CN1473891A - Nano composite inner wall antiseptic emulsion paint - Google Patents

Nano composite inner wall antiseptic emulsion paint Download PDF

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Publication number
CN1473891A
CN1473891A CNA021259666A CN02125966A CN1473891A CN 1473891 A CN1473891 A CN 1473891A CN A021259666 A CNA021259666 A CN A021259666A CN 02125966 A CN02125966 A CN 02125966A CN 1473891 A CN1473891 A CN 1473891A
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China
Prior art keywords
titanium dioxide
dioxide
emulsion paint
nano composite
talcum powder
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CNA021259666A
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Chinese (zh)
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CN1273551C (en
Inventor
张贵洲
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Individual
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Individual
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Priority to CN 02125966 priority Critical patent/CN1273551C/en
Publication of CN1473891A publication Critical patent/CN1473891A/en
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Publication of CN1273551C publication Critical patent/CN1273551C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

The nano composite antiseptic emulsion paint for inner wall is prepared with the materials including poly(sodium acrylate), calgon, hydroxyethyl cellulose, titanium white, lithopone, aluminum silicate, silica, talcum powder, bentonite, glycol, dodecyl alcohol ester, isothiazolinone, styrene-acrylic copolymer, organosilicon modified acrylic acid and thickener. The present invention has the advantages of double antibacterial and bacteriostasis, lasting acting, no toxcicity and lasting effect.

Description

A kind of nano composite inner wall antiseptic emulsion paint
Technical field
The present invention relates to a kind of nano composite inner wall antiseptic emulsion paint, described emulsion paint uses nano material to be raw material production.
Background technology
Existing interior wall coating ubiquity water-repellancy is poor, the easily aging problem of peeling off and going mouldy of paint film, in order to solve the problem that existing coating exists, Chinese patent 00125488.X discloses a kind of high-elasticity nanometer paint, and 11 kinds of chemical feedstockss have been adopted in this invention, and wherein part has been used nano material, but, do not dissolve in long acting antibiotic composition and the anti-aging composition of peeling off in its material, so the performance of this coating does not still reach gratifying effect.Therefore, need to propose a kind of nano composite inner wall antiseptic emulsion paint.
Summary of the invention
The object of the present invention is to provide a kind of nano composite inner wall antiseptic emulsion paint, this emulsion paint has photochemical catalysis and the dual antibacterial and bacteriostasis of metal ion, can significantly improve the comprehensive physicochemical property of coating, can effectively improve the indoor pollution problem.
The objective of the invention is to realize by following technical proposals: a kind of nano composite inner wall antiseptic emulsion paint,
This emulsion paint is formed by following feedstock production, and the weight ratio of described raw material is:
Pure water 72
Sodium polyacrylate 1
Sodium hexametaphosphate 99 0.5-0.6
Natvosol 0.4
Titanium dioxide 20-30
Zinc sulfide white 31-41
Pure aluminium silicate 2
Silicon-dioxide 0.06-0.1
Talcum powder 16
Wilkinite 0.5
Ethylene glycol 3
12 carbon alcohol esters 2
Isothiazolones 0.2
Styrene-propene acid copolymer 40
Organosilicon-modified acrylic 5
Thickening material 0.3-0.4;
Wherein, described titanium dioxide is a titanium dioxide; Nano level titanium dioxide is 10% of a used titanium dioxide total amount;
Described silicon-dioxide is nano level, and its consumption is the 3-5% of used pure aluminium silicate total amount;
Described talcum powder is two kinds of granular mixtures, and its two kinds of particulate ratio of mixture are 800 orders: 1200 orders are 9: 1;
Described isothiazolones is the multipolymer of 5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone;
Described thickening material is ethyl propenoate, Sipacril 2739OF;
The present invention compared with prior art has following advantage:
1, because the present invention has adopted the composite antibiosis raw material, therefore, the present invention has the ability of organic unwanted volatile (VOC) in the decomposition chamber, can reduce indoor harmful gas content, removes peculiar smell, purifies air.
2, because the specific surface area of nano composite material of the present invention is big, and the paint film of its formation is tridimensional network, strong covering power sticking power is big, water-fast scrubbing.
3, the present invention can increase airborne negative ion concentration, but fresh air improves people's sleep quality.
4, because the present invention has adopted nano combined raw material, therefore, have elasticity preferably, can remedy the body of wall crackle, can improve decorative effect.
5, the present invention has adopted nano composite material, and the paint film color and luster of its formation is beautiful lasting, and resistance to crocking is strong.
6, because the present invention has adopted nano combined raw material, and the exclusive photocatalysis of nano material, can make the material of hydrocarbon be oxidized to gas or change into and be easy to the material cleaned, therefore, any contamination is at the material of the hydrocarbon of surface of wall under the irradiation of light, comprise bacterium, greasy dirt or the like, be easy to be eliminated.
Embodiment
Embodiment one:
A kind of nano composite inner wall antiseptic emulsion paint is formed by following feedstock production, and the weight ratio of described raw material is:
Pure water 72
Sodium polyacrylate 1
Sodium hexametaphosphate 99 0.5
Natvosol 0.4
Titanium dioxide 20
Zinc sulfide white 41
Pure aluminium silicate 2
Silicon-dioxide 0.06
Talcum powder 16
Wilkinite 0.5
Ethylene glycol 3
12 carbon alcohol esters 2
Isothiazolones 0.2
Styrene-propene acid copolymer 40
Organosilicon-modified acrylic 5
Thickening material 0.3;
Wherein, described titanium dioxide is a titanium dioxide; Nano level titanium dioxide is 10% of a used titanium dioxide total amount;
Described silicon-dioxide is nano level, and its consumption is 3% of a used pure aluminium silicate total amount;
Described talcum powder is two kinds of granular mixtures, and its two kinds of particulate ratio of mixture are 800 orders: 1200 orders are 9: 1;
Described isothiazolones is the multipolymer of 5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone;
Described thickening material is ethyl propenoate, Sipacril 2739OF; The production technique of present embodiment is as follows:
1, gets 72 parts water and add in the stainless steel agitation vat, start stirrer and stir with the speed of 1200r/min;
2, the sodium polyacrylate that adds above-mentioned component under whipped state is as dispersion agent;
3, dispersion agent and water are stirred after, order imports nano level titanium dioxide and nano level silicon-dioxide, its import volume carries out according to above-mentioned proportioning;
4, add Sodium hexametaphosphate 99, Natvosol, titanium dioxide, zinc sulfide white, pure aluminium silicate, talcum powder, wilkinite then successively under whipped state, carry out high-speed stirring and sheared 30-40 minute, rotating speed is 1200r/min;
5, make stirrer remain on the rotating speed state of 600r/min, ethylene glycol, 12 carbon alcohol esters, isothiazolones, styrene-propene acid copolymer, organosilicon-modified acrylic are added in the agitation vat, stirred 30-40 minute;
6, regulate its pH value with ammoniacal liquor, make it reach 8-9;
7, last, thickening material added in the agitation vat stirred about 10 minutes;
8, stop to stir, leave standstill and treated after the bubble collapse in 2 hours, filter with 100 order nylon leaching nets, preparation process finishes.
Embodiment two:
A kind of nano composite inner wall antiseptic emulsion paint is formed by following feedstock production, the weight ratio of described raw material
For:
Pure water 72
Sodium polyacrylate 1
Sodium hexametaphosphate 99 0.6
Natvosol 0.4
Titanium dioxide 30
Zinc sulfide white 31
Pure aluminium silicate 2
Silicon-dioxide 0.1
Talcum powder 16
Wilkinite 0.5
Ethylene glycol 3
12 carbon alcohol esters 2
Isothiazolones 0.2
Styrene-propene acid copolymer 40
Organosilicon-modified acrylic 5
Thickening material 0.4;
Wherein, described titanium dioxide is a titanium dioxide; Nano level titanium dioxide is 10% of a used titanium dioxide total amount;
Described silicon-dioxide is nano level, and its consumption is 5% of a used pure aluminium silicate total amount;
Described talcum powder is two kinds of granular mixtures, and its two kinds of particulate ratio of mixture are 800 orders: 1200 orders are 9: 1;
Described isothiazolones is the multipolymer of 5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone;
Described thickening material is ethyl propenoate, Sipacril 2739OF; The production technique of present embodiment is identical with embodiment one.

Claims (1)

1, a kind of nano composite inner wall antiseptic emulsion paint is characterized in that: formed by following feedstock production, the weight ratio of described raw material is:
Pure water 72
Sodium polyacrylate 1
Sodium hexametaphosphate 99 0.5-0.6
Natvosol 0.4
Titanium dioxide 20-30
Zinc sulfide white 31-41
Pure aluminium silicate 2
Silicon-dioxide 0.06-0.1
Talcum powder 16
Wilkinite 0.5
Ethylene glycol 3
12 carbon alcohol esters 2
Isothiazolones 0.2
Styrene-propene acid copolymer 40
Organosilicon-modified acrylic 5
Thickening material 0.3-0.4; Wherein, described titanium dioxide is a titanium dioxide; Nano level titanium dioxide is 10% of a used titanium dioxide total amount;
Described silicon-dioxide is nano level, and its consumption is the 3-5% of used pure aluminium silicate total amount;
Described talcum powder is two kinds of granular mixtures, and its two kinds of particulate ratio of mixture are 800 orders: 1200 orders are 9: 1;
Described isothiazolones is the multipolymer of 5-chloro-2-methyl-4-isothiazoline-3-ketone and 2-methyl-4-isothiazoline-3-ketone;
Described thickening material is ethyl propenoate, Sipacril 2739OF.
CN 02125966 2002-08-07 2002-08-07 Nano composite inner wall antiseptic emulsion paint Expired - Fee Related CN1273551C (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 02125966 CN1273551C (en) 2002-08-07 2002-08-07 Nano composite inner wall antiseptic emulsion paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 02125966 CN1273551C (en) 2002-08-07 2002-08-07 Nano composite inner wall antiseptic emulsion paint

Publications (2)

Publication Number Publication Date
CN1473891A true CN1473891A (en) 2004-02-11
CN1273551C CN1273551C (en) 2006-09-06

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100357375C (en) * 2004-12-16 2007-12-26 中国地质大学(武汉) Anti-bacteria mildew-proof internal-wall emulsion paint and preparation method therefor
CN101831207A (en) * 2010-04-28 2010-09-15 上海榕源环境科技有限公司 All-weather nano photocatalyst product for controlling decoration pollution
CN102690572A (en) * 2012-06-19 2012-09-26 谢锋 Emulsion paint capable of absorbing automobile exhaust
CN104987783A (en) * 2015-07-29 2015-10-21 刘善江 Interior wall water paint for children's bedroom and preparation method for interior wall water paint
CN108929601A (en) * 2018-06-19 2018-12-04 佛山市高明区首邦化工有限公司 A kind of preparation method of antibiotic emulsion paint
CN109796814A (en) * 2018-12-27 2019-05-24 宁波中一石化科技股份有限公司 Antibacterial inner wall paint and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN100357375C (en) * 2004-12-16 2007-12-26 中国地质大学(武汉) Anti-bacteria mildew-proof internal-wall emulsion paint and preparation method therefor
CN101831207A (en) * 2010-04-28 2010-09-15 上海榕源环境科技有限公司 All-weather nano photocatalyst product for controlling decoration pollution
CN101831207B (en) * 2010-04-28 2013-01-02 上海榕源环境科技有限公司 All-weather nano photocatalyst product for controlling decoration pollution
CN102690572A (en) * 2012-06-19 2012-09-26 谢锋 Emulsion paint capable of absorbing automobile exhaust
CN104987783A (en) * 2015-07-29 2015-10-21 刘善江 Interior wall water paint for children's bedroom and preparation method for interior wall water paint
WO2017016091A1 (en) * 2015-07-29 2017-02-02 河北晨阳工贸集团有限公司 Interior wall water paint for children's bedroom and preparation method therefor
CN108929601A (en) * 2018-06-19 2018-12-04 佛山市高明区首邦化工有限公司 A kind of preparation method of antibiotic emulsion paint
CN109796814A (en) * 2018-12-27 2019-05-24 宁波中一石化科技股份有限公司 Antibacterial inner wall paint and preparation method thereof

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Publication number Publication date
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Granted publication date: 20060906

Termination date: 20110807