CN1481202A - Display device mixed electro luminescence with luminescence - Google Patents

Display device mixed electro luminescence with luminescence Download PDF

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Publication number
CN1481202A
CN1481202A CNA031467768A CN03146776A CN1481202A CN 1481202 A CN1481202 A CN 1481202A CN A031467768 A CNA031467768 A CN A031467768A CN 03146776 A CN03146776 A CN 03146776A CN 1481202 A CN1481202 A CN 1481202A
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CN
China
Prior art keywords
layer
display device
bar shaped
photic
light
Prior art date
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Pending
Application number
CNA031467768A
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Chinese (zh)
Inventor
何大伟
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Beijing Jiaotong University
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Beijing Jiaotong University
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Filing date
Publication date
Application filed by Beijing Jiaotong University filed Critical Beijing Jiaotong University
Priority to CNA031467768A priority Critical patent/CN1481202A/en
Publication of CN1481202A publication Critical patent/CN1481202A/en
Pending legal-status Critical Current

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Abstract

Display device includes substrate layer, bar shaped electrode photoetched, dielectric layer, electro photoluminescence layer, dielectric layer, bar shaped ITO electrode photoetched, transparent glass. Luminescent material ZnF2:GdF3 capable of generating blue ultraviolet light is selected as the material of electro photoluminescence layer between two dielectric layers. Photoluminescence is aligned and glued to ITO electrode with their bar shaped density and relative position total overlapped. Under power source driving in different frequencies, the electro photoluminescence material is capable of emitting strong ultraviolet light to excite photoluminescence so as to realize tabulate display with monocolor and multicolor shown. Two times of emissive power is enhanced in the invention.

Description

A kind of electricity causes/photic mixed luminescence display device
One, technical field
The present invention relates to a kind of flat-panel monitor.
Two, background technology
The main difficulty of current thin film electroluminescent device (TFELD) is to realize panchromaticization.In three primary colors, red and green all can meet the demands, and the brightness of blue light is then not enough.For this reason, the various countries researcher has launched many-sided research work round the brightness and the colorimetric purity that improve blue TFELD.
Generally concentrate on and select matrix and impurity and improve on the crystalline state of blue light material about the work of the brightness of blue membrane electroluminescent device, should make the energy gap increase of material make device send blue light, avoiding collecting in the sandwich just again, electronics source, electronics acceleration and these three processes of collision excitation luminescence center make the bottleneck process of thin film electroluminescence be difficult to overcome in the difficulty of one deck.The material that conventional interlayer thin-film electroluminescent displays part uses mainly is SrS:Ce, SrGa 2S 4: Ce, SrS:Cu etc., in the process of film preparation, because the difference of vapour pressure, the subnormal stoicheiometry of the sulfur content among the SrS causes serious mistake sulphur, and is although mend the crystallization that sulphur can improve material, bigger to the pollution of coating system; The tradition method for annealing can cause that the elements such as oxygen in the insulating barrier spread to luminescent layer, and destroys the performance of luminescent layer.
Three, summary of the invention
In order to overcome the existing in prior technology problem, the present invention selects suitable electroluminescent material, utilizes strong ultraviolet light that electroluminescence (EL) device sends as excitaton source, and excitated fluorescent powder makes it to produce visible light.Provide a kind of electricity to cause/photic mixed luminescence display device, strengthen conventional interlayer thin-film electroluminescent displays part luminous intensity to reach.
Technical program of the present invention lies in: in traditional sandwich electroluminescent display, the material selection of the electroluminescence layer between two dielectric layers can produce the luminescent material ZnF of ultraviolet light 2: GdF 3The bar shaped density of luminescence generated by light layer and ITO electrode and relative position be overlapping the alignment fully, bonding.Electroluminescent material can be launched strong ultraviolet light under the different frequency power drives, the exciting light electroluminescent layer realizes monochrome, multiple flat panel display such as colour.
The present invention compares the beneficial effect that is had with prior art: (1) is because structure and the electroluminescent material of selecting for use cause this device to realize monochromatic and colored the demonstration easily.(2) widened the used material of the monochromatic and colored demonstration of realization.(3) have only ITO electrode pair electroluminescence (EL) emission to produce and absorb, absorption loss reduces greatly, and emissive porwer has strengthened twice approximately.
Four, description of drawings
Fig. 1 electricity causes/photic mixed luminescence display device structural representation
Among the figure: electrode, 3 dielectric layers, 4 electroluminescence layers, 5 dielectric layers, 6 that 1 substrate layer, 2 is photo-etched into bar shaped are photo-etched into ITO electrode, 7 luminescence generated by light layers, 8 clear glasses of bar shaped
Five, embodiment
Below in conjunction with accompanying drawing to electricity of the present invention cause/photic mixed luminescence display device is further described.The present invention is that a kind of thin-film electro of sandwich construction causes/photic mixed luminescence device.
Electricity of the present invention causes/and photic mixed luminescence display device comprises: is followed successively by substrate layer 1, is photo-etched into electrode 2, dielectric layer 3, electroluminescence layer 4, dielectric layer 5, the ITO electrode 6 that is photo-etched into bar shaped, luminescence generated by light layer 7, the thin clear glass 8 of bar shaped.
Execution mode one
1. choosing has the substrate layer 1 that is photo-etched into strip electrode 2 (Al), line density 3/mm.
2. vacuum sputtering or electron beam evaporation evaporation SiO on electrode 2 2(dielectric layer 3).
3. at SiO 2On the dielectric layer 3, adopt electron beam evaporation plating can produce the luminescent material ZnF of ultraviolet light 2: GdF 3(electroluminescence layer 4).
4. on electroluminescence layer 4, vacuum sputtering or electron beam evaporation SiO 2(dielectric layer 5).
5. on dielectric layer 5, use bushing evaporation In 2O 3: Sn (ITO electrode 6), 3/mm of line density is vertical with the Al strip electrode.
6. on clear glass 8, vacuum evaporation Y successively 2O 3: Eu (red), Zn 2SiO 4: Mn (green), BaMgAl 10O 17: Eu (indigo plant), red, green, blue luminescence generated by light layer 7 is distributed be bar shaped alternate, its bar shaped density and relative position and the density and the relative position that are photo-etched into the ITO electrode 6 of bar shaped are consistent.
The bar shaped density of luminescence generated by light layer 7 and ITO electrode and relative position be overlapping the alignment fully, after bonding, the sealing, makes flat-panel display device of the present invention.This flat-panel monitor is exchanging under the 100-380V voltage, is colored and shows.
Execution mode two
Green light material ZnS:Cu or red light material SrS:Eu or blue material aluminate with electron beam evaporation plating or silk screen printing on thin clear glass 8; Other technologies are identical with execution mode one with condition, and this flat-panel monitor is exchanging under the 100-380V voltage, are monochromatic show (red green or blue).
Two dielectric layers 3,5 of the present invention both can adopt same material, also available different materials.Two dielectric layers can adopt symmetrical structure (two layers of thickness unanimity) and unsymmetric structure (two layers of thickness is different).Dielectric layer 3,5 of the present invention can also be selected yttria (Y for use 2O 3), hafnium oxide (HfO 2), aluminium oxide (Al 2O 3), silicon nitride Si 3N 4, tantalum pentoxide Ta 2O 5And ferroelectric material lead titanates PbTiO 3With barium titanate BaTiO 3Deng material.
The material of electroluminescent material layer 4 of the present invention can also adopt the luminescent material ZnF that can produce ultraviolet light 2: Gd 2S 3, ZnF 2: Gd 2O 3Deng.
The material of luminescence generated by light layer 7 of the present invention also can adopt green light material ZnS:Cu, BaAl 12O 19: Mn, SrAl 2O 4: Eu, (Ce, Tb) MgAl 11O 19, LaPO 4: Tb, Ce; Red light material CaS:Eu, SrS:Eu, (Y, Gd) BO 3Blue light material BaMgAl 14O 23: the combination of one or more among the Eu.

Claims (5)

1. an electricity causes/photic mixed luminescence display device, comprise: be followed successively by substrate layer (1), be photo-etched into electrode (2), dielectric layer (3), electroluminescence layer (4), dielectric layer (5), the ITO electrode (6) that is photo-etched into bar shaped, the clear glass (8) of bar shaped, it is characterized in that: the material selection of the electroluminescence layer (4) between two dielectric layers (3) and (5) can produce the luminescent material ZnF of ultraviolet light 2: GdF 3The bar shaped density of luminescence generated by light layer 7 and ITO electrode and relative position be overlapping the alignment fully, bonding.
2. the electricity according to claim 1 causes/photic mixed luminescence display device, it is characterized in that: dielectric layer (3,5) both can adopt same material, also can adopt different materials, two dielectric layers (3,5) can adopt symmetrical structure (two layers of thickness unanimity) and unsymmetric structure (two layers of thickness is different).
3. cause/photic mixed luminescence display device according to claim 1,2 described electricity, it is characterized in that: the material of electroluminescence layer (4) also adopts ZnF 2: Gd 2S 3, ZnF 2: Gd 2O 3
4. cause/photic mixed luminescence display device according to claim 1,2 described electricity, it is characterized in that: the material of dielectric layer (3,5) also can be: yttria (Y 2O 3), hafnium oxide (HfO 2), silica (SiO 2), aluminium oxide (Al 2O 3), silicon nitride Si 3N 4, tantalum pentoxide Ta 2O 5And ferroelectric material lead titanates PbTiO 3With barium titanate BaTiO 3
5. cause/photic mixed luminescence display device according to claim 1,2 described electricity, it is characterized in that: the material of luminescence generated by light layer (7) adopts green light material ZnSCu, BaAl 12O 19: Mn, SrAl 2O 4: Eu, (Ce, Tb) MgAl 11O 19, LaPO 4: Tb, Ce; Red light material CaS:Eu, SrS:Eu, (Y, Gd) BO 3Blue light material BaMgAl 14O 23: the combination of one or more among the Eu.
CNA031467768A 2003-06-26 2003-06-26 Display device mixed electro luminescence with luminescence Pending CN1481202A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CNA031467768A CN1481202A (en) 2003-06-26 2003-06-26 Display device mixed electro luminescence with luminescence

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Application Number Priority Date Filing Date Title
CNA031467768A CN1481202A (en) 2003-06-26 2003-06-26 Display device mixed electro luminescence with luminescence

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CN1481202A true CN1481202A (en) 2004-03-10

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105161634A (en) * 2015-09-10 2015-12-16 京东方科技集团股份有限公司 Active matrix/organic light emitting diode (AMOLED) device, fabrication method thereof and display device fabricated from same
CN109545932A (en) * 2017-09-22 2019-03-29 三星显示有限公司 Light emitting diode

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105161634A (en) * 2015-09-10 2015-12-16 京东方科技集团股份有限公司 Active matrix/organic light emitting diode (AMOLED) device, fabrication method thereof and display device fabricated from same
CN105161634B (en) * 2015-09-10 2017-11-24 京东方科技集团股份有限公司 A kind of AMOLED devices and preparation method thereof, by its obtained display device
CN109545932A (en) * 2017-09-22 2019-03-29 三星显示有限公司 Light emitting diode
CN109545932B (en) * 2017-09-22 2024-03-08 三星显示有限公司 Light emitting diode

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