CN1459479A - Water base preparation and method for coating slide-proof layer and product containing his slide-proof layer - Google Patents
Water base preparation and method for coating slide-proof layer and product containing his slide-proof layer Download PDFInfo
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- CN1459479A CN1459479A CN 02117357 CN02117357A CN1459479A CN 1459479 A CN1459479 A CN 1459479A CN 02117357 CN02117357 CN 02117357 CN 02117357 A CN02117357 A CN 02117357A CN 1459479 A CN1459479 A CN 1459479A
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Abstract
A water-base preparation used for coating antiskid layer on the surface of object contains composite water-base paint, synthetic particles, and water-base solidifying agent. Its preparing process, its application method and the product with the said antiskid layer on its surface are also disclosed.
Description
Technical field
The present invention relates to a kind of water-base preparation that is used for the surface coated non-skid finish, wherein said preparation contains a kind of water base paint compositions, particulate material and water base solidifying agent.
Background technology
United States Patent (USP) 2; 793; 136 disclose a kind of preparation that is used for the surface coated non-skid finish, wherein are coated with the discrete particles or the fluid dispersion of crude resin particles dispersed in liquid plasticizer at one deck band in small, broken bits angle from the teeth outwards, disclose the goods that contain above-mentioned non-skid finish simultaneously.Resin particle in the softening agent must be partly soluble when softening agent is heated or can form gel.More particularly, after this dispersion liquid is coated the surface, obtained the hardened resin grain that one deck embeds.Particle size can be different, but are preferably 1/16 to 1/2 inch, and the fluid that a part of particle is stretched out have cured disperses more than the upper surface of liquid layer.Then, should heat with corresponding layer on the surface, make resin particle be partly dissolved in the softening agent.Obtained one after the cooling and embedded particulate Hookean body layer, wherein at least a portion particle reaches more than the upper surface of described layer.Resin particle is preferably the homopolymer of multipolymer, polyvinyl chloride, polymethylmethacrylate, vinylchlorid and the vinylidene chloride of vinylchlorid and vinyl acetate, and softening agent wherein is preferably ester, as dioctyl phthalate (DOP).Yet, according to United States Patent (USP) 2,793,136 coating composition, it does not contain the solidifying agent that can make softening agent crosslinked, and thisly crosslinkedly can provide more attrition resistant non-skid finish.
UK Patent Application 2156672 also discloses a kind of such preparation.A kind of coating composition that rough coatings is provided for sanitary product has been described in this patent application.Visit composition and comprise a kind of polymkeric substance, particularly a kind of polymethylmethacrylate, a kind of filler, a kind of particulate material and a kind of solidifying agent, preferred benzoyl peroxide.Particulate material is that 200 to 800 microns granulated glass sphere is formed by size preferably.For example can aforementioned coating composition be coated at as bathtub, shower floor the end, thereby provide nonskidcoating for it with the mode of brush.
A shortcoming of the coating of UK Patent Application 2156672 is, coatingsurface has big relatively polarity, this is because this coating is made up of polymethyl acrylate and granulated glass sphere, thereby makes water be easy to rest between the glass beads coated, and it is unfavorable for the non-skid property of coating.Because the existence of water, bacterium and mould also are easy to be grown in wherein, and this is not only harmful to HUMAN HEALTH, bring detrimental action also can for simultaneously the non-skid property of coating.
WO88/00018, DE-A3320929 and US4363145 also disclose preparation and the composition for one or more surface coated surface anti-skidding layers of sanitary product.WO88/00018 has described a kind of elastomeric coating composition that contains.This coating composition can be applied to the bottom of sanitary product, because its bottom is coated with aforementioned coating composition, so the frictional behaviour of this sanitary product is improved.
DE-A3320929 has described a kind of method of using the synthetic materials that contains rubber to be coated with coating as sanitary product.The coating that aforesaid method obtains is rough.We find to use the bathtub of this coating composition or the bottom on shower floor not to have enough non-skid properties, because do not contain particulate material in this coating composition, thereby cause the concavity deficiency of this coating.
U.S. Pat 4,363,145 have described a kind of method of coating being coated enamel material.In this method, will there be the template of opening to be placed on the surface of having cleaned, coating layer be etched away and clean the position of this etching with acid on the surface of opening part then.Order is coated with the silica containing sand of enamel, one deck and another layer that one deck contains urethane and contains being coated with of urethane then.Remove template at last and with the coating curing that obtains.The shortcoming of this method is that work is heavy.Another shortcoming of this method is the sand that contains silicon-dioxide that will use particle smaller usually.For example, when the method according to this United States Patent (USP) is coated with the shower floor, there is the place of sand very sharp, thereby does not feel like oneself.
Summary of the invention
Therefore, the objective of the invention is to overcome above-mentioned shortcoming, a kind of preparation that is used for the coating surface non-skid finish is provided, wherein said preparation comprises a kind of water base paint compositions that contains water-based resin and particle synthetic materials, it is characterized in that, this coating composition further contains a kind of water base solidifying agent, and used particle synthetic materials is apolar substance, and Shore hardness is 50-85.Using synthetic advantage of particulate is their ratios, for example granulated glass sphere, to contain the silicon-dioxide sand soft.Therefore, have according to the surperficial touch perception of non-skid finish of the present invention fine.
According to other advantage of preparation of the present invention is to access colour-fast, firm, scratch resistance and attrition resistant non-skid finish, and outstanding weather resistance is arranged when outdoor application, and chemical substance is had good resistivity.
Described synthetic particle is by the non-polar material manufacturing.For example, the example of this nonpolar synthetic materials has the multipolymer of polypropylene, polyethylene, polystyrene, ethene and vinyl acetate between to for plastic, and ethene and unsaturated olefin are as the multipolymer and the EPDM rubber of propylene, 1-butylene, 1-hexene and 1-octene.By using the synthetic particle of nonpolar synthetic materials, make that the coating polarity that obtains was lower, therefore, does not have or have only water seldom can be retained between the particle of coating when preparation according to the present invention was applied to surperficial going up.In addition, described synthetic materials can to unite use also very important with described water base paint compositions.According to the present invention, the synthetic materials of use is preferably polypropylene and EPDM rubber, preferred especially EPDM rubber grain.The preferred polypropylene that uses has following performance:
Melt flow index is (according to ASTM D 238; 5kg/230 ℃): 2g/10min is to 200g/10min.
Density (according to DIN 53479): 0.9-1.2g/cm
3
Fusing point: 60-180 ℃
Shore hardness (shore D hardness) (ASTM D2240): 50-85
Suitable synthetic particulate selects to depend on especially the hardness of synthetic materials.If possible, wish to use softer synthetic materials, for example use HDPE (Shore hardness according to ASTM D2240 is approximately 65-69), LDPE (Shore hardness according to ASTM D2240 is approximately 60-65), perhaps even poly-1-butylene (Shore hardness according to ASTM D2240 is approximately 55).According to the present invention, the synthetic particulate Shore hardness (according to ASTM D224) of use is at least 65, preferably is at least 85.Synthetic particle can be an all size, and the purposes of preparation is depended in the selection of size.For example, if preparation is to be used to be coated with bathtub or bathing base, then the synthetic particulate size of Xuan Zeing will make the coating of acquisition touch up comfortable.According to the present invention, synthetic particulate mean size is the 20-400 micron, preferred 30-300 micron.As mentioned above, synthetic particulate size will be complementary with desired purposes.Therefore, especially, synthetic particulate mean sizes is 30-100 micron or 100-300 micron.Yet verified, it also is possible using the particle that is roughly 4mm.
According to the present invention, well adhere from the teeth outwards in order to make preparation, preferably also contain a kind of tensio-active agent in the preparation.This tensio-active agent is preferably polysiloxane, for example propyl-triethoxysilicane, hexadecyl Trimethoxy silane, vinyl three (2-methoxy ethoxy) silane, 3-azido-propyl-triethoxysilicane, 3-thiocyano propyl triethoxy silicane, 3-aminopropyltriethoxywerene werene and two (3-triethoxysilylpropyltetrasulfide) amine.Especially, tensio-active agent is 3-aminopropyltriethoxywerene werene and/or two (3-triethoxysilylpropyltetrasulfide) amine of technical grade.According to preparation of the present invention, preferably contain the tensio-active agent of 0.01-5% (weight), special preferred content is 0.1-2% (weight).
Can also comprise one or more other reagent according to water-base preparation of the present invention, as reagent, brightener, dyestuff and/or the pigment of filler, raising resistance to marring.When preparation contained filler, the non-skid finish that then uses this preparation to obtain was opaque.Colored nonskidcoating can obtain by using dyestuff and/or pigment.
Preferably comprise a kind of vibrin according to coating composition of the present invention, polyacrylate resin, halogen-containing fluoropolymer resin, Resins, epoxy, polyamide resin, urethane resin or Synolac.
If coating composition comprises vibrin, preferred resin is the saturated polyester that contains terminal hydroxy groups, and the content of hydroxyl is (weight percent) between 4.0-7.0%.
If coating composition comprises polyacrylate resin, preferred resin is the polyacrylate resin that contains terminal hydroxy groups, and the content of hydroxyl is between 3-5% (weight percent) preferably.
Fluoropolymer is the example of suitable polymer containing halogen.
If coating composition contains Resins, epoxy, this Resins, epoxy preferred source is from dihydroxyphenyl propane or Epicholorohydrin, and molecular weight is less than 700.
If coating composition contains urethane resin, preferred aliphatic series urethane resin then, this aliphatic urethane resin can solidify by enough hexamethylene diisocyanates.This resin can also be a polyester-polyurethane fat resin, for example the Uracron CY499E of DSM Resin company sale.
Preparation of the present invention also contains a kind of solidifying agent except the coating composition that contains particulate material.Described solidifying agent has guaranteed that when preparation was coated the surface, coating composition can be crosslinked, thereby produces non-skid finish.When coating composition contained the saturated polyester with terminal hydroxy groups, the polyacrylic ester with terminal hydroxy groups or fluoropolymer, solidifying agent was preferably vulcabond, particularly hexamethylene diisocyanate.When containing Resins, epoxy in the coating composition, solidifying agent is preferably vulcabond, and particularly 2,4-two isocyanato toluene or contain the amino polymeric amide of end, for example be derived from those of dibasic carboxylic acid and excessive polyamine, as N-(2-amino-ethyl)-1,2-ethane diamine.
Preferably exist according to water-base preparation of the present invention with two components system forms.Water base coating composition and water base solidifying agent mixed 15 to 60 minutes with volume ratio before use in 1: 1 to 1: 10.The volume ratio of preferred coating compositions and solidifying agent is 1: 2 to 1: 6, and special preferably approximately is 1: 2.Be at least 4 hours the storage period in the time of 20 ℃, preferably at least 8 hours.
Further contain the synthetic particle of preferred 5-50% weight according to water-base preparation of the present invention, preferred especially 10-30% (weight percent).
Water-base preparation according to the present invention has wetting, the anti-pitting attack of good especially base material, and shellfish receives the character of eddy flow nest (Benard cells), scratch resistance and ventilation property aspect.
Can comprise one or more organic solvents or water as thinner according to water-base preparation of the present invention.Preferably, water-base preparation according to the present invention is the preparation with high solid content, for example, and so-called " high solid coating " (" high solids coatings ") or only contain the preparation of water as thinner.Preferably be diluted to 40-50% (volume percent) (corresponding to the about 10-25% of weight percent) according to water-base preparation of the present invention.
Can pass through brush, roll-in, injection, blade coating or the coating of painted method according to water-base preparation of the present invention.Preferably, use so-called " large volume low pressure " (" high volume lowpressure ") equipment sprays or is coated with said preparation with special brushing tool.
Can randomly comprise a kind of crosslinking accelerator according to water-base preparation of the present invention, as peroxidation dibenzyl or dibutyl tin dilaurate fat.Importantly this crosslinking accelerator can at room temperature work herein.Though those at high temperature, for example following effective crosslinking accelerator also can use up to 100 ℃.
Water-base preparation according to the present invention is suitable for the surface applied nonskidcoating at various materials, for example brick, cement, wood, stone, synthetic materials, steel, iron, enamel material, bed course ethene etc.Surface to be coated can be plane, convex surface or concave surface.For example, tile work ground, shower floor and bathtub.
The invention still further relates to a kind of method at the surface coated non-skid finish, wherein, earlier should the surface in the first step with clean-out system and adhesion promotor pre-treatment, second step was that water-base preparation of the present invention is applied on this surface.With clean-out system and the pretreated purpose of adhesion promotor is in order to obtain preparation and surperficial good adhesive property.
If the surface is to contain silicon face, as stone or cement, so at first clean with clean-out system, clean with polysiloxane then, according to the present invention, polysiloxane wherein is preferably the mixture of 3-aminopropyltriethoxywerene werene and two (the silica-based propyl group of the 3-triethoxy first) amine of technical grade.A kind of product of particularly suitable is, for example Boran adhesion promotor (Boran adhesive Promoter).
If the surface is the surface that contains synthetic materials, the preferred processing with clean-out system earlier in this surface uses the adhesion promotor of being made up of polar polymer liquid to handle then.A kind of example of suitable adhesion promotor is Boran Adhesive KK 363, and it is sold by Baderet Int.B.V. company.Another adhesion promotor that is fit to is HK 463.
According to the present invention, the clean-out system of use preferably comprises the organic liquid of one or more polar organic compounds.A kind of suitable clean-out system is Boran Degreaser, and it is sold by Baderet Int.B.V. company.
The invention still further relates to a kind of method, wherein used synthetic particulate material, particularly polypropylene GRANULES or EPDM particle at a surface coated non-skid finish.
The invention still further relates to a kind of product with non-skid finish, this product comprises a kind of preparation that contains particulate material, and this particulate material is made of synthetic particle, particularly polypropylene GRANULES and EPDM particle.The product that can use non-skid finish has, and for example bathtub, shower floor and tile work ground are as the tile work ground in hospital, hotel and the natatorium.
The following examples are used for further explaining the present invention.
Embodiment 1
At first thoroughly clean the surface on tile work ground with soap and water.Thorough drying should the surface then, and pretreated last step comprises coat binding promotor (3-aminopropyltriethoxywerene werene/two of technical grade (the silica-based propyl group of 3-triethoxy first) amine).
Pass through then water-borne polyurethane coatings (AquaBoran Gloss or AquaBoranSemiGloss, sell by Baderet Int.B.V. company) and the water base solidifying agent (AquaBoran Harder is sold by Baderet Int.B.V. company) that contains hexamethylene diisocyanate mix at 1: 2 with volume ratio and prepare preparation of the present invention.Add weight percent then and be 0.3% crosslinking accelerator in the gained mixture, add weight percent again and be 12% polypropylene GRANULES, this polypropylene GRANULES size is the 5-90 micron, and melt flow index is (according to ASTM D238; 5kg/230 ℃) be 180g/min, Shore hardness (ASTM D2240) is 70, density is 0.905g/cm
3, melting range (DSC:10 ℃/min) be 163-2-168 ℃.Stirred this mixture (BoranStructuur, Gloss or Semi-Gloss) about 5 minutes, and afterwards the preparation that obtains was coated on the tile work ground by means of " large volume low pressure " (" high volume low pressure ") japanning injector.
Coat the ground non-skid finish of tile work and need pass through about four hours drying.Thereby after four hours, the people just can walk on this tile work ground in non-skid finish coating back.The fraction of coverage of about 50 microns bed thickness is approximately 10m
2/ kg.Embodiment 2
Repeat the experiment among the embodiment 1, different is that non-skid finish is coated on the shower floor, has used the template of four leaf cloverleaf patterns (four-leaf clover) for this reason.Resulting non-skid finish is made of unconnected four-Ye trifolium shape zone.
Embodiment 3
In this embodiment, respectively the preparation process of the preparation with finestructure and coarse texture described.
Table A finestructure Boran Semi-Gloss
a: Boran Harder
bRatio of mixture: 100: 38-100: 50 (w/w)
cStorage period (20 ℃): the mean sizes of minimum 8 hours polypropylene GRANULES: 5-90 micron crosslinking accelerator: 0.04% (weight) thinner
d(using the brush coating): 20% (weight) thinner
d(using spraying): (high gloss＞80% is according to Glans 60 for 20-30% (weight) a. polyurethane coating; Flash-point＜20 ℃; Density=1.1-1.3g/cm
344% weight solid content).B. hexamethylene diisocyanate c. is according to color d.Boran Thinner
Table B coarse texture Boran Gloss
a: the ratio of mixture of Boran Harder: 100: 48 (w/w) storage periods (20 ℃): the mean sizes of minimum 6 hours polypropylene GRANULES: 20-200 micron crosslinking accelerator: 0.04% (weight) thinner
b(use and brush cloth): 15% (weight) thinner
b(using spraying): (semi-matt 20-40% is according to Glans 60 for 15-20% (weight) a. polyurethane coating; Flash-point＜21 ℃; Density=1.1-1.3g/cm
3The solid content of 44% weight) b.Boran Thinner diluent B oran Thinner contains organic solvent (dimethylbenzene, acetic acid n-butyl and 2-butanone) and a kind of tracer agent (tracer).
In embodiment 4 present embodiments, the ratio of mixture according to preparation of the present invention (table C) as the function of preparation color has been described.
Table C
Lure bright type:Coating
a: solidifying agent
b100: 50 (w/w) synthesizes particle 12% (weight) thinner
c15% (weight)
The light color type:Coating
a: solidifying agent
b100: 38 (w/w) synthesizes particle 10% (weight) thinner
c20% (weight)
Dark type:Coating
a: solidifying agent
b100: 48 (w/w) synthesizes particle 10% (weight) thinner
c15% (weight) a. polyurethane coating b. hexamethylene diisocyanate c.Boran thinner example implements 5
Boran Semi-Gloss polyurethane coating can be made up of following :-urethane resin 47.8% (weight)-scratch resistance promotor 2.4% (weight)-brightener 8.8% (weight)-crosslinking accelerator 0.1% (weight) thinner 28.9% (weight) polypropylene GRANULES 12.0% (weight)
100% gross weight
Embodiment 6 the following examples have provided a kind of composition of water-base preparation: coating
a61.9% (weight) solidifying agent
b13.55% (weight) water (deionization) 23.50% (weight) tensio-active agent 0.35% (weight) tackiness agent
c0.70% (weight) a. aliphatic polyester-urethane b. hexamethylene diisocyanate (NCO content: 23% weight) c. water, dimethylethanolamine and acetic acid ethoxycarbonyl propyl ester or acetic acid methoxy-propyl ester mixture
40% solution; PH=7.0-8.5; The polypropylene GRANULES (according to embodiment 1) or the EPDM rubber grain that add 6% (weight) in hydroxyl value (according to solid matter)=3.1-3.6 mixture.
Embodiment 7 the following examples have provided a kind of composition of water-base preparation:
Table E coating
a: 21.1% (weight) solidifying agent
b: 36.9% (weight) water (deionization): 40.7% (weight) tensio-active agent: 0.55% (weight) matting agent: (viscosity is approximately 3250mPa.s to 0.75a. Resins, epoxy, oxirane value=0.525, average epoxy equivalent (weight) (average epoxy equivalence)=190; Solid content=100%) (viscosity is approximately 40000mPa.s to b. amine, amine value=125, active equivalent (active equivalence)=335; Solid content=50%) polypropylene GRANULES (according to embodiment 1) or the EPDM rubber grain of adding about 6% (weight) in the mixture.
Claims (19)
1. preparation that is used for the surface coated non-skid finish, wherein said preparation comprises a kind of water base paint compositions, particle synthetic materials and a kind of water base solidifying agent, it is characterized in that described particulate material is by synthetic granulometric composition.
2. preparation according to claim 1 is characterized in that described synthetic particle made by the homopolymer or the EPDM rubber of homopolymer, ethene and the unsaturated olefin of polypropylene, polyethylene, polystyrene, ethene and vinyl acetate between to for plastic.
3. preparation according to claim 1 and 2 is characterized in that described synthetic particle is the particle of being made by polypropylene or EPDM rubber.
4. according to one of aforesaid right requirement described preparation, it is characterized in that described synthetic particulate mean sizes is the 20-400 micron.
5. preparation according to claim 4 is characterized in that described synthetic particulate mean sizes is the 30-100 micron.
6. preparation according to claim 4 is characterized in that described synthetic particulate mean sizes is the 100-300 micron.
7. according to one of aforesaid right requirement described preparation, it is characterized in that described preparation contains a kind of tensio-active agent.
8. preparation according to claim 7 is characterized in that described tensio-active agent is a polysiloxane.
9. according to one of aforesaid right requirement described preparation, it is characterized in that described preparation also comprises one or more fillers, promotes scratch resistant reagent, brightener, dyestuff and/or pigment.
10. a method for preparing the described preparation of claim 1 to 9 is characterized in that coating composition and solidifying agent mixed with volume ratio in 1: 1 to 1: 10.
11. method according to claim 10 is characterized in that described coating composition comprises vibrin, polyacrylate resin, polymer containing halogen resin, Resins, epoxy, polyamide resin, urethane resin or Synolac.
12. the method at the surface coated non-skid finish is characterized in that:
(i) should the surface with the soap pre-treatment;
(ii) each described preparation of claim 1 to 9 is coated this surface.
13. method according to claim 12 is characterized in that containing silicon face with the polysiloxane pre-treatment.
14. method according to claim 13 is characterized in that described polysiloxane comprises 3-aminopropyltriethoxywerene werene and/or two (3-triethoxysilylpropyltetrasulfide) amine.
15. method according to claim 12 is characterized in that using the tackiness agent pre-treatment of mainly being made up of polar polymer liquid to contain the surface of synthetic materials.
16. method according to claim 15 is characterized in that described tackiness agent mainly contains one or more synthetic resins.
17. have the product of non-skid finish, this non-skid finish contains a kind of preparation that comprises particulate material, it is characterized in that particulate material is by synthetic granulometric composition.
18. comprise of the application of synthetic particulate preparation at the coating surface non-skid finish.
19. application according to claim 18 is characterized in that described synthetic particle is the particle by polypropylene or the preparation of EPDM rubber.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 02117357 CN1459479A (en) | 2002-05-20 | 2002-05-20 | Water base preparation and method for coating slide-proof layer and product containing his slide-proof layer |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 02117357 CN1459479A (en) | 2002-05-20 | 2002-05-20 | Water base preparation and method for coating slide-proof layer and product containing his slide-proof layer |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013274A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Surface skid-resistant coating composition |
| CN103436109A (en) * | 2013-08-23 | 2013-12-11 | 吴江市英力达塑料包装有限公司 | Antiskid coating suitable for woven bags and preparation method thereof |
| CN103725123A (en) * | 2013-12-31 | 2014-04-16 | 顾宏喜 | Antiskid material and application method thereof |
| CN105131822A (en) * | 2015-10-19 | 2015-12-09 | 苏州群力防滑材料有限公司 | Non-slip strip sprayed with anti-slip materials |
| CN106030007A (en) * | 2013-12-23 | 2016-10-12 | 2-H化学有限公司 | Anti-slip flooring material, method for manufacturing anti-slip flooring material, and method for constructing floor by using anti-slip flooring material |
| CN111032777A (en) * | 2017-08-18 | 2020-04-17 | 维克托·帕戈扎-梅勒洛 | High-tolerance waterproof composition and product prepared by using same |
-
2002
- 2002-05-20 CN CN 02117357 patent/CN1459479A/en active Pending
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103013274A (en) * | 2012-11-28 | 2013-04-03 | 天长市开林化工有限公司 | Surface skid-resistant coating composition |
| CN103013274B (en) * | 2012-11-28 | 2016-03-09 | 安徽开林新材料股份有限公司 | A kind of surface anti-skidding coating composition |
| CN103436109A (en) * | 2013-08-23 | 2013-12-11 | 吴江市英力达塑料包装有限公司 | Antiskid coating suitable for woven bags and preparation method thereof |
| CN106030007A (en) * | 2013-12-23 | 2016-10-12 | 2-H化学有限公司 | Anti-slip flooring material, method for manufacturing anti-slip flooring material, and method for constructing floor by using anti-slip flooring material |
| EP3088632A4 (en) * | 2013-12-23 | 2017-09-13 | Two H Chem Ltd. | Anti-slip flooring material, method for manufacturing anti-slip flooring material, and method for constructing floor by using anti-slip flooring material |
| CN103725123A (en) * | 2013-12-31 | 2014-04-16 | 顾宏喜 | Antiskid material and application method thereof |
| CN105131822A (en) * | 2015-10-19 | 2015-12-09 | 苏州群力防滑材料有限公司 | Non-slip strip sprayed with anti-slip materials |
| CN111032777A (en) * | 2017-08-18 | 2020-04-17 | 维克托·帕戈扎-梅勒洛 | High-tolerance waterproof composition and product prepared by using same |
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