CN1456632A - Ice and snow melting cleaner - Google Patents
Ice and snow melting cleaner Download PDFInfo
- Publication number
- CN1456632A CN1456632A CN 03141386 CN03141386A CN1456632A CN 1456632 A CN1456632 A CN 1456632A CN 03141386 CN03141386 CN 03141386 CN 03141386 A CN03141386 A CN 03141386A CN 1456632 A CN1456632 A CN 1456632A
- Authority
- CN
- China
- Prior art keywords
- parts
- agent
- content
- grams
- ice
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002844 melting Methods 0.000 title description 2
- 230000008018 melting Effects 0.000 title 1
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 11
- LLSDKQJKOVVTOJ-UHFFFAOYSA-L calcium chloride dihydrate Chemical compound O.O.[Cl-].[Cl-].[Ca+2] LLSDKQJKOVVTOJ-UHFFFAOYSA-L 0.000 claims abstract description 11
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 11
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 11
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 11
- 239000000853 adhesive Substances 0.000 claims description 10
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 8
- 229910052791 calcium Inorganic materials 0.000 claims description 8
- 239000011575 calcium Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 239000002253 acid Substances 0.000 claims description 7
- 239000001506 calcium phosphate Substances 0.000 claims description 7
- 229910000389 calcium phosphate Inorganic materials 0.000 claims description 7
- 235000011010 calcium phosphates Nutrition 0.000 claims description 7
- JRBPAEWTRLWTQC-UHFFFAOYSA-N dodecylamine Chemical compound CCCCCCCCCCCCN JRBPAEWTRLWTQC-UHFFFAOYSA-N 0.000 claims description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 7
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 claims description 7
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 claims description 7
- NEEHYRZPVYRGPP-IYEMJOQQSA-L calcium gluconate Chemical compound [Ca+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O NEEHYRZPVYRGPP-IYEMJOQQSA-L 0.000 claims description 6
- 238000003756 stirring Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 5
- 230000008014 freezing Effects 0.000 abstract description 4
- 238000007710 freezing Methods 0.000 abstract description 4
- 238000004140 cleaning Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 abstract description 2
- 238000010257 thawing Methods 0.000 abstract 2
- 229910004844 Na2B4O7.10H2O Inorganic materials 0.000 abstract 1
- 238000010298 pulverizing process Methods 0.000 abstract 1
- 239000005413 snowmelt Substances 0.000 description 6
- 230000004927 fusion Effects 0.000 description 5
- 230000003179 granulation Effects 0.000 description 5
- 238000005469 granulation Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000370738 Chlorion Species 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229910000975 Carbon steel Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RGHNJXZEOKUKBD-UHFFFAOYSA-N D-gluconic acid Natural products OCC(O)C(O)C(O)C(O)C(O)=O RGHNJXZEOKUKBD-UHFFFAOYSA-N 0.000 description 1
- RGHNJXZEOKUKBD-SQOUGZDYSA-N Gluconic acid Natural products OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C(O)=O RGHNJXZEOKUKBD-SQOUGZDYSA-N 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000010962 carbon steel Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000174 gluconic acid Substances 0.000 description 1
- 235000012208 gluconic acid Nutrition 0.000 description 1
- 230000002650 habitual effect Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000011295 pitch Substances 0.000 description 1
- 239000011150 reinforced concrete Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- GOLXNESZZPUPJE-UHFFFAOYSA-N spiromesifen Chemical compound CC1=CC(C)=CC(C)=C1C(C(O1)=O)=C(OC(=O)CC(C)(C)C)C11CCCC1 GOLXNESZZPUPJE-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Materials Applied To Surfaces To Minimize Adherence Of Mist Or Water (AREA)
Abstract
A ice and snow thawing agent for road is prepared from CaCl2.2H2O, corrosion inhibitor, antiskid agent (Na2B4O7.10H2O), and adherend (carboxymethyl cellulose) through pulverizing and stirring. Its advantages are high effect on thawing ice and snow and cleaning road, low freezing point, high speed, low corrosion and cost, and no affection to plant.
Description
Technical field:
The present invention relates to a kind of novel ice-melt snow sanitising agent, belong to a kind of composition, mainly can be used for road ice-melt in winter, snow, also can be used for the dedusting cleaning of road simultaneously.
Background technology:
Along with the development of road construction, northern China traditional artificial snow removing in winter can not meet the needs of far away at present.Habitual road snow-melting agent---sodium-chlor, because the reinforced concrete structure of traffic facilities, highway, bridge and vehicle, road plant on both sides of the road etc. are had in various degree infringement, China some areas have begun to forbid with it as the agent of road ice-melt snow, and northern large-and-medium size cities road in winter disappear ice snow melt very urgent, so the exploitation environment-friendly snowmelt agent significant.
Summary of the invention:
The object of the present invention is to provide a kind of be used for road disappear the ice snow melt, can also be as a kind of novel ice-melt snow sanitising agent of large-and-medium size cities road dedusting agent.
Purpose of the present invention is implemented by following technical scheme: it includes: Calcium dichloride dihydrate (CaCL
22H
2O), inhibiter, slipproofing agent (Na
2B
4O
710H
2O), adhesive agent (carboxymethyl cellulose), by weight, described Calcium dichloride dihydrate (CaCL
22H
2O) content is 800 parts～900 parts; Inhibiter content is 30 parts～100 parts; Slipproofing agent (Na
2B
4O
710H
2O) content is 10 parts～50 parts; Adhesive agent (carboxymethyl cellulose) content is 20 parts～80 parts.Behind fusion, stirring, granulation, choosing grain, promptly make novel ice-melt snow sanitising agent.
By weight, described Calcium dichloride dihydrate (CaCL
22H
2O) content is preferably 800 parts～900 parts; Inhibiter content is preferably 50 parts; Slipproofing agent (Na
2B
4O
710H
2O) content is preferably 25 parts; Adhesive agent (carboxymethyl cellulose) content is preferably 30 parts.
Described inhibiter includes polymerization calcium wolframate, amino dodecane base polyphosphonic acid ammonium, calglucon, wooden calcium phosphate, by weight, described polymerization calcium wolframate content is that 350 parts～450 parts, amino dodecane base polyphosphonic acid ammonium content are that 250 parts～350 parts, gluconic acid calcium contents are that 150 parts～200 parts, wooden calcium phosphate content are 80～105 parts.This inhibiter is the high-efficient corrosion inhibitor of muriate salt and high chloride ion medium, can effectively suppress chlorion corrosion of metal is damaged, and slows down chlorion to disorganization effect between metal surface protection film and product, the work-ing life of significant prolongation equipment.Inhibiter can prevent the corrosive damage that Snow Agent causes the environment metallic facility in addition.Nontoxic non-corrosiveness, safe and harmless, pollution-free to environment for use.
Advantage of the present invention is: this product is mainly used in the road ice snow melt that disappears, can also be as the road dedusting agent of large-and-medium size cities.The water-absorbent of this product utilization calcium chloride is extremely strong, is exposed in the air very easily deliquescence, and is soluble in water, emits a large amount of heat simultaneously, and in addition multiple auxiliary agent is made novel ice-melt snow sanitising agent.This product has high-level efficiency, low freezing point, easily dissolving, low burn into advantage cheaply.This product snow melt speed is fast, and suitable operating temperature range is big, and very little to corrosion of carbon steel, pitch, cement pavement is not had in 15 days destroy, and plant is not had influence; This product is used before snow, and economical and effective not only the most important thing is to reduce to greatest extent the obstruction and the accident of traffic, can avoid traffic jam and accident that winter, snowfall was brought.Behind snow, use the agent of ice-melt snow and can reduce the freezing point of water, thereby prevent that it from freezing.Ice-melt snow sanitising agent is sprayed in the snow back, and snow melt speed is fast, can reduce traffic jam.
Embodiment:
Embodiment 1: produce the novel ice-melt snow of 1000 grams sanitising agent and comprise having: Calcium dichloride dihydrate (CaCL
22H
2O): 800 grams; Inhibiter: 100 grams, wherein inhibiter includes the polymerization calcium wolframate: 40 grams, amino dodecane base polyphosphonic acid ammonium: 35 kilograms, calglucon: 15 grams, wooden calcium phosphate: 10 grams; Slipproofing agent (Na
2B
4O
710H
2O): 20 grams; Adhesive agent (carboxymethyl cellulose): 80 grams; Through fusion, stirring, mix, promptly make novel ice-melt snow sanitising agent after the granulation, choosing grain.
Embodiment 2: produce the novel ice-melt snow of 1000 grams sanitising agent and comprise having: Calcium dichloride dihydrate (CaCL
22H
2O): 820 grams; Inhibiter: 80 grams, wherein inhibiter includes the polymerization calcium wolframate: 32 grams, amino dodecane base polyphosphonic acid ammonium: 24 grams, calglucon: 16 grams, wooden calcium phosphate: 8 grams; Slipproofing agent (Na
2B
4O
710H
2O): 3 grams; Adhesive agent (carboxymethyl cellulose): 60 grams; Through fusion, stir, mix, promptly make novel ice-melt snow sanitising agent after the granulation, choosing grain.
Embodiment 3: produce the novel ice-melt snow of 1000 grams sanitising agent and comprise having: Calcium dichloride dihydrate (CaCL
22H
2O): 860 grams; Inhibiter: 50 grams, wherein inhibiter includes the polymerization calcium wolframate: 20 grams, amino dodecane base polyphosphonic acid ammonium: 18 grams, calglucon: 10 grams, wooden calcium phosphate: 5 grams; Slipproofing agent (Na
2B
4O
710H
2O): 40 grams; Adhesive agent (carboxymethyl cellulose): 50 grams; Through fusion, stir, mix, promptly make novel ice-melt snow sanitising agent after the granulation, choosing grain.
Embodiment 4: produce the novel ice-melt snow of 1000 grams sanitising agent and comprise having: Calcium dichloride dihydrate (CaCL
22H
2O): 900 grams; Inhibiter: 40 grams, wherein inhibiter includes the polymerization calcium wolframate: 16 grams, amino dodecane base polyphosphonic acid ammonium: 12 grams, calglucon: 8 grams, wooden calcium phosphate: 4 grams; Slipproofing agent (Na
2B
4O
710H
2O): 50 grams; Adhesive agent (carboxymethyl cellulose): 50 grams; Through fusion, stir, mix, promptly make novel ice-melt snow sanitising agent after the granulation, choosing grain.
Four above embodiment can be that 100% novel ice-melt snow sanitising agent directly is spread on the road surface with concentration in concrete the use, also can water be that the solution of different concns such as 15%, 20%, 25%, 30% is spread on the road surface with its dilution, amount of application will be according to the snowfall type, conditional decisions such as the size of snowfall and weather conditions.
Claims (3)
1, a kind of novel ice-melt snow sanitising agent is characterized in that it includes: Calcium dichloride dihydrate (CaCL
22H
2O), inhibiter, slipproofing agent (Na
2B
4O
710H
2O), adhesive agent (carboxymethyl cellulose), its by weight, described Calcium dichloride dihydrate (CaCL
22H
2O) content is 800～900 parts; Inhibiter content is 30～100 parts; Slipproofing agent (Na
2B
4O
710H
2O) content is 10～50 parts; Adhesive agent (carboxymethyl cellulose) content is 20～80 parts.
2, a kind of novel ice-melt snow sanitising agent according to claim 1 is characterized in that, by weight, and described Calcium dichloride dihydrate (CaCL
22H
2O) content is preferably 800～900 parts; Inhibiter content is preferably 100 parts; Slipproofing agent (Na
2B4O
710H
2O) content is preferably 30 parts; Adhesive agent (carboxymethyl cellulose) content is preferably 30 parts.
3, a kind of novel ice-melt snow sanitising agent according to claim 1 and 2 is characterized in that described inhibiter includes polymerization calcium wolframate, amino dodecane base polyphosphonic acid ammonium, calglucon, wooden calcium phosphate, by weight, and its institute
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031413862A CN1182224C (en) | 2003-06-06 | 2003-06-06 | Ice and snow melting cleaner |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB031413862A CN1182224C (en) | 2003-06-06 | 2003-06-06 | Ice and snow melting cleaner |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1456632A true CN1456632A (en) | 2003-11-19 |
| CN1182224C CN1182224C (en) | 2004-12-29 |
Family
ID=29411833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB031413862A Expired - Fee Related CN1182224C (en) | 2003-06-06 | 2003-06-06 | Ice and snow melting cleaner |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1182224C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012129742A1 (en) * | 2011-03-30 | 2012-10-04 | 中交第一公路勘察设计研究院有限公司 | Eco-friendly road surface coating material for thawing ice and snow and methods of preparing and using the same |
| WO2013131489A1 (en) * | 2012-03-09 | 2013-09-12 | 华烁科技股份有限公司 | Asphalt pavement sustained-releasing deicing material and preparing method thereof |
-
2003
- 2003-06-06 CN CNB031413862A patent/CN1182224C/en not_active Expired - Fee Related
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2012129742A1 (en) * | 2011-03-30 | 2012-10-04 | 中交第一公路勘察设计研究院有限公司 | Eco-friendly road surface coating material for thawing ice and snow and methods of preparing and using the same |
| WO2013131489A1 (en) * | 2012-03-09 | 2013-09-12 | 华烁科技股份有限公司 | Asphalt pavement sustained-releasing deicing material and preparing method thereof |
| US8778216B2 (en) | 2012-03-09 | 2014-07-15 | Haiso Technology Co., Ltd | Slow release anti-icing material for bituminous pavement and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1182224C (en) | 2004-12-29 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| ASS | Succession or assignment of patent right |
Owner name: BEIJING XINHE XINRONGTECHNOLOGY CO., LTD.; ALASHA Free format text: FORMER OWNER: ZHOU ZHENGPING Effective date: 20080314 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20080314 Address after: Room 3A01T3, Silver Valley Building, 9 North Fourth Ring Road, Haidian District, Beijing, zip code: 100080 Co-patentee after: Alashanmeng Xinhe Tech. Co., Ltd. Patentee after: Beijing Xinhe Xinrong Technology Co., Ltd. Address before: The Inner Mongolia Autonomous Region Alashan Azuoqi town jartai Boyuan Industrial Co. Ltd. postcode: 750333 Patentee before: Zhou Zhengping |
|
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20041229 Termination date: 20140606 |