CN1478459A - Hair dyeing agent using rutin or guercetin as dyestuff - Google Patents
Hair dyeing agent using rutin or guercetin as dyestuff Download PDFInfo
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- CN1478459A CN1478459A CNA031191711A CN03119171A CN1478459A CN 1478459 A CN1478459 A CN 1478459A CN A031191711 A CNA031191711 A CN A031191711A CN 03119171 A CN03119171 A CN 03119171A CN 1478459 A CN1478459 A CN 1478459A
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- hair
- rutin
- dye
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Abstract
A hair dyeing agent contains hair softener, dye (rutin or quercetin) and chelating agent of Al ions or Fe ions. Its advantages are no poison, no toxic by-effect, no hypersensitivity and sure effect to soften blood vessel.
Description
Technical field
The invention belongs to cosmetics industry is the hair caring product, and promptly hair dye is characterized in that having used in prescription rutin or Quercetin to be dyestuff.
Background technology
Popular in the market hair dye is to be that dyestuff is made with p-phenylenediamine (PPD) class and diphenols chemical compound basically.This class hair dye toxicity is big, and is very easily irritated, causes red swelling of the skin, twinge, stream yellow fluid, and What is more, and service time is of a specified duration, can cause skin cancer or leukemia.These existing at home many hygiene departments made statistics and report.Therefore, it is imperative to seek nontoxic hair dye colorants.
Summary of the invention
The purpose of this invention is to provide a kind of is the natural type hair dyed agent of dyestuff with rutin or Quercetin.
Natural type hair dye of the present invention comprises that hair softens inorganic agent, and dye formulations and metal ion chelation agent is characterized in that using rutin or its hydrolyzate Quercetin to be dye formulations, its structural formula:
Rutin molecular structural formula Quercetin molecular structural formula
Advantage of the present invention and effect are:
1) this hair dye is nontoxic, nothing is paid effect, do not have irritated phenomenon.
2) rutin and Quercetin energy vessel softening is to the human body beneficial.
3) natural, similar, the nothing hair dyeing vestige of color and luster to natural color development.
The specific embodiment
Hair dye of the present invention comprises three ingredients, that is, hair softens inorganic agent, and dye formulations and metal ion chelation agent is characterized in that using rutin or its hydrolyzate Quercetin to be dye formulations.
Rutin or the Quercetin characteristic as dye formulations at first is described.
Rutin is a kind of medicine of energy vessel softening.Its structural formula is:
Promptly 5,7,3 ', 4 '-tetrahydroxyflavonol-2-globulariacitrin
Its hydrolyzate is:
5,7,3 ', 4 '-tetrahydroxyflavonol-2, be commonly called as Quercetin.The two has identical physiologically active is vessel softening, antiinflammatory etc.
Purified rutin and Quercetin all are faint yellow crystallization, and medicinal rutin or Quercetin usually are pale yellow powder.Their can and metal ion effect and produce new color, for example with the aluminium ion effect, produce bright-coloured glassy yellow and iron ion action generation brownish black.They also can enter in the hair, change the color of hair, so they can make the hair dye that nontoxic nothing is paid effect.
Because the molecule of Quercetin and rutin is bigger, so the speed that enters in the hair is slower.We have taked hair is softened the method for handling, and the scale of hair are opened, dye molecule is easy to enter in the hair, can shorten the hair dyeing time like this.
Making the open chemical compound of scale of hair is sodium thioglycolate, sodium thiosulfate.The cystine linkage effect of their energy and hairline is opened the scale of hair, is made hair softening.
When the molecule of dyestuff enters in the hair and the metal ion-chelant that enters in the hair forms bigger molecule again, after the scale of hairline closes, can not go out, form the hair dye of permanent type.For example the molecule of aluminium ion and Quercetin meets and then forms
Make hair become glassy yellow, if metal ion be iron ion then form memnonious hair, consistent with yellow skin people's natural hair color.
This hair dye can be made powder or mastic.Being dyestuff with the rutin below, is that metal ion is talked prescription and application with the aluminium ion.
This hair dye is three dosage forms.First dose is called its effect of softening inorganic agent abbreviation softening agent is that the scale of hair is opened, and dye molecule is easy to enter.Second dose is played the colour developing effect for stain.The 3rd dose claims ion chelating agent, and the molecule chelating that is mainly its effect of metal ion and is with dyestuff forms bigger molecule, changes the Show Color of dyestuff.Simultaneously, more be difficult for oozing out hair after the hair dyeing and form Permanent Hair Dyeing Agent outward also because molecular change gets greatlyyer.Prescription: first dose of main component is sodium thioglycolate (2～4%); Sodium sulfite (0.5～1.5%);
Sodium Tvlose (0.5～2%); Disodiumedetate (0.2～0.5
%); Monoethanolamine (1～2%), all the other are water, add to 100%.
First dose another kind prescription is: sodium thiosulfate (15～20%); Sodium sulfite
(0.5～1.5%); Sodium carboxymethyl cellulose (0.5～2%); Ethylenediaminetetraacetic acid
Disodium (0.2～0.5%); Monoethanolamine (1～2%), all the other are water.
Second dose of main component is rutin (6～8%); Sodium carboxymethyl cellulose (1～30%); Ten
Sodium dialkyl sulfate (1.0～1.7%), all the other are water, add to 100%.
The 3rd dose mainly becomes aluminum sulfate (6～8%), sodium carboxymethyl cellulose (1～30%); Ten
Sodium dialkyl sulfate (1.0～1.7%), all the other are water, add to 100%.
Preparation: each agent got ready to stir behind the medicine by prescription get final product,, surpass 10 kilograms of homogenizers the most handy, pack again after the homogenizing if amount is big.
The hair that dyes of more than filling a prescription is a glassy yellow, if change the aluminum sulfate in the 3rd dose into hair that ferrous sulfate (all the other components unchanged, the proportioning consumption is constant) just can be dyed pitchy.
If change rutin into Quercetin, its prescription and proportioning are all constant.
During production, produce respectively, pack respectively and deposit for three doses.
Using method: with two doses of isopyknic being added in the nonmetallic vessel of potion, reuse one non-metallic rods stirs evenly, use special small brushes (or toothbrush) to be coated in mixed medicine on the hair uniformly then, about 15～20 minutes Deng 20～30 ℃ of a period of time room temperatures, temperature can suitably heat or time expand when low, after the hair deliquescing, and water flush away medicinal liquid, reuse is done same operation for the 3rd dose, is coated on the hair.(the about 5 minutes) hair of waiting promptly becomes required color, cleans hair and gets final product.
Consumption: decide on hair.One or two doses each 15 milliliters of general in men's style bob, three doses 20 milliliters.Each 20 milliliters of one or two doses of pacts of woman's bob, three doses about 30 milliliters.Longhair, one or two doses each 40 milliliters, three doses 60 milliliters.
Need to prove,, then need correct loss of hairs color if the hair color people dyes yellow hair, utilize commercially available depigmenting agent or decolouring milk all can, hair color is taken off to needed light color, implement dyeing operation again.
Claims (5)
1. the hair dye of a natural type comprises that hair softens inorganic agent, and dye formulations and metal ion chelation agent is characterized in that using rutin or its hydrolyzate Quercetin to be dye formulations, its structural formula:
Rutin molecular structural formula Quercetin molecular structural formula
2. according to the described hair dye of claim 1, it is characterized in that the ion in the wherein said metal ion chelation agent is the metallic aluminium ion.
3. according to the described hair dye of claim 1, the ion that it is characterized in that wherein said metal ion chelation agent is metallic iron ion or ferrous ion.
4. according to claim 2 or 3 described hair dyes, it is characterized in that wherein said softening inorganic agent main component sodium thioglycolate (2～4%); Sodium sulfite (0.5～1.5%); Sodium Tvlose (0.5～2%); Disodiumedetate (0.2～0.5%); Monoethanolamine (1～2%), all the other are water.
5. according to claim 2 or 3 described hair dyes, it is characterized in that wherein said softening inorganic agent composition: sodium thiosulfate (15～20%); Sodium sulfite (0.5～1.5%); Sodium carboxymethyl cellulose (0.5～2%); Disodiumedetate (0.2～0.5%); Monoethanolamine (1～2%), all the other are water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03119171 CN1197544C (en) | 2003-03-18 | 2003-03-18 | Hair dyeing agent using rutin or guercetin as dyestuff |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 03119171 CN1197544C (en) | 2003-03-18 | 2003-03-18 | Hair dyeing agent using rutin or guercetin as dyestuff |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1478459A true CN1478459A (en) | 2004-03-03 |
| CN1197544C CN1197544C (en) | 2005-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 03119171 Expired - Fee Related CN1197544C (en) | 2003-03-18 | 2003-03-18 | Hair dyeing agent using rutin or guercetin as dyestuff |
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|---|---|
| CN (1) | CN1197544C (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015174868A1 (en) | 2014-05-12 | 2015-11-19 | Zito Spółka Cywilna | Colouring composition and application of the colouring composition |
| CN105106076A (en) * | 2015-09-22 | 2015-12-02 | 贵州省工程复合材料中心 | Yellow plant hair dye and preparation method thereof |
| US9345654B2 (en) | 2012-08-24 | 2016-05-24 | Natural Medicine Institute Of Zhejiang Yangshengtang Co., Ltd. | Hair dye product |
| CN109925205A (en) * | 2019-01-31 | 2019-06-25 | 西南大学 | Natural botanical hair dye and its application method of the compound common Chinese medicine effective component as dyestuff |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| TWI756913B (en) * | 2020-11-11 | 2022-03-01 | 國立臺北科技大學 | Composition of hair dye and formula of commercial hair dye |
| TWI771134B (en) * | 2021-08-04 | 2022-07-11 | 國立臺北科技大學 | Natural hair dye and its commercialized formula |
-
2003
- 2003-03-18 CN CN 03119171 patent/CN1197544C/en not_active Expired - Fee Related
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9345654B2 (en) | 2012-08-24 | 2016-05-24 | Natural Medicine Institute Of Zhejiang Yangshengtang Co., Ltd. | Hair dye product |
| WO2015174868A1 (en) | 2014-05-12 | 2015-11-19 | Zito Spółka Cywilna | Colouring composition and application of the colouring composition |
| CN105106076A (en) * | 2015-09-22 | 2015-12-02 | 贵州省工程复合材料中心 | Yellow plant hair dye and preparation method thereof |
| CN109925205A (en) * | 2019-01-31 | 2019-06-25 | 西南大学 | Natural botanical hair dye and its application method of the compound common Chinese medicine effective component as dyestuff |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1197544C (en) | 2005-04-20 |
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Granted publication date: 20050420 Termination date: 20100318 |