CN1480661A - Tooth belt and its prepn. method - Google Patents
Tooth belt and its prepn. method Download PDFInfo
- Publication number
- CN1480661A CN1480661A CNA031496075A CN03149607A CN1480661A CN 1480661 A CN1480661 A CN 1480661A CN A031496075 A CNA031496075 A CN A031496075A CN 03149607 A CN03149607 A CN 03149607A CN 1480661 A CN1480661 A CN 1480661A
- Authority
- CN
- China
- Prior art keywords
- toothed belt
- covering fabric
- belt
- thermoplastic elastomer
- tooth
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
- F16G1/00—Driving-belts
- F16G1/28—Driving-belts with a contact surface of special shape, e.g. toothed
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D29/00—Producing belts or bands
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16G—BELTS, CABLES, OR ROPES, PREDOMINANTLY USED FOR DRIVING PURPOSES; CHAINS; FITTINGS PREDOMINANTLY USED THEREFOR
- F16G1/00—Driving-belts
- F16G1/06—Driving-belts made of rubber
- F16G1/08—Driving-belts made of rubber with reinforcement bonded by the rubber
- F16G1/12—Driving-belts made of rubber with reinforcement bonded by the rubber with metal reinforcement
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
Abstract
To provide a method for manufacturing a toothed belt which can improve a jumping performance and durability by suppressing occurrence of an allophone as compared with a prior art. The method for manufacturing the toothed belt includes the steps of arranging an extendible canvas 2 on a toothed surface of a mold 1 having a tooth shape, fixing a resin film 3 extendible in synchronism with the canvas 2 fixed to the surface side of the canvas 2 in contact with the mold 1 and set to a higher melting point than a belt body material 5, and molding the belt body material 5 of a flowable state at the melting point or lower by the mold 1. (C)2004,JPO.
Description
Background of invention
1. technical field
The present invention relates to a kind ofly to can be used for power transmission, toothed belt that is prepared from by thermoplastic elastomer of aspect and preparation method thereof such as transport.
2. correlation technique brief introduction
Traditional toothed belt is that (for example open (kokai) H11-182632 (1-2 page or leaf, Fig. 1)) of Japan special permission or thermosetting polyurethane elastomer are prepared from, aspect such as be usually used in power transmission, transport by rubber.This profile of tooth is meshed with belt wheel at the bottom of having tooth and tooth.
Along with the functions of the equipments of using the toothed belt structure are increasingly sophisticated, increasing toothed belt all can not satisfy current line belt technical requirements (especially when tooth pitch is very little) aspect anti-tooth jumping ability, durability, reduction driving friction and the sensitivity.In addition,, in the process of using, then be easy to peel off or separately, thereby unusual noise occur, unsuitable tooth is jumped and the reduction of durability if resin or elastomer are exposed to the tooth table.
Summary of the invention
Therefore, one object of the present invention just provides and a kind ofly has more excellent anti-tooth with respect to traditional product (rubber tape and heat-curable urethane band) and jump ability, good durability, the low toothed belt that drives friction, high sensitivity and can eliminate abnormal sound.
According to the present invention, toothed belt provided by the present invention is characterized in that by belt body, constitutes as the cotton rope of tensional element and the covering fabric that covers the band tooth surface.Wherein belt body is made by the thermoplastic elastomer that has rubber and plastics excellent properties (elasticity and intensity) concurrently.This thermoplastic elastomer contains the copolymer that a kind of hard segment by crystallised phase and noncrystalline soft chain segment are mutually formed, and at room temperature shows rubber elasticity, at high temperature shows plasticity and can mould.
As mentioned above, because toothed belt of the present invention is such structure,, also can prevent oozing out and reducing to drive and rub of resin so for traditional rubber tape, it possesses excellent anti-tooth and jumps ability, good durability, high sensitivity etc.
At this, for example, the material of covering fabric can be nylon, polyester, aromatic copolyamide, cotton and pbo fiber etc.In addition, the material of cotton rope can be polyester, glass fibre, aromatic copolyamide, steel, carbon fiber and pbo fiber etc.
Thermoplastic elastomer is preferably polyester elastomer.This thermoplastic polyether ester can be made up of with the copolymer of aliphatic polyether (noncrystalline (soft chain segment) mutually) aromatic polyester (crystallised phase (hard segment)).The preferred high-melting-point aromatic polyester of hard segment wherein is because it possesses high crystalline rate, high strength, heat resistanceheat resistant deformation, good plasticity, chemical stability and resistant to thermal aging performance.And soft chain segment is preferably the aliphatic polyether with lower glass transition temperatures, because it possesses pliability, HI high impact absorption and low-temperature characteristics.Can select the hard segment and the soft chain segment design of proper ratio to make the elastomer that has above-mentioned excellent properties concurrently.
The toothed belt that adopts above-mentioned material to make with this structure possesses noise free, shock-resistant, shock resistance, low-temperature flexibility, high bending strength, good anti-environment (low external pressure) ability and keeps the advantage of food sanitation.
As a kind of thermoplastic elastomer, thermo-plastic polyurethane's elastomer also can be used for preparing toothed belt.Thermo-plastic polyurethane's elastomer comprises two kinds of polyester type and polyether-types, is made of hard segment and soft chain segment.Wherein soft chain segment comprises polyethylene adipate, polybutylene adipate, other adipate ester (ADP), polycaprolactone (PCL), polycarbonate (PC) (PC) or other aliphatic polyester diol, polytetramethylene ether glycol (PTMG), polyethyleneglycol (PEG), polypropylene glycol (PPG), other aliphatic polyether diol or other polyatomic alcohol polybasic alcohol (long chain diol).Hard segment comprises vulcabond and short chain dihydroxylic alcohols.
When soft chain segment was made of polyester polyol such as polyethylene adipate, polybutylene adipate, other adipate ester (ADP), polycaprolactone (PCL), polycarbonate (PC) (PC) or other aliphatic polyester diol, thus obtained thermo-plastic polyurethane's elastomer then had excellent mechanical property, heat resistanceheat resistant performance, friction resistant performance and chemical stability.On the other hand, when soft chain segment was polytetramethylene ether glycol (PTMG) or other polyether polyol, thus obtained thermo-plastic polyurethane's elastomer then had excellent water repelling property and low-temperature characteristics.In addition, as for the basic thermo-plastic polyurethane's elastomer of MDI (MDI) of hard segment, when the chain length of chain extender increased, its cohesion energy density and physical property all descended to some extent for aliphatic ethylene glycol chain extender.
Aforesaid toothed belt possesses more excellent burnish resistance, durability and bottom surface transmissibility (because high μ value).
The thermoplastic elastomer that also can adopt hardness to reach A70～A95 (shore hardness of JIS-K6253) prepares toothed belt.This toothed belt has excellent flexibility, durability and high load performance.
Toothed belt of the present invention can prevent effectively that thermoplastic elastomer from oozing out the band tooth surface from the place that covering fabric scatters.When toothed belt turned round, the thermoplastic elastomer that is exposed to the toothed belt surface was easy to peel off and is deposited in belt wheel bottom, thus aging, the low durability that causes relatively poor engagement, frequent tooth to be jumped causing and the generation of abnormal sound.
Another object of the present invention just provides a kind of preparation method of above-mentioned toothed belt, and the toothed belt that makes thus can prevent that resin from oozing out or overcome some molding defects from the band tooth surface.
Just, according to the present invention, the preparation method of toothed belt provided by the invention, it is characterized in that at first forming the pre-shaped articles of thermoplastic elastomer, again covering fabric, cotton rope and described pre-shaped articles are put into shaping die, from outside hot pressing said composition material, under the solidification point of thermoplastic elastomer and the uniform temperature between the melt temperature,, and keep a period of time to forming the band tooth from the mould inside heating.
In the preparation process of toothed belt, can be from outside hot pressing said composition material, thereby under the solidification point of thermoplastic elastomer and the uniform temperature between the melt temperature from the flowability of mould inside heating a period of time control thermoplastic elastomer.The said temperature condition can be kept a period of time to promote toothed formation.That is to say, carry out the toothed belt plastotype since can under the state that the flowability of thermoplastic elastomer is controlled by above-mentioned specific molding temperature condition, keep a period of time, so just can prevent effectively that thermoplastic elastomer is exuded to the band tooth surface from the space of covering fabric.In addition, also can prevent the top chamfer that produces when the generation of molding defect and tooth can not be completed into.
Notice that molding temperature is chosen in the solidification point that is higher than thermoplastic elastomer but is lower than a scope of its melt temperature, normally 125 ℃～190 ℃.
In becoming the process of tooth, can make it be approximately 5 * 10 by regulating molding temperature and controlling the flow of thermoplastic elastomer heating time
-4～6 * 10
-3Milliliters/second (50kgf/cm
2Load, the aperture of 1mm * 1mm and length).
If the molding temperature condition that is provided with makes the flow of thermoplastic elastomer be approximately 5 * 10
-4To 6 * 10
-3Milliliters/second, the molding temperature scope is between the solidification point and melt temperature of thermoplastic elastomer, can prevent effectively that then thermoplastic elastomer is exuded to the generation of band tooth surface and toothed belt molding defect (top chamfer that produces when tooth can not be completed into) from the space of covering fabric, so mould-forming is just more accurate.
In order to test the flow of thermoplastic elastomer, can select the flow detector CET-500 of preparation such as Shimdzu Mfg., test condition is: load 50kgf/cm
2, 100 seconds preheat time, sectional area is 1cm
2Plunger piston, die head aperture * length is 1mm * 1mm.Reach temperature (probe temperature) and preheating 100 seconds (keeping same temperature 100 seconds so that whole sample reaches identical temperature) are set after, utilize piston to bestow 50kgf/cm to sample
2Load, can record the flow that the sample per second flows out from die holes.
The filament denier of covering fabric is preferably 0.5～3.0 than (parallel/warp), and thread density is preferably 0.5～1.0 than (parallel/warp), and the specific elongation of covering fabric is approximately 50～150% (under 50mm spacing/2kgf).If this covering fabric was handled through resin or wet-cured type urethane before molding, then performance is more excellent.
Adopt the covering fabric of structure as mentioned above, this covering fabric is overlayed on the thermoplastic elastomer that flows in moulding process, even be stretched, it is overlapping also can to produce long filament, perforate reduces, thereby can prevent effectively that thermoplastic elastomer is exuded to the generation of band tooth surface and molding defect (top chamfer that produces when tooth can not be completed into) from the space of covered structure, so mould-forming is just more accurate.In addition, if handle through resin or wet-cured type urethane before the covering fabric molding, then the bonding of thermoplastic elastomer and covering fabric will be more firm.
In addition, the invention provides a kind of preparation method of toothed belt, it is characterized in that to have the shape tooth surface that certain flexible covering fabric is put into the shaping die with tooth-shape structure, be laminated to then contiguous shaping die covering fabric the surface and and the resin film that stretches together of covering fabric, the melt temperature of this resin film is higher than the melt temperature as the thermoplastic elastomer of belt body material, makes thermoplastic elastomer be lower than fluidised form moulding under the temperature of its fusing point in shaping die at last.
Adopt the toothed belt of method for preparing, wherein resin film is laminated to the covering fabric surface of contiguous shaping die, and stretches together with covering fabric, has the melt temperature higher than thermoplastic elastic body.When the belt body material is being lower than under the uniform temperature of melting point resin with the space of flowing state by covering fabric, has more dystectic resin film and be not in molten state, thereby stoped passing of belt body material.Therefore, the belt body material just can not be exuded to the band tooth surface, also just can not be exposed to toothed surface.
In addition, covering fabric and resin film can be overlayed in the belt body material that flows during the moulding toothed belt, are expanded to the groove of being close to shaping die together, form thickness identical substantially covering fabric and resin film.If the covering fabric as the bottom has consistent thickness, it is stable that nodel line will become, and cotton rope also can be protected, thereby favorable durability is provided.
After placing the material of sheet material or some other deformable solid shape on the shaping die, the belt body material can be heated or make it to be transformed into a kind of fluidised form (liquid resin or molten state), and charges in the shaping die by equipment such as extruders.Also can make flowable belt body material from the space of covering fabric, pass and and resin film merge together.
In the forming process of toothed belt, resin plays emollescence to a certain degree.By flowable belt body material is passed from the space of covering fabric and and resin film merge together, cool off then, belt body material, covering fabric and resin film just can be stacked mutually more firmly.Wherein can use polyether ester as the belt body material, the polyetherester resins film is as resin film.
As the belt body material, preferred thermoplastic elastomer, various thermoplastic elastomers all can use.On the other hand, various resins or elastomer all can be used as resin film.In these materials, polyether ester is preferably two kinds of components, because polyetherester resins is to have better hot properties, the high-strength and rubber elasticity from low temperature to high temperature in thermoplastic elastomer.Thereby possess wide serviceability temperature scope, more excellent shock absorbing, anti-profit and chemical stability, and the gearing noise between reduction and the belt wheel, and low friction pair effect has brought better durability.In addition, also can use liquid injection molding moulding resin or elastomer to pass through injection forming equipment moulding toothed belt, or select thermoplastic elastomer by extruder moulding toothed belt as the belt body material.
In said method, form a kind of phenolic resin layer, the phenol of this phenolic resin layer through containing tool unsaturated bond side chain and/or a kind of component modified of phenolic group carboxylic acid at the outermost surface of covering fabric.When implementing this kind method, the cohesiveencess of covering fabric and the belt body material made by polyetherester resins is more excellent.Before forming the phenolic resin layer on the covering fabric, be very beneficial for reducing friction between the covering fabric yarn, improve the wear resistance of covering fabric with the processing of latex or RFL.
In said method, cotton rope embeds wherein, and the outermost surface of covering fabric forms a kind of phenol and/or phenolic resin layer of modifying of a kind of component of phenolic group carboxylic acid through containing tool unsaturated bond side chain.When adopting this method moulding, the adhesive property of cotton rope and the belt body material made by polyetherester resins is more excellent.Attention is in order to increase the bonding strength of cotton rope (glass fibre or aromatic polyamide fiber) and belt body, for example, cotton rope can be as required and resorcinol-formaldehyde resin (RFL) layer or have with the bonding more firm outer field resorcinol-formaldehyde resin layer moulding of RFL layer.
Description of drawings
Description and corresponding accompanying drawing thereof by preferred embodiment as follows can better understand the present invention, wherein:
Fig. 1 be first kind of embodiment of the present invention toothed belt sectional schematic diagram;
Fig. 2 is an expression profile of tooth of the present invention perspective view with well;
Fig. 3 is the schematic representation of expression Resin Flow and temperature relation;
Fig. 4 is an oil resistance test result schematic representation;
Fig. 5 drives the CROCKING TEST result schematic diagram;
Fig. 6 is the schematic representation of the structure of expression rotation validity testing instrument;
Fig. 7 is a rotation validity test result schematic representation;
Fig. 8 is the sensitivity test result schematic diagram;
Fig. 9 is that tooth is jumped the test result schematic representation;
Figure 10 is a grease resistance test result schematic representation;
Figure 11 is a stop place validity test result schematic representation;
Figure 12 is the durability test schematic representation;
Figure 13 is the sectional schematic diagram of the toothed belt of second kind of embodiment of the present invention;
Figure 14 is preparation method's schematic representation of the toothed belt of second kind of embodiment of the present invention;
Figure 15 is the planimetric map of the space state of expression covering fabric;
Figure 16 is the traditional preparation process method schematic representation of toothed belt.
Preferred embodiment
Below in conjunction with relevant drawings the preferred embodiments of the disclosure is illustrated.Introduce first kind of embodiment at first with reference to the accompanying drawings.
[first kind of embodiment]
Fig. 1 is the sectional schematic diagram of the toothed belt 10 of first kind of embodiment of the present invention.Toothed belt 10 is made of the belt body material 15 that becomes tooth and the covering fabric 12 on toothed belt 10 surfaces.In addition, the cotton rope 16 as tensional element is embedded in the belt body material 15.
Next the method that is prepared toothed belt by thermoplastic elastomer is described.At first, thermoplastic resin is moulded the plate like pre-shaped articles of class (resin flake) by extruder die.
Used thermoplastic elastomer is made up of thermoplastic polyester elastomer and thermo-plastic polyurethane's elastomer.The thermoplastic polyester elastomer has hard segment structure and the soft chain segment structure shown in chemical formula (2) shown in chemical formula (1).For example can use the elastomer of the Pelprene by name that produces by Toyobo company (Toyoho CO.LTD.) or by the elastomer of the Hytrel by name of production such as DUPONT-TORAY (DUPONT-TORAY CO.LTD.) company of etc.ing etc.
In addition, thermo-plastic polyurethane's elastomer of making pre-shaped articles can use the elastomer of the Miractran by name that is produced by NipponMiractran or the elastomer of the Elastran by name that BASF Japan produces etc.
The material of cotton rope for example, can use polyester, glass fibre, aromatic copolyamide, steel, carbon fiber, pbo fiber etc.
The material of covering fabric for example, can be nylon, polyester, aromatic copolyamide, cotton or pbo fiber etc.In addition, if selecting the filament denier of covering fabric is 0.5～3.0 than (parallel/warp), thread density is 0.5～1.0 than (parallel/warp), specific elongation is about 50～150% (under 50mm spacing/2kgf), and before molding, handle through resin or wet-cured type urethane, in moulding process, it is overlayed in the thermoplastic elastomer that flows then, even covering fabric is stretched so, it is overlapping also can to produce long filament, perforate reduces, thereby prevent that effectively thermoplastic elastomer is exuded to the generation of band tooth surface and some molding defects (top chamfer that produces when tooth can not be completed into) from the space of covering fabric, therefore mould-forming is just more accurate, bonding also more firm between thermoplastic elastomer and covering fabric.
Toothed metal mold is put in resilient covering fabric, cotton rope and pre-shaped articles combination, coated with rubber bag.With the pressure of 500～3000Kpa and 70～200 ℃ temperature it is carried out hot pressing in the rubber bag outside, and then heat with the uniform temperature between thermoplastic elastomer solidification point (different and different) and the melt temperature (different and different) and keep a period of time with resin grades with resin grades at mould inside.The molding temperature scope is to be higher than the solidification point of thermoplastic elastomer but to be lower than its melt temperature, and difference is generally 125 ℃～190 ℃ along with the resin grades difference.
In forming process, molding temperature is arranged between the solidification point and melt temperature of thermoplastic elastomer, so that the flow of thermoplastic elastomer is about 5 * 10
-4～6 * 10
-3Milliliters/second (50kgf/cm
2The aperture of load and 1mm * 1mm and length), and from mould inside heating a period of time.By regulating molding temperature, the flow that thermoplastic elastomer is set is about 5 * 10
-4～6 * 10
-3Milliliters/second just can make the correct moulding of toothed belt and the top chamfer that produces when not having thermoplastic elastomer to be exuded to tooth table or tooth can not to be completed into.
After hot press molding finished, the cooling material also took out from mould and promptly obtains toothed belt sleeve pipe (see figure 2).The sleeve pipe of toothed belt 1 has at the bottom of tooth 2 and the tooth 3 to be meshed with belt wheel etc.Then, again sleeve pipe is cut into certain width and can obtain toothed belt (speed belt).
(embodiment of thermoplastic elastomer)
Next, set the embodiment of thermoplastic elastomer flow shown in Fig. 3 and table 1.
Fig. 3 is the schematic representation of expression Resin Flow and temperature relation.In the drawings, TPEE-A and TPEE-B are thermoplastic polyester elastomer (Toyobo company produce, Pelprene by name), and TPEE-C and TPEE-D also are thermoplastic polyester elastomer (DUPONT-TORAY company produce, Hytrel by name).In addition, TRU-A is thermo-plastic polyurethane's elastomer (BASFJapan produces, Elastran by name), and TRU-B and TRU-C also are thermo-plastic polyurethane's elastomer (Nippon Miractran produce, Miractran by name).
Table 1 has shown the relation between resinous type and the toothed belt plasticity.(covering fabric and covering fabric E all are illustrated in the table 2 of back.)
The type of table 1 resin and plasticity
| Resin | Molding temperature (℃) | Resin Flow (ml/s) | Ooze out | Chamfering | The overall evaluation |
| ?TPEE-A | ????125 | ????4.20E-04 | Not | Be | ????× |
| ?TPEE-A | ????1?30 | ????5.54E-03 | Not | Not | ????○ |
| ?TPEE-A | ????135 | ????1.03E-02 | Be | Not | ????× |
| ?TPEE-B | ????140 | ????1.24E-03 | Not | Not | ????○ |
| ?TPEE-B | ????145 | ????3.95E-03 | Not | Not | ????○ |
| ?TPEE-C | ????150 | ????6.20E-04 | Not | Not | ????○ |
| ?TPEE-C | ????155 | ????3.30E-03 | Not | Not | ???○ |
| ?TPEE-D | ????165 | ????1.62E-03 | Not | Not | ???○ |
| ?TPEE-D | ????170 | ????5.43E-03 | Not | Not | ???○ |
| ?TRU-A | ????180 | ????3.53E-03 | Not | Not | ???○ |
| ?TRU-B | ????180 | ????2.57E-03 | Not | Not | ???○ |
| ?TRU-C | ????185 | ????1.85E-03 | Not | Not | ???○ |
| ?TRU-C | ????190 | ????6.14E-03 | Be | Not | ???× |
| ?TRU-C | ????195 | ????9.12E-03 | Be | Not | ???× |
Covering fabric E
At first, in the embodiment of TPEE-A, when molding temperature was set to 130 ℃, flow was 5.54 * 10
-3Milliliters/second (50kgf/cm
2The aperture of load and 1mm * 1mm and length) or 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the generation of tooth table or top chamfer.
Next, in the embodiment of TPEE-B, when molding temperature was set to 140 ℃, flow was 1.24 * 10
-3Milliliters/second, and temperature is when being 145 ℃, flow is 3.95 * 10
-3Milliliters/second or 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the tooth table or produce top chamfer.
Next, in the embodiment of TPEE-C, when molding temperature was set to 150 ℃, flow was 6.02 * 10
-4Milliliters/second, and temperature is when being 155 ℃, flow is 3.30 * 10
-3Milliliters/second or 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the tooth table or produce top chamfer.
In the embodiment of TPEE-D, when molding temperature was set to 165 ℃, flow was 1.62 * 10
-3Milliliters/second, and temperature is when being 170 ℃, flow is 5.43 * 10
-3Milliliters/second or 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the tooth table or produce top chamfer.
In the embodiment of TPU-A, when molding temperature was set to 180 ℃, flow was 3.53 * 10
-3Milliliters/second is perhaps 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the tooth table or produce top chamfer.
In the embodiment of TPU-B, when molding temperature was set to 180 ℃, flow was 2.57 * 10
-3Milliliters/second is perhaps 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the tooth table or produce top chamfer.
In the embodiment of TPU-C, when molding temperature was set to 185 ℃, flow was 1.85 * 10
-3Milliliters/second is perhaps 5 * 10
-4～6 * 10
-3In the scope of milliliters/second, can make the correct moulding of toothed belt and do not have thermoplastic elastomer to be exuded to the tooth table or produce top chamfer.
(embodiment of covering fabric)
The type of table 2 covering fabric and plasticity
| The top layer fabric | Filament denier is than (fabric/warp) | Thread density is than (fabric/warp) | Specific elongation | Handle | Ooze out | Chamfering | The overall evaluation |
| ????A | ????1.00 | ????0.59 | ????28 | Resin | Be | Be | ????× |
| ????B | ????3.80 | ????0.63 | ????48 | Resin | Not | Be | ????× |
| ????C | ????2.67 | ????0.63 | ????61 | Resin | Not | Not | ????○ |
| ????D | ????2.67 | ????0.63 | ????58 | RFL | Be | Not | ????× |
| ????E | ????0.95 | ????0.65 | ????63 | Resin | Not | Not | ????○ |
| ????F | ????0.95 | ????0.65 | ????68 | Urethane | Not | Not | ????○ |
| ????G | ????0.95 | ????0.38 | ????51 | Resin | Not | Be | ????× |
| ????H | ????0.95 | ????0.98 | ????131 | Resin | Not | Not | ????○ |
| ????I | ????0.95 | ????0.98 | ????162 | Urethane | Be | Not | ????× |
| ????J | ????0.95 | ????0.98 | ????136 | RFL | Be | Not | ????× |
| ????K | ????0.46 | ????0.98 | ????142 | Resin | Be | Not | ????× |
| ????L | ????0.71 | ????1.60 | ????180 | Resin | Be | Not | ????× |
Resin: TPEE-B
Molding temperature: 145 ℃
As shown in table 2, for example, in the embodiment of covering fabric C, parallel is set at 2.67 with the warp filament denier than (parallel/warp), and thread density (number) is set at 0.63 than (parallel/warp).The specific elongation of the covering fabric that makes by this way when 50mm spacing/2kgf is 61%, passes through RESIN FINISH then.Can make the correct moulding of toothed belt and not have thermoplastic elastomer to be exuded to tooth table or generation top chamfer.
Next, in the embodiment of covering fabric E, filament denier is set at 0.95 than (parallel/warp), and thread density (number) is set at 0.65 than (parallel/warp), the specific elongation of covering fabric is 63% (under 50mm spacing/2kgf), passes through RESIN FINISH then.Can make the correct moulding of toothed belt and not have thermoplastic elastomer to be exuded to tooth table or generation top chamfer.
In the embodiment of covering fabric F, filament denier is set at 0.95 than (parallel/warp), thread density (number) is set at 0.65 than (parallel/warp), and the specific elongation of covering fabric is 68% (50mm spacing/2kgf), handle through the wet-cured type urethane then.Can make the correct moulding of toothed belt and not have thermoplastic elastomer to be exuded to tooth table or generation top chamfer.
In the embodiment of covering fabric H, filament denier is set at 0.95 than (parallel/warp), and thread density (number) is set at 0.98 than (parallel/warp), and the specific elongation of covering fabric is 131% (50mm spacing/2kgf), pass through RESIN FINISH then.Can make the correct moulding of toothed belt and not have thermoplastic elastomer to be exuded to tooth table or generation top chamfer.
(embodiment of test result)
To the test result assessment of close-toothed shape band of the present invention be introduced below.The tooth pitch of this kind toothed belt is 2mm.
Toothed belt is immersed in fully carries out oil resistance test in the lubricant oil.As shown in Figure 4, embodiment 1 and 2 toothed belt are littler with respect to the variation of comparative example 1 on size (width and thickness), so performance is more excellent.
Comparative example 2 toothed belt is made by the gravity die neoprene, and comparative example 3 toothed belt is made by soft type neoprene, and comparative example 4 toothed belt is made by castability thermoset polyurethane elastomer.
Utilize the difference in torque of driving side and passive side to drive CROCKING TEST as driving friction.Shown in the result of Fig. 5, although embodiment 3,4 and 5 higher with respect to the toothed belt hardness of comparative example 2,3 and 4, tape thickness is bigger, has identical driving torque.The toothed belt that also shows embodiment 3,4 and 5 thus has littler driving torque when increasing its durability, therefore more excellent.
As shown in Figure 6, utilize running accuracy testing instrument (by the non-contact type speed change metering mechanism LV-203 that is used to measure rotational speed of Mitsubishi Electric preparation) to test.Toothed belt is of a size of 318-2GT-10, covering fabric is 3A, and cotton rope is 40:0 under 200D/1, and belt wheel is of a size of P14/P14 (specific requirement is identical with durability test), rotational speed is 200 minutes-1 (266666 pps 1/160 drive), and installation tension force is 28.05N (standard).
Shown in the result of Fig. 7, the driven wheel of embodiment 6 toothed belt is littler with respect to the amplitude that comparative example 5 vibrates when rotated, and is therefore more excellent.
Embodiment 7 toothed belt is to be got by (being produced Hytrel 4057 by name by the DUPONT-TORAY company) preparation of thermoplastic polyester elastomer under aforesaid condition of moulding.Comparative example 6 toothed belt is made by castability thermoset polyurethane elastomer.
By when roulette wheel is braked, sensitivity test being carried out in the measurement of driven wheel residual oscillation displacement.Shown in the result of Fig. 8, embodiment 7 toothed belt has littler hyperharmonic attenuation vibration faster with respect to comparative example 6, and is therefore more excellent.
The also preparation moulding under above-mentioned condition of moulding of embodiment 8,9 and 10 toothed belt.Embodiment 8 toothed belt (is produced by DUPONT-TORAY company by the thermoplastic polyester elastomer, Hytrel 4057 by name) makes, embodiment 9 toothed belt is made by thermoplastic polyester elastomer (Hytrel G3548L by name), and embodiment 10 toothed belt is made by thermoplastic polyester elastomer (Hytrel 3046 by name).
Comparative example 7 toothed belt is made by the gravity die neoprene, and comparative example 8 toothed belt is made by soft type neoprene, and comparative example 10 toothed belt is made by castability thermoset polyurethane elastomer.
Then toothed belt is placed on the testing instrument and rotate with certain speed, the moment of torsion of the magnetic hysteresis that raises gradually vibration carries out tooth and jumps test.Shown in the result of Fig. 9, embodiment 8,9 and 10 toothed belt have higher tooth with respect to the toothed belt of comparative example 7,8 and 9 and jump moment of torsion, and be therefore more excellent.
Next, preparation is carried out following test apart from the tooth toothed belt greatly, and the tooth pitch of this kind toothed belt is 9.525mm.
Embodiment 11 toothed belt is to be got by (being produced Hytrel 4057 by name by the DUPONT-TORAY company) preparation of thermoplastic polyester elastomer under aforesaid condition of moulding.Comparative example 10 toothed belt is made by neoprene.
Toothed belt is immersed in a week in the machinery oil, then by the test of toothed belt size and hardness being carried out the grease resistance test.Shown in the result of Figure 10, embodiment 11 toothed belt is littler with respect to the variation of comparative example 10 on size and hardness, and is therefore more excellent.
Position accuracy test by the testing instrument shown in Figure 11 upper left corner.Shown in the result of Figure 11, embodiment 12 toothed belt has littler displacement with respect to comparative example 11, and wherein displacement comprises because load converts deflection cause on the nodel line to the angle of swing on wheel, and is so more excellent.
Embodiment 13 toothed belt is to be got by (being produced Hytrel 4057 by name by the DUPONT-TORAY company) preparation of thermoplastic polyester elastomer under aforesaid condition of moulding.Comparative example 12 toothed belt is made by neoprene.
Toothed belt holds belt wheel, gives certain load and certain rotation speed and carries out durability test.Shown in the result of Figure 12, under identical test condition, embodiment 13 toothed belt has bigger deflection with respect to comparative example 12, and is therefore more excellent.
In this embodiment, molding temperature is arranged between the solidification point and melt temperature of thermoplastic elastomer, thereby prevents that resin is exuded to the formation of tooth table and top chamfer.Therefore, this embodiment provides a kind of toothed belt that possesses more excellent anti-tooth jumping ability, durability, sensitivity and low driving friction with respect to traditional product.
[second kind of embodiment]
Below in conjunction with accompanying drawing second kind of embodiment of toothed belt and preparation method thereof described.
Figure 13 is the sectional schematic diagram of the toothed belt 10 of second kind of embodiment of the present invention.Just be to have added one deck resin film 20 again with first kind of embodiment's difference on the surface of covering fabric 12.Resin film 20 plays sealer in moulding process, the later protective layer as toothed belt of moulding.
Be the preparation method of the toothed belt of second kind of embodiment below.Shown in Figure 14 A, 14B and 14C, in the preparation process of toothed belt, place the shape tooth surface of shaping die 17, resin film 20 to be laminated in advance on the surface of covering fabric 12 of shape tooth surface of contiguous shaping die 17 rubber-like covering fabric 12 with tooth-shape structure.Again cotton rope 16 is adhered on the covering fabric 12 of the shape tooth surface of contiguous shaping die 17.In the drawings, reference character 19 expressions are used for the rubber bag of moulding.In the moulding process, resin film 20 and covering fabric 12 stretch together, are close to shaping die 17.
The fusing point of resin film 20 is higher than belt body material 15.Polyetherester resins is as belt body material 15, and the polyetherester resins film is as resin film 20.
In addition, when under belt body material 15 is being lower than the uniform temperature of resin film 20 fusing points, being in a kind of fluidised form, just can moulding in shaping die 17.In the forming process, because the pressure of belt body material 15 (seeing Figure 15 B), the space 18 of covering fabric 12 (seeing Figure 15 A) is stretched and expands, and belt body material 15 will pass cotton rope 16 from the bottom surface, oozes out from the space 18 of covering fabric 12 and resin film 20 fusions.
In the preparation process of this toothed belt, the fusing point of resin film 20 is higher than the fusing point of belt body material 15 and overlays shape tooth surface (seeing Figure 14 A) in covering fabric 12.Even belt body material 15 passes the space 18 of covering fabric 12 from the bottom surface in forming process, thereby resin film 20 also can prevent that it from arriving tooth table (seeing Figure 14 C) with 15 fusions of belt body material.That is to say to have more dystectic resin film 20 and in moulding process, be not molten state, thereby stoped passing of belt body material 15.
This shows that belt body material 15 is exuded to tooth table (seeing the belt body material 21 that oozes out shown in Figure 16) and can be effectively controlled, and can not be exposed to many advantages that the tooth table is brought so possessed material.Be that belt body material 15 exposes and there is not unbalanced state in unexposed place, therefore the generation of abnormal sound will be effectively suppressed with respect to former toothed belt, and anti-tooth is jumped and durability also is improved.
In addition, because the structure of toothed belt is that the covering fabric 12 that is positioned at described toothed belt tooth table is close to 20 layers of resin films, so just can prevent that oil and water etc. from infiltrating 20 layers of resin films and band tooth surface.Therefore the dimensional stability of toothed belt is more excellent, longer service life.
Can use different types of resin or elastomer as belt body material 15, but when using polyetherester resins, high-strength because it has better hot properties in thermoplastic elastomer, the rubber elasticity from low temperature to high temperature.So the serviceability temperature scope is very wide, have more excellent shock absorbing, anti-profit and chemical stability, reduced and belt wheel between gearing noise, low friction pair effect and the favorable durability brought.
Notice that belt body material 15 also can select liquid castability resin or elastomer by injection forming equipment moulding toothed belt, or select thermoplastic elastomer by extruder moulding toothed belt.
(embodiment 1 of toothed belt preparation)
Introduce the preparation method of toothed belt in the embodiment of the invention below.
The resin film 20 (Hytrel film) that nylon covering fabric 12 (tooth clothing) and fusing point is higher than belt body material 15 (Hytrel thin slice) is pressed into thin slice, cuts into preliminary dimension then and bondingly (is referred to as " covering fabric protecting jacket ").
After covering fabric was handled via latex and RFL, outermost surface had just formed the phenolic resin layer that contains the unsaturated bond side chain.Notice that also available a kind of process contains the phenolic resin layer of the component modification of phenolic group carboxylic acid and replaces above-mentioned phenolic resin layer.
The covering fabric protecting jacket overlays on the shape tooth surface of shaping die 17 outer surfaces so that the resin film 20 (Hytrel film) and the surface of shaping die 17 and contacts, and then glass cotton rope 16 is spirally wound on its outer surface.
The outermost surface of cotton rope 16 is made of the phenolic resin layer that contains the unsaturated bond side chain.In order further to increase the bonding strength of cotton rope 16 and belt body, also can on cotton rope 16, form a RFL layer, thereby form and the bonding better skin of RFL layer.
Under the normal temperature belt body material 15 is wrapped on the cotton rope 16 and with adhesive tape and fixes, again peeling paper is wrapped in belt body material 15 (Hytrel thin slice) and goes up and fix, should make up insertion shell bag then, place sulfurizing pot, be hot pressed into band plate with adhesive tape.Hot pressing temperature is set to be equal to or higher than the fusing point of belt body material 15 (Hytrel thin slice) but the fusing point that is lower than resin film 20 (Hytrel film).Pressure and heating time also are provided with respectively so that belt body material 15 flows and is completed into the band tooth.
That is to say, earlier with belt body material 15 (Hytrel thin slice) be pressed into the covering fabric 12 of thin slice and be not heated the cotton rope 16 that is the resin sheet with resin film 20 and put into shaping die 17.In forming process, belt body material 15 is begun to impose hot pressing to molding temperature from room temperature then, 15 plasticizings of belt body material are fluidised form and form the band tooth.
Therefore, in forming process, the resin film 20 (Hytrel film) and the covering fabric 12 that are laminated on the covering fabric 12 are stretched together, and the covering fabric 12 that is coated with resin film 20 has just formed the surface of tooth in band tooth forming process.
Moulding reduces near room temperature the temperature of shaping die 17 rapidly after finishing, and shaping die 17 is taken out from the shell bag, with mould unloading equipment molded good plate is taken out from shaping die again.And then grind to form the template bottom surface with dull and stereotyped grinding machine and remove peeling paper and be complementary with the tape thickness with pre-design, print at last and cut into the profile of tooth band.
The toothed belt of gained is 20 layers of resin films successively, comprises 12 layers of the covering fabrics and the belt body material 15 (having cotton rope 16) of belt body material 15 from the tooth table in order thus.That is to say that the covering fabric 12 that is coated with resin film 20 has formed toothed surface, and just because of the existence of resin film 20, belt body material 15 is exuded to the tooth table just can be stoped effectively.
(toothed belt preparation method's embodiment 2)
Introduce another embodiment of toothed belt preparation method below.
The resin film 20 (Hytrel film) that nylon covering fabric 12 (tooth clothing) and fusing point is higher than belt body material 15 (Hytrel thin slice) is pressed into thin slice, carries out pre-shaping by pre-shaping equipment (unlisted) then so that the band tooth surface is Hytrel film 20 (being referred to as " preformed covering fabric ").
Preformed covering fabric is complementary with the number of teeth and the facewidth with shaping die 17 through the cutting bonding.Be placed on the shape tooth surface of forming die 17 outer peripheries then, interim fastening so that its in groove, do not slide.Again glass cotton rope 16 spirals are wound on the shaping die 17.
Under the normal temperature, belt body material 15 (Hytrel thin slice) is wrapped on the cotton rope 16 and with adhesive tape fixes, again peeling paper is wrapped in belt body material 15 (Hytrel thin slice) and goes up and fix, be inserted into then in the shell bag, be hot pressed into band plate with adhesive tape.
Hot pressing temperature is set to be equal to or higher than the fusing point of belt body material 16 (Hytrel sheet) but the fusing point that is lower than resin film 20 (Hytrel film).Also are provided with respectively pressure and heating time so that resin flows and be completed into the band tooth.
Moulding reduces near room temperature the temperature of shaping die 17 rapidly after finishing.Shaping die 17 is taken out from the shell bag, with mould unloading equipment molded good plate is taken out from shaping die 17 again.And then grind to form the template bottom surface with dull and stereotyped grinding machine and remove peeling paper and be complementary with the tape thickness with pre-design, print at last and cut into the profile of tooth band.
When adopting this method moulding, because covering fabric 12 and resin film 20 (Hytre1 film) do not stretched fully, so just can reduce the variation of covering fabric 12 thread densities and resin film 20 thickness etc.Prepared excellent product performance is durable.
In this embodiment, the fusing point resin film material 20 and the covering fabric 12 that are higher than belt body material 15 is pressed into thin slice.Molding temperature is arranged between the fusing point of resin film 20 and belt body material 15.So although belt body material 15 has certain fluidity, also still can prevent oozing out of belt body material 15 by hard resin film 20.Belt body material 15 exposes and just can there be unbalanced state in unexposed place, and the generation of abnormal sound will be effectively suppressed with respect to former toothed belt, and anti-tooth jumps ability and durability also is improved.
At last, describing the preceding all is the preferred embodiment of technical solution of the present invention, is not breaking away under flesh and blood of the present invention and the off-limits situation, and those of ordinary skills propose various modifications and are readily appreciated that.
Claims (12)
1. the toothed belt that has the tooth table comprises the belt body of being made by thermoplastic elastomer; Embed in the belt body cotton rope as tensional element; With the covering fabric that is covered in described tooth table.
2. toothed belt as claimed in claim 1, wherein said thermoplastic elastomer are the thermoplastic polyester elastomers.
3. toothed belt as claimed in claim 1, wherein said thermoplastic elastomer are thermo-plastic polyurethane's elastomers.
4. toothed belt as claimed in claim 1, the hardness of wherein said thermoplastic elastomer are A70～A95 (shore hardness of JIS-K6253).
5. the preparation method of a toothed belt comprises: the pre-shaped articles that forms thermoplastic elastomer; Covering fabric, cotton rope and described pre-shaped articles are put into shaping die form a combination material; From the outside hot pressing said composition of above-mentioned shaping die material; Under the solidification point of above-mentioned thermoplastic elastomer and the certain molding temperature between the melt temperature from mould inside to said composition material heating time enough so that form the band tooth on the surface of combination material.
6. the preparation method of toothed belt as claimed in claim 5, wherein said band tooth be by be provided with make molding temperature and heating time described thermoplastic elastomer flow 5 * 10
-4～6 * 10
-3Between the milliliters/second.(load 50kgf/cm
2, aperture and length are 1mm * 1mm).
7. the preparation method of toothed belt as claimed in claim 5, the filament denier ratio of wherein said covering fabric parallel/warp is 0.5～3.0, the thread density ratio of parallel/warp is 0.5～1.0, this covering fabric was handled through resin or wet-cured type urethane before forming the combination material, and its specific elongation is approximately 50～150% (under 50mm spacing/2kgf) of original length.
8. the preparation method of a toothed belt comprises: with fusing point be higher than the belt body material and and the resin film that stretches together of covering fabric join the surface of the covering fabric that is close to shaping die with shape tooth surface; This covering fabric of rubber-like is covered on the above-mentioned shape tooth surface; Cotton rope is wrapped on this covering fabric; Utilize above-mentioned shaping die to make described belt body material be lower than fluidised form moulding under the temperature of its fusing point.
9. the preparation method of toothed belt as claimed in claim 8, in forming process, merge mutually with above-mentioned resin film in the space that the belt body material of this fluidised form passes covering fabric.
10. the preparation method of toothed belt as claimed in claim 8 wherein before adding step, forms the phenolic resin layer that one deck is modified by the component of phenol that contains tool unsaturated bond side chain or phenolic group carboxylic acid at the outermost surface of described covering fabric.
11. the preparation method of toothed belt as claimed in claim 8 wherein before winding step, forms the phenolic resin layer of being modified by the component of the phenol of the side chain that contains the tool unsaturated bond or phenolic group carboxylic acid at the outermost surface of described cotton rope.
12. the preparation method of toothed belt as claimed in claim 8, wherein said belt body material comprises polyether ester, and described resin film comprises polyether ester.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2002225115A JP4038789B2 (en) | 2002-08-01 | 2002-08-01 | Toothed belt manufacturing method |
| JP2002225115 | 2002-08-01 | ||
| JP2003146118A JP2004347054A (en) | 2003-05-23 | 2003-05-23 | Toothed belt and manufacturing method thereof |
| JP2003146118 | 2003-05-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1480661A true CN1480661A (en) | 2004-03-10 |
| CN1300487C CN1300487C (en) | 2007-02-14 |
Family
ID=34196504
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031496075A Expired - Fee Related CN1300487C (en) | 2002-08-01 | 2003-08-01 | Tooth belt and its prepn. method |
Country Status (4)
| Country | Link |
|---|---|
| KR (1) | KR100951625B1 (en) |
| CN (1) | CN1300487C (en) |
| SG (1) | SG121785A1 (en) |
| TW (1) | TWI295713B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111164331A (en) * | 2017-09-29 | 2020-05-15 | 康蒂泰克驱动系统有限公司 | Transmission belt and method for manufacturing same |
| CN117222826A (en) * | 2021-04-30 | 2023-12-12 | 阪东化学株式会社 | toothed belt |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6527549B2 (en) * | 2016-06-06 | 2019-06-05 | 三ツ星ベルト株式会社 | Toothed belt and method of manufacturing the same |
| JP6510130B1 (en) * | 2017-11-21 | 2019-05-08 | ニッタ株式会社 | Belt belt, endless belt, and method for manufacturing the same |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4443281A (en) * | 1981-02-06 | 1984-04-17 | Dayco Corporation | Method of making an arched endless belt |
| JPH06249292A (en) * | 1992-12-29 | 1994-09-06 | Bridgestone Corp | Toothed belt |
| GB2351336B (en) * | 1996-06-20 | 2001-02-14 | Unitta Co Ltd | Toothed Belt |
| JP3468265B2 (en) * | 1996-11-25 | 2003-11-17 | ゲイツ・ユニッタ・アジア株式会社 | Canvas and toothed belt using this canvas |
| JPH10213182A (en) * | 1997-01-30 | 1998-08-11 | Bando Chem Ind Ltd | Nonchargeable toothed belt |
| JP2986442B2 (en) | 1997-09-22 | 1999-12-06 | バンドー化学株式会社 | Toothed belt |
| US6296588B1 (en) * | 1998-06-12 | 2001-10-02 | The Gates Corporation | High temperature flexible thermoplastic composites for endless belt driving surfaces |
| CN2384914Y (en) * | 1999-07-08 | 2000-06-28 | 张建 | Thermoplastic elastic body conveyer belt |
| JP2002106642A (en) * | 2000-09-29 | 2002-04-10 | Unitta Co Ltd | Belt |
-
2003
- 2003-07-30 KR KR1020030052676A patent/KR100951625B1/en not_active IP Right Cessation
- 2003-07-30 TW TW092120888A patent/TWI295713B/en not_active IP Right Cessation
- 2003-07-30 SG SG200304291A patent/SG121785A1/en unknown
- 2003-08-01 CN CNB031496075A patent/CN1300487C/en not_active Expired - Fee Related
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111164331A (en) * | 2017-09-29 | 2020-05-15 | 康蒂泰克驱动系统有限公司 | Transmission belt and method for manufacturing same |
| CN117222826A (en) * | 2021-04-30 | 2023-12-12 | 阪东化学株式会社 | toothed belt |
Also Published As
| Publication number | Publication date |
|---|---|
| SG121785A1 (en) | 2006-05-26 |
| TW200404964A (en) | 2004-04-01 |
| KR100951625B1 (en) | 2010-04-09 |
| KR20040012546A (en) | 2004-02-11 |
| CN1300487C (en) | 2007-02-14 |
| TWI295713B (en) | 2008-04-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5597545B2 (en) | Toothed belt | |
| JP6221011B1 (en) | Toothed belt | |
| JP5465346B1 (en) | Toothed belt | |
| CN1502019A (en) | Thermoplastic jacket belt | |
| EP2687750A1 (en) | Toothed belt | |
| CN1821614A (en) | Power transmission belt and method of forming a power transmission belt | |
| EP3467342B1 (en) | Toothed belt and manufacturing method therefor | |
| CN1092434A (en) | Multiple grinding long filament and manufacture method thereof, its goods and use the method for these goods | |
| CN1093452A (en) | The method for making of composite pipe goods, particularly gasoline pipe and this goods | |
| KR20120022752A (en) | Flat belt | |
| JPWO2013088718A1 (en) | Friction transmission belt and manufacturing method thereof | |
| US20210324177A1 (en) | 3d-printed elastic products reinforced by means of continuous fibres and having asymmetrical elastic properties | |
| JP2005155682A (en) | Treatment liquid for transmission belt duck, duck for transmission belt, and transmission belt | |
| CN1300487C (en) | Tooth belt and its prepn. method | |
| CN1488869A (en) | Resin pulley | |
| JP2008144965A (en) | Polyurethane toothed belt and its manufacturing method | |
| CN1655913A (en) | Tape-shaped molding and belt for ball chain | |
| JP5215274B2 (en) | Toothed belt | |
| KR102155328B1 (en) | Toothed belt and its manufacturing method | |
| JP2008115933A (en) | Toothed belt | |
| JP2010210088A (en) | Toothed belt | |
| JP5684502B2 (en) | Tip split endless belt | |
| JP2010133551A (en) | High load transmission belt | |
| JP5355324B2 (en) | Toothed belt | |
| JP4978980B2 (en) | Applicator belt |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20070214 Termination date: 20140801 |
|
| EXPY | Termination of patent right or utility model |