CN1463793A - Ferromanganese catalyst for Fischer-Tropsch synthesis and method for preparing the same - Google Patents
Ferromanganese catalyst for Fischer-Tropsch synthesis and method for preparing the same Download PDFInfo
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- CN1463793A CN1463793A CN 02121248 CN02121248A CN1463793A CN 1463793 A CN1463793 A CN 1463793A CN 02121248 CN02121248 CN 02121248 CN 02121248 A CN02121248 A CN 02121248A CN 1463793 A CN1463793 A CN 1463793A
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- Prior art keywords
- catalyzer
- fischer
- catalyst
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- 239000003054 catalyst Substances 0.000 title claims abstract description 36
- 238000000034 method Methods 0.000 title abstract description 12
- 230000015572 biosynthetic process Effects 0.000 title abstract description 5
- 238000003786 synthesis reaction Methods 0.000 title abstract description 5
- 229910000616 Ferromanganese Inorganic materials 0.000 title 1
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 title 1
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 239000002243 precursor Substances 0.000 claims abstract description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 50
- 239000011572 manganese Substances 0.000 claims description 30
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 24
- 229910052748 manganese Inorganic materials 0.000 claims description 22
- 229910052742 iron Inorganic materials 0.000 claims description 21
- 239000000243 solution Substances 0.000 claims description 20
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 17
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- 238000002156 mixing Methods 0.000 claims description 14
- 229910052700 potassium Inorganic materials 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 229910000027 potassium carbonate Inorganic materials 0.000 claims description 11
- 235000011181 potassium carbonates Nutrition 0.000 claims description 11
- 239000012266 salt solution Substances 0.000 claims description 10
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 8
- 239000012065 filter cake Substances 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- 238000010009 beating Methods 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000002244 precipitate Substances 0.000 claims description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910002651 NO3 Inorganic materials 0.000 claims description 3
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 3
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 239000007864 aqueous solution Substances 0.000 claims description 2
- 238000000748 compression moulding Methods 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- 229940071125 manganese acetate Drugs 0.000 claims description 2
- UOGMEBQRZBEZQT-UHFFFAOYSA-L manganese(2+);diacetate Chemical compound [Mn+2].CC([O-])=O.CC([O-])=O UOGMEBQRZBEZQT-UHFFFAOYSA-L 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 238000000247 postprecipitation Methods 0.000 claims description 2
- 235000015320 potassium carbonate Nutrition 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 238000001556 precipitation Methods 0.000 abstract description 10
- 230000008569 process Effects 0.000 abstract description 8
- 230000008901 benefit Effects 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 8
- 239000010703 silicon Substances 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 229910052799 carbon Inorganic materials 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 6
- 230000032683 aging Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 230000009467 reduction Effects 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- 229910004298 SiO 2 Inorganic materials 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 229910002091 carbon monoxide Inorganic materials 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003345 natural gas Substances 0.000 description 1
- 210000003739 neck Anatomy 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011882 ultra-fine particle Substances 0.000 description 1
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Abstract
Description
Claims (8)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02121248 CN1203920C (en) | 2002-06-12 | 2002-06-12 | Ferromanganese catalyst for Fischer-Tropsch synthesis and method for preparing the same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 02121248 CN1203920C (en) | 2002-06-12 | 2002-06-12 | Ferromanganese catalyst for Fischer-Tropsch synthesis and method for preparing the same |
Publications (2)
Publication Number | Publication Date |
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CN1463793A true CN1463793A (en) | 2003-12-31 |
CN1203920C CN1203920C (en) | 2005-06-01 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN 02121248 Expired - Lifetime CN1203920C (en) | 2002-06-12 | 2002-06-12 | Ferromanganese catalyst for Fischer-Tropsch synthesis and method for preparing the same |
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CN (1) | CN1203920C (en) |
Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1297343C (en) * | 2004-11-30 | 2007-01-31 | 中国科学院山西煤炭化学研究所 | Iron/manganese catalyst used for Fischer Tropsch synthesis, its preparation method and application |
WO2009094936A1 (en) * | 2008-01-23 | 2009-08-06 | Accelergy Shanghai R & D Center Co., Ltd. | Catalyst for fischer-tropsch synthesis and its preparation method |
WO2009100663A1 (en) * | 2008-01-23 | 2009-08-20 | Accelergy Shanghai R & D Center Co., Ltd. | Iron-based fischer-tropsch catalyst and method for making the same |
WO2010121516A1 (en) * | 2009-04-22 | 2010-10-28 | 中科合成油技术有限公司 | Fischer–tropsch synthesis catalyst, preparation and application thereof |
CN102076413A (en) * | 2008-06-24 | 2011-05-25 | 克斯莫石油株式会社 | Catalyst for fischer-tropsch synthesis, and process for production of hydrocarbon |
CN102209699A (en) * | 2008-11-11 | 2011-10-05 | 吉坤日矿日石能源株式会社 | Method for manufacturing unsaturated hydrocarbon and oxygenated compound, catalyst, and manufacturing method therefor |
CN102441384A (en) * | 2010-10-12 | 2012-05-09 | 中国石油化工股份有限公司 | Method for preparing low-carbon olefin catalyst by high-activity-stability carrier-type iron-based synthetic gas |
US8758596B2 (en) | 2008-12-26 | 2014-06-24 | Jx Nippon Oil & Energy Corporation | Hydrogenation isomerization catalyst, method for producing same, method for dewaxing hydrocarbon oil, and method for producing lubricant base oil |
CN105688926A (en) * | 2014-11-24 | 2016-06-22 | 神华集团有限责任公司 | Fischer-tropsch iron-based catalyst high in low carbon olefin yield, and preparation method thereof |
CN107617442A (en) * | 2016-07-15 | 2018-01-23 | 神华集团有限责任公司 | The method that F- T synthesis precipitated iron-based catalyst and its preparation method and application and synthesis gas synthesize hydrocarbon compound processed through syrup state bed Fischer Tropsch |
-
2002
- 2002-06-12 CN CN 02121248 patent/CN1203920C/en not_active Expired - Lifetime
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1297343C (en) * | 2004-11-30 | 2007-01-31 | 中国科学院山西煤炭化学研究所 | Iron/manganese catalyst used for Fischer Tropsch synthesis, its preparation method and application |
WO2009094936A1 (en) * | 2008-01-23 | 2009-08-06 | Accelergy Shanghai R & D Center Co., Ltd. | Catalyst for fischer-tropsch synthesis and its preparation method |
WO2009100663A1 (en) * | 2008-01-23 | 2009-08-20 | Accelergy Shanghai R & D Center Co., Ltd. | Iron-based fischer-tropsch catalyst and method for making the same |
CN102076413B (en) * | 2008-06-24 | 2013-06-19 | 克斯莫石油株式会社 | Catalyst for fischer-tropsch synthesis, and process for production of hydrocarbon |
CN102076413A (en) * | 2008-06-24 | 2011-05-25 | 克斯莫石油株式会社 | Catalyst for fischer-tropsch synthesis, and process for production of hydrocarbon |
CN102209699A (en) * | 2008-11-11 | 2011-10-05 | 吉坤日矿日石能源株式会社 | Method for manufacturing unsaturated hydrocarbon and oxygenated compound, catalyst, and manufacturing method therefor |
US8758596B2 (en) | 2008-12-26 | 2014-06-24 | Jx Nippon Oil & Energy Corporation | Hydrogenation isomerization catalyst, method for producing same, method for dewaxing hydrocarbon oil, and method for producing lubricant base oil |
WO2010121516A1 (en) * | 2009-04-22 | 2010-10-28 | 中科合成油技术有限公司 | Fischer–tropsch synthesis catalyst, preparation and application thereof |
RU2477654C1 (en) * | 2009-04-22 | 2013-03-20 | Синфьюэлс Чайна Текнолоджи Ко., Лтд | Fischer-tropsh synthesis catalyst, its production and application |
CN102441384A (en) * | 2010-10-12 | 2012-05-09 | 中国石油化工股份有限公司 | Method for preparing low-carbon olefin catalyst by high-activity-stability carrier-type iron-based synthetic gas |
CN105688926A (en) * | 2014-11-24 | 2016-06-22 | 神华集团有限责任公司 | Fischer-tropsch iron-based catalyst high in low carbon olefin yield, and preparation method thereof |
CN105688926B (en) * | 2014-11-24 | 2020-08-21 | 国家能源投资集团有限责任公司 | Fischer-Tropsch iron-based catalyst for producing more low-carbon olefins and preparation method thereof |
CN107617442A (en) * | 2016-07-15 | 2018-01-23 | 神华集团有限责任公司 | The method that F- T synthesis precipitated iron-based catalyst and its preparation method and application and synthesis gas synthesize hydrocarbon compound processed through syrup state bed Fischer Tropsch |
CN107617442B (en) * | 2016-07-15 | 2020-07-14 | 神华集团有限责任公司 | Fischer-Tropsch synthesis precipitated iron-based catalyst, preparation method and application thereof, and method for preparing hydrocarbon compound by Fischer-Tropsch synthesis of synthesis gas through slurry bed |
Also Published As
Publication number | Publication date |
---|---|
CN1203920C (en) | 2005-06-01 |
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Owner name: ZHONGKE SYNTHETIC OIL TECHNOLOGY CO., LTD., DISTR Free format text: FORMER OWNER: SHANXI INST. OF COAL CHEMISTRY, CHINESE ACADEMY OF SCIENCES Effective date: 20070126 |
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C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20070126 Address after: 030006 Taiyuan hi tech Zone, South Central Cyberport, port 4, zone 2, A and B Patentee after: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. Address before: 165 mailbox 030001, Shanxi City, Taiyuan Province Patentee before: Shanxi Institute of Coal Chemistry, Chinese Academy of Sciences |
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C56 | Change in the name or address of the patentee | ||
CP02 | Change in the address of a patent holder |
Address after: 101407 Beijing city Huairou District Yanqi Economic Development Zone C District No. 1 south two Street Park Patentee after: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. Address before: 030006, Taiyuan hi tech Zone, Shanxi, South Central Cyberport, port 4, 2 floor, A, B Patentee before: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. |
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CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: 101407 No. 1, south 2nd Street, paradise, Zone C, Yanqi Economic Development Zone, Huairou District, Beijing Patentee after: Zhongke synthetic oil Technology Co.,Ltd. Address before: 101407 No. 1, south 2nd Street, paradise, Zone C, Yanqi Economic Development Zone, Huairou District, Beijing Patentee before: SYNFUELS CHINA TECHNOLOGY Co.,Ltd. |
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CX01 | Expiry of patent term |
Granted publication date: 20050601 |
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CX01 | Expiry of patent term |