: it includes:
(1) between the motor engine exhaust duct, be provided with the leading portion catalyst of an oxidized form, and the exhaust duct at leading portion catalyst rear is provided with the back segment catalyst of another reduced form, possesses a spacing between this leading portion catalyst and back segment catalyst;
(2) import secondary air in the exhaust duct before the leading portion catalyst, and control the importing flow of this secondary air;
(3) make the value that has leading portion air fuel ratio A/F＞14.7 by the waste gas in the exhaust duct between leading portion catalyst and the secondary air introducing port, be convenient to the leading portion catalyst and carry out oxidation reaction, carbon monoxide and hydrocarbon harmful in the waste gas are changed into harmless carbon dioxide and water;
(4) make the value that has another back segment air fuel ratio A/F 14.7 by the waste gas in the exhaust duct between leading portion catalyst and the back segment catalyst, be convenient to the back segment catalyst and carry out reduction reaction, conversion of nitrogen oxides harmful in the waste gas is become harmless nitrogen and oxygen.
At least contain platinum in this leading portion catalyst.At least contain palladium in this leading portion catalyst.At least contain rhodium in this back segment catalyst.This leading portion catalyst is to separate simultaneously in the baffler that is arranged on this exhaust duct with the back segment catalyst.This leading portion catalyst is to be located in the preceding ware-ejecting-tube road of baffler.This back segment catalyst is to be located in the baffler.The mode of this importing secondary air is to adopt secondary air control valve, by the action of engine negative pressure, in the exhaust duct before the secondary air importing leading portion catalyst in the external world.The mode of this importing secondary air is to adopt to give air pump, obtain engine running speed by engine control unit on the motorcycle, then wait ratio control to air pump give gas speed, make proportionally, import in the exhaust duct before the leading portion catalyst in order to secondary air the external world.
Major advantage of the present invention is: at the engine exhaust pipeline leading portion catalyst of one oxidized form and the back segment catalyst of another reduced form are set, make two catalyst carriers, one section heat-dissipating distance at interval, and before the leading portion catalyst, import secondary air, control the flow of this secondary air, make the waste gas that enters in the leading portion catalyst and air fuel ratio＞14.7 of secondary air mixed gas, and make the waste gas that enters in the back segment catalyst and the air fuel ratio 14.7 of secondary air mixed gas.
Use method of the present invention, will help to utilize the leading portion catalyst that carbon monoxide (CO) harmful in the waste gas and hydrocarbon (HC) are filled part and be oxidized to harmless carbon dioxide (CO
2) and water (H
2O), and simultaneously nitrogen oxide (NOX) harmful in the waste gas is filled part and be reduced into harmless nitrogen (N by the back segment catalyst
2) and oxygen molecule (O
2), to promote the efficient of harmful matter in the catalytic control waste gas.
Describe in detail below in conjunction with preferred embodiment and accompanying drawing.
Description of drawings
Fig. 1 is traditional catalyst reaction properties schematic representation.
Fig. 2 is an application flow schematic representation of the present invention.
Fig. 3 is front and back of the present invention section catalyst reaction properties schematic representation.
Fig. 4 is the application flow schematic representation figure of embodiments of the invention 2.
Embodiment
Consult Fig. 2-shown in Figure 3, the present invention discloses the method that a kind of motor engine of not installing Lambda sensor reduces harmful matter in the waste gas, includes:
10 of exhaust ducts at motor engine exhaust end 1 are provided with a leading portion catalyst 2; This leading portion catalyst 2 is the catalyst of an oxidized form, in the enforcement for the platinum (Pt) that utilizes in a metal or the ceramic monolith at least even coating requirement and/(or) palladium precious metals such as (Pd) is made.
The exhaust duct 10 at the present invention and above-mentioned leading portion catalyst 2 rears is provided with another back segment catalyst 3; This back segment catalyst 3 is a reduced form catalyst, and at least evenly rhodium (Rh) precious metal of coating requirement is made in a metal or the ceramic monolith in order to utilize in the enforcement.
Above-mentioned leading portion catalyst 2 and back segment catalyst 3 can be set at the baffler 11 interior (as shown in Figure 2) on the exhaust duct 10 simultaneously, and this leading portion catalyst 2 is to separate setting with 3 of back segment catalyst, make and possess a spacing h that can supply carrier to dispel the heat therebetween, avoid above-mentioned catalyst when transforming waste gas, because of the reaction temperature of oxidation or reduction too high working life that influences carrier.
The group of TG 2 above-mentioned two section type catalyst is established, and the present invention must import secondary air 4 simultaneously on the exhaust duct before the leading portion catalyst 2 10, and controls the importing flow of this secondary air.
The method of control secondary air import volume is to adopt modes such as negative pressure importing or electronic control importing on the implementation.
The preferred mode that this negative pressure imports, be to utilize a secondary air control valve, and this valve body is installed in the negative pressure end of engine or Carburetor, accept intermittent negative-pressure sucking and move, and then extraneous fresh air (being secondary air) is imported on the exhaust duct 10 before the leading portion catalyst 2.This mode easily makes the secondary air import volume increase and decrease along with the height of engine running speed, in other words, can make that secondary air import volume and air displacement are proportional, will help to control the air fuel ratio in the exhaust duct.
Utilize electronic control to import the mode of secondary air, be to obtain comparatively accurate engine running speed by engine control unit on the motorcycle (ECU), then wait ratio control one to import the air pump of giving that secondary air uses, make to air pump give gas speed and engine running speed proportional, be beneficial to control the interior air fuel ratio of exhaust duct 10.
When utilizing aforesaid way to import secondary air 4, the importing flow of secondary air is to increase or to reduce with the engine exhaust amount, therefore, engine exhaust end 1 has the content of exhaust gases in the content of secondary air and the discharging waste gas to the exhaust duct 10 of 2 of leading portion catalyst just can obtain control, that is the leading portion air fuel ratio 12 (A/F) in the exhaust duct 10 before the control leading portion catalyst 2 and between the secondary air introducing port, this leading portion air fuel ratio 12 (A/F) must be greater than 14.7 in the present invention.
Obtain in control under the situation of leading portion air fuel ratio 12 (A/F)＞14.7, to help to promote oxidized form leading portion catalyst 2 platinum (Pt) and (or) harmful carbon monoxide (CO) and the conversion ratio (as shown in Figure 3) of hydrocarbon (HC) in palladium (Pd) oxidation gaseous effluent, make carbon monoxide (CO) be oxidized to harmless carbon dioxide (CO
2) and water (H
2O), so along with exhaust duct 10 by back segment catalyst 3 and be vented to extraneous 5 (as shown in Figure 2).
By still containing not oxidized oxynitrides (NOX) in the waste gas behind the leading portion catalyst 2, and position back segment air fuel ratio in the exhaust duct 10 13 between leading portion catalyst 2 and back segment catalyst 3 is A/F14.7 this moment.Because leading portion catalyst 2 has transformed a certain proportion of oxygen (O in the waste gas that consumes leading portion air fuel ratio 12 (A/F＞14.7) and secondary air (Air) mixed gas
2), impel back segment air fuel ratio 13 to become A/F 14.7.
The value that control obtains back segment air fuel ratio 13 (A/F) is less than or equal to 14.7 benefit, it is the conversion ratio (as shown in Figure 3) of nitrogen oxide (NOX) harmful in rhodium (Rh) the reduction waste gas that can promote back segment catalyst 3, make nitrogen oxide (NOX) harmful in the waste gas, can be reduced into harmless nitrogen (N
2) and oxygen (O
2), and then along with other harmless waste gas together is vented to extraneous 5.
The practice by above importing secondary air 4, control leading portion air fuel ratio＞14.7, control back segment air fuel ratio 14.7, conversion ratio in the time of will effectively promoting leading portion catalyst 2 oxidizing carbon monoxides (CO) with hydrocarbon (HC), and the conversion ratio (as shown in Figure 3) when promoting back segment catalyst 3 nitrogen oxides reductions (NOX), to reach the toxic emission quality that promotes motor engine.
Consult shown in Figure 4, the mode of execution of the above-mentioned Fig. 2 that exemplifies of the present invention, wherein so long as oxidized form leading portion catalyst 2 and reduced form back segment catalyst 3 are arranged at intervals at 10 of exhaust ducts, promptly belong to application category of the present invention, this leading portion catalyst 2 might not be arranged in the baffler 11 with back segment catalyst 3.
In other words, also can implement oxidized form leading portion catalyst 2 is arranged in baffler 15 exhaust duct 14 outward, again reduced form back segment catalyst 3 is located at the form of (as shown in Figure 4) in the baffler 15, also belong to application of the present invention.
In sum, the invention provides the method that a kind of motor engine of not installing Lambda sensor reduces harmful matter in the waste gas, though its usefulness can not match in excellence or beauty with the car engine that is provided with Lambda sensor, but the single-cylinder motor engine to a large amount of employing Carburetors or electronic oil injection system brings greatest benefiting, particularly can make carbon monoxide (CO) harmful in the waste gas, hydrocarbon (HC) and nitrogen oxide (NOX), all can together be cleaned removing, so under the existing limited configuration surroundings of motor engine, have the remarkable result that promotes purifying exhaust air, have novelty, creativeness and practicability.
Claims (9)
1, a kind of motor engine of not installing Lambda sensor reduces the method for harmful matter in the waste gas, and it is characterized in that: it includes:
(1) between the motor engine exhaust duct, be provided with the leading portion catalyst of an oxidized form, and the exhaust duct at leading portion catalyst rear is provided with the back segment catalyst of another reduced form, possesses a spacing between this leading portion catalyst and back segment catalyst;
(2) import secondary air in the exhaust duct before the leading portion catalyst, and control the importing flow of this secondary air;
(3) make the value that has leading portion air fuel ratio A/F＞14.7 by the waste gas in the exhaust duct between leading portion catalyst and the secondary air introducing port, be convenient to the leading portion catalyst and carry out oxidation reaction, carbon monoxide and hydrocarbon harmful in the waste gas are changed into harmless carbon dioxide and water;
(4) make the value that has another back segment air fuel ratio A/F 14.7 by the waste gas in the exhaust duct between leading portion catalyst and the back segment catalyst, be convenient to the back segment catalyst and carry out reduction reaction, conversion of nitrogen oxides harmful in the waste gas is become harmless nitrogen and oxygen.
2, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that: contain platinum at least in this leading portion catalyst.
3, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that: contain palladium at least in this leading portion catalyst.
4, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that: contain rhodium at least in this back segment catalyst.
5, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, and it is characterized in that: this leading portion catalyst is to separate simultaneously in the baffler that is arranged on this exhaust duct with the back segment catalyst.
6, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that: this leading portion catalyst is to be located in the preceding ware-ejecting-tube road of baffler.
7, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that this back segment catalyst is to be located in the baffler.
8, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that: the mode of this importing secondary air is to adopt secondary air control valve, by the action of engine negative pressure, in the exhaust duct before the secondary air importing leading portion catalyst in the external world.
9, the motor engine of not installing Lambda sensor according to claim 1 reduces the method for harmful matter in the waste gas, it is characterized in that: the mode of this importing secondary air is to adopt to give air pump, obtain engine running speed by engine control unit on the motorcycle, give gas speed then wait ratio to control to air pump, make proportional, in the exhaust duct that the secondary air in the external world is imported before the leading portion catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02156644 CN1225595C (en) | 2002-12-17 | 2002-12-17 | Method for reducing harmful matter of exhaust for motorcycle engine unmounted with oxygen sensor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02156644 CN1225595C (en) | 2002-12-17 | 2002-12-17 | Method for reducing harmful matter of exhaust for motorcycle engine unmounted with oxygen sensor |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1508407A true CN1508407A (en) | 2004-06-30 |
| CN1225595C CN1225595C (en) | 2005-11-02 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 02156644 Expired - Fee Related CN1225595C (en) | 2002-12-17 | 2002-12-17 | Method for reducing harmful matter of exhaust for motorcycle engine unmounted with oxygen sensor |
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| Country | Link |
|---|---|
| CN (1) | CN1225595C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020008981A1 (en) * | 2018-07-05 | 2020-01-09 | 株式会社キャタラー | Exhaust gas purification catalyst device |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4363398B2 (en) * | 2005-12-08 | 2009-11-11 | トヨタ自動車株式会社 | Air-fuel ratio control device for internal combustion engine |
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2002
- 2002-12-17 CN CN 02156644 patent/CN1225595C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2020008981A1 (en) * | 2018-07-05 | 2020-01-09 | 株式会社キャタラー | Exhaust gas purification catalyst device |
| JP2020006301A (en) * | 2018-07-05 | 2020-01-16 | 株式会社キャタラー | Exhaust gas purification device |
| JP7245613B2 (en) | 2018-07-05 | 2023-03-24 | 株式会社キャタラー | Exhaust gas purification catalyst device |
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| Publication number | Publication date |
|---|---|
| CN1225595C (en) | 2005-11-02 |
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| C14 | Grant of patent or utility model | ||
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Address after: The North Industrial Zone of Jimei city of Fujian province Xiamen Tianyang Road No. 51 Patentee after: XIAMEN XINYUAN ENVIRONMENT PROTECTION TECHNOLOGY CO., LTD. Address before: Xiamen city of Fujian Province Patentee before: Xiamen Xinyuan Traffic Appratus Co., Ltd. |
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| C56 | Change in the name or address of the patentee |
Owner name: XIAMEN XINYUAN ENVIRONMENTAL PROTECTION TECHNOLOGY Free format text: FORMER NAME: XIAMEN XINYUAN TRAFFIC EQUIPMENT CO., LTD. |
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Granted publication date: 20051102 Termination date: 20121217 |