CN1450146A - Method for producing kerosene type solvent oil and catalyst thereof - Google Patents
Method for producing kerosene type solvent oil and catalyst thereof Download PDFInfo
- Publication number
- CN1450146A CN1450146A CN 03126138 CN03126138A CN1450146A CN 1450146 A CN1450146 A CN 1450146A CN 03126138 CN03126138 CN 03126138 CN 03126138 A CN03126138 A CN 03126138A CN 1450146 A CN1450146 A CN 1450146A
- Authority
- CN
- China
- Prior art keywords
- kerosene
- oil
- carrier
- catalyst
- hydrogenation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003350 kerosene Substances 0.000 title claims abstract description 40
- 239000003054 catalyst Substances 0.000 title claims abstract description 38
- 239000002904 solvent Substances 0.000 title claims abstract description 20
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 24
- 238000005984 hydrogenation reaction Methods 0.000 claims abstract description 17
- 239000001257 hydrogen Substances 0.000 claims abstract description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 12
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 229910017318 Mo—Ni Inorganic materials 0.000 claims abstract description 4
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 11
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 9
- 229910052721 tungsten Inorganic materials 0.000 claims description 8
- 238000004517 catalytic hydrocracking Methods 0.000 claims description 7
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 150000002431 hydrogen Chemical class 0.000 claims description 5
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical group S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 20
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 10
- 231100000252 nontoxic Toxicity 0.000 abstract description 8
- 230000003000 nontoxic effect Effects 0.000 abstract description 8
- 150000004945 aromatic hydrocarbons Chemical class 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 4
- 229910003076 TiO2-Al2O3 Inorganic materials 0.000 abstract 2
- 239000003921 oil Substances 0.000 description 30
- KBJMLQFLOWQJNF-UHFFFAOYSA-N nickel(ii) nitrate Chemical compound [Ni+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O KBJMLQFLOWQJNF-UHFFFAOYSA-N 0.000 description 12
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 9
- 239000005864 Sulphur Substances 0.000 description 9
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 238000012545 processing Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 6
- 230000009967 tasteless effect Effects 0.000 description 6
- -1 polyoxyethylene Polymers 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 239000008367 deionised water Substances 0.000 description 4
- 229910021641 deionized water Inorganic materials 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 239000010742 number 1 fuel oil Substances 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 3
- 238000011835 investigation Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 241000219782 Sesbania Species 0.000 description 2
- XFBXDGLHUSUNMG-UHFFFAOYSA-N alumane;hydrate Chemical compound O.[AlH3] XFBXDGLHUSUNMG-UHFFFAOYSA-N 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- 238000007598 dipping method Methods 0.000 description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002808 molecular sieve Substances 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 231100000989 no adverse effect Toxicity 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 2
- 230000006641 stabilisation Effects 0.000 description 2
- 150000003464 sulfur compounds Chemical class 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 241000219793 Trifolium Species 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 239000005030 aluminium foil Substances 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 239000002199 base oil Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 239000008157 edible vegetable oil Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Abstract
Description
Project | Catalyst A | Catalyst B |
Chemical constitution, % | ||
??WO 3 | ??28.5 | ??20.5 |
??MoO 3 | ??/ | ??6.8 |
??NiO | ??2.5 | ??3.0 |
??TiO 2 | ??15.3 | ??15.3 |
??Al 2O 3 | Surplus | Surplus |
Physical properties | ||
Specific surface, m 2/g | ??110 | ??121 |
Pore volume, ml/g | ??0.23 | ??0.23 |
Bulk density, kg/m 3 | ??1150 | ??1100 |
Profile | Trifolium | Cylinder |
Project | Virgin kerosene I | Virgin kerosene II | Hydrocracking kerosene |
Density, kg/m 3 | ??810.1 | ??807.5 | ??789.3 |
Color (Saybolt colour number) | ??21 | ??17 | ??20 |
Sulphur, μ g/g | ??805.1 | ??2220 | ??<2 |
Nitrogen, μ g/g | ??5.0 | ??12 | ??<2 |
Aromatic hydrocarbons, % | ??10.5 | ??17.5 | ??6.3 |
Smell | Irritating smell | Irritating smell | Irritating smell |
Boiling range, ℃ | |||
IBP/10% | ??195/213 | ??203/214 | ??138/165 |
50%/90% | ??230/250 | ??225/245 | ??189/241 |
98% | ??262 | ??273 | ??247 |
Stock oil | Virgin kerosene I | ||||
Numbering | ????A-1 | ??A-2 | ??A-3 | ??A-4 | ??A-5 |
Processing condition | |||||
The hydrogen dividing potential drop, MPa | ????10.0 | ??7.0 | ??12.0 | ??15.0 | ??15.0 |
Temperature of reaction, ℃ | ????280 | ??300 | ??320 | ??300 | ??340 |
Volume space velocity, h -1 | ????0.4 | ??1.0 | ??1.5 | ??1.0 | ??2.0 |
Hydrogen to oil volume ratio | ????300 | ??400 | ??500 | ??400 | ??700 |
Hydrogenated products character | |||||
Density, kg/m 3 | ????803.2 | ??802.5 | ??801.9 | ??802.3 | ??801.0 |
Color (Saybolt colour number) | ????30 | ??30 | ??30 | ??30 | ??30 |
Sulphur, μ g/g | ????<1 | ??<1 | ??<1 | ??<1 | ??<1 |
Nitrogen, μ g/g | ????<1 | ??<1 | ??<1 | ??<1 | ??<1 |
Aromatic hydrocarbons, % | ????0.018 | ??0.25 | ??0.14 | ??0.015 | ??0.11 |
Smell | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour |
Boiling range, ℃ | |||||
????IBP/10% | ????190/208 | ??185/205 | ??183/206 | ??184/206 | ??181/20 ??3 |
????50%/90% | ????227/248 | ??226/247 | ??225/246 | ??226/247 | ??222/24 ??5 |
????98% | ????261 | ??260 | ??260 | ??261 | ??258 |
Stock oil | Hydrocracking kerosene | |||
Numbering | ??H-1 | ??H-2 | ??H-3 | ??H-4 |
Processing condition | ||||
The hydrogen dividing potential drop, MPa | ??10.0 | ??7.0 | ??12.0 | ??15.0 |
Temperature of reaction, ℃ | ??270 | ??260 | ??280 | ??290 |
Volume space velocity, h -1 | ??0.8 | ??0.4 | ??1.0 | ??1.5 |
Hydrogen to oil volume ratio | ??400 | ??300 | ??400 | ??600 |
Hydrogenated products character | ||||
Density, kg/m 3 | ??786.7 | ??786.9 | ??786.5 | ??786.0 |
Color (Saybolt colour number) | ??30 | ??30 | ??30 | ??30 |
Sulphur, μ g/g | ??<1 | ??<1 | ??<1 | ??<1 |
Nitrogen, μ g/g | ??<1 | ??<1 | ??<1 | ??<1 |
Aromatic hydrocarbons, % | ??0.011 | ??0.015 | ??0.018 | ??0.020 |
Smell | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour |
Boiling range, ℃ | ||||
????IBP/10% | ??136/164 | ??137/165 | ??135/165 | ??133/163 |
????50%/90% | ??187/239 | ??188/239 | ??187/239 | ??186/239 |
????98% | ??247 | ??247 | ??245 | ??244 |
Stock oil | Virgin kerosene II | ||||
Numbering | ??B-1 | ??B-2 | ??B-3 | ??B-4 | ??B-5 |
Processing condition | |||||
The hydrogen dividing potential drop, MPa | ??12.0 | ??7.0 | ??10.0 | ??15.0 | ??15.0 |
Temperature of reaction, ℃ | ??310 | ??300 | ??320 | ??320 | ??340 |
Volume space velocity, h -1 | ??0.7 | ??0.4 | ??1.0 | ??1.0 | ??2.0 |
Hydrogen to oil volume ratio | ??500 | ??400 | ??500 | ??600 | ??800 |
Hydrogenated products character | |||||
Density, kg/m 3 | ??798.6 | ??799.0 | ??797.6 | ??797.0 | ??796.0 |
Color (Saybolt colour number) | ??30 | ??30 | ??30 | ??30 | ??30 |
Sulphur, μ g/g | ??<1 | ??<1 | ??<1 | ??<1 | ??<1 |
Nitrogen, μ g/g | ??<1 | ??<1 | ??<1 | ??<1 | ??<1 |
Aromatic hydrocarbons, % | ??0.016 | ??0.12 | ??0.20 | ??0.019 | ??0.18 |
Smell | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour | Free from extraneous odour |
Boiling range, ℃ | |||||
????IBP/10% | ??194/208 | ??195/209 | ??192/206 | ??191/205 | ??188/202 |
????50%/90% | ??222/240 | ??222/241 | ??220/239 | ??220/239 | ??218/238 |
????98% | ??272 | ??273 | ??271 | ??271 | ??270 |
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03126138 CN1190474C (en) | 2003-05-05 | 2003-05-05 | Method for producing kerosene type solvent oil and catalyst thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 03126138 CN1190474C (en) | 2003-05-05 | 2003-05-05 | Method for producing kerosene type solvent oil and catalyst thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1450146A true CN1450146A (en) | 2003-10-22 |
CN1190474C CN1190474C (en) | 2005-02-23 |
Family
ID=28684435
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN 03126138 Expired - Lifetime CN1190474C (en) | 2003-05-05 | 2003-05-05 | Method for producing kerosene type solvent oil and catalyst thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN1190474C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101942326A (en) * | 2009-07-09 | 2011-01-12 | 中国石油化工股份有限公司抚顺石油化工研究院 | Method for producing low-aromatics solvent oil by hydrogenation |
CN1840618B (en) * | 2005-03-31 | 2011-08-10 | 中国石油化工股份有限公司 | Hydrogenation catalyst with silicon oxide-alumina as carrier and its preparation |
-
2003
- 2003-05-05 CN CN 03126138 patent/CN1190474C/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1840618B (en) * | 2005-03-31 | 2011-08-10 | 中国石油化工股份有限公司 | Hydrogenation catalyst with silicon oxide-alumina as carrier and its preparation |
CN101942326A (en) * | 2009-07-09 | 2011-01-12 | 中国石油化工股份有限公司抚顺石油化工研究院 | Method for producing low-aromatics solvent oil by hydrogenation |
CN101942326B (en) * | 2009-07-09 | 2015-01-14 | 中国石油化工股份有限公司 | Method for producing low-aromatics solvent oil by hydrogenation |
Also Published As
Publication number | Publication date |
---|---|
CN1190474C (en) | 2005-02-23 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 100029 Beijing City, Chaoyang District Hui Street No. 6 Co-patentee after: LUOYANG PETROCHEMICAL ENGINEERING CORPORATION, SINOPEC Patentee after: CHINA PETROLEUM & CHEMICAL Corp. Address before: 100029 Beijing City, Chaoyang District Hui Street No. 6 Co-patentee before: Luoyang Petrochemical Engineering Co.,Ltd./SINOPEC Patentee before: CHINA PETROLEUM & CHEMICAL Corp. |
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ASS | Succession or assignment of patent right |
Free format text: FORMER OWNER: SINOPEC LUOYANG PETROCHEMICAL ENGINEERING CORPORATION Effective date: 20130326 Owner name: SINOPEC LUOYANG PETROCHEMICAL ENGINEERING CORPORAT Free format text: FORMER OWNER: SINOPEC GROUP Effective date: 20130326 |
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C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 100029 CHAOYANG, BEIJING TO: 471003 LUOYANG, HENAN PROVINCE |
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TR01 | Transfer of patent right |
Effective date of registration: 20130326 Address after: 471003 Zhongzhou West Road, Henan, China, No. 27, No. Patentee after: LUOYANG PETROCHEMICAL ENGINEERING CORPORATION, SINOPEC Address before: 100029 Beijing City, Chaoyang District Hui Street No. 6 Patentee before: CHINA PETROLEUM & CHEMICAL Corp. Patentee before: LUOYANG PETROCHEMICAL ENGINEERING CORPORATION, SINOPEC |
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CX01 | Expiry of patent term |
Granted publication date: 20050223 |
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CX01 | Expiry of patent term |